Engineering Commons^™

High-Surface-Area Ficus Leaf-Extracted Cuo-Zno-Nio Ternary Nanocomposites For Rapid Adsorption-Assisted Uv-A Degradation Of Direct Blue 15, Kafa’A H. Ali, Mohammed A. Atiya, Ahmed K. Hassan

Karbala International Journal of Modern Science

Direct Blue 15 (DB15) is a long-lasting synthetic dye that pollutes water and is difficult to remove during wastewater treatment. Conventional treatments fail to remove DB15 adequately due to rapid electron-hole recombination, which necessitates photocatalysts with reduced recombination rates for effective dye removal. The study aims to synthesize and evaluate a CuO-ZnO-NiO ternary system as an integrated adsorption and UV-A photocatalysis platform for DB15 removal. Ficus leaf-extracted CuO-ZnO-NiO nanocomposites with four Cu:Zn:Ni ratios (1:1:1, 1:1:2, 1:2:1, 2:1:1) were prepared by co-precipitation, followed by extensive chemical and physical characterization and dye-removal performance measurements. The CuO-ZnO-NiO nanocomposite exhibited hexagonal zinc oxide, cubic …

Valorization Of Ductile Cast Iron Solid Waste As A High-Performance Adsorbent For Crystal Violet Removal: Characterization, Optimization, And Mechanistic Insights, Ibrahim Ibrahim Mr., Abdel Mohsen Turky Dr., Nasser Mostafa Prof., Mai H. Roushdy

Chemical Engineering

Industrial textile wastewater containing synthetic dyes cause serious environmental and health risk, whereas ductile cast iron (DCI) foundries generate over 500 000 tons of waste annually. This study utilizes DCI solid waste as an adsorbent to remove the crystal violet (CV) dye from wastewater. Techniques (XRF, XRD, BET, SEM-EDX, FTIR, TGA-DTG, zeta potential) proved that the waste contains 88.0 wt% periclase (MgO) with nanoscale, high surface area, and abundant surface hydroxyl groups. Response surface methodology showed that the most significant parameters were the adsorbent dose and time contact. The optimal conditions give 93.7% removal efficiency at initial concentration: 38.7 mg …

The Design And Manufacturing Process Of The Concealed Shelf, Mexrojiddinbek Sattorov

Honors Theses

This document contains information regarding the design and build process of the Concealed Shelf, which is a furniture product with hidden storage capability. First, the team members decided on the design of the product, followed by market analysis and manufacturing feasibility. Lean manufacturing principles were applied to improve the process efficiency and reduce waste.

Multiple prototypes were built with varying raw materials and locking mechanisms. Jigs and fixtures were handcrafted to ensure more consistent product quality. Two production runs were conducted to evaluate performance and identify areas for improvement.

The final design includes economic considerations, manufacturing layout, and continuous improvement …

The Design And Optimization Of A Styrene Production Plant, Kaylee Hardenstein, Amanda Anderson

Honors Theses

This thesis presents the design and economic optimization of a Styrene Production Plant targeting a capacity of 100,000 tonnes/yr at a product purity of 99.8 wt%. The process relies on the dehydrogenation of ethylbenzene in a packed-bed reactor system. Downstream separation is achieved through a series of cooling, phase separation, and distillation operations to recover styrene while recycling unreacted ethylbenzene and recovering valuable byproducts.

A base case design was developed and evaluated using a process simulation software, Aspen Plus V14, and an economic analysis. Sensitivity analysis identified the styrene market price and ethylbenzene raw material cost as the dominant factors …

Synthesis And Investigation Of Tungsten–Copper Oxide Composites For Enhanced Photocatalytic Applications, Janak Paudel, John Nichols

Research and Creative Works Expo

No abstract provided.

