Engineering Commons^™

Bio-Oils From Microwave Assisted Pyrolysis Of Cellulose Using A Multi Mode Batch Reactor, Marco Frediani, Piero Frediani, Luca Rosi, Mattia Bartoli

5th International Congress on Green Process Engineering (GPE 2016)

The end of fossil fuels era is becoming day by day [1] however the request of raw materials and fuels from industry is growing every year [2]. As a consequence research for renewable resource to supply oil is became very attractive [3]. Biomasses are very promising sources to satisfy the growing request of energy and raw materials [4-6] and in the same time to reduce the environmental impact due to their production [7]. Cellulose is particular interesting among different available biomasses because it is not interfere with the availability of …

Development Of A Mobile 100 Kg/H Plant For Pyrolysis Using A Mechanically Fluidized Reactor, Dhiraj Kankariya, Stefano Tacchino, Dominic Pjontek, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Current pyrolysis processes perform the thermal decomposition of biomass into a liquid bio-oil, bio-char and non-condensable gases, at around 500 °C, without the addition of oxygen gas. The bio-oil is a complex mixture of many components that is used either as a substitute for fuel oil or for applications such as liquid smoke and bio-phenol resins that do not require pure chemicals.

The large-scale mechanical fluidized reactor (MFR) is a new technology for the pyrolysis of biomass developed by ICFAR, which does not require a sand bed and, thus, provides an undiluted solid char residue, which is essential to realize …

Technological Breakthrough And Innovation In The Production Of Whey Powders, With 30-40% Reduction In Energy Costs, Pierre Schuck, Anne Dolivet, Serge Méjean, Gaelle Tanguy, Daniel Garreau, Corrado Vezzani, Romain Jeantet

5th International Congress on Green Process Engineering (GPE 2016)

There are two essential stages in the elimination of water for the production of whey and permeate powders: concentration by vacuum evaporation followed by spray drying. These two operations alone represent 25% of the energy consumed by the French dairy industry, the major part of which is due to the drying stage. Indeed, 96.7% of the whey water is removed during the vacuum evaporation/concentration stage, whereas drying, which removes only 3.3% of the water, requires 31% of the total energy used over the entire process.

One possible way to reduce energy consumption would be for the product to enter the …

Integrating Batch Pyrolysis And Fractional Condensation (2d Mfr) To Get High-Value Products From Biomass, Mohammad Hossain, Chiara Barbiero, Ian Scott, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Agricultural crop residues are a source of inexpensive biomass to convert into bioproducts. The recovery of valuable chemicals from plant waste would partly solve the disposal issue and offer a more environmentally friendly alternative to synthetic chemical production. One approach to separate and concentrate valuable chemicals from biomass is pyrolysis using a batch reactor process. A mechanically fluidized reactor (MFR) was developed to pyrolyze biomass from ambient to temperatures near 600 °C, forming gases that are then condensed in an ice-chilled condenser to form a bio-oil. The bio-oil produced by the MFR can be separated within temperature ranges, termed one-dimensional …

Microwave Assisted Pyrolysis Of Kraft Lignin At Reduce Pressure In A Multimode Oven, Mattia Bartoli, Marco Frediani, Luca Rosi, Piero Frediani

5th International Congress on Green Process Engineering (GPE 2016)

Lignin is the third-most abundant natural polymer after cellulose and hemicellulose[1] and the only renewable source of aromatics in nature. Moreover lignin is the most relevant waste from industry of paper and bioethanol[2]. Nowadays the common way to dispose it is combustion but the possibility to recovery aromatic moiety from thermochemical conversion of lignin has been received a grown attention. In this field the most promising approach is pyrolysis[3] and particularly interesting is use of microwave (MW) like heating source[4]. Microwave assisted pyrolysis (MAP) was successfully applied in the treatment of plastic …

Production Of Glycerol 1,2-Carbonate From Glycerol With Aid Of Ionic Liquid As Catalyst, Nor Asrina Sairi, Zati Ismah, Yatimah Alias, Rozita Yusoff, Mohamed Kheireddine Taieb Aroua,

5th International Congress on Green Process Engineering (GPE 2016)

The surplus formation of glycerol (glycerine or 1,2,3-propanetriol) during biodiesel production has led to a major concern. Glycerol price has dropped and it exerts a great impact on the refined glycerol market. This has triggered an extensive research focus to find an innovative way to revalorize glycerol and transform to value-added chemicals. Yet, it is undeniably a necessary move towards achieving greener and sustainable processes. For instance, glycerol 1,2-carbonate (4-hydroxymethyl-1, 3-dioxolan-2-one) is currently one of the most celebrated glycerol derivatives that captured arising scientific and industrial attentions due to its extensive potential applicability. This cyclic ester of glycerol with carbonic …

Development And Industrial Application Of Novel Non-Cr Passivity For Electrolytic Manganese, Siming Chen, Dongping Duan, E Zhou, Ting Li

5th International Congress on Green Process Engineering (GPE 2016)

No abstract provided.

