Engineering Commons^™

Deformation Processes At The Leading Edge Of The Sevier Fold And Thrust Belt, Southwest Utah, William Joseph Michael Chandonia

Masters Theses

"Deformation processes leading to formation and abandonment of 'triangle zones' along the leading edge of the Sevier fold and thrust belt are investigated near Kanarraville, Utah through construction of a detailed geologic map and cross-section along Spring Creek. Here the eastern limb of the Kanarra fold, a Sevier structure, is well exposed along the Hurricane Cliffs due to uplift and erosion of the footwall of the Hurricane Fault. The east-verging Kanarra fold changes from upright to overturned within Spring Creek. Within the fold limb, parasitic folds, minor thrust faults, and duplex structures result in local tectonic overthickening of units and …

Advanced Buffer Materials For Indoor Air Co₂ Control In Commercial Buildings, Pavithra Ethi Rajan

Masters Theses

"The following describes a novel passive approach to control the indoor CO₂ levels in enclosed spaces, primarily focusing on commercial buildings. Amine impregnated silica sorbents were identified as suitable candidates and synthesized; the amine loading ratio was varied to create a range of materials. These samples along with other commercial zeolite candidates have been tested over a range of CO₂ concentrations to determine the CO₂ adsorption capacity in laboratory systems and under simulated room conditions. The research work also focuses on the CO₂ desorption capacity of the candidate adsorbents. The desorption is allowed to occur gradually …

Combined Flue Gas Cleanup Process For Simultaneous Removal Of SoX, NoX, And Co₂ -- A Techno-Economic Analysis, Amit Narendrasing Hajari

Masters Theses

"Flue gas cleanup often requires the removal of SO_x, NO_x and CO₂ in separate units before atmospheric emission. The step-wise treatment process currently in place incurs significant cost and energy penalty. A single-step adsorption process based on pressure swing adsorption (PSA) by which these impurities are removed is envisioned as an efficient means of flue gas cleanup that can be applied relatively easily. In this study, the technological and economic feasibility of a single-step separation process in which SO_x, NO_x and CO₂ are simultaneously removed from flue gas streams are assessed. Capital …

Evaluation Of Swelling And Re-Swelling Of Preformed Particle Gels (Ppg) When Exposed To Co₂, Sujay Suresh

Masters Theses

"Long term water/gas flooding induces high permeability channels in reservoirs. Reservoir heterogeneity becomes the most prominent challenge faced in mature oil fields. Gel treatment has been a proven solution to counter the problem of reservoir heterogeneity, to provide in-depth treatment and improve the sweep efficiency for reservoirs. Preformed particle gels (PPGs) were developed as an alternative to in-situ gels as they preferentially penetrate and shutoff high permeability zones, leaving the low permeability zones undamaged. These gels have been predominantly used in water flooding projects, but have not been employed in carbon dioxide (CO₂) flooding projects. CO₂ Resistant …

Study Of Surface Complexation And Mineral Dissolution During Water-Rock Interaction In High Salinity Waterflooding At Elevated Temperatures, Sameer Salasakar

Masters Theses

"High salinity waterflooding for carbonate reservoirs is efficient and cheap method used for improved oil recovery. Various mechanisms have been proposed including adsorption/desorption on rock surface, mineral dissolution and precipitation, multicomponent ion exchange, interfacial tension reduction, fine migration and double layer expansion. These all process alter the wettability which leads to improved oil recovery.

Objective of this study was to understand processes that occur during water-rock interaction when high salinity water is flooded into the reservoir. In this work, effect of temperature on water-rock interaction is studied along with effect of pH and specific surface areas of calcite at normal …

Effect Of Fracture Heterogeneity On Proppant Transport And Settling Mechanism, Dhurgham Abdulameer Kadhim

Masters Theses

"Proppant transport modeling through fractures with slickwater fluid systems assumes uniform and homogeneous fracture widths by implying constant fluid behavior at wall boundaries. Hydraulic fracturing mineback operations have demonstrated that induced fractures are heterogeneous and varying in width. This work investigates the impact of fracture width heterogeneity, roughness, and leak-off on ceramic proppant transport and settling, using proppant distribution concepts of Equilibrium Dune Level (EDL) and equilibrium Dune Length (EDX). Experimental work was conducted to investigate the impact of fracture width heterogeneity by varying fracture width along two plexiglass sheets. To mimic actual hydraulic fractures, the injection side was designed …

