Engineering Commons^™

Analysis Of Errors Of The Ultrasonic Level And Increasing The Accuracy Of Measuring The Level Of Liquid Materials In Non-Stationary Media, Azamat Alijonovich Yusupov

Chemical Technology, Control and Management

This article is devoted to the analysis of the total error of an ultrasonic level meter designed to measure the level of liquid materials in order to improve the accuracy of the measuring system in tanks. The components of the total error of the process of measuring transformation of the liquid level are determined and the analysis of the main characteristics is carried out, to reduce the random error of the measurement system, the task of ensuring the accuracy of measurement and control of the level using an ultrasonic level gauge is presented, by averaging the measurement results when calculating …

Formalization Of The Procedure For Choosing The Optimality Criterion And Formulation The Problem Of Ammonium Nitrate Production Control, Husan Zakirovich Igamberdiev, Uktam Farkhodovich Mamirov

Chemical Technology, Control and Management

The article discusses the questions of formalization of the procedure for choosing an optimality criterion and setting the problem of controlling the production of ammonium nitrate. The analysis of the technical and economic features of the considered production is carried out. As a criterion for the efficient operation of ammonium nitrate production, such a technological indicator as specific technological costs for the main stages, determined by the interval of quasi-stationarity of the object, is used, i.e. the time of its stable work. To solve the control problem, it is proposed to use the decomposition of the control problem into a …

Dft Study Of NiM@Pt1AuN-M-1 (N=19, 38, 55, 79; M = 1, 6, 13, 19) Core-Shell Orr Catalyst, Wen-Jie Li, Dong-Xu Tian, Hong Du, Xi-Qiang Yan

Journal of Electrochemistry

The slow kinetics of oxygen reduction reaction (ORR) limits the performance of low temperature fuel cells. Thus, it needs to design effective catalysts with low cost. Core-shell clusters (CSNCs) show promising activity because of their size-dependent geometric and electronic effects. The ORR activity trend of Ni_m@Pt₁Au_n-m-1(n = 19, 38, 55, 79; m = 1, 6, 13, 19) was studied using the GGA-PBE-PAW methods. The adsorption configurations of *O, *OH and *OOH were optimized and the reaction free energies of four proton electron (H⁺ + e^-) transfer steps …

One-Pot Synthesis Of Fe2O3@Fe-N-C Oxygen Reduction Electrocatalyst And Its Performance For Zinc-Air Battery, Hua Lin, Yi-Jin Wu, Jun-Tao Li, Yao Zhou

Journal of Electrochemistry

Oxygen reduction reaction (ORR) plays a profound role in determining cathode performance in metal-air batteries and fuel cells. Owing to its inherently sluggish kinetics, high-performance ORR catalysts which favors the scissoring of O-O bond and formation of O-H bond are a requisite. In this regard, Pt has been explored as the most efficient ORR electrocatalysts. Nevertheless, due to its expensiveness, the usage of Pt catalysts represents one of the major sources of cost in those energy conversion devices. Thus, the development of alternative ORR electrocatalysts with minimized Pt utilization has been widely pursued over the past few decades. Metal-nitrogen-carbon catalysts …

Preparation And Electrochemical Evaluation Of Mos2/Graphene Quantum Dots As A Catalyst For Hydrogen Evolution In Microbial Electrolysis Cell, Hong-Yan Dai, Hui-Min Yang, Xian Liu, Xiu-Li Song, Zhen-Hai Liang

Journal of Electrochemistry

Microbial electrolysis cell (MEC) is a relatively new bioelectrochemical technology that produces H₂ and meanwhile treats organic wastewater. Cathode hydrogen evolution catalyst plays a key role in MEC. The doping of Graphene Quantum Dots (GQDs) into MoS₂ nanosheets can improve the catalytic activity of MoS₂ by creating abundant defect sites both in the edge plane and the basal plane, as well as enhancing the electrical conductivity. In this paper, using Na₂MoO₄ , cysteine and GQDs as raw materials, a series of MoS₂/GQDs composites were firstly synthesized via hydrothermal method, and then loaded …

