Engineering Commons^™

High‐Tensile Strength, Composite Bijels Through Microfluidic Twisting, S. P. Kharal, Robert P. Hesketh, Martin F. Haase

Henry M. Rowan College of Engineering Departmental Research

Rope making is a millennia old technique to collectively assemble numerous weak filaments into flexible and high tensile strength bundles. However, delicate soft matter fibers lack the robustness to be twisted into bundles by means of mechanical rope making tools. Here, weak microfibers with tensile strengths of a few kilopascals are combined into ropes via microfluidic twisting. This is demonstrated for recently introduced fibers made of bicontinuous interfacially jammed emulsion gels (bijels). Bijels show promising applications in use as membranes, microreactors, energy and healthcare materials, but their low tensile strength make reinforcement strategies imperative. Hydrodynamic twisting allows to produce continuous …

0.03 V Electrolysis Voltage Driven Hydrazine Assisted Hydrogen Generation On Nico Phosphide Nanowires Supported Nicohydroxide Nanosheets, Mujie Li, Zhongyi Zhang, Hailang Xiong, Linan Wang, Shuxian Zhuang, Morris D. Argyle, Yang Tang, Xiaojin Yang, Yongmei Chen, Pingyu Wan, Maohong Fan

Faculty Publications

In order to decrease the electricity consumption of hydrogen generation, hydrazine-assisted water electrolysis is intensively investigated recently. Herein, hierarchical nanostructure of ultrathin NiCo(OH)_x nanosheets (NSs) that in-situ grown on the NiCoP nanowires (NWs) was deposited on nickel foam (NF) to construct NiCo(OH)_x@NiCoP/NF electrode. NiCoP NWs extend the surface area, spatial utilization of NF and enhance the electron conduction to the outmost NiCo(OH)_x NSs. NiCo(OH)_x NSs interlace to form regular mesoporous channels, which improve the structural stability and mass transfer rate. Moreover, NiCoP NWs enhance the adsorption of protons and the transfer of electrons, while NiCo(OH) …

Study Of Rheological Properties Of Solutions And Pulp During Dicalcium Phosphate Formation Process, Navruzbek Ibraimovich Khurramov, Tulkin Isamurodovich Nurmurodov, Nilufar Negboevna Bozorova, Zarifa Umarovna Karimova

Chemical Technology, Control and Management

This article presents the rheological properties of suspensions obtained on the basis of nitric acid decomposition of unfired phosphorites of the Central Kyzylkum, as well as the chemical compositions of dicalcium phosphate and solid residues after the filtration process. The mass-spectral analysis of the pure dicalcium phosphate salt obtained by ammonization of the liquid part separated from the solid residue and subjected to filtration was studied.

Procedure Formalization For Constructing An Adaptive Control System With A Reference Model Based On The Lyapunov Function, Tulkin Vafoqulovich Botirov

Chemical Technology, Control and Management

Discusses the formalization of the procedure for constructing an adaptive control system with a reference model based on the Lyapunov function. It is shown that the asymptotic stability of the extended system of differential equations guarantees accurate tracking of the desired output signal of the model. At the same time, the expediency of analyzing the asymptotic stability of the system in extended space using the Lyapunov function is shown. The above algorithms help to stabilize the computational matrix inversion procedure and thereby increase the accuracy of estimating the adjustable parameter in an adaptive control system.

Improving The Electrochemical Method Of Wastewater Treatment, Dilrabo Akramovna Muhammadieva, Diyor Asadullaevich Hadjibaev, Furkat Ilyasovich Erkabaev

Chemical Technology, Control and Management

With an electrochemical method of wastewater treatment, the preliminary isolation of iron, calcium and magnesium compounds from them contributes to a more intensive recovery process. The purpose of this work is to improve the efficiency of electrochemical treatment of industrial wastewater contaminated with chromium(III) and chromium(VI) ions. The research has determined the optimal conditions for increasing the yield of chromium in the Park during electrochemical treatment of chromate-containing wastewater by using modified bentonite for pre - treatment of wastewater. Pre-softening of wastewater with modified bentonite before electrochemical treatment made it possible to increase the current yield of chromium from 17% …

Modeling Of Monitoring Systems Of Solar Power Stations For Telecommunication Facilities Based On Wireless Nets, Ilkhomjon Xakimovich Siddikov, Khalimjon Ergashevich Khujamatov, Doston Turayevich Khasanov, Ernazar Nurjamiyevich Reypnazarov