Optimising The Performance Of Cement-Based Batteries, Aimee Byrne, Shane Barry, Niall Holmes Dr., Brian Norton

Articles

The development of a battery using different cement-based electrolytes to provide a low but potentially sustainable source of electricity is described. The current, voltage, and lifespan of batteries produced using different electrolyte additives, copper plate cathodes, and (usually) aluminium plate anodes were compared to identify the optimum design, components, and proportions to increase power output and longevity. Parameters examined include water/cement ratio, anode to cathode surface area ratio, electrode material, electrode spacing, and the effect of sand, aggregate, salts, carbon black, silica fume, and sodium silicate on the electrolyte. The results indicate that the greatest and longest lasting power can …

Comprehensive Model Of Single Particle Pulverized Coal Combustion Extended To Oxy-Coal Conditions, Troy Michael Holland, Thomas H. Fletcher

Faculty Publications

Oxy-fired coal combustion is a promising potential carbon capture technology. Predictive CFD simulations are valuable tools in evaluating and deploying oxy-fuel and other carbon capture technologies either as retrofit technologies or for new construction. However, accurate predictive simulations require physically realistic submodels with low computational requirements. In particular, comprehensive char oxidation and gasification models have been developed that describe multiple reaction and diffusion processes. This work extends a comprehensive char conversion code (CCK), which treats surface oxidation and gasification reactions as well as processes such as film diffusion, pore diffusion, ash encapsulation, and annealing. In this work several submodels in …

Model For The Evolution Of Pore Structure In A Lignite Particle During Pyrolysis. 2. Influence Of Cross-Linking Reactions, Molten Metaplast, And Molten Ash On Particle Surface Area, He Yang, Thomas H. Fletcher, Sufen Li, Haoquan Hu, Lijun Li

Faculty Publications

A model for the evolution of the pore structure in a lignite particle during pyrolysis was established previously based on the chemical percolation devolatilization (CPD) model, using coal polymer network parameters to calculate the surface area and porosity of the particle. In this paper, to get the accurate surface area of coal particle at high pyrolysis temperature, the previous model was improved by considering the effects of cross-linking reactions, molten Metaplast, and ash. The good agreement of the predicted surface area with experiments at temperature below 1200 K in the previous model is maintained, and model accuracy is improved at …

Efficacy And Mechanistic Insights Into Endocrine Disruptor Degradation Using Atmospheric Air Plasma, Chaitanya Sarangapani, M. Danaher, Brijesh Tiwari, Peng Lu, Paula Bourke, Patrick J. Cullen

Articles

Endocrine disruptors are a class of contaminants found in water and process effluents at low concentrations. They are of concern due to their high estrogenic potency. Their presence in the environment has led to the search for effective techniques for their removal in wastewater. For this purpose, an atmospheric air plasma reactor was employed for the study of the degradation of three endocrine disruptor chemicals (EDC) namely; bisphenol A (BPA), estrone (E1) and 17β-estradiol (E2) within a model dairy effluent. Identification of the plasma induced active species both in the gas and liquid phases were performed. Also studied was the …

Evaluation Of Combined Low-Salinity Water And Microgel Treatments To Improve Oil Recovery Using Partial Fractured Carbonate Models, Ali K. Alhuraishawy, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Combining two methods in one process to enhance oil recovery represents a needed cost savings in the oil industry. Microgels are used as conformance control agents to improve oil sweep efficiency and control excess water production. Low-salinity waterflooding (LSWF) is used as a wettability alteration agent in carbonate reservoirs and improves displacement efficiency. This paper offers a comprehensive understanding of the combined technology through laboratory experiments. The focus of this study is to see how microgels and low water salinity perform in porous media by creating flow resistance to injected fluid thereby changing the wettability and enhancing the sweep and …

Ior Methods In Unconventional Reservoirs Of North America: Comprehensive Review, Dheiaa Alfarge, Mingzhen Wei, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Unconventional resources have played a significant role in changing oil industry plans recently. Shale formations in North America have huge oil in place, 900 billion barrels of recoverable oil in Bakken only. However, the predicted primary recovery is still low as less than 10%. Therefore, seeking for improved oil techniques to increase oil recovery in these complex plays is inevitable. In this paper, three stages of review have been combined to find out the applicability of the most feasible IOR methods in these unconventional reservoirs. Firstly, the most common fluid and rock properties of these reservoirs have been investigated and …

Selection Criteria For Miscible-Gases To Enhance Oil Recovery In Unconventional Reservoirs Of North America, Dheiaa Alfarge, Mingzhen Wei, Baojun Bai, Mortadha Alsaba