Response Surface Modelling And Multi-Objective Optimisation Of Asphalt Binder And Mixture Properties Modified With Reclaimed Automotive Lubricants And Waste Glass Bottle Powder, Nura Shehu Aliyu Yaro, Jacob Adedayo Adedeji, Luvuno Nkosinathi Jele, Nasir Khan, Aliyu Usman, Jacob Olumuyiwa Ikotun

Journal of Sustainable Construction Materials and Technologies

Large volumes of reclaimed automotive lubricant (RAL) and waste glass bottle powder (WGBP) are disposed of inappropriately, causing serious environmental concerns. Furthermore, the paradigm shift towards sustainability in the pavement industry has prompted academics to investigate alternatives to conventional materials. As a result, one possible approach is to use these waste products as alternative materials in the asphalt pavement sector. This study investigated the combined use of RAL and WGBP as complementary modifiers, extending beyond the conventional single-modifier approaches reported in previous studies. Thus, in this study, response surface methodology (RSM) was utilised to optimise and predict the synergistic effects …

Optimization And Dynamic Control Of Acetone Production From Isopropyl Alcohol, Thomas W. Wasson

Honors Theses

This paper investigates the optimization and dynamic control of acetone production via catalytic dehydrogenation of isopropyl alcohol. Optimization was conducted using steady-state Aspen Plus modeling with product specifications of 30,000 metric tons per year of 99.9% pure acetone by weight. Dynamic modeling of the feed preparation and reaction portions of the process was conducted in Aspen Plus Dynamic. Through optimization efforts the primary economic factor, net present value (NPV), was increased from $(126.6) million to $(83.2) million, representing a $43.4 million increase. This was primarily accomplished through a switch to low temperature catalyst, optimization of reactor dimensions, pressurization of key …

Study Of Pv Panel Degradation Under Extreme Weathering Within Uae Climate Conditions, Maitha Abdulla Almheiri

Thesis/ Dissertation Defenses

The thesis studies monocrystalline and polycrystalline photovoltaic modules under desert operating conditions. The study uses long term outdoor exposure at the UAEU Falaj Hazza campus. Dust deposition, strong temperature variation, and high irradiance shape field performance at the site. The work sets three objectives. Track performance degradation over time. Identify dominant loss mechanisms. Define maintenance strategies supported by experimental data and field observations. The experimental plan uses two module groups. A reference group receives daily cleaning. A test group stays uncleaned across several weeks of exposure. A monitoring system records electrical outputs such as current, voltage, and power. The same …

Design Of Air-Entrained Concrete For Airport Pavements Through Local Aggregate Utilization: Performance Optimization And Economic Analysis, Li Wentao, Rizwan Qadir, Arslan Mushtaq, Hilal Khan, Kamran Jillani

Journal of Sustainable Construction Materials and Technologies

Airport pavement construction in developing countries faces critical challenges balancing international performance standards with economic constraints, while limited research exists on optimizing air-entrained concrete mixes using locally sourced materials for cost-effective solutions. This study investigated the development of economical air-entrained concrete mix designs for airport pavements utilizing Pakistani aggregates and systematic cement content optimization. Comprehensive experimental evaluation included material characterization through petrographic analysis, alkali-aggregate reactivity assessment via accelerated mortar bar testing, and mechanical property development across cement contents from 360-450 kg/m3. Air entrainment was achieved through controlled admixture dosing while maintaining target slump of 50mm. Results demonstrated that locally sourced …

Molybdenum-Doped Zinc Oxide Nanocomposite For Sustainable Photoelectrocatalytic Degradation Of Dyes And Antimicrobial Activity, Samar A. Salim

Nanotechnology Research Centre

Mo-doped ZnO nanocomposite was synthesized by using auto-combustion method. X-ray diffraction patterns of prepared nanocomposite indicated effective construction of crystalline Mo/ZnO NCs with co-existence of MoO2 and ZnO in required weight ratio. XRD results revealed also that ZnO crystallite size decreased as Mo-doping concentration increased. The direct band gap reduced from 3.309 eV of (MZ-0) to 3.258 eV of (MZ-5), demonstrating a negative correlation with Mo-doping levels. The electrocatalytic activity of Mo/ZnO NCs was assessed by their capability to degrade Indigo Carmine (IC) and Murexide (ME) dyes, and their antibacterial properties were also evaluated. The electrocatalytic (EC) degradation efficiencies for …

Turning Down The Heat: Fine-Tuning Tempo-Modified Nanocellulose And Emim-Ac Ionic Liquid Membranes For Kidney Dialysis, Olivia Reid