Chemical Technology, Control and Management

In this paper described of modelling processes of the real-time remote monitoring system of solar power sources, modelled and investigated by wireless sensor nets of telecommunications devices. As a modelling environment was obtained Proteus software. In processes of modelling of the system, structure and a block diagram of the system were developed, each of elements is deleted to parts of the system and separately described. Specially created software for the research system. The structure of the system developed and software tested by modelling processes. The results of modelling of monitoring system presented in a virtual terminal, an oscillography, and a …

Analysis Of Information Security Methods In Biosystems And Application Of Intelligent Tools In Information Security Systems, Sherzod Sayfullaev

Chemical Technology, Control and Management

In this paper, the methods of information protection in bio systems are studied. The paper considers the use of intelligent tools in information security systems and the use of adaptive information security systems. Several articles on the field of information protection in bio systems are analyzed. Disadvantages and advantages of neural network technologies in modern information security systems are described. The characteristics of bio systems and the specificity of DNA, the main features of the DNA code that provide information security and functional stability of bio systems data protection structure. Application of intelligent tools to create a comprehensive adaptive protection …

New Methods For Obtaining Quality Drinking Water In A Water Treatment Plant, Djaloliddin Nosirovich Muxiddinov, Nilufar Abdusomi Qizi Yunusova, Islom Abdisalim Ugli Daynovov

Chemical Technology, Control and Management

The article discusses modern methods, the scientific justification and the study of effective technologies in water treatment schemes for the removal of pollution of natural and man-made origin to produce high-quality drinking water. And also the proposed water treatment plant has a high resource and the ability to effectively purify water from a large number of contaminants and can be used to purify and provide high-quality drinking water to small settlements and industrial facilities located away from transport highways, as well as residential facilities of social institutions, enterprises Catering.

Developing Highly Efficient Industrial Contact Heat Exchanger, Khoshim Shayimovich Bakhronov, Abdumalik Abduvahobovich Akhmatov, Yorkin Bakhodirovich Kadirov

Chemical Technology, Control and Management

The paper presents the results of an experimental study of the intensification of heat transfer of a swirling flow in a cylindrical channel with two tangential and axial swirlers. During the experiments, such parameters were measured as: air flow in front of the vortex apparatus; hot water consumption; pressure drop in the vortex apparatus; temperature of working media at the inlet to the apparatus and at the outlet of it. A method for intensifying the heat transfer process, which is based on swirling a gas stream by its tangential supply, has been developed and investigated. Experimental studies of the intensity …

Methods For Ensuring The Stability Of Design Reliability In Rural Telecommunications Network During Its Operation, Akbar Daniyarovich Normurodov Mr.

Chemical Technology, Control and Management

The article discusses methods to ensure the stability of the design reliability of a rural telecommunications network during its operation. In rural areas, for a number of reasons, the power supply from the power supply network is interrupted at random times. In this regard, backup power sources are provided for the power supply of OLT equipment. To provide a telecommunication network with stable power supply, it is proposed to use solar sources of electricity.

Study Of Temperature Profile In Drying Process, Shaxnoza Abduvaxitovna Sultanova, Jasur Esirgapovich Safarov, Tojiniso Tursunboyevna Raxmanova

Chemical Technology, Control and Management

The article describes the simulation of the temperature field in a wide range of structural and operational parameters of the drying process. A qualitatively new representation of the temperature field profile in the chamber is revealed. As a result of the experiments, criteria were found for the unevenness of the temperature profiles on the pallets of the dispersion of the temperature of the material and the slope of the approximating line at fixed values of the average temperature of the substance. In the course of the work, an interrelation between the criteria of unevenness was revealed, which is clearly manifested …

Electronic Spam Filtering Based On Neural Networks, Tulkun Fayzievich Bekmuratov, Fayzullajon Bakhtiyorovich Botirov, Elshod Dilshod Ugli Haydarov

Chemical Technology, Control and Management

This article analyzes the problem of filtering spam messages and addressing spam messages, Bayesian theorems based on artificial intelligence, LVQ algorithms (LVQ learning vector quantization) and a filtering scheme for systems based on neural networks. The direct construction of an effective neural network model of spam filtering using database recognition technology is considered. The parameters of access to the neural network how to include predefined statistical and non-statistical attributes of messages are given. The structure of neural network technology for classifying emails is also considered. The procedure for analyzing incoming data using the tool included in the analytical platform Deductor …

Distributed Information Space As An Associative Environment Of Communication Setting, Yusupbekov Rustambekovich Nodirbek, Shukhrat Manapovich Gulyamov, Nargiza Baxtiyorbekovna Usmanova, Malika Yuldashovna Doshchanova

Chemical Technology, Control and Management

Modeling the structure of a distributed network can be based on the architecture of an associative infocommunication network, which displays the processes and mechanisms of interaction of components in the corresponding nodes of the structure. It is shown that for the description and functional representation of a distributed network, it is appropriate to apply decomposition for the field of software engineering, the purpose of which is to create theories that interact with each other according to well-defined rules. A conceptual representation of the distributed space behavior model is given. The paper discusses the modeling of the evolutionary search.

