Engineering Commons^™

Advanced Process Modeling And Optimization Of Amine-Based Carbon Capture Process, Paul Jide Terhemba Akula

Graduate Theses, Dissertations, and Problem Reports (ETD)

With the rise of carbondioxide (CO2) concentration in the atmosphere to more than 400 parts per million (ppm), research efforts have been focused on achieving net-zero carbon emission technologies. Post-combustion CO2 capture (PCC) is a key strategy in reducing CO2 emissions. Amine-based CO2 capture is the baseline technology for retrofitting existing power stations. However, the integration of amine-based PCC technology with power plants to reduce greenhouse gas emissions incurs a high energy penalty, decreasing a powerplant’s efficiency by about 23 percentage points. Understanding the capture plant dynamics plays an important role in its technical and economic performance. Rigorous models are …

Immunomodulatory Functions Of Human Mesenchymal Stromal Cells Are Enhanced When Cultured On Hep/Col Multilayers Supplemented With Interferon-Gamma, Mahsa Letter-Mahsa Haseli, David A. Castilla-Casadiego, Luis Carlos Pinzon-Herrera, Alexander Hillsley, Katherine A. Miranda-Munoz, Srikanth Sivaraman, Adrianne M. Rosales, Raj R. Rao, Jorge Almodovar

Chemical Engineering Faculty Publications and Presentations

Human mesenchymal stromal cells (hMSCs) are multipotent cells that have been proposed for cell therapies due to their immunosuppressive capacity that can be enhanced in the presence of interferon-gamma (IFN-γ). In this study, multilayers of heparin (HEP) and collagen (COL) (HEP/COL) were used as a bioactive surface to enhance the immunomodulatory activity of hMSCs using soluble IFN-γ. Multilayers were formed, via layer-by-layer assembly, varying the final layer between COL and HEP and supplemented with IFN-γ in the culture medium. We evaluated the viability, adhesion, real-time growth, differentiation, and immunomodulatory activity of hMSCs on (HEP/COL) multilayers. HMSCs viability, adhesion, and growth …

Machine Learning Based Real-Time Quantification Of Production From Individual Clusters In Shale Wells, Ayodeji Luke Aboaba

Graduate Theses, Dissertations, and Problem Reports (ETD)

Over the last two decades, there has been advances in downhole monitoring in oil and gas wells with the use of Fiber-Optic sensing technology such as the Distributed Temperature Sensing (DTS). Unlike a conventional production log that provides only snapshots of the well performance, DTS provides continuous temperature measurements along the entire wellbore.

Whether by fluid extraction or injection, oil and gas production changes reservoir conditions, and continuous monitoring of downhole conditions is highly desirable. This research study presents a tool for real-time quantification of production from individual perforation clusters in a multi-stage shale well using Artificial Intelligence and Machine …

Quantitative Analysis Of Rate Transient Analysis In Unconventional Shale Gas Reserviors, Gabriel Quintero

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rate Transient Analysis is a quick reservoir modeling solution that has been used throughout the oil and gas industry over its continuous development and has provided breakthroughs for modeling conventional plays for decades. As the Marcellus Shale play continues to be a massive producer of Natural Gas in the world, operators look to find economical yet fairly accurate solutions to develop accurate reservoir models of their wells given the complex nature of unconventional reservoirs. Due to extremely low permeability and heterogeneity along with its complex fracture networks, it becomes an extremely difficult problem to model and predict the fluid flow …

Ethane Dehydrogenation For Light Olefins Production Over Stable Catalyst, Xiaoyan Wang

Graduate Theses, Dissertations, and Problem Reports (ETD)

Accompanied by the development of modern industry, the demand for light olefins (e.g., ethylene, propylene, butene, butadiene) increases year by year. Light olefins are important intermediates in producing polymers (Polyethylene, Polypropylene, etc.) and rubber (Styrene Butadiene Rubber, Polybutadiene rubber, etc.). The primary process for the production of light olefins is steam cracking of petroleum liquids (naphtha and distillate fuel oil). It is an energy-intensive process, requiring high temperature (750-850℃) and pressure (1.0-4.5 MPa). Meanwhile, due to undesired side reactions, this process has lowered the efficiency of light olefins production and suffers from severe coking issues. Furthermore, as petroleum liquids become …

A Workflow For Unconventional Reservoirs Optimization Using Supervised Machine Learning In Conjunction With Orthorhombic Elasticity Modeling, Aymen Ab Ali Alhemdi

Graduate Theses, Dissertations, and Problem Reports (ETD)