Preparation Of Coo/Rgo@Ni Foam Electrode And Its Electrocatalytic Reduction Of Co2, Qian Guo, Jia-Long Fu, Cheng-Yan Zhang, Chao-Yue Cai, Cheng Wang, Li-Hua Zhou, Rui-Bo Xu, Ming-Yan Wang

Journal of Electrochemistry

The worldwide extensive release of carbon dioxide (CO₂) has caused serious environmental pollution and unprecedented climate change problems. Thus, for the sustainable development of human society, it is very necessary to convert CO₂ to renewable fuels through clean and economical processes. The electrochemical CO₂ reduction reaction (CO₂RR) is regarded as a promising approach for the recycling of carbon resource and the generation of sustainable fuels. However, the slow kinetics and formation of multiple products in CO₂RR hinder its large-scale application. Hence, great research efforts are made to develop electrocatalysts with high product …

No Ordinary Proteins: Adsorption And Molecular Orientation Of Monoclonal Antibodies, Ankit D. Kanthe, Andrew Ilott, Mary Krause, Songyan Zheng, Jinjiang Li, Wei Bu, Mrinal K. Bera, Binhua Lin, Charles Maldarelli, Raymond S. Tu

Publications and Research

The interaction of monoclonal antibodies (mAbs) with air/water interfaces plays a crucial role in their overall stability in solution. We aim to understand this behavior using pendant bubble measurements to track the dynamic tension reduction and x-ray reflectivity to obtain the electron density profiles (EDPs) at the surface. Native immunoglobulin G mAb is a rigid molecule with a flat, “Y” shape, and simulated EDPs are obtained by rotating a homology construct at the surface. Comparing simulations with experimental EDPs, we obtain surface orientation probability maps showing mAbs transition from flat-on Y-shape configurations to side-on or end-on configurations with increasing concentration. …

Merging Of Horizontally And Vertically Separated Small-Scale Buoyant Flames, Thomas H. Fletcher, Denver Haycock, Seth Tollefsen, David Lignell

Faculty Publications

The purpose of this study was to investigate the merging behavior of small-scale buoyant flames that might be representative of flames from a leaf in a shrub. Zirconia felt pads soaked in n-heptane were suspended on thin rods and spaced both horizontally and vertically. Time-dependent video images from flames from two-pad and three-pad configurations were analyzed to determine merging probability, combined flame characteristics (height, area, and width), and changes in burn time. Correlations of these combined flame characteristics were developed based on horizontal and vertical spacing between the pads. Merging probability correlated with an exponential function that was quadratic in …

Engineering The Surface Of Fe3o4 Nanoparticles For Catalytic And Magnetic Applications, Natalia Da Silva Moura

LSU Doctoral Dissertations

With the rapid depletion of the U.S. energy resources coupled with population growth, heat management technologies must be improved to sustain our quality of life. Precisely, in catalysis, it is estimated that only ~50% of the energy supplied to the reactor is used for product conversion due to dissipation losses. Among the emerging technologies with a promising reduction in heat losses is induction heating, offering targeted heat delivery with magnetic nanoparticles. Under alternating magnetic fields (AMF), these nanoparticles can absorb the energy from Radio-Frequency (RF) fields and dissipate it as heat on the nanoparticle surface. This in situ heat generation …

Gum Arabic-Capped Silver Nanoparticles For Electrochemical Amplification Sensing Of Methylene Blue In River Water, Ziad Khalifa, Moustafa Zahran, Magdy Zahran, Magdi Abdelazzem

Chemical Engineering

Herein, a novel electrochemical amplification sensor is developed for detecting methylene blue (MB) us- ing gum Arabic-capped silver nanoparticles (AgNPs) for the first time. Gum Arabic-AgNPs were fabricated via a direct chemical reduction technique using silver nitrate as an AgNPs precursor and gum Arabic as a reducing and capping agent. They were characterized using ultraviolet-visible (UV–Vis) spectrophotom- etry, square wave voltammetry (SWV), and transmission electron microscopy (TEM). UV–Vis and SWV results show the characteristic absorption and electrochemical oxidation peaks of the AgNPs at 431 nm and 0.18 V, respectively. Additionally, TEM images of the AgNPs show that they are spherical …

Analytical Model For Electromagnetic Induction In Pulsating Ferrofluid Pipe Flows, Huiyu Wang, John G. Monroe, Swati Kumari, Serhiy O. Leontsev, Erick S. Vasquez, Scott M. Thompson, Matthew J. Berg, Dibbon Keith Walters, Keisha B. Walters

Chemical and Materials Engineering Faculty Publications

No abstract provided.

