Engineering Commons^™

Who Was Who In Polymer Science: Q, Otto Vogl

Emeritus Faculty Author Gallery

Qian, Baogong

Qian, Renyuan

Who Was Who In Polymer Science: P, Otto Vogl

Emeritus Faculty Author Gallery

Pacynkievics, Stanislaw

Palit, Shalit

Panayotov, Ivan M.

Patat, Franz

Pauling, Linus

Pearce, Eli M.

Penczek, Stanislaw

Pepper, David

Perutz, Max F.

Peterlin, Anton

Philipp, Burkart

Pino, Piero

Platé, Nokolai A.

Plesch, Peter

Porri, Lido

Porter, Roger

Pospisil, Ian

Powers, Paul O.

Price, Charles C.

Who Was Who In Polymer Science: R, Otto Vogl

Emeritus Faculty Author Gallery

Raetzsch, Manfred

Ranby, Bengt

Rempp, Paul;

Reneker, Darrell;

Riess, Gerard;

Ringsdorf, Helmut

Rizzardo, Ezio

Who Was Who In Polymer Science: T, Otto Vogl

Emeritus Faculty Author Gallery

Tada, Koichi

Tadokoro, Hiroyuki

Takahiko, Tadeshi

Takayanagi, Motowo

Takemoto, Kiichi

Tani, Hisaya

Taylor, Edward C.

Teller, Edward

Teramoto, Akio

Tobolsky, Arthur

Trapasso, Italo

Truett, William L.

Tsuruta, Teiji

Tüdös, Ferenc

Tuppy, Hans

Who Was Who In Polymer Science: S, Otto Vogl

Emeritus Faculty Author Gallery

Sadron, Charles

Saegusa, Takeo

Sakurada, Ichiro

Salamone, Joseph C.

Schloegl, Karl

deSchruyver, Frans

Schulz, Rolf

Schurz, Josef

Sebenda, Jan

Semenov, Nikolai Nikolaevich

Seymour, Raymond

Shida, Ken-ichi

Shima, Mikiko

Shopov, Ivan

Sigwalt, Pierre

Simionescu, Cristofer I.

Smets, George

Sobue, Hiroshi

Solomon, David M.

Stannett, Vivian

Staudinger, Hermann

Staverman, Albert Jan

Stein, Richard S.

Stille, John D.

Stockmayer, Walter H.

Sumitomo, Hiroshi

Sundholm, Franciska

Szwarc, Michael

Who Was Who In Polymer Science: U, Otto Vogl

Emeritus Faculty Author Gallery

Uematsu, Ichitaro

Who Was Who In Polymer Science: X, Otto Vogl

Emeritus Faculty Author Gallery

Xi, Fu

Who Was Who In Polymer Science: Z, Otto Vogl

Emeritus Faculty Author Gallery

Zaikov, Gennardy Eframovich

Ziegler, Karl

Who Was Who In Polymer Science: W, Otto Vogl

Emeritus Faculty Author Gallery

Wang Baoren

Wang, Fosong

Ward, Ian Macmillan

Webster, Owen

Wichterle, Oto

Wilke, Guenther

Winslow, Fields

Wooten, Carl

Wu, Shikanh

Who Was Who In Polymer Science: V, Otto Vogl

Emeritus Faculty Author Gallery

Vandenberg, Edward

Vogl, Otto

Who Was Who In Polymer Science: Y, Otto Vogl

Emeritus Faculty Author Gallery

Yamazaki, Noburo

Yamashita, Shinzo

Yuki, Heimei

Yu, Tongyin

Separation Of Technetium From Uranium And Waste Form Synthesis, Kenneth Czerwinski

Waste Forms Campaign (TRP)

In this project, systematic investigations on the Tc-Zr binary metal system will be evaluated for the first time. The synthesis of metallic Tc as well as its alloys with Zr will be evaluated. In order to provide valuable data to AFC R&D, the thermodynamic equilibrium phases, as well as their performance under repository conditions, will be examined.

The research objectives of this project are as follows:

• Evaluate anion exchange methods for achieving the separation of Tc from U.

• Synthesize metallic Tc from the separated product.

• Synthesize and characterize Tc alloys.