Image Processing Of Technological Objects, Lyudmila Petrovna Varlamova

Chemical Technology, Control and Management

The article considers the problem of creating a smoke detection and fire detection system for technological objects. Fire detection is carried out using a vision system. Monitoring of technological objects is carried out using an unmanned aerial vehicle. For further actions, processing and classification of images is necessary. When observing the technological apparatuses of the chemical and petrochemical industry, problems arise associated with the large size, distribution and extent of objects. There may be situations in which there are violations of the technological regulations and, as a result, the occurrence of fire, fire and smoke. Using the technology of unmanned …

Synthesis Of Carbide Ceramics Via Reduction And Carburization Of Oxyanions Adsorbed Onto An Activated Carbon Matrix, Grant Wallace

Graduate Theses & Non-Theses

Carbide ceramics rank high among the hardest and most chemically resistant materials. Their ability to resist physical and chemical attack under conditions where more traditional materials fail make them very desirable for a number of industrial applications. Their use is limited, however, due to the expensive and energy-intensive methods required to produce them commercially.

A more versatile and energy-efficient process for commercial carbide production has been developed by synthesizing micron/sub-micron carbide ceramic particles through the adsorption and subsequent carburization of anions on an activated carbon matrix. Oxyanion solutions containing sodium tungstate, sodium molybdate, or sodium metasilicate are adsorbed onto activated …

A Study Of The Thermodynamics Of Small Systems And Phase Transition In Bulk Square Well-Hard Disk Binary Mixture, Gulce Kalyoncu

Graduate Theses and Dissertations

Under the umbrella of statistical mechanics and particle-based simulations, two distinct problems have been discussed in this study. The first part included systems of finite clusters of three and 13 particles, where the particles are interacting via Lennard Jones potential. A machine learning technique, Diffusion Maps (DMap), has been employed to the large datasets of thermodynamically small systems from Monte Carlo simulations in order to identify the structural and energetic changes in these systems. DMap suggests at most three dimensions are required to describe and identify the systems with 9 (N = 3) and 39 (N = 13) dimensions. At …

Nonlinear Dimensionality Reduction For The Thermodynamics Of Small Clusters Of Particles, Aditya Dendukuri

Graduate Theses and Dissertations

This work employs tools and methods from computer science to study clusters comprising a small number N of interacting particles, which are of interest in science, engineering, and nanotechnology. Specifically, the thermodynamics of such clusters is studied using techniques from spectral graph theory (SGT) and machine learning (ML). SGT is used to define the structure of the clusters and ML is used on ensembles of cluster configurations to detect state variables that can be used to model the thermodynamic properties of the system. While the most fundamental description of a cluster is in 3N dimensions, i.e., the Cartesian coordinates of …

What Difference Does A Catalyst Make?, Tammy Guthrie, Mike Jackson, Holly Haney

High School Lesson Plans

Students will use different catalysts for the decomposition of Hydrogen Peroxide, to determine if different catalysts affect the energy that is generated during the reaction.

Solid Materials Discovery For Thin Films, Oxide Catalysts, And Polymer Sealants, Benjamin Ruiz-Yi

Theses and Dissertations

Solid materials are made up of multiple classes, including metals, ceramics, and polymers. While each class can be developed for general purpose applications or highly specialized, discovery of new materials in order to improve upon desired properties is a non-trivial task for any type of material. A wide variety of materials encompass expansive design spaces, consisting of parameters such as chemical compositions, synthesis conditions, and post-processing. Due to this, narrowing down the design space to fit within a given figure-of-merit and economic viability becomes time consuming at best and infeasible at worst. High-throughput experimentation

High-throughput experimentation (HTE) is a methodology …

Synthesis Of Polyurethane Incorporated By Calcium Oxide And Magnesium Oxide For Heavy Metal Removal From Water, Fard Mohsen Vafaei