Elementary Reaction-Based Kinetic Model For The Fate Of: N -Nitrosodimethylamine Under Uv Oxidation, Benjamin Barrios, Divya Kamath, Erica Coscarelli, Daisuke Minakata

Michigan Tech Publications, Part 1

UV photolysis is an effective process to remove nitrosamines from contaminated water resources. Nitrosamines represent a class of compounds with high potential for carcinogenicity and, therefore, there are serious concerns regarding their threat to human health and their environmental toxicity. Although the photochemical parameters of parent nitrosamines and their initial reaction pathways are well understood, the fate of nitrogen-containing species and reactive nitrogen species generated from nitrosamine degradation has not yet been elucidated. In this study, we develop an elementary reaction-based kinetic model for the photolysis of N-nitrosodimethylamine (NDMA) and the photochemical transformation products. We use density functional theory quantum …

Novel Method Of Manufacture Of Metal Nanoparticles And Metal Single-Atom Materials On Various Substrates And Novel Compositions, Xinhua Liang, Xiaofeng Wang

Chemical and Biochemical Engineering Faculty Research & Creative Works

The present invention discloses a novel method and novel compositions comprising well-dispersed particulate metal materials, including metal nanoparticles and/or metal single-atom materials, on various substrates, said method comprising the use of atomic layer deposition (ALD) and optimization of the metal precursor dose time and the number of ALD cycles. Illustrative of the metals are Fe, Ni, Co, Ru, Rh, Ir, Os, Pt, Pd, and the like; and illustrative of the various substrates are carbon nanotubes (CNTs) (including multi-walled carbon nanotubes (MWCNTs), SiO₂, TiO₂, alumina, CeO₂, ZnO, ZrO₂, activated carbon, CuO, Fe_{2 …}

Heteroacene-Based Amphiphile As A Molecular Scaffold For Bioimaging Probes, Tharindu A. Ranathunge, Mahesh Loku Yaddehige, Jordan H. Varma, Cameron Smith, Jay Nguyen, Iyanuoluwani Owolabi, Wojciech Kolodziejczyk, Nathan I. Hammer, Glake Hill, Alex Flynt, Davita L. Watkins

Faculty and Student Publications

The challenges faced with current fluorescence imaging agents have motivated us to study two nanostructures based on a hydrophobic dye, 6H-pyrrolo[3,2-b:4,5-b’]bis [1,4]benzothiazine (TRPZ). TRPZ is a heteroacene with a rigid, pi-conjugated structure, multiple reactive sites, and unique spectroscopic properties. Here we coupled TRPZ to a tert-butyl carbamate (BOC) protected 2,2-bis(hydroxymethyl)propanoic acid (bisMPA) dendron via azide-alkyne Huisgen cycloaddition. Deprotection of the protected amine groups on the dendron afforded a cationic terminated amphiphile, TRPZ-bisMPA. TRPZ-bisMPA was nanoprecipitated into water to obtain nanoparticles (NPs) with a hydrodynamic radius that was comparison, TRPZ-PG was encapsulated in pluronic-F127 (Mw = 12 kD), a polymer surfactant …

Electrochemical Micro-Aptasensors For Exosome Detection Based On Hybridization Chain Reaction Amplification, Wenfen Zhang, Zhenhua Tian, Shujie Yang, Joseph Rich, Shuaiguo Zhao, Mikael Klingeborn, Po-Hsun Huang, Zhishang Li, Alexander Stout, Quinn Murphy, Edward Patz, Shusheng Zhang, Guozhen Liu, Tony Jun Huang

