Engineering Commons^™

Preparation And Properties Of Monomers Derived From Hydroxyhexyl Methacrylate For Dental Adfesive, Ren-Dar Ku

Theses

Although methacrylic acid is the simplest unsaturated carboxylic acid and its hydroxyl ester polymerize readily, yielding useful resins, no adequate study of the preparation and application of the higher hydroxyl alkyl methacrylates has been published. The commercially important hydroxyethyl and hydroxypropyl methacrylates are manufactured from the appropriate alcohol in the presence of sulfuric acid, a method which appears to be less suitable for production of higher hydroxyl alkyl methacrylates. The purpose of the present work was to prepare the hydroxyhexyl methacrylate (HHMA) by a generally applicable method and determine its common physical properties. In addition, the urethane methacrylates were synthesized …

Reactions Of Chlorocarbon Species With Hydrogen Over Palladium On Alumina Catalyst And Zeolite Catalyst-Development Of Deactivation Models, Yuh-Der Yang

Dissertations

Four catalytic dechlorination reactions were studied experimentally using a fixed-bed reactor at atmosphere pressure. Reaction mechanisms were proposed, and the kinetics modelled.

The first reaction is 1,2-dichloroethane with hydrogen over zeolite catalyst. Catalyst deactivation models were examined.

The second reaction was between 1,2-dichloroethane and hydrogen over palladium catalyst on alumina support. Formation of two intermediates on the catalyst surface is proposed, which then produced ethane, ethylene, and ethyl chloride. Higher conversion to ethane and ethylene was observed at temperatures above 218°C while conversion to chloroethane is higher at temperatures below 218°C. The activation energy was found to be 15 Kcal/gm-mole. …

Electrochemical Reduction Of Quaternary Ammonium Salts, Rudolph K. Kapichak

Theses

The electrochemical reduction of two highly hindered quaternary ammonium salts was attempted. The reductions were performed in hexamethylphosphoramide at a controlled potential using platinum electrodes. It was anticipated that these reductions would provide a route to the formation of anti-Bredt bridgehead olefins. This work is an extension of the work of Dubois, Monvernay and Lacaze who electrochemically reduced quaternary ammonium salts such as trimethyl-t-butylammonium iodide (XX).

Trimethy1-2,4,4-trimethy1-2-pentylammonium iodide (XXIII) was reduced to form 2,4,4-trimethyl-l-pentene (XXVI) and 2,2,4-trimethylpentane (XXV). The yields of the two runs of this reduction were 10% and 20% and in the first run of the reduction 75% …

Submicron Silicon Powder Production In An Aerosol Reactor, Jin Jwang Wu, Richard C. Flagan, Otto J. Gregory

Chemical, Biomolecular, and Materials Engineering Faculty Publications

Powder synthesis by thermally induced vapor phase reactions is described. The powder generated by this technique consists of spherical, nonagglomerated particles of high purity. The particles are uniform in size, in the 0.1–0.2 μm size range. Most of the particles are crystalline spheres. A small fraction of the spheres are amorphous. Chain agglomerates account for less than 1% of the spherules.

Linear Process Calculations As Convergence Accelerators In Flowsheet‐Sequenced Programs, S. M. Milani, Marshall E. Findley

Chemical and Biochemical Engineering Faculty Research & Creative Works

Linear process calculations were developed for use in conjunction with flow‐sheet‐sequenced calculations, as methods of convergence acceleration. Two such methods were compared with the successive substitution and Wegstein methods on relatively simple processes. "Linear Process Simulation," which requires user‐derived equations, produced the best results. Copyright © 1986 American Institute of Chemical Engineers

Growth Of Ultrafine Particles By Brownian Coagulation, S. H. Suck Salk, R. E. Thurman, Chang-Soo Kim