Due to the anisotropy and heterogeneous nature of unconventional reservoirs like shale, a comprehensive parametric study to optimize hydraulic fracture treatment for such reservoirs is a tough challenge, especially when natural fractures are present. Most of the current frac simulators do not consider the anisotropy of rock elasticity in the shales. Besides, using the fracture simulation linked with reservoir simulation for the parametric study to understand the impact of multiple different design parameters on fracture propagation and production is time expensive and low efficient. The study proposes a workflow including a new orthorhombic (OB) rock algorithm to interpret geomechanical properties …

Microwave-Assisted Carbon Nanotube Growth From Methane On Surface Catalyst Exsolving Perovskite Oxide, Angela M. Deibel

Graduate Theses, Dissertations, and Problem Reports (ETD)

The novel method of using a perovskite exsolution catalyst, strontium titanium nickel oxide (STNO), proved capable of simultaneously producing carbon nanotubes (CNTs) and CO_x-free hydrogen during methane decomposition under microwave irradiation. An optimization of common perovskite materials was conducted for microwave-responsiveness with the results reported in this study. Out of the materials screened, strontium titanium nickel oxide (STNO) was the best candidate to achieve an acceptable methane conversion rate as well as a decent responsiveness to microwave. STNO was further optimized through Ni content, reduction dwell time, and reduction temperature to produce the best methane conversion and CNT …

Nano-, Encapsulated Manganese Oxide (Nemo) Particles For Mri Enhancement In Microfluidic Tumor Models, Kasey Alexis Freshwater

Graduate Theses, Dissertations, and Problem Reports (ETD)

Breast cancer is among the deadliest cancers in women, with approximately 2.3 million new cases and 685,000 deaths reported globally in 2020 alone. Magnetic Resonance Imaging (MRI) is commonly used to diagnose, stage, and develop treatment plans for patients predisposed to breast cancer. However, current MRI-based screening of breast cancer has high false-positive rates up to 25%, leading to unnecessary invasive follow-up screening and testing. The gold-standard intravenous gadolinium (Gd)-based contrast agents (GBCAs) account for false-positive rates because they are always “ON”, providing a constant MRI signal that highlights both benign and malignant tumors. The work detailed in this thesis …

Reinforcement Learning For Process Control: Applications To Energy Systems, Elijah Ballard Hedrick

Graduate Theses, Dissertations, and Problem Reports (ETD)

Reinforcement learning (RL) is a machine learning method that has recently seen significant research activity owing to its successes in the areas of robotics and gameplaying (Silver et al., 2017). However, significant challenges exist in the extension of these control methods to process control problems, where state and input signals are nearly always continuous and more stringent performance guarantees are required. The goal of this work is to explore ways that modern RL algorithms can be adapted to handle process control problems; avenues for this work include using RL with existing controllers such as model predictive control (MPC) and adapting …

A Vacuum-Driven Distillation Technology Of Aqueous Solutions And Mixtures, Guo Guangyu

Dissertations

Distillation of aqueous solutions and aqueous mixtures has vast industrial applications, including desalination, wastewater treatment, and fruit juice concentration. Currently, two major distillation technologies are adopted in the industry, membrane separation and thermal distillation. However, both of them face certain inevitable drawbacks. Membrane separation has disadvantages as relying on high-grade energy, requiring membrane, fouling problem, narrow treatment range, limited scalability, and vibrating and noisy operating conditions. Traditional thermal distillation technologies can avoid above concerns but has other shortcomings, such as relatively low energy efficiency and yield rate, complicated and bulky system structure, and scaling problem.

This project proposes an innovative …

Hydrodynamic Characterization Of Laboratory And Production Equipment For Pharmaceutical Testing And Manufacturing Using Experimental And Computational Approaches, Chadakarn Sirasitthichoke

Dissertations

The hydrodynamics of process units used in pharmaceutical industry, i.e., the distribution of velocity profiles and shear stresses within the vessel, often controls the process performance, significantly affecting product quality. The hydrodynamics is strongly influenced by several factors such as the vessel shape, stirrer type, presence of internals and baffles, agitation intensity, and liquid properties. Most of these parameters can be varied by the process designers and the operators to achieve the desired process outcomes. The impact of the hydrodynamics on the process outcome can be profound in both large vessels (e.g., reactors) and smaller vessels (e.g., dissolution vessels), involving …

Electric-Field-Driven Processes In Multiphase Fluid Systems, Qian Lei

Dissertations

Advantages of using electric fields in miniaturized apparatuses for a wide range of applications are revealed by numerous experimental and theoretical studies over the last several decades as it offers a simple and efficient method for manipulation of multiphase fluid systems. This approach is considered to be especially beneficial for control of boiling processes and colloidal suspensions considered in the presented work.