Faculty Publications

Exosomes are cell-derived nanovesicles that have recently gained popularity as potential biomarkers in liquid biopsies due to the large amounts of molecular cargo they carry, such as nucleic acids and proteins. However, most existing exosome-based analytical sensing methods struggle to achieve high sensitivity and high selectivity simultaneously. In this work, we present an electrochemical micro-aptasensor for the highly sensitive detection of exosomes by integrating a micropatterned electrochemical aptasensor and a hybridization chain reaction (HCR) signal amplification method. Specifically, exosomes are enriched on CD63 aptamer-functionalized electrodes and then recognized by HCR products with avidin-horseradish peroxidase (HRP) attached using EpCAM aptamers as …

Threshold Concentration And Random Collision Determine The Growth Of The Huntingtin Inclusion From A Stable Core, Sen Pei, Theresa C. Swayne, Jeffrey F. Morris, Lesley Emtage

Publications and Research

The processes underlying formation and growth of unfolded protein inclusions are relevant to neurodegenerative diseases but poorly characterized in living cells. In S. cerevisiae, inclusions formed by mutant huntingtin (mHtt) have some characteristics of biomolecular condensates but the physical nature and growth mechanisms of inclusion bodies remain unclear. We have probed the relationship between concentration and inclusion growth in vivo and find that growth of mHtt inclusions in living cells is triggered at a cytoplasmic threshold concentration, while reduction in cytoplasmic mHtt causes inclusions to shrink. The growth rate is consistent with incorporation of new material through collision and coalescence. …

Droplet And Particle Dynamics In Aerosol Reactors And Environmental System, Sukrant Dhawan

McKelvey School of Engineering Graduate Student Theses & Dissertations

Aerosol science and engineering is an enabler for continual advances in nanomaterial synthesis. The spray-based techniques have been used extensively for the large-scale production of nanoparticles. Synthesis of particles with a desired the size and morphology is of key importance for exploiting their properties for their use in several emerging technologies. In contrast to useful nanomaterials, the aerosols from industrial flue gas, dust, indoor cooking, pathogens, and wildfire etc. are harmful to human health. It is important to understand how these harmful aerosols travel through the environment and potentially impact the health. It is also very critical to improve the …

Influence Of Aerosols During Amine-Based Co2 Capture: Evolution And Control, David Immanuel Arthur Dhanraj

McKelvey School of Engineering Graduate Student Theses & Dissertations

Driven by escalating concerns on global warming and climate change, significant efforts have recently been initiated to reduce atmospheric CO2 concentration. Power generation from fossil fuels is the largest source of anthropogenic CO2. The US government has incentivized carbon capture through Section 45Q Tax code, which provides US$50/tCO2 (per metric ton) of qualified carbon dioxide captured and sequestered, as tax credits. The cost for carbon capture, transport and sequestration is US$75 – 150/t CO2, with the state-of-the-art capture technology costing between US$20 – 100/t CO2. Amine based post-combustion CO2 capture is the most economic technology suited for large power plants. …

Direct Activation Of Light Alkanes To Value-Added Chemicals Using Supported Metal Oxide Catalysts, Md Ashraful Abedin

LSU Doctoral Dissertations

One of the most challenging aspects of modern-day catalysis is the conversion of methane. Direct conversion of methane via dehydroaromatization (MDHA) is a well-known process which can produce valuable hydrocarbons. Mo oxide supported on ZSM-5/MCM-22 has been studied extensively in recent years for MDHA. Mo carbides are responsible for activating methane by forming CHx species. These are dimerized into C2Hy and oligomerized on ZSM-5/MCM-22 Brønsted acid sites to form aromatics. Sulfated zirconia (SZ) supported Mo catalyst contains the acid sites necessary to produce benzene in MDHA. Here, sulfated hafnia (SH), a homologous oxide like SZ, has been proposed to provide …

Rapid Computation Of Effective Conductivity Of 2d Composites By Equivalent Circuit And Spectral Methods., Ben J. Ransom, Dean R. Wheeler

Faculty Publications

This work presents models for homogenizing or finding the effective transport or mechanical properties of microscale composites formed from highly contrasting phases described on a grid. The methods developed here are intended for engineering applications where speed and geometrical flexibility are a premium. A canonical case that is mathematically challenging and yet can be applied to many realistic materials is a 4-phase 2-dimensional periodic checkerboard or tiling. While analytic solutions for calculating effective properties exist for some cases, versatile methods are needed to handle anisotropic and non-square grids. A reinterpretation and extension of an existing analytic solution that utilizes equivalent …