• Investigate Tc-corrosion and Tc-leaching of binary …

Interaction Between Metal Fission Products And Triso Coating Materials, Clemens Heske

Fuels Campaign (TRP)

This project focuses on the chemical bonding and interface formation of metal fission products with the coating materials used in tri-isotropic (TRISO) fuel particles for gas-cooled reactors. By combining surface- and bulk-sensitive spectroscopic and microscopic methods, intermediate chemical phases at the interface, intermixing/diffusion behavior, and the electronic interface structure for different coating materials and metals are examined.

In detail, the project studies the interface formation of Pd, Cs, and Ag with SiC and pyrolytic carbon. Using SiC single crystals and highly-ordered pyrolytic carbon (HOPG) as substrates, interfaces are prepared under controlled conditions in an ultra-high vacuum environment and are studied …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski

Fuels Campaign (TRP)

This project will examine inert fuels containing ZrO₂ and MgO as the inert matrix. Ceramics with this inert matrix, Ce, U and eventually Pu will be synthesized and examined. While the Advanced Fuel Cycle Initiative focus is on inert fuels with Pu as the fissile component, this task will perform initial laboratory experiments with Ce and U. The initial work with Ce will be performed early in the project with results used as a basis for U studies. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf. …

Impact Of The Synthesis Process On Structure Properties For Afci Fuel Candidates, Kenneth Czerwinski

Fuels Campaign (TRP)

The research objectives are:

• To explore a low-temperature fluoride route to synthesize actinide nitrides. • To characterize actinide nitrides structurally and thermally.

• To use high resolution TEM techniques to explore the microstructure of the radioactive samples.

Solution-Based Synthesis Of Nitride Fuels, Kenneth Czerwinski, Tyler A. Sullens

Fuels Campaign (TRP)

One of the original synthetic routes devised for the synthesis of U (III)N involved the entire reaction taking place in liquid ammonia. Several experimental reactions were conducted in an attempt to synthesize the UI₃(NH₃)_x and U(NH₂)₃(NH₃)_x precursors of U(III) N. Each attempt involved cleaning of the uranium metal to remove the oxide coating of the metal reagent with 3 washes of concentrated nitric acid, each followed by a rinse with liquid ammonia. Success of this cleaning procedure was varied, with a majority of cleaned metal oxidizing rapidly once …

University Of Nevada, Las Vegas Transmutation Research Program Annual Progress Report Academic Year 2007-2008, Anthony Hechanova, Rebecca Paulson

Transmutation Research Program Reports (TRP)

It is my pleasure to present the UNLV Transmutation Research Program’s seventh annual report that highlights the academic year 2007-2008. Supporting this document are the many technical reports and theses that have been generated over the past seven years.

In the seventh year of our program, we continued to see growth in the Radiochemistry Ph.D. program with a total of 20 students in the fourth year of the program (we anticipated twelve in the program proposal). Since our inception, the program has sponsored to their conclusion 48 M.S. and 6 Ph.D. degrees. The program supported 53 graduate students, 11 undergraduates, …

Improved High-Temperature Stability And Sun-Light-Driven Photocatalytic Activity Of Sulfur-Doped Anatase Tio2, Suresh Pillai, Declan Mccormack, Pradeepan Periyat, John Colreavy, Steve Hinder

Articles

No abstract provided.

Oligo(Vinylidene Fluoride) Langmuir-Blodgett Films Studied By Spectroscopic, Rafal Korlacki, J. Travis Johnston, Jihee Kim, Stephen Ducharme, Daniel W. Thompson, Vladimir M. Fridkin, Zhongxin Ge, James M. Takacs

Stephen Ducharme Publications

Thin films of amphiphilic vinylidene fluoride oligomers prepared by Langmuir–Blodgett deposition on silicone substrates were investigated by comparing experimental and theoretical mid-infrared (IR) spectra. The experimental spectra were obtained using infrared spectroscopic ellipsometry. Theoretical spectra were calculated using density functional theory. Excellent correspondence of major IR bands in both data sets shows that the molecular backbone is oriented with the long axis normal to the substrate plane. This is in contrast to poly vinylidene fluoride[1] LB films, in which the polymer chains are parallel to the substrate.