Sox Trapping Performances Of Cuo Based Silica Mesoporous Adsorbents For Desulfurization Of Industrial Flue Gas Stream, Sophie Dorge, Marc Berger, Habiba Nouali, Laure Michelin, Ludovic Josien, Matthieu Vierling, Michel Molière, Emmanuel Fiani, David Habermacher, Joël Patarin, Jean-François Brilhac, Pierrick Gaudin

5th International Congress on Green Process Engineering (GPE 2016)

In the present work, CuO/SBA-15 SOx regenerable adsorbents were elaborated. Synthesis conditions were controlled in order to obtain highly dispersed Cu²⁺ species assumed to be Cu-O-Si species. Materials were evaluated as SOx adsorbents through multicycle adsorption/regeneration experiments. Their performances decrease along cycles due to copper species sintering and there is an optimal copper loading for a maximal SOx adsorption efficiency.

Please click Additional Files below to see the full abstract.

Catalytic Property Of Olivine For Bio-Oil Gasification, Mohammad Latifi, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Introduction

Biomass is an attractive renewable source of fuel and energy. Thermochemical processes can convert biomass to a liquid bio-oil or to a syngas. The advantage of using bio-oil as an intermediate is that, in contrast with both raw biomass and gas, it can easily be produced in small distributed units, stored and transported. Not only can platform chemicals and clean fuels be produced from syngas, but hydrogen is itself an alternative fuel. A high hydrogen production is usually desired: for example, methanol production requires a syngas with a molar H₂/CO ratio of 2. Therefore, maximum hydrogen production …

Influence Of Pre-Treatment On Grass Pyrolysis For High Value Products, Chiara Barbiero, Charles Greenhalf, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Pyrolysis of biomass is a process which yields high quality, clean, and green products like bio-oil and bio-char. Bio-oil has a wide range of applications and also includes liquid fuels and raw chemical products. Therefore, it will be attractive to tailor the bio-oil properties to improve the yields of specific compounds that are economically interesting. In particular, pyrolytic sugar can be used for fermentation while phenolic compounds have an array of industrial applications such as adhesives; moreover, they can substitute petroleum-based phenols. However, it is difficult to achieve high yields of specific chemicals in the bio-oil without adequate biomass pre-treatments. …

Pyrolysis Of Residues From Well-Established Biochemical Processes For Biomass Conversion Into Liquid Fuel, Devon Barry, Cedric Briens, Franco Berruti

5th International Congress on Green Process Engineering (GPE 2016)

This project focuses on the pyrolysis of residues from well-established biochemical processes into liquid fuel. The residues examined come from two major conversion processes; wastewater treatment facilities, and biogas digesters. These processes produce low value, unconverted residues that are refractory to further biochemical conversion. Pyrolysis is an aggressive thermochemical conversion process that is ideally suited to such residues.

Currently, these residues are viewed as a low-value or waste products that must be disposed of. The environmentally friendly disposal of wastewater sludge is a common problem for many municipalities, where the sludge is often incinerated or disposed of in landfills. Anaerobic …

Adhesives From Biomass Pyrolysis, Dongbing Li, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Fast pyrolysis of waste biomass with high lignin content, such as birch wood, birch bark, hydrolysis lignin, kraft lignin or low-cost digestate from biogas production, provides oils that can be substituted for phenol in phenol-formaldehyde resins. Biomass fast pyrolysis was performed in a dedicated fluidized bed pyrolyzer that incorporated two crucial innovations: a fractional condensation train provided dry bio-oils with ~1% of moisture and much reduced acidity; autothermal pyrolysis with partial oxidation reduces operating and capital costs, as well as increasing the quality of the dry bio-oil. Dry bio-oil obtained from autothermal fast pyrolysis of kraft lignin can be used …