Boiling. Today's trends for enhancing boiling heat transfer in terrestrial and space applications focus on removal of bubbles to prevent formation of a vapor layer over the surface at a high overheat. In contrast, this dissertation presents a …

Bodipy Based Photodynamic Therapy And Potassium Probes, Xiangshan Liu

Dissertations

Boron dipyrromethene (BODIPY) has become more and more popular in photophysical and biological applications. BODIPY based fluorescence compounds have numerous advantage properties including low toxicity, high absorption extinction coefficients, high fluorescence quantum yields, sharp fluorescence emissions, and resistance to photobleaching. All the good properties lead to the wide applications of BODIPY based compounds. In this research, two different kinds of BODIPY are synthesized. Firstly, BDBrC containing carbazole and BODIPY core is synthesized. Cellular uptake research shows BDBrC can target on lysosome and singlet oxygen generation research result indicates that BDBrC can be used in photodynamic therapy. BDBrC also shows pH-sensitive …

Flexible Microfluidic Device With Nonplanar Interdigitated Microelectrodes, Saud Alssaidy

Theses

The lab-on-a-chip concept has improved significantly in recent years to meet global demand for various applications with the advent of new technologies. Much progress has been achieved, but many microfluidic devices still suffer from design limitations in terms of sensitivity and selectivity because they use rigid, fragile substrate materials and conventional electrodes, which do not provide high sensitivity or selectivity and suffer from signal-to-noise ratio issues. This work proposes a novel device architecture that uses flexible, transparent top and bottom layers integrated with (nonplanar interdigitated microelectrodes) to create a sandwich-like flexible substrate base. The top and bottom layers consist of …

Itraconazole Nanocomposites Prepared Via Rotary Evaporator Drying Of Nanomilled Suspensions, Alexander Santos Coelho

Theses

The aim of this study is to explore the feasibility of rotary evaporation for drying wetmilled drug suspensions as a novel approach to produce drug nanocomposites that exhibit fast redispersion and immediate drug release. To this end, the physical stability of the nanomilled itraconazole (drug) suspensions, a.k.a., nanosuspensions, during the milling and storage; the drying of the itraconazole nanosuspensions via the rotary evaporator; and the type/loading of various polymers/surfactants (dispersants) on aqueous redispersion and drug release from the nanocomposites were examined. Our results suggest that smaller drug particle size, owing to nanomilling, and smaller nanocomposite particle size, owing to optimized …

Overview On The Lebanese Environmental Governance System: Main Hazards In The Oil And Gaz Sector, Rami Harkous

BAU Journal - Science and Technology

Due to harsh environment and vulnerability of marine ecosystems, many challenges are faced regarding offshore oil and gas activities. Many steps are currently undertaken to overcome such challenges.

As Lebanon is inside the new oil and gas sector in its offshore region, plans should be made to address environmental challenges that may occur in this sector. The Lebanese environmental governance system meets international standards in various aspects but some gaps are addressed to manage such risks that may be encountered with oil and gas activities in the Lebanese offshore. This article ends by a fast run through environmental regulatory authority, …

Removal Of Methylene Blue By Adsorption Of Water Hyacinth Derived Active Carbon Embedded With Cobalt Nanoparticles, Hany A. Elazab, A. O. Okasha, M. A. Radwan, M. A. Sadek, Amin Firouzi, Tamer T. El-Idreesy

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this research, active carbon-based catalyst synthesis and characterization were tested for potential catalysts to be used in dye removal of methylene blue (MB). Water hyacinth is one of the major problems that is facing humankind and especially here in Egypt. One of the implications of industrial activities is environmental pollution. Dyes used in the production of textiles, paper, and clothes are one of the major pollutants. The waste of those dyes discharged into water supplies without treatment or with ineffective treatment harmfully impacts the environment. In this research, the treatment is implemented using active carbon-based catalysts using embedded nanoparticles. …

Scale Model Equations And Optimization For Annular Flow Of Non-Newtonian Fluids Between Eccentric And Rotating Cylinders, Wei Zhang, Pooya Khodaparast, Amin Mehrabian Dr., Amir Shojaei

Progress in Scale Modeling, an International Journal

A broad range of engineering applications involves helical flow of non-Newtonian fluids between two eccentric cylinders. These applications often require estimation of the frictional pressure losses along the axes of the cylinders. Laboratory flow loops are commonly used to study the flow characteristics at smaller scales of investigation. This study uses the laws of similarity and dimensional analysis to obtain a set of scaling equations between the laboratory and prototype scales of the described annular flow. These equations are derived for four types of fluid rheology including Newtonian, power-law, Bingham-plastic, and yield power-law.