Comparison Of Concrete And Steel Jacket Methods For Reinforcing A Concrete Bridge Pier By Numerical And Experimental Studies, Hadi Faghihmaleki

Makara Journal of Technology

Various rehabilitation and strengthening procedures have been developed in recent decades. A study to determine which methods can be implemented to increase the useful life of the bridge before strengthening must be performed. In this study, the seismic behavior of a reinforced concrete bridge pier with dimension 3.5 × 3.5 m, which was reinforced by two steel and a concrete jacket, was investigated. Nonlinear geometric models and materials were analyzed to estimate the seismic parameters of the pier. Results show an increase in energy absorption, ultimate strength, and ductility for the steel jacket, as well as a greater increase in …

Effect Of Arc Plasma Sintering On The Structural And Microstructural Properties Of Fe-Cr-Ni Austenitic Stainless Steels, Parikin Parikin, M. Dani, A. Dimyati, N. D. Purnamasari, B. Sugeng, M. Panitra, A. Insani, T. H. Priyanto, S. Mustofa, Syahbuddin Syahbuddin, A. Huang

Makara Journal of Technology

X-ray diffraction techniques were performed to determine the actual crystal structure of A2 austenitic stainless steel (ASS) as-cast and A2 ASS after arc plasma sintering (APS) for 2 s. Computations were conducted on the basis of the Bragg arithmetic formula by comparing the S2 arithmetic with the interplanar spacing. The Bragg arithmetic formula is a simple series for the determination of the crystalline phase of materials based on the Miller indices of cubic shapes or other shapes. A2 ASS as-cast was identified to have a crystal structure of face-centered cubic with lattice parameter a = 3.58 Å. A similar crystal …

Trend Significance Levels Of Rain Onset And Cessation And Lengths Of The Wet And Dry Seasons In Epe, Lagos State, Nigeria, Adekunle Adedeji Alli, Olorunwa Eric Omofunmi

Makara Journal of Technology

This study aims to reduce crop failure resulting from a dry spell, which is the first occurrence of unsustainable rainfall that deceives farmers into planting. Thus, trends need to be tested using hypothesis, kurtosis, and other statistics to analyze the risks associated with unstable planting calendars and their possible mitigation strategies. The daily rainfall data from 1982 to 2018 were obtained from the archive of NASA/POWER SRB/FLASH, and the research location is Epe, Lagos State, Nigeria, which lies at latitude 6.585° N and longitude 3.962° E. Microsoft Excel was used to perform the tests. Results show that the null hypothesis …

Kinetic Modeling Study Of Laminar Burning Velocity Of Gasoline–Ethanol–Methanol Blends At Elevated Temperature And Pressure, Ahmad Syihan Auzani, Cahyo Setyo Wibowo, Riesta Anggarani, Yulianto Sulistyo Nugroho, Bambang Sugiarto

Makara Journal of Technology

Gasoline–ethanol–methanol (GEM) blends have been considered to replace pure gasoline as spark ignition engine fuel. Their physical and chemical properties and performance and emission measurements from real engines have been reported previously. However, a fundamental study that can explain the unique results of GEM compared with those of pure gasoline is lacking. This study aims to compare the laminar burning velocity of GEM blends at different mixtures, equivalence ratios, temperatures, and pressures with that of pure gasoline. A laminar flame propagation model and reaction mechanisms from the literature were were for a numerical simulation. In this study, the chemical components …

Improvement Of Electrical Properties Of Cmc-Pva Doped With Various Contents Of Lino3 As An Application For Hybrid Polymer Electrolytes, Amalia Zulkifli, Norfatihah Mazuki, Ahmad Salihin Samsudin

Makara Journal of Technology

The present work was carried out with the development of hybrid polymer electrolytes (HPEs) by using carboxymethyl cellulose (CMC)–polyvinyl alcohol (PVA) doped with different contents of lithium nitrate (LiNO3) for the determination of their structural and conduction properties. The structural analysis was conducted by using Fourier transform infra-red spectroscopy and showed the interaction between the blend host polymer and ionic dopant, which formed via the coordinating site of CMC-PVA and Li+-NO3−. The complexes of CMC-PVA doped LiNO3 led to an increment in ionic conductivity, as observed by electrical impedance spectroscopy, and the sample containing 20 wt% LiNO3 obtained the highest …