Performance And Emissions Of A Diesel Engine Fueled With Biodiesel Doped With A Renewable Antioxidant Additive, Alberto Gonzalo, Jorge Arroyo, Francisco Moreno, Mariano Muñoz, Carlos Monné, Ana Bautista, Noemí Gil-Lalaguna, Cristina Dueso, José Luis Sánchez

5th International Congress on Green Process Engineering (GPE 2016)

1. INTRODUCTION

Biodiesel is a mixture of alkyl esters obtained by transesterification of vegetable oils and animal fats with a short chain alcohol (mainly methanol or ethanol) and catalyzed by acids or bases (usually NaOH or KOH) [1]. Final properties of the biodiesel are similar to those of petroleum derived-diesel. Therefore, biodiesel can be used in diesel conventional engines without significant modifications or mixed in any proportion with fossil diesel.

Some of the main drawbacks of biodiesel to be used as fuel are the low oxidation stability and poor cold flow properties (freezing point and flowability of the …

Hydrothermal Treatment Of Bio-Oil For The Production Of Biodiesel Antioxidants, Noemí Gil-Lalaguna, Ana Bautista, Lucía Botella, Alberto Gonzalo, José Luis Sánchez, Jesús Arauzo

5th International Congress on Green Process Engineering (GPE 2016)

1. INTRODUCTION

Fuel consumption is inevitable for industrial development and growth of any country. In the last years, diesel fuels have gained an increasingly important role in the transportation sector. However, the rapid depletion of crude oil resources, as well as the worldwide concern about the environmental damage related to the increase in the emissions of carbon dioxide and other pollutants, has led to an increasing awareness about the development and use of renewable fuels. In this context, biodiesel appears as a good alternative to fossil diesel because of its renewable and biodegradable character, also being a non-toxic and clean fuel …

The Integrated Forest Biorefinery, An Example Of Green Engineering, Miyuru Kannangara, Mariya Marinova, Michel Perrier, Jean Paris

5th International Congress on Green Process Engineering (GPE 2016)

1. Introduction

Confronted by a steady decline in the demand for commodity papers, the pulp and paper industry has undertaken intensive R&D efforts to identify and develop new non paper products that could be manufactured from the forest biomass. The components of wood that can be separated and converted into new non paper products are the cellulose, hemicelluloses and lignin. Celluloses and hemicelluloses are polymers of various sugars and lignin is a polymer of phenylpropane units. This paper treats the specific case of lignin and hemicellulose extraction from a Kraft pulping process. Two processes have been investigated for the extraction …

Two-Stage Thermochemical Valorisation Of Sugar-Derived Humins, Paul De Wild

5th International Congress on Green Process Engineering (GPE 2016)

The majority of commercial bulk chemicals is still derived from fossil resources. The development of green biobased chemicals is high on the global research and development agenda. Lignocellulosic biomass and particularly the cellulose and hemicellulose fraction are considered interesting feeds for the production of key bulk chemicals to serve as building blocks for the chemical industry. Efficient chemo-catalytic conversion technologies for C5 and C6 sugars are under development to generate selected existing bulk chemicals, such as Levulinic acid (LA), caprolactam (CAP), butadiene (BD), furfural and 5-hydroxymethylfurfural (HMF), a very promising platform chemical for the synthesis of a.o. novel monomers for …

Process For Removal And Recovery Of Phenolic Compounds From Switchgrass, Robert M. Counce, Nikki Labbé, Michelle L. Lehmann, Jack S. Watson, Jingming Tao

5th International Congress on Green Process Engineering (GPE 2016)

Introduction

This paper describes a process for the separation and recovery of non-structural phenolic compounds from switchgrass. This process is proposed as a preliminary step of a biorefinery incorporating the organosolv process for biomass fractionation. The economics of such an addition to separate and recover phenolic compounds is then investigated.

Switchgrass has been selected as a dedicated feedstock for bioprocesses producing liquid fuels such as ethanol and advanced fuels. The University of Tennessee has been heavily involved in the development of switchgrass as one of the feedstocks for bioenergy production in the southeast (Tiller 2011). Biofuels have the potential to …

Marketable Bioproducts And Biomaterials From Research To Commercial Manufacture For Sustainability, Greenhouse Gas Emission Reductions And A Circular Economy, Richard Jewell

5th International Congress on Green Process Engineering (GPE 2016)

Enerkem produces clean fuels and green chemicals from waste with improved economics and greater sustainability than technologies that rely on fossil sources. Enerkem’s technology converts non-recyclable municipal solid waste, such as household garbage, into clean fuels and renewable chemicals.

