Engineering Commons^™

Nitrate Dynamics In An Arid Irrgation Network: Can Nutrient Loops Be Closed With Management Techniques?, Kelsey B. Bicknell

Civil Engineering ETDs

Nutrients are the third leading cause of impairment in aquatic ecosystems, yet they remain necessary to support our growing agriculture system. Mining (as with phosphorus) and manufacturing (as with synthetic nitrogen) fertilizers deplete non-renewable resources and consume large amounts of energy. We have opportunities to optimize food-energy-water (FEW) resources, particularly in arid regions where wastewater, rather than agriculture, is the number one contributor of nutrients. This study evaluates the capacity of three unique channels (i.e., the Drain canal, the Delivery canal, and the Rio Grande River) within the agriculture system of the Middle Rio Grande Valley to process nutrients from …

Fluoride Removal From Water Using A 3d Printed Calcium Carbonate Filter, Sophia Bakar, David Kahler, Benjamin S. Goldschmidt

Undergraduate Research and Scholarship Symposium

Groundwater containing high concentrations of fluoride is the most common source of drinking water in rural areas in parts of east Africa, India, and China. The elevated levels of fluoride cause skeletal and dental fluorosis, which is the weakening and decay of bone structures due to the leeching of calcium from the body as calcium and fluoride bond by the process of adsorption. Over 150 million people are suffering from some form of fluorosis due to the consumption of groundwater. Calcium carbonate has been demonstrated to influence fluoride removal in several forms. To make fluoride removal a cost-effective and user-friendly …

Groundwater Irrigation System For Sustainable Agriculture, Peter Koros, Richard Matthews, Ciara Murphy

Civil, Environmental and Sustainable Engineering Senior Theses

The aim of this project was to develop a prototype that may be a model to help relieve food insecurity in rural Liberia. This was accomplished by designing a groundwater extraction, recharge, and irrigation system to facilitate year-long crop-growth. The project was in partnership with BRAID Africa and a community in Zwedru, located in east Liberia, near the border of Côte D’Ivoire. During 2010 and 2011, a civil war broke out in Côte D’Ivoire and led to the citizens of the country taking refuge in Liberia (Leaf 2015). Many refugees have decided to stay in Liberia and are struggling to …

Experimental Investigation Of The Thermochemical Reduction Of Arsenite And Sulfate: Low Temperature Hydrothermal Copper, Nickel, And Cobalt Arsenide And Sulfide Ore Formation, Nicholas Allin

Graduate Theses & Non-Theses

Experiments were conducted to determine the relative rates of reduction of aqueous sulfate and aqueous arsenite (As(OH)₃,aq) using foils of copper, nickel, or cobalt as the reductant, at temperatures of 150ºC to 300ºC. At the highest temperature of 300°C, very limited sulfate reduction was observed with cobalt foil, but sulfate was reduced to sulfide by copper foil (precipitation of Cu₂S (chalcocite)) and partly reduced by nickel foil (precipitation of NiS₂ (vaesite) + NiSO₄·xH₂O). In the 300ºC arsenite reduction experiments, Cu₃As (domeykite), Ni₅As₂, or CoAs (langisite) …

Global Opportunities To Increase Agricultural Independence Through Phosphorus Recycling, Stephen M. Powers, R. B. Chowdhury, G. K. Macdonald, A, H.W. Beusen, A. F. Bouwman, S. E. Hampton, Brooke K. Mayer, M. L. Mccracklin, D. A. Vaccari

Civil and Environmental Engineering Faculty Research and Publications

Food production hinges largely upon access to phosphorus (P) fertilizer. Most fertilizer P used in the global agricultural system comes from mining of nonrenewable phosphate rock deposits located within few countries. However, P contained in livestock manure or urban wastes represents a recyclable source of P. To inform development of P recycling technologies and policies, we examined subnational, national, and global spatial patterns for two intersections of land use affording high P recycling potential: (a) manure‐rich cultivated areas and (b) populous cultivated areas. In turn, we examined overlap between P recycling potential and nation‐level P fertilizer import dependency. Populous cultivated …

The Professional Constructor, Full Issue, Volume 44, Number 01

The Professional Constructor

No abstract provided.