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Unconventional resources have played a significant role in changing oil industry plans recently. Shale formations in North America such as Bakken, Niobrara, and Eagle Ford have huge oil in place, 100-900 billion barrels of oil in Bakken only. However, the predicted primary recovery is still low as 5-10%. Therefore, seeking for techniques to enhance oil recovery in these complex plays is inevitable. In this paper, two different approaches have been integrated to investigate the feasibility of three different miscible gases which are CO₂, lean gases, and rich gases. Firstly, numerical simulation methods of compositional models have been incorporated …

Wellbore Stability Evaluation For Mishrif Formation, Ethar H.K. Alkamil, Husam R. Abbood, Ralph E. Flori, Andreas Eckert

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

During drilling operations for the E oilfield in the Mishrif formation in southern Iraq, stuck pipe has been identified as a significant geomechanical problem for several wells. In this study, a 1-D mechanical earth model (MEM) of the Mishrif formation is compiled based on its state of stress and rock strength parameters and is utilized to assess the contribution of borehole collapse leading to the stuck pipe problems. The MEM model is based on the principal in situ stresses and their orientation obtained from wireline logs measurements, measuring while drilling (MWD), and leak off test (LOT). Rock strength properties are …

Effect Of Molecular-Diffusion Mechanisim On Co2 Huff-N-Puff Process In Shale-Oil Reservoirs, Dheiaa Alfarge, Mingzhen Wei, Baojun Bai, Abdullah Almansour

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Unconventional resources have played a significant role in changing oil industry plans recently. Shale formations in North America such as Bakken, Niobrara, and Eagle Ford have huge oil in place, 100-900 billion barrels of recoverable oil in Bakken only. However, the predicted primary recovery is still low as less than 10%. Therefore, seeking for techniques to increase oil recovery in these complex plays is inevitable. In this paper, three different approaches have been combined to investigate the effect of molecular-diffusion mechanism on CO₂ huff-n-puff process in Bakken formation. Firstly, comprehensive review has been conducted on the reported experimental studies …

Optimizing Injector-Producer Spacing For Co2 Injection In Unconventional Reservoirs Of North America, Dheiaa Alfarge, Mingzhen Wei, Baojun Bai, Abdullah Almansour

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Shale oil reservoirs such as Bakken, Niobrara, and Eagle Ford have become the main target for oil and gas investors as conventional formations started to deplete and diminish in number. These reservoirs have a huge oil potential; however, the predicted primary oil recovery is still low as average of 7.5 %. Carbon dioxide (CO₂) flooding has been a controversial approach to increase oil recovery in these poor-quality formations. This study investigated the effect of injector-producer spacing, in range of 925-1664 ft, on CO₂ performance in these plays by using numerical simulation methods. CO₂ utilization value under …

Novel Environmentally Benign Hydrogel: Nano-Silica Hybrid Hydrolyzed Polyacrylamide/ Polyethyleneimine Gel System For Conformance Improvement In High Temperature High Salinity Reservoir, Liping Ma, Shitou Wang, Yifu Long, Changqian Zhu, Hongbin Yang, Tangying Yang, Xiaochun Liu, Xiaorong Li, Baojun Bai, Wanli Kang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

In order to address the conformance problem in high temperature and high salinity/hardness reservoir, an environmentally benign in-situ gel was developed based on hydrolyzed polyacrylamide (HPAM) and polyethyleneimine (PEI). Moreover, silica nanoparticle (SNP) was embedded to improve the performance of HPAM/PEI gel. To achieve the optimum formulation of HPAM/PEI-SNP gel, a comprehensive investigation was first conducted with the respect of gelation time, gel strength, and thermal stability. In addition, the particle size of SNP was determined by Dynamic Light Scatter (DLS) and the microstructure of HPAM/ PEI-SNP gel was characterized via Scanning Electron Microscopy (SEM). The optimum formulation, containing the …

Well Integrity Assessment Of Monitoring Wells At An Active Co2-Eor Flood, Andrew Duguid, Boyun Guo, Runar Nygaard

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Assessment of well integrity has become more important for CCS and CO₂-EOR as it has become apparent that wells represent the most likely migration pathway for CO₂ to leave a CCS storage unit or a CO₂-EOR reservoir. Although wells represent a migration pathway, they are also the best vehicle for employing technology monitoring CO₂ injection and storage. This contradiction of being a potential migration path and key monitoring technology leads to a need to understand how monitoring wells may be similar or different in comparison to other types of wells with respect to migration …