Electrical and Computer Engineering Faculty Research & Creative Works

Current atmospheric observations tend to support the view that continental tropospheric aerosols (particularly urban aerosols) show multimodal mass distributions in the size range of 0.01-100 μm. The origin of these aerosols is both natural and anthropogenic. Recently, trimodal sub-μm size distributions from combustion measurements at 0.008, 0.035 and 0.15 μm were also observed. Our interest in the present study is the secondary process of growth of sub-μm size aerosols by the coagulation process alone. Using the 'J-space' (integer-space) distribution method of Salk (Suck) and Brock (1979, J. Aerosol Sci. 10, 58-590), we report an accurate numerical simulation study of the …

A New Automated Pulse Testing Analysis Method Applying Inflection Point Theory, Jose Maria Donoso

Masters Theses

"This paper describes a new technique for pulse test analysis that combines the simplicity of the tangent method with the result repeatability of the iterative methods. Inflection points are used instead of time lag with the added advantage that they are calculated by a simple algorithm and are not subject to graphical misinterpretation. Charts are made for the calculation of transmissibility and storage for unequal pulse and shut-in periods from 0.1 to 0.9 relating inflection time to pulse response amplitude and dimensionless inflection time.

The graphs presented for this technique have the same dimensionless cycle period ranges (from 0.44 to …

Predicting Shunt Currents In Stacks Of Bipolar Plate Cells, Ralph E. White, C. W. Walton, H. S. Burney, R. N. Beaver

Faculty Publications

A method is presented for predicting shunt currents in stacks of undivided and divided bipolar plate cells. The method is an efficient way of solving the coupled sets of algebraic equations that arise from using circuit analog models to represent the current paths in stacks of undivided or divided bipolar plate cells. These algebraic equations can be eitherlinear or nonlinear depending upon the current-potential relationships used in the model (i.e., nonlinear circuit elements can be included). The method is used to show the importance of including nonsymmetrical resistances and nonlinear circuit elements in the models. Also, the method …

A Two-Dimensional, Three-Phase Reservoir Simulator Using The Impes Formulation, Ralph Ross Roesler

Masters Theses

"A numerical model for two dimensional, three-phase fluid flow has been developed using the IMPES formulation. Reservoir heterogeneities have been included, such as areal variations in porosity, permeability, thickness, and depth from a reference point. The model can also solve the problem of variable bubble points.

To check the accuracy of the model, a comparison was made with the Buckley-Leverett technique of predicting waterflood performance. The reservoir in the comparison is a 40 acre five spot with an initial gas saturation of 15 percent. The study shows that the two models are in good agreement, except for differences due to …

A Purchase Estimator For Oil And Gas Reserves, Ronald Ernest Robbins

Masters Theses

"A computerized means for analyzing the profitability and purchase potential of producing oil and gas properties was developed. LOTUS 1- 2-3, a computerized spreadsheet package, was utilized in this development. The basic input data required for the implementation of the purchase estimator (BUYOUT) are the forecasts of production, price, and expense. BUYOUT itself is composed of three separate, but interactive, parts: and the system macro. the profitability model, the acquisition table,

A before federal income tax cash-flow model and several economic indicators constitute the profitability model. The profitability model is then fully interactive with an acquisition table which contains six …

Measurement Of The Dusty Gas Model Parameters For Activated Carbon, Philip James Gloor

Masters Theses

"Included in the dusty gas equation are three constants, C₀, C₁ and C₂, which depend only upon the porous medium. Values for C₀ and C₁ can be obtained for a particular porous material by performing pure gas flow experiments and a value for C₂ can be obtained for the same material by performing Wicke-Kallenbach experiments. In this work, values for the dusty gas model parameters, for activated carbon, were obtained by performing the necessary experiments. The design and operation of the experimental equipment is presented along with the results obtained. The activated …

Water Desalination Using Nocturnal Radiation Cooling, Ali Mufarreh Saleh Al-Amri

Masters Theses

"In this investigation nocturnal radiation condensation cooling is considered to determine the possibility of using this method as a desalination process in remote areas, villages and resorts, etc. An experimental study was made and programs were developed to calculate water collection under ideal conditions. Both experimental and theoretical work indicated that this process is useful for small scale water production where there is no available energy sources. It can be used also in conjunction with solar desalination processes. Cost analysis and a preliminary design are included"--Abstract, page ii.