Results are expressed through a set of …

Numerical Investigation On The Effect Of Spectral Radiative Heat Transfer Within An Ablative Material, Raghava S. C. Davuluri, Rui Fu, Kaveh A. Tagavi, Alexandre Martin

Mechanical Engineering Faculty Publications

The spectral radiative heat flux could impact the material response. In order to evaluate it, a coupling scheme between KATS - MR and P1 approximation model of radiation transfer equation (RTE) is constructed and used. A Band model is developed that divides the spectral domain into small bands of unequal widths. Two verification studies are conducted: one by comparing the simulation computed by the Band model with pure conduction results and the other by comparing with similar models of RTE. The comparative results from the verification studies indicate that the Band model is computationally efficient and can be used to …

Effect Of Glycol Based Coolant Pollution On Pem Fuel Cells Stack And Recovery Measures, Cong-Yi Zhu, Xiao-Hui Li, Quan-Quan Gan

Journal of Electrochemistry

As the heat conduction medium of fuel cell cooling system, coolant is very important for the thermal management of fuel cell stack. In practical application, coolant leakage into the stack often occurs. Due to the randomness of fault location of components, the location of coolant leakage is uncertain, which may occur on the cathode side or anode side of some or all single cells. The main effects of coolant pollution on fuel cell stack are as follows: the output of open circuit voltage decreases sharply, the consistency of single cells voltage decreases and so on, which seriously affects the normal …

Formation And Morphological Evolution Of Nanoporous Anodized Iron Oxide Films, Jin-Wei Cao, Nan Gao, Zhao-Qing Gao, Chen Wang, Sheng-Yan Shang, Yun-Peng Wang, Hai-Tao Ma

Journal of Electrochemistry

The preparation of iron oxide films with nanoporous structure by anodization has attracted much attention for its potential applications. However, the formation mechanism of porous structure during anodization is still unclear. In this paper, the composition of anodic current during the formation of nanoporous anodized iron oxide film was analyzed in combination with the current density-potential response (I-V curve) and the derivation of Faraday’s law. The results showed that the anodic current consisted of an ionic current (leading to the migration of ions to form oxide) and an electronic current (leading to the oxygen evolution), and the …

Copper Nanoparticles In-Situ Anchored On Nitrogen-Doped Carbon For High-Efficiency Oxygen Reduction Reaction Electrocatalyst, Hui-Fang Yuan, Yue Zhang, Xing-Wu Zhai, Li-Bing Hu, Gui-Xian Ge, Gang Wang, Feng Yu, Bin Dai

Journal of Electrochemistry

Compared with noble metal platinum (Pt)-based catalysts, inexpensive non-noble metal electrocatalysts have attracted extensive attention for oxygen reduction reaction (ORR). Herein, chitosan as a kind of biomass resource rich in nitrogen and carbon was used to prepare nitrogen-doped carbon (N-C) and N-C in-situ anchored by copper nanoparticles (Cu/N-C). The as-obtained N-C and Cu/N-C nanoparticles were successfully used as non-noble eletrocatalysts tested for ORR. Compared with the N-C, the Cu/N-C showed the high surface area of 607.3 m ²·g^-1 with the mean pore size of 2.5 nm and the pore volume of 0.40 cm³·g^{-1 …}

Structure Analysis Of Pemfc Cathode Catalyst Layer, Rui-Qing Wang, Sheng Sui

Journal of Electrochemistry

The sluggish oxygen reduction reaction (ORR) on the cathode of the proton exchange membrane fuel cell (PEMFC) has always been one of the key factors limiting its commercialization. The optimization of the cathode catalytic layer structure plays an important role in improving fuel cell performance and reducing production costs. In this paper, two different catalysts (platinum nanoparticles (Pt-NPs) and platinum nanowires (Pt-NWs)) were prepared by using catalyst coated substrate (CCS) method. By constructing a double-layer catalytic layer structure, we analyzed the effect of different catalytic layer structures by performing a single cell test. The results showed that the dense platinum …

Development Of Asphalt-Resin-Paraffin Deposits Solvent, Gulmira Todjiyeva, F Badriddinova, M Tursunov, H Kadirov, E Cherkasova

Technical science and innovation

A solvent which is a mixture of aromatic hydrocarbons of the C₉ fraction and aliphatic alcohols in a 1:1 ratio, a nonionic surfactant in an amount of 1 - 3% by weight has been developed. It leads to an increase in the dissolving and washing capabilities of the solvent for more than 2 times in relation to paraffin-type AS. The ability of the chemical composition, which is a solvent composition, to have a depressant-dispersing effect in relation to paraffin-type AS has been determined.