Chemical Engineering Undergraduate Honors Theses

TEMPO modified nanocellulose membranes are utilized across various laboratory and industrial applications from protein purification to advancements in kidney dialysis. This study investigates the effect of varying coagulation temperatures on the morphology and transport properties of these membranes to enhance their performance for targeted filtration. It was hypothesized that higher temperatures would accelerate the solvent-nonsolvent exchange during phase inversion, resulting in larger pore structures. Conversely, lower temperatures were expected to slow solvent diffusion, yielding smaller, more uniform pores. The membranes[JH1]  were synthesized using 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) to improve selectivity and antifouling characteristics. Scanning electron microscopy (SEM) served as the primary …

Strengthening Kidney Dialysis One Membrane At A Time: Enhancing Tempo-Oxidized Nanocellulose And Ionic Liquid Membrane Strength Through The Variation Of Cosolvents, Bailey M. Butler

Chemical Engineering Undergraduate Honors Theses

Chronic kidney disease occurs when the kidneys lose the ability to effectively filter the blood, which causes waste build up. End-stage kidney disease (ESKD) is the most severe case of kidney disease and requires either dialysis or a kidney transplant. Hemodialysis, the most common form of dialysis, is an extremely time-intensive and physically burdensome process that is currently limited by membrane performance. The polysulfone (PSf) membranes that are widely used for dialysis today have many limitations, including fouling, toxin rejection, and essential protein loss. Recently, new membranes made from TEMPO-Oxidized nanocellulose dissolved in 1-ethyl-3-methylimidazolium acetate (EMIM-Ac) have shown promising characteristics, …

From Kernel To Carbon Footprint: Using Life Cycle Analysis To Teach Sustainability In Chemical Engineering, Neal Z. Kinney

Chemical Engineering Undergraduate Honors Theses

Many chemical engineering departments in the United States are currently lacking developed sustainability coursework, leaving many students without a developed understanding of topics such as life cycle analysis (LCA). [1] Therefore, there is a need for engaging and flexible educational tools that can be easily incorporated into course frameworks. This study develops an interactive learning module, expanding upon the work from Pollution Prevention Through Popcorn, a study developed by Rowan University. [2] The module combines experimental analysis of popcorn popping methods with life cycle assessment using OpenLCA to evaluate the environmental impacts of common types of popcorn packaging. Results of …

Shooting For The Stars: Stem Outreach Strategies Between 2nd And 7th Grade, Paige Miller

Chemical Engineering Undergraduate Honors Theses

Engineering and planetary science outreach programs are increasingly important as industries and research organizations face growing demand for STEM professionals. Despite the importance of these fields, many students receive little exposure to engineering careers during their early educational experiences. This honors thesis examines the effectiveness of interactive STEM outreach presentations designed for elementary and middle school students. Specifically, this study evaluates outreach activities centered on chemical engineering applications and the NASA M2M CO₂ regeneration project for Martian environments.

Two student age groups participated in this study: 2nd grade students at Butterfield Elementary School and 7th grade students at Woodland Junior …

A Baseline Study Of Artificial Intelligence Use Among Chemical Engineering Undergraduates At The University Of Arkansas, Natalie J. Erickson

Chemical Engineering Undergraduate Honors Theses

In recent years, artificial intelligence (AI) has shifted from a novel innovation to a tool used in daily life, particularly within higher education. While anecdotal evidence suggests high levels of student engagement with AI, empirical data regarding usage patterns remains limited. This baseline study investigates AI integration among undergraduate chemical engineering students at the University of Arkansas. Through an anonymous survey (N=68; comprising 20 freshmen, 14 sophomores, 16 juniors, and 18 seniors), researchers assessed usage frequency, student comfort levels, and their evolving relationship with AI tools. The findings reveal that 75% of respondents utilize AI for coursework at least once …

Adsorption Of Pfas On Bridged Functionalized Organosilica Materials, Elisha Lawerh Kabutey