Enerkem develops and delivers biorefineries in North America and globally, using internal process engineering groups to develop and build biorefineries that are modular and standardize plant fabrication and manufacturing.

The success of Enerkem’s process engineering acumen is demonstrated in Enerkems rollout of the world’s first commercial biorefinery to use municipal solid waste feedstock to produce methanol and ethanol. This facility, called …

Fundamental Study And Applications To Biomass Pyrolysis Of The Mechanically Fluidized Reactor, Valentina Lago, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Lignin has great potential for the production of aromatics currently derived from petroleum, since it is the most abundant source of aromatics in nature. At present, Kraft lignin is used as fuel within the pulping process but, alternatively, it could be converted to high-value chemicals using thermochemical processes such as pyrolysis. Kraft lignin, however, is a very cohesive and thermally sensitive powder with foaming and agglomerating tendency under reaction conditions. Consequently, a novel reactor design, designated as Mechanically Fluidized Reactor (MFR) has been developed to successfully process Kraft lignin.

Please click Additional Files below to see the full abstract.

Using The Jiggled Bed Reactor To Develop Activated Carbons From Biomass Residues, Anastasia Colomba, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Activated carbons are the most used adsorbent material. Their applications range from wastewater treatment, air purification, removal of contaminants and many others. According to “Global Activated Carbon Market Forecast & Opportunities 2017”, the demand for activated carbon is expected to increase more than 10% per year for the next 5 years to make it a $3 billion market by 2017. Current processes for the production of activated carbons from renewable resources do not provide valuable co-products. This presentation focuses on the conversion to activated carbon of the bio-char co-product of the pyrolysis process. Pyrolysis also provides valuable bio-oil, which is …

Catalyst Layer Design In Polymer Membrane Fuel Cells, Sarah Stariha

Chemical and Biological Engineering ETDs

One of the biggest obstacles to commercializing polymer electrolyte membrane fuel cells is the use of platinum as a catalyst. One way to overcome this obstacle is to replace platinum with non-platinum group metal (non-PGM) catalysts, particularly for the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). The most realistic method of estimating the performance of non-PGM catalysts is testing within membrane electrode assemblies (MEAs). One key issue is that non-PGM catalysts are not as active as platinum. One way to increase their performance is to optimize the catalyst layer composition, specifically the components responsible for ionic …

The Design And Testing Of A Novel Batch Photocatalytic Reactor And Photocatalyst, Shawn Sasser

USF Tampa Graduate Theses and Dissertations

With an ever-increasing human population, the importance in having sustainable energy resources is becoming increasingly evident, as the current energy habits have brought about massive atmospheric pollution in the form of CO₂ emissions, resulting in a rise in the average global temperature. To battle the effects of climate change, many alternative energy resources have been investigated. Among these, photocatalytic conversion of CO₂ to renewable hydrocarbon fuels such as methane and methanol is one of the most desirable, as it provides the opportunity to utilize the sun’s energy to convert CO₂ to renewable fuels. The work in this …

Development And Implementation Of Problem-Based Chemistry Experiments For Engineering Students In A Multi-Disciplinary Course, Tiffany Hesser, Stephanie R. Bunyea

Chemistry and Chemical Engineering Faculty Publications

This paper will describe the implementation and continuing development of five problem based laboratory experiments in a general chemistry course designed specifically for multiple disciplines of engineering students at the University of New Haven. The Problem Based Laboratory Experiments (PBLE) were developed to provide students with the opportunity to perform and develop experimental procedures working in interdisciplinary teams, while achieving a greater understanding of the role of chemistry in engineering fields. In each PBLE, students first complete a traditional chemistry experiment to gain an understanding of the chemical concepts and to become familiar with executing a written procedure with a …

Influence Of Socio-Demography And Operating Streetscape On Last-Mile Mode Choice, M. Meng, P. P. Koh, Y. D. Wong

Journal of Public Transportation

This study investigated how personal and operational factors (travel distance and streetscape) influence traveler mode choice decisions for the last-mile home-bound trip stage from rail transit stations. Personal factors include the socio-demography of travelers, and attributes of the streetscape include the built environment (degree of areal development), prevalence of cycling, availability of short-range transport modes, and walking/cycling infrastructure. Interviewers randomly intercepted pedestrians to administer a mode choice survey at five rail transit station exits and engaged all available cyclists at bicycle parking areas in the vicinity of stations in Singapore. A multimodal logit regression model revealed a significant relationship between …