Using Theoretical And Experimental Particle Packing For Aggregate Gradation Optimization To Reduce Cement Content In Pavement Concrete Mixtures, Miras Mamirov

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

The main objective of this study was to evaluate the effect of aggregate particle packing optimization and cement reduction on Nebraska slip-form pavement concrete performance. A literature review was conducted to examine different aggregate optimization tools, quality control tests, and historical data of Nebraska Department of Transportation (NDOT) mixtures. It was found that the Modified Toufar Model has good potential in optimizing particle packing and predicting packing degrees. The combined void content test was found to be useful to experimentally justify optimized aggregate gradations. Two specific pavement concrete workability tests, i.e., the Box Test and the VKelly Test, were used …

Production Of Secondary Organic Aerosol During Aging Of Biomass Burning Smoke From Fresh Fuels And Its Relationship To Voc Precursors, A. T. Ahern, E. S. Robinson, D. S. Tkacik, L. E. Hatch, Kelley Barsanti, C. E. Stockwell, Robert J. Yokelson, Multiple Additional Authors

Civil and Environmental Engineering Faculty Publications and Presentations

After smoke from burning biomass is emitted into the atmosphere, chemical and physical processes change the composition and amount of organic aerosol present in the aged, diluted plume. During the fourth Fire Lab at Missoula Experiment, we performed smog‐chamber experiments to investigate formation of secondary organic aerosol (SOA) and multiphase oxidation of primary organic aerosol (POA). We simulated atmospheric aging of diluted smoke from a variety of biomass fuels while measuring particle composition using high‐resolution aerosol mass spectrometry. We quantified SOA formation using a tracer ion for low‐volatility POA as a reference standard (akin to a naturally occurring internal standard). …

The Effects Of Reactant Concentration And Air Flow Rate In The Consumption Of Dissolved O2 During The Photochemistry Of Aqueous Pyruvic Acid, Alexis J. Eugene, Marcelo I. Guzman

Chemistry Faculty Publications

The sunlight photochemistry of the organic chromophore pyruvic acid (PA) in water generates ketyl and acetyl radicals that contribute to the production and processing of atmospheric aerosols. The photochemical mechanism is highly sensitive to dissolved oxygen content, [O₂(aq)], among other environmental conditions. Thus, herein we investigate the photolysis (λ ≥ 305 nm) of 10–200 mM PA at pH 1.0 in water covering the relevant range 0 ≤ [O₂(aq)] ≤ 1.3 mM. The rapid consumption of dissolved oxygen by the intermediate photolytic radicals is monitored in real time with a dissolved oxygen electrode. …

Estimation Of Number Of People Living In Developing Countries That Received Water From A Spring Source, Prapti Shinde

USF Tampa Graduate Theses and Dissertations

In the year 2000, 170 countries decided to stand together and solve some primary and common global problems like poor health, water, and sanitation. Obtaining access to safe drinking water is every individual’s right. The UN defines safe drinking water as “the water required for each personal or domestic use must be safe, therefore free from micro-organisms, chemical substances and radiological hazards that constitute a threat to a person's health” (UNDESA, 2014). This thesis focuses on identifying the number of people who potentially receive spring water from a piped source in rural mountainous areas. There are three significant steps and …

Development And Application Of Decision-Making Tool For Rural Spring-Sourced Gravity-Fed Community Managed Water Systems, Oswaldo Galicia

USF Tampa Graduate Theses and Dissertations

People all over the world still lack access to safe drinking water service. Those with access experience several issues during the first few years of installation that impede on their overall access. In order to improve water services, not only is a proper decision-making tool necessary, taking into account key factors that impact sustainable water service, but proper monitoring and evaluation is also important in ensuring service for the long term. There are several developed assessment tools used for monitoring and evaluation of water systems post-construction, applicable in various scenarios. However, there are only few tools available to facilitate the …

Behavior Of Non-Ductile Slender Reinforced Concrete Columns Retrofit By Cfrp Under Cyclic Loading, Wisam Amer Aules