Student Works (2020-2029)

Water contaminated by heavy metals such as copper, lead, nickel, and cadmium has significant adverse impacts on receiving water. In recent years, various methods, such as adsorption, chemical precipitation, and ion exchange, have been extensively studied for the elimination of heavy metals. Adsorption is one of the numerously and diversely reported mechanisms of removing heavy metals due to its simplicity and costeffectiveness. In this study, highly permeable rigid polyurethanes (PU) incorporating calcium oxide (CaO) (PU/CaO) composite materials were prepared via a facile and economic one-pot synthesis method and characterized for remediation of heavy metal from water. To investigate the effect …

Developing A New Formula For Predicting Oil Recovery Factor In Water Flooded-Heterogeneous Reservoirs, Mohamed Khaled Aljifri

Theses

In this work, two sets of empirical correlations were developed for predicting the recovery factor (RF) in water-flooded layered oil reservoirs. The first set of these correlations encompasses four key parameters believed to have a significant impact on waterflooding performance, namely, reservoir heterogeneity (permeability variation coefficient), injected water viscosity, permeability anisotropy (ratio of vertical permeability to horizontal permeability), and water injection rate. This first set consists of two expanded forms, one for predicting the RF at water breakthrough time (BT) and the other for predicting the RF at the end of the project (EOP). Out of the aforementioned four key …

The Response Of Synechococcus Sp. Pcc 7002 To Micro-/Nano Polyethylene Particles - Investigation Of A Key Anthropogenic Stressor, Mary C. Machado, Gina V. Vimbela, Tania T. Silva-Oliveira, Arijit Bose, Anubhav Tripathi

Chemical, Biomolecular, and Materials Engineering Faculty Publications

Microplastics or plastic particles less than 5 mm in size are a ubiquitous and damaging pol- lutant in the marine environment. However, the interactions between these plastic particles and marine microorganisms are just starting to be understood. The objective of this study was to measure the responses of a characteristic marine organism (Synechococcus sp. PCC 7002) to an anthropogenic stressor (polyethelene nanoparticles and microparticles) using molecular techniques. This investigation showed that polyethylene microparticles and nanoparticles have genetic, enzymatic and morphological effects on Synechococcus sp. PCC 7002. An RT-PCR analysis showed increases in the expression of esterase and hydro- lase genes …

Fundamental Studies Of Oxygen Electrocatalysis In Alkaline Electrochemical Cells, Victoria F. Mattick

Theses and Dissertations

Until recently the world’s main source of energy has been fossil fuels, such as coal and petroleum. However, these energy sources are polluting our planet, becoming scarce and increasingly inaccessible, and are costly to extract. Therefore, much attention has been directed to harvesting clean, abundant, and renewable energy, such as solar rays and wind. However, the intermittency of solar and wind power generation requires an effective energy buffering solution (aka energy storage) to become efficient and reliable. With high efficiency and energy density, rechargeable batteries and reversible fuel cells are two of the best methods for this purpose. Unfortunately, a …

Investigation Of Oxidized Carbon Supported Au Catalysts Synthesized Via Strong Electrostatic Adsorption Of Au(En)2Cl3 For The Hydrochlorination Of Acetylene To Vinyl Chloride Monomer, Sean Reginald Noble

Theses and Dissertations

Over 20 million tons of vinyl chloride monomer (VCM) is produced every year using acetylene hydrochlorination using a supported mercuric chloride catalyst. During this process mercury is reduced and sublimes into the environment harming all living animals and humans, so carbon-supported Au catalysts have been developed in attempts to replace it. Various techniques have been used to make these catalysts including several variations of dry impregnation. In this study we investigate the ability of Strong Electrostatic Adsorption (SEA) of Au(en)₂Cl₃ onto various supports to demonstrate the ability to rationally and consistently synthesize gold catalysts with ultra-small particle …

Theoretical Investigation Of The Biomass Conversion On Transition Metal Surfaces Based On Density Functional Theory Calculations And Machine Learning, Wenqiang Yang

Theses and Dissertations

During the past decades, heterogenous catalyzed conversion of biomass to hydrocarbons with similar or identical properties to conventional fossil fuels has gained significantly academic and industrial interest. However, the conventional heterogeneous catalysts such as sulfided NiMo/Al₂O₃ and CoMo/Al₂O₃ used have various drawbacks, such as short catalyst lifetime and high sulfur content of product. To overcome the limitations of the conventional sulfided catalysts, new catalysts must be developed, which requires a better understanding of the reaction mechanism of the biomass conversion. Based on density functional theory, in this thesis, we reported a computational calculation study …