Analysis Of Ior Pilots In Bakken Formation By Using Numerical Simulation, Dheiaa Alfarge, Mingzhen Wei, Baojun Bai, Mortadha Alsaba

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Bakken is the most productive formation among unconventional plays in North America. This formation has 7.4 billion barrels of recoverable oil. However, the primary oil recovery is still low as 5-10%. Miscible natural gas and carbon dioxide (CO₂) might be the most two potential strategies to improve oil recovery in such complex play. In this study, some of the IOR pilots which have been conducted in Montana, North Dakota, and South Saskatchewan have been presented. The performance results of these pilots in US-Bakken versus Canadian-Bakken have been compared. Moreover, the reasons beyond the successful IOR pilots in Canadian-Bakken …

Integrating Microgels And Low Salinity Waterflooding To Improve Conformance Control In Fractured Reservoirs, Ali Alhuraishawy, Mingzhen Wei, Baojun Bai, Abdullah Almansour

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The recovery from fractured reservoirs is usually low. The areal heterogeneity is one result of the fractured reservoir. Low salinity waterflooding (LSWF) and preformed particle gel (PPG) have recently investigated by some researchers. The main objective of this study was to determine whether the combining technologies can improve conformance control in fractured sandstone reservoirs. Semi-transparent five-spot models made of sandstone cores and acrylic plates were built. The effect of low salinity waterflooding on oil recovery was studied. Models were designed with three parallel open fractures. Sodium chloride (1.0, 0.1, 0.01, and 0.001 wt. % NaCl) were used for brine flooding …

Updated Criterion To Select Particle Size Distribution Of Lost Circulation Materials For An Effective Fracture Sealing, Mortadha Alsaba, Mohammed F. Al Dushaishi, Runar Nygaard, Olav Magnar Nes, Arild Saasen

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This paper presents a new criterion to select particle size distribution (PSD) for an effective fracture sealing. The method was developed based on a comprehensive laboratory investigation that was conducted to determine the relationship between effectiveness of different lost circulation material (LCM) treatments in terms of the sealing efficiency and PSD. The results were compared with the current selection methods, which were developed to enhance the bridging capabilities for drill-in fluid, to investigate their applicability in designing effective treatments for fracture sealing. A statistical investigation was carried out to develop new criteria that suggest PSD based on the expected fracture …

A Quartz Crystal Microbalance Study Of Thiol:Ene Poly(Ionic Liquid) Polymerization And Gas Absorption, Yueming Wu

Murray State Theses and Dissertations

ABSTRACT

The polymerization process of, and gas absorption by, imidazolium-containing thiol:ene poly (ionic liquid)s (PILs), prepared from bisallylimidazolium bis(trifluoromethyl sulfonyl)imide [NTf₂^-] and pentaerythritoltetrakis(3 mercaptopropionate), was studied. The thiol:ene PILs examined were recently reported by groups at Murray State University. The advantage of thiol:ene PILs over other reported PILs is that thiol:ene polymers are made rapidly by UV exposure and exhibit high mechanical and thermal stability due to high cross-linking. The properties of interest for the thiol:ene PILs were studied using a quartz crystal microbalance (QCM). QCM techniques are based on the piezoelectric effect, where certain crystals (e.g., …

Preparation And Application Of Catalysts For The Stereospecific Reduction And Photooxygenation Of Olefins In Continuous Operations: A Novel Method For The Production Of Artemisinin, Daniel C. Fisher

Theses and Dissertations

Over the last two centuries, the discovery and application of catalysts has had a substantial impact on how and what chemicals are produced.Given their broad significance, our group has focused on developing new catalyst systems that are recoverable and reusable, in an attempt to reduce concomitant costs.

Our efforts have centered on constructing a recyclable chiral heterogeneous catalyst capable of effecting asymmetric hydrogenations of olefins with high stereoselectivity. A class of phosphinoimidazoline ligands, developed by researchers at Boehringer-Ingelheim, known as BIPI ligands, have proven efficacious in the asymmetric reduction of alkenes. However, these chiral ligands are homogeneous and coordinated to …

Determination Of Significant Parameters That Drive Fracture Optimization In The Glauconite Formation, Southern Chile, Ghassan Saleh Mahdi Alqatrani

Masters Theses

"The Glauconite Formation in the Magallanes Basin of Southern Chile is a clay- and silica-rich formation with low permeability. As with many of the unconventional resources, the Glauconite Formation requires a hydraulic fracturing operation to enhance the productivity of the wells in this area.