Dissertations and Theses

In the Middle East region and many countries in the world, older reinforced concrete (RC) columns are deemed to be weak in seismic resistance because of their low amount of reinforcement, low grades of concrete, and large spacing between the transverse reinforcement. The capacity of older RC columns that are also slender is further reduced due to the secondary moments. Appropriate retrofit techniques can improve the capacity and behavior of concrete members. In this study, externally bonded Carbon Fiber Reinforced Polymer (CFRP) retrofit technique was implemented to improve the behavior of RC columns tested under constant axial load and cyclic …

Hydrological Drought Persistence And Recovery Over The Conus: A Multi-Stage Framework Considering Water Quantity And Quality, Behzad Ahmadi, Ali Ahmadalipour, Hamid Moradkhani

Civil and Environmental Engineering Faculty Publications and Presentations

Hydrological droughts have considerable negative impacts on water quantity and quality, and understanding their regional characteristics is of crucial importance. This study presents a multi-stage framework to detect and characterize hydrological droughts considering both streamflow and water quality changes. Hydrological droughts are categorized into three stages of growth, persistence, retreat, and water quality variables (i.e., water temperature, dissolved oxygen concentration, and turbidity) are utilized to further investigate drought recovery. The framework is applied to 400 streamflow gauges across the Contiguous United States (CONUS) over the study period of 1950–2016. The method is illustrated for the 2012 US drought, which affected …

Implementing Unbiased Decision-Making In Construction: A Lean Approach, Somik Ghosh, Michelle Robinette, Howard Tapia

The Professional Constructor

Construction project-teams are frequently faced with the task of decision-making as part of their responsibility. The positive effects of the decisions made at various stages of the projects lead to improved project performances, while negative effects can hinder the performances. The project teams take up the task of decision-making surrounded by multiple criteria, which can be arduous and clouded with subjectivity. This paper presents an approach based on the Lean principle of providing more autonomy to the project-teams and supporting collaborative and decentralized process in pursuit of unbiased decision-making. This Lean way of decision-making is formalized as Choosing by Advantage …

Effect Of Stoniness On The Hydraulic Properties Of A Soil From An Evaporation Experiment Using The Wind And Inverse Estimation Methods, Nerea Arias, Iñigo Virto, Alberto Enrique, Paloma Bescansa, Riley Walton, Ole O. Wendroth

Plant and Soil Sciences Faculty Publications

Stony soils are distributed all over the world. The study of their characteristics has gained importance lately due to their increasing use as agricultural soils. The effect that rock fragments exert on the soil hydraulic properties is difficult to measure in situ, and is usually derived from the fine earth properties. However, the corrections used so far do not seem accurate for all types of stony soils. Our objective was to assess the adequacy of estimating the hydraulic properties of a stony soil from the fine earth ones by correcting the latter by the volume occupied by rock fragments. To …

Limits To The World’S Green Water Resources For Food, Feed, Fiber, Timber, And Bioenergy, Joep F. Schyns, Arjen Y. Hoekstra, Martijn J. Booij, Rick J. Hogeboom, Mesfin Mekonnen

Daugherty Water for Food Global Institute: Faculty Publications

Green water––rainfall over land that eventually flows back to the atmosphere as evapotranspiration––is the main source of water to produce food, feed, fiber, timber, and bioenergy. To understand how freshwater scarcity constrains production of these goods, we need to consider limits to the green water footprint (WFg), the green water flow allocated to human society. However, research traditionally focuses on scarcity of blue water––groundwater and surface water. Here we expand the debate on water scarcity by considering green water scarcity (WSg). At 5 × 5 arc-minute spatial resolution, we quantify WFg and the maximum sustainable level to this footprint (WFg,m), …

Aesthetics, Ethics, And Lose-Lose Dilemmas In The Anthropocen, Adam Liska

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Anthropogenic climate change will cause violence to increase globally, and nonlinear increases in sea level could cause a major escalation in global conflict. After 2100, a 22-meter sea-level rise is estimated here to dislocate two billion people from coastal areas. These impending civilization-changing events require us to again reevaluate our prevalent aesthetic preferences for luxury that produce a significant fraction of anthropogenic greenhouse gas emissions. Due to industrial inertia, a central dilemma discussed here is the contradictions between the goals and impacts of aesthetics and ethics. Either we lose our own well-being (a loss of high-emission aesthetics) for the benefit …

From Drought To Food-Energy-Water-Security Nexus: An Assessment Of Food Insecurity In The Middle East, Maysoun Ayad Hameed