Determining The Modified Derivative In Pressure Analysis, Scott Michael Frailey

Masters Theses

"The derivative type of curve technique of Bourdet for analyzing pressure tests requires calculating the derivative of the storage plot. Four numerical methods are used to evaluate the derivative: a five-point formula, Richardson's Extrapolation, a parabolic fit, and a central difference procedure. The parabolic fit and the central difference technique are good methods of determining the derivative. The effects of logarithmic s pacing of the data, using a central difference method, are studied. An investigation of the second derivative and the integral is conducted"-- Abstract, p. ii

Swelling Pressure Studies Of Shales, S. L. Huang, N. B. Aughenbaugh, John D. Rockaway

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

A swelling model was developed to predict the swelling pressure which occurs within shale or shale material when it is immersed in water. This model is also capable of estimating the magnitude of shale swelling when subject to humidity changes. The model was developed on a basis of the moisture susceptibility of the shale and the initial humidity of the ventilated mine air. The Moisture Activity Index (IRH) was selected to describe the susceptibility of shale to moisture because of its close association with the other physical properties, its strong correlation with the swelling of the shale, and because it …

On The Mean Time Between Failures For Repairable Systems, Max Engelhardt, Lee J. Bain

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Much of the recent work on modeling repairable systems involves Poisson processes with nonconstant intensity functions, viz, nonhomogeneous Poisson processes. Since times between failures are not identically distributed when the process is nonhomogeneous, it is not clear what concept should take the place of the mean time between failures in assessing the reliability of a repairable system. A number of alternate concepts can be found in the literature. We investigate the relationship between two of the most frequently considered alternatives: the reciprocal of the intensity function, and the mean waiting time from t until the next failure. Theorem 1 states …

A Mathematical Model Of A Zn/Br2 Cell On Charge, M J. Mader, Ralph E. White

Faculty Publications

A mathematical model of a parallel plate electrochemical cell with a separator and a homogeneous bulk reaction is presented. The model is based on the Zn/Br₂ redox couple and can be used as an aid for the design of an efficient rechargeable storage battery. It is shown that four independent variables exist for the system at a fixed temperature: the effective separator thickness, the residence time, the channel width, and the potential driving force. Performance criteria of interest for the Zn/Br₂ battery are defined. Predictions of performance during the charging process are presented. It is shown that the …

Parallel-Plate Electrochemical Reactor Model: A Method For Determining The Time-Dependent Behavior And The Effects Of Axial Diffusion And Axial Migration, T. V. Nguyen, C. W. Walton, Ralph E. White, J. Van Zee

Faculty Publications

A method is presented for determining the effects of time dependence, axial diffusion, and axial migration in aparallel-plate electrochemical reactor (PPER). The method consists of formulating the governing equations and applying a numerical integration technique to solve a set of time-dependent, nonlinear, coupled, multidimensional equations. This formulation reveals that the steady-state performance of the PPER depends on the cell potential and three dimensionless groups. Predictions of the concentration, potential, and local current distributions in a PPER are presented for the electrowinning of copper from an aqueous, hydrochloric acid solution. These predictions show that axial diffusion and axial migration are significant …

Simple Models For Diaphragm-Type Chlorine/Caustic Cells Ii. Effect Of Acidic Anolyte On Steady-State Caustic Yield, John Van Zee, Ralph E. White

Faculty Publications

A simple steady-state model of a diaphragm-type chlorine/caustic cell in which the diaphragm is divided into two regions by a homogeneous acid-base reaction is presented. The location of the reaction affects significantly the caustic yield and effluent concentration. The model is used to predict the location of this reaction as a function of the operating variables, the physical constants, and three measurable properties of the diaphragm. These measurable properties are the MacMullin number or resistivity ratio of electrolyte-filled diaphragm relative to the electrolyte, the Darcy's law diaphragmpermeability, and the diaphragm thickness. The model is used to predict a maximum in …