Fluid Analysis In Solar Heat Pipes, Ben Krumholz, Michael Agavo, William Dundon

Mechanical Engineering

Evacuated tube solar collectors are efficient systems that use heat pipes to facilitate heat transfer. They use incoming solar radiation to heat water. Professor Mason Medizade tasked the team with choosing a component of the system to research and test its influence on system performance. The team investigated the working fluid that runs through the heat pipes. Distilled water, acetone, and ethanol at a range of fill volumes form 1 mL to 11 mL were tested. The team's goal was to find a volume for each fluid to maximize performance of the system. Performance was defined as average temperature rise …

Microstructural Properties And Four-Point Bend Fatigue Behavior Of Ti-6.5al-2zr-1mo-1v Welded Joints By Electron Beam Welding, Peng Liu, Tongguang Zhai, Yuanbin Zhang

Chemical and Materials Engineering Faculty Publications

With the help of a four-point-bend of fatigue rig, high-cycle fatigue tests were carried out on an Ti–6.5Al–2Zr-1Mo-1V titanium alloy at room temperature, 20 Hz and R = 0.1 in ambient air. The test results indicated that the fatigue strength of base metal, 888 MPa, is about 120% of yield strength. The fatigue strength of joints is 814 MPa. It is about 110% of yield strength of base metal. When the loading stress is higher, the fatigue failure region is located in middle weld zone of weld face, which the cracks are propagated along coarse β phase’s grain boundary. When …

Micro Debris Generator, Gordan Bradaric, Ross Byers, Stephen Quanci

Mechanical Engineering

This senior project team at Cal Poly consisting of Stephen Quanci, Gordan Bradaric, and Ross Byers has been commissioned by Erik Brown of Lawrence Livermore National Labs to create a way to reliably and consistently entrain microscopic particles into the hot HTTU flow. These particles will be used to compare the loading rates of new HEPA filters by measuring the pressure drop across the filter. The generated particles would simulate typical conditions in which these HEPA filters are expected to operate, namely fine ash. The particles used for loading the filter are intended to simulate the particulate reaching the LLNL …

Minimization Of Metamerism In Wood Grain Printing Using Different Gcr Settings, Vinay Anil Turke

Masters Theses

In printing industry, prototyping is necessary to ensure quality reproduction of jobs. Conventional printing processes like gravure cannot be used for prototyping because of high manufacturing cost of gravure cylinders. Such challenges can be successfully tackled by use of relatively cheap and flexible printing processes, such as inkjet. Even though inkjet printing is a cost effective way for prototyping, it has its own limitations, especially in the case of woodgrain printing. Wood-grain patterns need to be printed with a release coating and adhesive. Inkjet printers are incapable of printing release coating and adhesive because release coat and adhesive require certain …

Thermal And Convective Loading Methods For Releasing Hydrophobic Therapeutics From Contact Lenses, Ryan Ruben Horne

Theses and Dissertations

This thesis investigates the feasibility of loading silicone hydrogel (SiHy) contact lenses with two different hydrophobic therapeutics, latanoprost and DMPC (1,2-dimyristoyl-sn-glycero-3-phosphocholine), for treatment of glaucoma and hyperemia respectively. The two methods of loading were 1) thermal loading in an aqueous medium and 2) convective loading in a solution of n-propanol. Dailies Total1® lenses prepared in this manner were tested for their loading and their release into artificial tears. Continuous release over 1-4 days at therapeutic levels is achievable from thermal loading of DMPC, convective loading of DMPC, and convective loading of latanoprost. The DMPC loading processes can be naturally integrated …

Dynamic Liquefied Natural Gas (Lng) Processing With Energy Storage Applications, Farhad Fazlollahi

Theses and Dissertations

The cryogenic carbon capture™ (CCC) process provides energy- and cost-efficient carbon capture and can be configured to provide an energy storage system using an open-loop natural gas (NG) refrigeration system, which is called energy storing cryogenic carbon capture (CCC-ES™). This investigation focuses on the transient operation and especially on the dynamic response of this energy storage system and explores its efficiency, effectiveness, design, and operation. This investigation included four tasks.The first task explores the steady-state design of four different natural gas liquefaction processes simulated by Aspen HYSYS. These processes differ from traditional LNG process in that the CCC process vaporizes …