Simulation And Optimal Control Of Crude Oil Separation Process At Offshore Facilities To Improve Efficiency Of Oil And Condensate Recovery, Yee Kai Chin

Student Works (2020-2029)

Crude oil separation process is the most crucial process in offshore production facilities in ensuring the well fluid is separated efficiently and persistently. Waxy crude or sluggish feed stream is the major disturbance that could cause operational issues and production loss due to process upset. The main objective of this research is to model offshore crude oil separation process and introduce state space control to optimize the control of total liquid and water level within the permissible range as well as to evaluate the effect of disturbances to the controls. This work presents two different modelling methods in developing three-phase …

Syntheses, Characterisations And Electrochemical Studies Of Nickel(Ii) And Cobalt(Ii)-Ligand Assisted Cooperative Complexes, Subramaniam Jeevithra Dewi

Student Works (2020-2029)

A newly designed tetradentate ligand L1 (L1 = 3,6-bis(pyrazol-1-yl)-pyridazine) which offers multinucleation sites on its moiety structure has been prepared. The reaction of L1 with different molar ratio of nickel and cobalt salts lead to the formation of di- and tetranuclear complexes [NiII 2(L1)2(CH3CN)4](PF6)4 (1), [NiII 4(L1)4(μ-OH)4](ClO4)4 (2) and [CoII/III(L1)4(μ-CH3O)2(μ-O)2](PF6)3(NO3) (3), which served as the attempt to design of catalysts based on cheap and earth-abundant metals for carbon dioxide reduction. The presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as the base controls the nuclearity of the complex formation. In the absence of DBU, complex 1 was formed in dinuclear fashion whereas complex 2 …

Physical And Chemical Characteristics Of Supramolecular Complexes Of Glycirrizinic Acid With Phytohormones, Djuraev Tulqin, Esanov Rakhmatillo, Gafurov Makhmudjon, Kushiev Khabibjon

CHEMISTRY AND CHEMICAL ENGINEERING

The process of formation of supramolecular complexes of glycyrrhizinic acid with some phytohormones (indolylacetic acid, indolylbutyric acid, α-naphthyl acetic acid and kinetin) were studied with the aim of creation the plant growth stimulator. The complexes structure was studied using IR and UV spectroscopy methods. The prepared compounds described by some physicochemical parameters. The stability constants and stoichiometric composition of complexes were determined in an aqueous solution at pH of 7,2 using UV spectrometry method. In result, all complexes have composition as 1:1 ratio, except the kinetin complex which has 2:1 ratio. The stability constants were equal: KGA:IAA=1,86±1×104; KGA:IBA=2,51±1×103; KGA:NAA =2,70±1×103 …

Study Of The Process For The Removal Of Dyeing Matters Of The Plant Occimum Basilicum L. Lamiaceae, Usmonjonova Khulkar, Atkhamova Saida, Dodaev Kuchkor

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the work is dedicated isolation of anthocyanins by ethanol from herbal plant of Occimum basilicum L. Lamiaceae basis. The were studied influencing of temperature, concentration of ethanol to isolation of anthocyanins. There were passed investigations on studying influence level of heating and hydromodule system of rav material-solvent to maximal isolating of anthocyanins. The colors define by fotokolorometrical method at wave length 400-600 nm. There are shown at 540 nm maximal peak of anthocyanins and it is geven as a grapfical diagram. From the obtained depends on content of alcohol in aquatic solution from outlet of colors is …

The Research Of Conditions For The Formation Of Phenol Formaldehyde Resins Modified With Hydroxyl Containg Polyether Polyol, Magrupov Farkhad, Umarov Sherali, Tohirov Murodjon, Radjabova Zukhra

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the study was to study the conditions of copolycondensation of phenol alcohol with hydroxyl-containing polyether polyol in the presence of maleic anhydride chain extender in order to obtain modified thermoset phenolic-formaldehyde oligomers. Investigation of the dependence of the content of free phenol, formaldehyde and methylol groups on time during the synthesis of the modified phenol-formaldehyde resin with the ratios hydroxyl-containing polyether polyol:phenol alcohol 1:60 mol/mol and 1:100 mol/mol. It was revealed that maleic anhydride, present in the reaction medium as a copolycondensation catalyst, also participates in copolycondensation reactions as a chain extender. Moreover, as the molar fraction …