Electronic Theses and Dissertations

PFAS are hazardous contaminants that have a devastating impact on human health and the environment. Their hazardous nature has led to the development of various adsorption methods for removing these contaminants from water sources. In this study, functionalized organosilica materials were synthesized from bis[3-(trimethoxysilyl)propyl] amine using the sol-gel method. The surface amino groups of the organosilica were converted into amine hydrochloride groups. Their adsorption properties were evaluated using salts of perfluorooctanoic acid, perfluorooctanesulfonic acid, and perfluorobutanesulfonic acid. Results showed excellent adsorption capacity of the materials. Adsorption of PFAS leads to particle agglomeration and flotation of the spent material. A column …

Dynamic Mechanical Insertion Analysis Of Gelatin Methacryloyl Microneedles Under Realistic Insertion Conditions, Moloud Amini Baghbadorani, Masoumeh Zargar, Abdellah Shafieian, Majid Tolouei-Rad

Research outputs 2022 to 2026

Despite the great potential of Gelatin Methacryloyl (GelMA) microneedles (MNs) for minimally invasive drug delivery and interstitial fluid extraction, their performance under realistic insertion conditions and across diverse geometrical and mechanical parameters has remained uncharacterized. In this study, dynamic and static finite-element analyses were conducted for the first time to compare three types of crosslinked GelMA MNs: conical, pyramidal, and tapered-conical with and without base support. Insertion force, von Mises stress, and safety factors were evaluated at insertion velocities of 2-6 m/s under varying crosslinking times and polymer concentrations. The tapered-conical geometry demonstrated the best overall mechanical reliability, combining moderate …

Engineered Uio-66-Nh2 Hybrid Nanocomposites For Antifouling Ultrafiltration Membranes With Dual Resistance To Microplastics And Protein Fouling, Mitra Golgoli, Mohadeseh Najafi, Javad Farahbakhsh, Masoumeh Zargar

Research outputs 2022 to 2026

The growing presence of microplastics (MPs) in water and their impact on ultrafiltration (UF) membranes during the early stages of wastewater treatment highlight the need for effective mitigation strategies. This study explores the innovative modification of UF membranes by incorporating various hybrid metal-organic frameworks (MOFs) nanoparticles, including UiO-66-NH2 hybrids with multi-walled carbon nanotubes (MWCNTs) (UiOM), chitosan (UiOC), and sulfobetaine zwitterions (UiOZ). These nanoparticles were synthesized and integrated into innovative UF membranes to compare their performance on MPs fouling effect in particular. The integration enhanced membrane hydrophilicity and altered surface roughness, creating a hydrophilic functional network that improved water permeability. Water …

Boron Nitride Nanotubes Assist The Self-Assembly Of Spherical Cholesteric Liquid Crystal Shells Of Cellulose Nanocrystals In Water, Tanner L. Larson, Brandon J. Heppe, Benjamin S. Flavel, Ralph Krupke, Geyou Ao

Chemical & Biomedical Engineering Faculty Publications

Spherical confinement of cholesteric liquid crystal (ChLC) droplets is emerging as an intriguing approach for achieving complex ordered structures for photonic applications and beyond. Previously, this has been achieved primarily through microfluidic assembly utilizing immiscible solvents or immiscible mesogen-solvent systems, such as oil-water or thermotropic liquid crystal-water systems, respectively. Here, we show the spontaneous assembly of spherical ChLC droplets with isotropic cores from lyotropic liquid crystals of mixed nanorods containing boron nitride nanotubes (BNNTs) and cellulose nanocrystals (CNCs) in all-aqueous environments. We show that the mixing of as low as 0.094 vol % of pectin-coated BNNTs with isotropic dispersions of …

Polymer Charge Effects On Scaling In Membrane Distillation, Lucia Milans Del Bosch

Chemical Engineering Undergraduate Honors Theses

This research evaluates the effectiveness of polymeric inhibitors at suppressing scaling during direct contact membrane distillation (DCMD). Anionic polyacrylic acid (PAA), neutral polyethylene glycol (PEG), and cationic polyethyleneimine (PEI), were investigated. Experiments were conducted using both hypersaline single-salt and multi-component mixed-salt feeds to determine how the presence of different ions influences performance. Results from single-salt experiments showed that PAA and PEG effectively maintained permeate flux through chelation and steric hindrance, respectively, while PEI caused rapid membrane failure due to interfacial aggregation and pore wetting. In complex mixed-salt solutions, PEG was the additive, maintaining a steady flux with only a 7.33% …