Despite a large number of studies devoted to the development of technologies for the removal of …

Research Of New Fireproof Supplied Polymer Composites Based On Epoxy Resin For Metal Structures, Kuvondiq Murtazaev, F.N. Nurkulov, D.N. Mukhiddinov, M.T. Аbdirova

Technical science and innovation

In the article proposes new compositions based on fire retardant expanded polymer composites of epoxy resin ED-20 and phosphorus-containing oligomers, catalysts, aluminum hydroxide and nitrogen-containing compounds.

The obtained sample of fire retardant expanded polymer composites based on epoxy resin, as well as the initial substances, were investigated by IR spectroscopy (Nicolet 5700), thermogravimetric analysis (TG) (SDT Q600) of physical and chemical properties and determination of fire retardant efficiency according to GOST R 53295-2009.

Infrared spectroscopy has been used to determine the bends and epoxy groups that characterize composites, as well as to determine the frequencies of phosphorus, nitrogen, and metal-containing …

Methods Of Improving Complex Cleaning Of Sand Plugs In Khodjaobad Underground Gas Wells, Abdulaziz Murodov, Muhriddin Muydinov, Saidaziz Khabibullaev, Aziz Abidov

Technical science and innovation

The purpose of the study is to develop recommendations for improving the methods of cleaning complex sand plugs in wells of underground gas storage. To organize the correct and efficient use of underground gas storage, the bottom of wells must be kept clean. The article develops recommendations on the use of optimal methods for cleaning wells from complex sand jams on the example of Khujabad UGS. In addition, recommendations were developed for the operation of production wells in the horizons of the XX-XXI-XXII underground gas storage of Khujabad

A Proper Framework For Studying Noise From Jets With Non-Compact Sources, Woutijn J. Baars, Nathan E. Murray, Charles E. Tinney

Faculty and Student Publications

A quantitative assessment of the acoustic source field produced by a laboratory-scale heated jet with a gas dynamic Mach number of 1.55 and an acoustic Mach number of 2.41 is performed using arrays of microphones that are traversed across the axial and radial plane of the jet's acoustic field. The nozzle contour comprises a method of characteristics shape so that shock-related noise is minimal and the dominant sound production mechanism is from Mach waves. The spatial topography of the overall sound pressure level is shown to be dominated by a distinct lobe residing on the principal acoustic emission path, which …

Design Lifecycle Management Of Technological Processes, Yusuf Shodiyevich Avazov

Chemical Technology, Control and Management

The issues of life cycle management of design processes of complex technological processes are considered. An analysis of works devoted to the automated design of technological processes and industries, product life cycle management, and the use of predominant modeling in design is presented. A structure for the implementation of the design of technological processes is proposed and it’s components are described. An algorithm is proposed to reduce the life cycle of the design of a technological process. The sequence of selection of the most optimal project options with the help of the proposed algorithm is described. It is shown that …

Uncertainty Of The Ultrasonic Method For Determining The Strength Of Concrete, Ortagoli Sharipovich Hakimov, Zamira Khudoyberdiyevna Ernazarova

Chemical Technology, Control and Management

The issues of measuring the strength of concrete by the method of surface sounding by ultrasound are considered. A measurement model and formulas for estimating the total standard measurement uncertainty, information about the standards used, measurement tools and methods, and environmental parameters are given. Information about the estimation of uncertainty in the form of "eight steps", such as: measurement task; mathematical model of measurement; analysis of input values; observation results; correlations; uncertainty budget; expanded uncertainty; measurement result. It has been established that the uncertainty of type B of the ultrasonic method for determining the strength of concrete is much less …

Quality Control Of Combustion Of Gaseous Fuel In Furnaces, Azamat Toirovich Rajabov

Chemical Technology, Control and Management

The issues of research and development of systems for monitoring the availability and quality of the process of fuel combustion in industrial furnaces are interpreted. The perspective of using new elements in control systems - communication sensors for the presence and quality in gas-burning installations and furnaces are shown. A method has been developed to control the optimal aeration coefficient based on the extreme of the total integral amplitude-frequency characteristic of the flame conductivity pulsations, which makes it possible to control the quality characteristics of gas-burner devices and control the ratio of the components of the combustible mixture with high …