Music Information Retrieval Based On Active Frequency, Hardianto Wibowo, Wildan Suharso, Yufis Azhar, Galih Wasis Wicaksono, Agus Eko Minarno, Dani Harmanto

Makara Journal of Technology

Music is the art of combining frequencies. A balance of frequencies gives rise to a harmonious tone. Several features of music can be analyzed, and they include sociocultural background, lyrics, mood, tempo, rhythm, harmony, melody, timbre, and instrumentation. In this study, we use the frequency of instrumentation as a feature for classification because each instrument has a frequency range. To test this frequency range, we use five music genres and one music playing skill. The five genres are dangdut, electronic dance music (EDM), metal, pop/rock, and reggae. The music playing skill is acoustic. Active frequencies are tested using the k-nearest …

Predictive Delivery Man Assignment Problem Using Deep Learning, Rahmadini Payla Juarsa, Taufik Djatna

Makara Journal of Technology

Dispatching is a critical part in current online shopping. It relates to how the delivery man assignment should minimize cost along with the service from a source to an end customer with an appropriate scheduled time. The problem arises as neither enough products to deliver nor delivery men are available for dispatch, resulting in suboptimal service and a waste of money. The study aimed to formulate the cost of restaurant dispatching for inducing a deep learning-based solution with the gated recurrent unit recurrent neural network to receive hourly order data and to engage the result for near feature delivery man …

Life Cycle Impact Assessment Of Biofuels Derived From Sweet Sorghum In The U.S., Karla G. Morrissey, Greg Thoma, Dora E. Lopez

Chemical Engineering Faculty Publications and Presentations

Background

The objective of this study was to evaluate the environmental impact of the production of a range of liquid biofuels produced from the combination of fermenting sorghum stalk juice (bioethanol) and the pyrolysis/hydrotreatment of residual bagasse (renewable gasoline and diesel). Life cycle impact assessment (LCIA) was performed on a farm-to-wheels system that included: (i) sorghum farming, (ii) juice extraction, (iii) juice fermenting, (iv) bagasse pretreatment, (v) bagasse thermochemical treatment (pyrolysis, hydroprocessing, and steam reforming), and (vi) typical passenger vehicle operation. LCIA results were compared to those of petroleum fuels providing the equivalent functional unit—cumulative kilometers driven by spark ignition …

The Effects Of Ceria Loading On Three-Way Catalysts For Passive Scr Operation, Calvin R. Thomas, Josh A. Pihl, Vitaly Y. Prikhodko, Michelle K. Kidder, Jochen A. Lauterbach, Todd J. Toops

Faculty Publications

Passive SCR systems, which employ both a three-way catalyst and SCR catalyst, are effective for the reduction of nitrogen oxide (NOx) emissions from lean burn gasoline engines. However, questions remain regarding the effect of three-way catalyst formulations on their performance in these systems. Here, Pd/CeOx/Al2O3 catalysts with variable CeOx loading were synthesized, characterized, and evaluated to determine the effects of CeOx on catalyst performance. While a small amount of ceria was beneficial for promoting essential reactions, excess ceria was detrimental due to the increase in oxygen storage capacity. Additionally, insights into potential reaction pathways for NH3 production were determined.

Aggregation Dynamics Of Bulk Nanoparticle Haloing Systems And The Influence Of Non-Ambient Temperatures., Marzieh Moradi

Electronic Theses and Dissertations

One of the methods of assembling colloids into 3D crystal structures is through the use of nanoparticle haloing. Nanoparticle haloing is a stabilization mechanism in binary particle suspensions possessing both a size and charge asymmetry, with which the nanoparticles aid in the bulk suspension’s stability. By altering the volume fractions of nanoparticles, it is possible to control the effective repulsion between the microparticles. Understanding the colloidal interactions and aggregate crystallinity as a function of nanoparticle concentration, temperature, and time are key challenges in developing future materials and designing crystalized 3D colloidal systems. In this study, we investigated the effect of …