Dissertations and Theses

Drought is an extreme climate phenomenon that happens slowly and periodically threatens the environmental and socio-economic sectors. Developing countries have experienced crucial conditions in meeting the needs for food, energy, and water security. Natural disasters contribute as risky sources of food insecurity and vulnerability in the Middle East. This dissertation presents a country-level review and quantitative assessment of the current issues associated with the Food-Energy-Water-Security (FEWS) Nexus in the Middle East. In this study, sixteen countries in the Middle East are chosen, namely, Arabian Peninsula, Iran, Syria, Lebanon, Israel, Palestine, Egypt, and Turkey. The most recent datasets are used to …

Irrigation Water Quality—A Contemporary Perspective, Arindam Malakar, Daniel D. Snow, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

In the race to enhance agricultural productivity, irrigation will become more dependent on poorly characterized and virtually unmonitored sources of water. Increased use of irrigation water has led to impaired water and soil quality in many areas. Historically, soil salinization and reduced crop productivity have been the primary focus of irrigation water quality. Recently, there is increasing evidence for the occurrence of geogenic contaminants in water. The appearance of trace elements and an increase in the use of wastewater has highlighted the vulnerability and complexities of the composition of irrigation water and its role in ensuring proper crop growth, and …

Twenty-Three Unsolved Problems In Hydrology (Uph) – A Community Perspective, Günter Blöschl, Christopher M. U. Neale, A Cast Of Thousands

Daugherty Water for Food Global Institute: Faculty Publications

This paper is the outcome of a community initiative to identify major unsolved scientific problems in hydrology motivated by a need for stronger harmonisation of research efforts. The procedure involved a public consultation through online media, followed by two workshops through which a large number of potential science questions were collated, prioritised, and synthesised. In spite of the diversity of the participants (230 scientists in total), the process revealed much about community priorities and the state of our science: a preference for continuity in research questions rather than radical departures or redirections from past and current work. Questions remain focused …

Separation Of Unburned Carbon From Coal Conversion Ash: Development And Assessment Of A Dry Method, Charlotte J. Badenhorst, Nicola J. Wagner, Bruno R.V. Valentim, Karel S. Viljoen, Ana C. Santos, Alexandra Guedes

Coal Combustion and Gasification Products Journal Archive

Unburned carbon found in coal conversion ash has the potential to be used in a variety of value-added applications. However, it is first necessary to separate the unburned carbon from the rest of the ash phases. This poses challenges due to the relatively low starting carbon-in-ash values (0.4 to 7.8 wt% reported for South African sources), and the high carbon grades (ideally ∼90 wt% carbon) and recoveries that need to be achieved. In this study a dry method for the separation of unburned carbon from coal ash was developed and assessed using fly, bottom, and gasification ash samples obtained from …

Timescales Of Global Tidal Flooding, Maria Bower

Honors Undergraduate Theses

Millions of people in low-lying areas are already affected by flooding, and the number will increase substantially in the future. Tidal flooding, the form of flooding caused by a combination of high tides and sea level rise to overcome protection levels, can cause damage and inconveniences such as road closures, overwhelmed drainage systems, and infrastructure deterioration from water damage. Tidal flooding already occurs annually in cities along the U.S. east coast, most notably Miami. However, the time it will take for other regions globally to begin to experience tidal flooding has not yet been assessed. Therefore, there is a limited …

A Machine Learning Approach For Improving Near-Real-Time Satellite-Based Rainfall Estimates By Integrating Soil Moisture, Ashish Kumar, Raaj Ramsankaran, Luca Brocca, Francisco Munoz-Arriola

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Near-real-time (NRT) satellite-based rainfall estimates (SREs) are a viable option for flood/drought monitoring. However, SREs have often been associated with complex and nonlinear errors. One way to enhance the quality of SREs is to use soil moisture information. Few studies have indicated that soil moisture information can be used to improve the quality of SREs. Nowadays, satellite-based soil moisture products are becoming available at desired spatial and temporal resolutions on an NRT basis. Hence, this study proposes an integrated approach to improve NRT SRE accuracy by combining it with NRT soil moisture through a nonlinear support vector machine-based regression (SVR) …