Surface-Functionalized Silica Nanoparticles For Enhanced Bioavailability In Ophthalmic Mucoadhesive Drug Delivery Applications, Kaylee M. Drake

Chemical Engineering Undergraduate Honors Theses

This study investigates the stimuli-responsive behavior of porcine gastric mucin (PGM) as a model for the conjunctival mucous membrane of the human eye to optimize mucoadhesive ophthalmic drug delivery. As a versatile biopolymer, PGM has a dynamic matrix structure that functions as a selectively permeable barrier, regulating transport across mucosal membranes. To improve drug bioavailability and retention in ocular treatments, silica nanoparticles (SiNPs) were modified with varying surface functional groups and incorporated into the mucin at different physiological pH levels to examine the resulting microstructural changes. Leveraging the amphiphilic and negatively charged characteristics of mucin, positively charged and hydrophobic SiNPs …

Transformation Efficiency And Gfp Expression In E. Coli, Jessica H. Hobbs

Honors Theses

Genetic transformation of bacteria is a foundational technique in molecular biology and biotechnology, enabling the introduction and expression of foreign genes for research, industrial, and educational applications. This thesis investigates the transformation efficiency and green fluorescent protein (GFP) expression in Escherichia coli using the pGLO plasmid system, with the primary objective of supporting the development of a graduate-level laboratory course focused on bioprocess engineering and molecular biotechnology. The pGLO plasmid contains a GFP reporter gene regulated by an arabinose-inducible promoter and an ampicillin resistance gene that allows for selective growth of transformed cells. Competent E. coli HB101 K-12 cells were …

Salt-Dependent Purification Of Green Fluorescent Protein Via Hydrophobic Interaction Chromatography, Katie L. Collins

Honors Theses

Green fluorescent protein, GFP, is a widely used fluorescent reporter, and its purification provides a clear model for studying downstream bioprocessing. This thesis investigates how binding-buffer salt strength affects GFP retention and elution during hydrophobic interaction chromatography, HIC, by comparing three conditions (1.0×, 0.8×, and 0.6×). GFP-expressing E. coli were lysed and clarified, and the lysate was purified on HIC columns; collected fractions were evaluated qualitatively under UV illumination to track fluorescence distribution. Results showed a salt-dependent trend in which higher salt improved retention and shifted fluorescence toward later elution fractions, while reduced salt weakened hydrophobic interactions and increased earlier …

Cationic Polymer-Grafted Magnetic Nanoparticles For Enhanced Removal Of Anionic Dyes From Wastewater, Joia A. Traver

Chemical Engineering Undergraduate Honors Theses

Water scarcity and pollution are escalating global challenges, with textile industry wastewater often enriched with toxic dyes posing significant risks to environmental and human health. These contaminants increase turbidity, reduce dissolved oxygen levels, and ultimately impair aquatic ecosystems. This thesis focuses on the remediation of dye-contaminated water using nanoscale polymeric adsorbents. Methyl orange, a common anionic dye widely used in textile and leather industries, was selected as the model contaminant due to its terminal sulfonate group, which enables strong electrostatic and hydrogen-bonding interactions with cationic functional materials.

In this work, magnetic nanoparticles grafted with cationic polymers were synthesized and evaluated …

Performance Of Zirconia-Based Catalysts For Cold Plasma-Assisted Dry Methane Reforming, Levi Pile

Chemical Engineering Undergraduate Honors Theses

This study investigates the performance of zirconia-based catalysts in non-thermal plasma (NTP)–assisted dry methane reforming (DMR) for synthesis gas (syngas) production. This work explores an alternative pathway for converting carbon dioxide and methane into valuable products under milder conditions than conventional thermal processes. Experiments were conducted in a radiofrequency plasma reactor to evaluate the effects of plasma power, feed flow rate, and reactant ratios on conversion efficiency. The performance of plasma-only conditions was compared with packed-bed systems using zirconia catalysts. Results show that plasma-only systems achieved modest conversion rates (~16.5% for CH₄ and ~12.0% for CO₂), while …