Data and pertinent information of fracturing, completion, and reservoir quality parameters along with post-fracture production data were collected to initiate a database of nearly 70 wells, to be used to develop a better understanding of the fracturing behavior, optimize the well stimulation, and overcome the major barriers in the hydraulic fracturing of the Glauconite Formation. The …

Cathodic Protection Measurement Through Inline Inspection Technology Uses And Observations, Briana Ley Ferguson

Masters Theses

"This research supports the evaluation of an impressed current cathodic protection (CP) system of a buried coated steel pipeline through alternative technology and methods, via an inline inspection device (ILI, CP ILI tool, or tool), in order to prevent and mitigate external corrosion. This thesis investigates the ability to measure the current density of a pipeline's CP system from inside of a pipeline rather than manually from outside, and then convert that CP ILI tool reading into a pipe-to-soil potential as required by regulations and standards. This was demonstrated through a mathematical model that utilizes applications of Ohm's Law, circuit …

Geomechanical Analysis Of The Wellbore Instability Problems In Nahr Umr Formation Southern Iraq, Haider Qasim Mohammed

Masters Theses

"Wellbore instability problems play a major rule of increasing nonproductive time (NPT) during drilling processes. In most cases, the cost of drilling a well can be reduced by designing a suitable operational window using geomechanical models. Several wellbore instability problems have been encountered during drilling Nahr Umr Formation in an oil field in southern Iraq. These problems include but are not limited to, mechanical stuck, caving, and tight holes. Data from twenty vertical wells are investigated to reveal the major factors that control the instability problems and to design an optimum mud window. A geomechanical model is developed to determine …

Preformed Particle Gel Conformance Control Performance In Partially Opened Fracture And Fully Opened Fracture Systems, Ghith Ali Ahmed Biheri

Masters Theses

"Conformance problems, such as reservoir heterogeneity can result in a significant decrease in oil recovery, and an excessive water production. Millimeter particle gels (PPG) have been used as conformance control agents to plug open fractures, however, very little research has been conducted to study their ability to plug partially open fractures. This research studies the ability of the PPG to plug partially open fracture to improve conformance and increase recovery in oil reservoirs. Rectangular Sandstone cores were used to conduct the experiments. Fracture widths used include 2, 3.5, 5 mm. For each fracture width, four gel strengths were used; gel …

Quantifying Ceramic Proppant Transport In Complex Fracture Networks, Vivekvardhan Reddy Kesireddy

Masters Theses

"Water fracs have become an essential part of unconventional reservoirs to create deeper fracture networks. Proppant transport in water fracs is challenging in terms of fluids ability to carry the proppant deeper into these fracture networks. This experimental study investigates the impact of the flow rates, fracture widths and complexity controlling the ability of proppant to flow into complex fracture networks. This research attempts to nullify the knowledge gap in understanding width heterogeneity in primary and secondary fractures. This study speaks for settling pattern and proppant transport through a slot flow model with a unique approach to understand stage wise …

Well Log Interpretation And 3d Reservoir Property Modeling Of Maui-B Field, Taranaki Basin, New Zealand, Aziz Mennan

Masters Theses

"Maui-B is one of the largest hydrocarbon-producing fields in the Taranaki Basin. Many previous works have estimated reservoir volume. This study uses 3D property modeling, which is one of the most powerful tools to characterize lithology and reservoir fluids distribution through the field. This modeling will help in understanding the reservoir properties and enhancing the production by selecting the best location for future drilling candidates. In this study, 3D seismic, core, and well log data were used to build and define a structural model, facies analysis, and petrophysical parameters. After well log interpretation and petrophysical parameter calculations, each parameter was …

A Comprehensive Analysis Of Lost Circulation Materials And Treatments With Applications In Basra's Oil Fields, Iraq: Guidelines And Recommendations, Husam Hasan Alkinani

Masters Theses

"Lost circulation materials (LCM's) have been widely used to avoid or stop losses. Due to a large number of current available LCM's and their different applications, classification of LCM's is very important. The most recent LCM classification was published around 50 years ago, and this paper intends to fill this gap with an updated classification including conventional and new technologies. Lost circulation materials and treatments are re-classified into various categories based on their appearance, applications, chemical and physical properties.

Wells in Basra's oil fields are highly susceptible to lost circulation problems when drilling through the Dammam, Hartha, and Shuaiba formations. …