South Africa’S Power Producer’S Revised Coal Ash Strategy And Implementation Progress, Kelley Reynolds-Clausen, Nico Singh

Coal Combustion and Gasification Products Journal Archive

The South African electricity public utility Eskom has embarked on a process to increase utilisation of the ash produced through the electricity generation process at its coal-fired power stations. In the 2014–2015 financial year, 119.2 million tons of coal was consumed, producing 34.4 million tons (28.9%) of ash. About 7% of the Eskom ash is sold from 6 of the 13 coal-fired power stations. Many stations are currently running out of ash storage space, and expansion of the ash disposal facilities is required, which could affect security of supply because of limited ashing areas. Additionally, legislative requirements lead to extra …

Analysis Of Construction Fall Protection Guardrails In A Population With Changing Anthropometrics, Connor S. Klinzing

Masters Theses

The construction trade has commonly been cited as one of the most dangerous industries within the United States, with falls from elevation being the most predominate cause for injuries and deaths. The OSHA standards related guardrails has not changed since its implementation in 1970. These standards originally derive from the 1950s, which expect a 160-pound person with 40 pounds of equipment, tools, etc. However, the anthropometries of the common working age citizen has dramatically changed in respects to their weight. This study examines the relationship of the guardrail system to the changing anthropometries to determine if a reform is necessary …

Microemulsion Based Soil Remediation Using Mixed Anionic And Extended Nonionic Surfactant, Virin Kittithammavong

Chulalongkorn University Theses and Dissertations (Chula ETD)

The anionic-nonionic mixed system has a synergistic effect on the microemulsion formation by a reduction of interfacial tension. The challenge of the mixed surfactant based on soil remediation is how to find the appropriate condition. This study aims to investigate the phase behaviors of the anionic-nonionic mixed systems and to formulate their hydrophilic-lipophilic deviation (HLD) equations. Then the mixed surfactant solutions are applied to determine the oil removal efficiency. The conventional anionic surfactants (i.e., sodium dodecyl sulfate (SDS), sodium dihexyl sulfosuccinate (SDHS), and sodium dioctyl sulfosuccinate (AOT)) and the extended nonionic surfactants (i.e., alcohol ethoxylate series (AE(EOn) and alkyl polyglycol …

การดูดซับไอบูโพรเฟนโดยตัวกลางดูดซับแบบโครงข่ายโลหะสารอินทรีย์ Mil-53(Al) ที่เคลือบเมโสพอรัสซิลิกา, บุญฤทธิ์ ศิริรังสรรค์กุล

Chulalongkorn University Theses and Dissertations (Chula ETD)