Predicting Personalized Myocardial Fibrosis Response Patterns Using A Mechanistic Signaling Network Model, Jared Noel

Chemical Engineering Undergraduate Honors Theses

Myocardial fibrosis is a key driver of heart failure progression and exhibits substantial patient-to-patient variability, complicating the development of effective personalized therapies. In this study, we present an integrated computational framework that combines a mechanistic signaling network model with patient-specific proteomic data to predict individualized fibrotic responses and therapeutic strategies. Using proteomic measurements from the Framingham Heart Study, we generated personalized baseline states and performed systematic in silico perturbation screens to evaluate candidate drug targets across 132 signaling nodes. Results reveal that while global network response structure is conserved, therapeutic efficacy varies widely between patients in both magnitude and breadth, …

Electrochemical And Mechanical Evaluation Of Cellulose Acetate Electrolyte Films As A Function Of Polyetherimide And Polyethylene Glycol Additives For Supercapacitor Applications, Chase E. Golden

Chemical Engineering Undergraduate Honors Theses

Polymer electrolytes for supercapacitor applications require a balance between mechanical robustness and electrochemical performance. In this study, cellulose acetate (CA) films were modified with additives such as polyetherimide (PEI) and polyethylene glycol (PEG) to test how compositional changes influence mechanical performance, ionic conductivity, and electrochemical charge storage. Films were cast using phase inversion, soaked in a 1 M NaCl aqueous solution, and characterized using Fourier-transform infrared spectroscopy (FTIR), electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and tensile testing. Films were also evaluated based on fluid uptake for insight into electrolyte retention.

Characterizations show that the addition of PEI increased ionic …

Demonstration Of The Relationship Between Irwin Spire Quantity And Boundary Layer Depth In The Chemical Hazards Research Center Wind Tunnel, Jace D. Beckwith

Chemical Engineering Undergraduate Honors Theses

Atmospheric Dispersion Models (ADMs) are computer-based simulations used to model gas releases for enforcing regulatory compliance, designing facilities, and responding to emergencies. Because ADMs rely on complex mathematical models, they require experimental validation to ensure accuracy. Wind tunnels offer a controlled, repeatable method for gathering validation data. The Chemical Hazards Research Center (CHRC) at the University of Arkansas operates an ultra-low speed wind tunnel for this purpose. A key feature of this tunnel is its simulated Atmospheric Boundary Layer (ABL). The simulated ABL is a turbulent layer in which wind speed increases logarithmically with height from near zero at the …

Design Of Aluminum-Air Battery Systems And Optimization Of Cetyltrimethylammonium Bromide And 8-Hydroxyquinoline Additives In Alkaline Electrolytes, Steve Chen

Chemical Engineering Undergraduate Honors Theses

The first portion of this thesis focuses on the design and component optimization of aluminum-air batteries to power a car for the Chem-E-Car competition. A range of separators, cathodes, and current collectors was evaluated to determine the optimal configuration for maximizing output. The resulting system consisted of 1000 series aluminum as the anode, cellulose separators saturated in 1 M potassium hydroxide as the electrolyte, and composite PVDF and graphite as the cathode. The improved batteries achieved a power density of 2.14 x 10^-4 W/cm² and were utilized for the Chem-E-Car competition. The second portion of the thesis investigates …

An Efficient Implementation Of Gibbs-Duhem Integration For Solid-Liquid Phase Coexistence In Binary Lennard-Jones System With Relevance To Aav Capsid Separation, Muhi Muntaka

Graduate Theses and Dissertations

Gene therapy using adeno-associated viruses (AAVs) holds promise for treating genetic diseases, but high manufacturing costs limit its widespread use. A major challenge is separating functional (full) AAV capsids from non-functional (empty) ones, which are produced in similar amounts and have nearly identical structures. Conventional purification methods, such as density gradient ultracentrifugation and chromatography, face drawbacks like low yield, poor scalability, and high cost, often requiring multi-step processes. Recently, selective crystallization has emerged as a promising alternative, offering improved efficiency, scalability, and product quality. However, optimizing this method requires a deep understanding of thermodynamic phase behavior in multicomponent systems. In …