Glass Transition Behavior Of Poly(Methyl Acrylate) End-Grafted By Atrp To Amorphous Silica, Manikantan B. Nair, Frank D. Blum

Chemistry Faculty Research & Creative Works

Ultra-thin polymer films attached to solid substrates (supported films) have attracted significant interest in recent years. Supported films are used in the design of advanced materials like photoresists, lubricants and other electronic devices. Glass transition temperatures (Tgs) of supported polymer films have also been of significant interest. The Tg has been shown to depend on the thickness of the polymer film on the surface and the inherent nature of the surface. The effect of end-grafting of a polymer chain to a surface, on the Tg of the polymer has been studied previously.1 Reports on the study of glass transition behaviors …

Thermal Analysis Of Adsorbed Poly(Vinyl Acetate) On Silica, Boonta Hetayothin, Frank D. Blum

Chemistry Faculty Research & Creative Works

The physical properties of polymers at interfaces can be quite different from those in bulk due to the interaction between the absorbed polymer and the surface. This phenomenon can be probed through the dynamic behavior of the polymer chains at the interface which can be experimentally probed by techniques such as nuclear magnetic resonance spectroscopy (NMR),1 viscoelasticity, and calorimetry. At the polymer-air interface, polymer chains have more flexibility than those at the polymer-substrate interface. On the other hand, at the silica-polymer interface, where chains are more restricted on the surface, a higher glass transition temperature (Tg) results as compared with …

Dynamics Of Adsorbed Pma-D₃ - Effect Of Substrate, Frank D. Blum, Burak Metin, Macduff O. Okuom

Chemistry Faculty Research & Creative Works

In the last few years, our group has focused much of our attention on studying the dynamics of polymers adsorbed at interfaces. Much of our work, to date has been on labeled poly(vinyl acetate)-d3 (PVAc-d3)1 and poly(methyl acrylate)-d3 (PMA-d3)2 on silica. We have been able to probe the effects of adsorbed amount,3 molecular mass,4,5 and the effect of overlayer.6 These studies have provided a view of the adsorbed polymer consistent with a motional gradient in the layer with the more mobile segments being those at the air-polymer interface and the less-mobile segments at the substratepolymer interface. However, we have not …

Dynamics Of Pipa-D₇ On Silica Surface, Piyawan Krisanangkura, Frank D. Blum

Chemistry Faculty Research & Creative Works

Molecular motion of polymer chains is an important determinant in understanding the physical properties of polymeric materials. Glass transition temperature (Tg) is a physical property of polymers, which is of primary interest. The study of the dynamics of polymer segments assists in understanding the dependence of Tg on polymer structure.1 For decades, studies have addressed the molecular motion in various polymers. Some of them have probed the dynamics of polymer backbones.2,3 the properties of a polymer at an interface may change because of the type of polymer, the substrate, or other variables. The side chain of a polymer can also …

Polyaniline Nanofiber-Based Gas Sensors, Zhe-Fei Li, Frank D. Blum, Massimo F. Bertino, Chang-Soo Kim

Chemistry Faculty Research & Creative Works

There has been recent interest in conducting polymers that have very promising chemical and electrical applications. Some of these polymers have shown great potential for use in sensors.1 Polyaniline is one particular example of a prospective material. In our laboratory, we have studied the synthesis of polyaniline nanofibers. We have carried out one-pot syntheses to obtain polyaniline nanofibers in aqueous solutions where the polymerization was influenced by γ-radiation2 or UV-radiation.3 This polymer can also be patterned with an appropriate photo mask. In our present report, polyaniline nanofiber thin film sensors have been fabricated in one step by employing UV-irradiation and …

Modeling The Physical Properties Of A Homologous Series On The Melting Temperatures And Densities Of N-Alkanes And Their Simple Alkyl-Derivatives, Antun Rubčić, Jasna Rubčić, James Chickos

Chemistry & Biochemistry Faculty Works

No abstract provided.

Activation Energy Of Surface Diffusion And Terrace Width Dynamics During The Growth Of In (4×3) On Si (100) - (2×1) By Femtosecond Pulsed Laser Deposition, M. A. Hafez, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The nucleation and growth of indium on a vicinal Si (100) - (2×1) surface at high temperature by femtosecond pulsed laser deposition was investigated by in situ reflection high energy electron diffraction (RHEED). RHEED intensity relaxation was observed for the first ∼2 ML during the growth of In (4×3) by step flow. From the temperature dependence of the rate of relaxation, an activation energy of 1.4±0.2 eV of surface diffusion was determined. The results indicate that indium small clusters diffused to terrace step edges with a diffusion frequency constant of (1.0±0.1) × 10¹¹ s^-1. The RHEED specular …