งานวิจัยนี้มีวัตถุประส่งค์เพื่อศึกษาประสิทธิภาพการดูดซับสารตกค้างจากยากลุ่มยาต้านการอักเสบที่ไม่ใช่สเตียรอยด์ไอบูโพรเฟน (IBP) ในนำ้เสียสังเคราะห์ โดยตัวกลางดูดซับโครงข่ายโลหะอินทรีย์ MIL-53(Al) และ MIL-53(Al) ที่เคลือบชั้นเมโสพอรัสซิลิกาที่สัดส่วนต่างๆ นอกจากนี้ยังศึกษาเสถียรภาพของ MIL-53(Al) ในนำ้เสียสังเคราะห์ทั้งก่อนและหลังการเคลือบชั้นเมโสพอรัสซิลิกา รวมถึงการศึกษาการนำตัวกลางดูดซับกลับมาใช้ใหม่ภายหลังจากฟื้นสภาพตัวกลางดูดซับด้วยเมธานอล จากผลการทดลองกระบวนการดูดซับภายใต้ระบบทีละเท พบว่า MIL-53(Al) มีอัตราเร็วในการดูดซับไอบูโพรเฟนสูงกว่าถ่านกัมมันต์ชนิดผง (PAC) โดยเข้าสู่สมดุลภายใน 75 นาที และเมื่อทำการเคลือบชั้นเมโสพอรัสซิลิกาที่สัดส่วนต่างๆ พบว่าอัตราเร็วในการดูดซับเพิ่มขึ้นอย่างมาก โดยใช้ระยะเวลาในการเข้าสู่สมดุลภายใน 25 และจลนพลศาสตร์การดูดซับของตัวกลางดูดซับทั้งหมดสอดคล้องกับจลนพลศาตร์การดูดซับเสมือนลำดับที่ 2 ในขณะที่ตัวกลางดูดซับเมโสพอรัสซิลิกาเพียงอย่างเดียวไม่พบการดูดซับ โดย MIL-53(Al) มีความสามารถในการดูดซับสูงสุด เมื่อเคลือบเมโสพอรัสซิลิกาที่สัดส่วนโดยโมลของ MIL-53(Al) ต่อเตตระเอธิลออร์โธซิลิเกต (TEOS) เท่ากับ 1:0.48 มีความสามารถในการดูดซับไอบูโพรเฟนสูงกว่าสัดส่วนอื่นๆ และไอโซเทอมการดูดซับสอดคล้องกับแบบจำลองของเรดลิช-ปีเตอร์สัน ถึงแม้ว่าการเคลือบชั้นเมโสพอรัสซิลิกาจะมีประสิทธิภาพในการดูดซับลดลง แต่ยังมีความสามารถในการดูดซับใกล้เคียงกับ PAC จากการศึกษาเสถียรภาพพบว่า MIL-53(Al) ที่เคลือบชั้นเมโสพอรัสซิลิกามีเสถียรภาพเพิ่มขึ้นและมีการชะละลายของสารอินทรีย์และโลหะน้อยลง นอกจากนี้ MIL-53(Al) ที่เคลือบชั้นเมโสพอรัสซิลิกาสามารถนำกลับมาใช้ใหม่ได้ถึง 2 ครั้งหลังจากสกัดด้วยเมทานอล ในขณะที่ MIL-53(Al) ไม่สามารถในการดูดซับไอบูโพรเฟนได้อีกเมื่อนำกลับมาใช้ใหม่ในครั้งที่ 2 เนื่องจากการพังทลายของโครงสร้าง

Hydrologic Impacts And Trade-Offs Associated With Forest-Based Bioenergy Development Across The Americas, Azad Heidari

Dissertations, Master's Theses and Master's Reports

A simulation-based framework for studying hydrologic impacts and associated tradeoffs for existing and proposed biofuel projects in the US (poplar), Argentina (eucalyptus) and Mexico (oil palm) is developed. For each case study, a representative watershed is selected and a SWAT model is set up and calibrated for an improved simulation of hydrologic processes and plant growth cycles. Potential bioenergy scenarios are developed that represent various planting densities, harvest cycles, fertilization and irrigation rates, land cover types being converted, slope, and locations across the watershed.

Simulations indicate that growth and biomass production are significantly dependent on nitrogen availability, making fertilization a …

Actual Evapotranspiration And Crop Coefficients Of Irrigated Lowland Rice (Oryza Sativa L.) Under Semiarid Climate, Koffi Djaman, Daran R. Rudnick, Yonnelle D. Moukoumbi, Abdoulaye Sow, Suat Irmak

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Lowland irrigated rice is the predominant crop produced in the Senegal River Valley characterized by very low annual rainfall, high temperatures, and low relative humidity. The Senegal River is shared by Senegal, Mali, Mauritania, and Guinea, and serves as the main source of irrigation water for the adopted double rice cropping system. Developing appropriate resource management strategies might be the key factor for the sustainability of rice production in the region. This study aims to estimate rice seasonal evapotranspiration (ETa), irrigation water requirement, and to develop rice growth stage specific crop coefficients (Kc) to improve rice water productivity. Field experiments …

Techno- Economic Feasibility Study Of Solar Water Pumping For Public Facilities In Nigeria, Anamika Singh

Cal Poly Humboldt theses and projects

This thesis presents a techno-economic feasibility analysis of solar water pumping systems in public facilities located in rural parts of Nigeria. Three different public facilities namely, a primary health care center in Ibwa (PHC, Ibwa), a comprehensive health care center in Kwali (CHC, Kwali), and the LEA Primary School in Mapa (LEA School, Mapa), all located in Federal Capital Territory (FCT) of Nigeria, were analyzed. The facilities considered in the study have varying levels of water demand (micro, small, and medium), and they are used as cases to establish the techno-economic suitability of solar water pumping systems to deliver water …