Simple Models For Diaphragm-Type Chlorine/Caustic Cells I. Dynamic Behavior, John Van Zee, Ralph E. White, A T. Watson

Faculty Publications

A simple model of the dynamic behavior of a diaphragm-type chlorine/caustic cell is presented. The model is based upon measurable diaphragm properties and the mass transfer of hydroxyl ion through the diaphragm. The anolyte is modeled simply as a region in which the OH^– ion concentration is fixed, the diaphragm is modeled as a plug-flow reactor with an electrochemical reaction occurring at the catholyte/diaphragm interface where the cathode is placed, and the catholyte is modeled as a completely stirred flow reactor. Analytical integration of the governing equations for thesemodels yields two mathematical expressions: one for the concentration distribution of …

Parallel Plate Electrochemical Reactor Model: Material Balance Closure And A Simplification, M J. Mader, C W. Walton, Ralph E. White

Faculty Publications

A material balance closure calculation is presented to test the consistency of a previously published model of a parallelplate electrochemical reactor. New expressions are used in this procedure to calculate the average concentration of species i and the average current density for reaction j from the predicted concentration and potential distributions. Also, the previously presented model equations are simplified by assuming that the axial concentration gradient for species i can be approximated by a step change from the known feed concentration to the unknown outlet concentration. This one-step model provides a qualitative evaluation of cell performance and adds insight into …

A Mathematical Model For A Parallel Plate Electrochemical Reactor, Cstr, And Associated Recirculation System, T V. Nguyen, C W. Walton, Ralph E. White

Faculty Publications

A mathematical model is presented for a system comprised of a parallel plate electrochemical reactor (PPER) and a continuous, stirred-tank reactor (CSTR) under both total and partial recycle. The model is used to predict the time dependent behavior of the electrowinning of copper from an aqueous, hydrochloric acid solution. The model includes many important aspects of a PPER/CSTR system which have been neglected previously. These aspects are the kinetics of electrode reactions, the electroneutrality condition, three mass transfer processes for ionic species in the electrolyte (diffusion, ionic migration, and convection) and the electrode gap in the PPER, and the inclusion …

The Modeling And Analysis Of Multi-Component, Multivalent Biospecific Adsorption, Bo Henrik Arve

Doctoral Dissertations

"A general model is presented and used to predict the dynamic behavior of the adsorption, wash, and elution stages of biospecific adsorption (affinity chromatography) in finite bath and column operations. The model accounts for film and pore diffusional mass transfer resistances and the rates of interaction between adsorbates and ligands. For column operations the effect of axial dispersion in the flowing fluid stream is included. The model is applicable to single and multi-component biospecific as well as non-specific adsorption, and the adsorbates may be monovalent or multivalent. In the elution stage both non-selective and selective elution of monovalent adsorbates is …

An Industrial Ethanol Azeotropic Distillation Process : Modeling, Analysis, And Simulation, Harpreet Singh Chawla

Dissertations

A steady state process simulator with extensive capabilities was developed for the simulation of process plants involving non-ideal multicomponent systems. A comprehensive stand alone program was developed to represent process systems encountering three phases. A computer program was also developed to handle simultaneous regression of vapor-liquid and liquid-liquid equilibria data to estimate the liquid phase activity coefficients via a global set of parameters for the ethanol azeotropic distillation process, using benzene as the entrainer.

An industrial ethanol azeotropic distillation process has been simulated using the developed process simulator (PROSIM). A study of the azeotropic column's aqueous ethanol feed composition reveals …

Enhancement Of The Thermophysical Capability Of The Chemical Engineering Simulation System, Joydeep Banerjee

Theses

The CHESS (Chemical Engineering Emulation System) is a generalized steady-state, sequential-modular chemical process simulation program. In this thesis, the thermophysical data prediction capability of CHESS has been expanded by: incorporating more accurate thermodynamic phase-behavior models, by utilizing these models in generating a wider range of thermophysical properties, and providing an updated and expanded database for pure-component physical properties.

The overall performance of the simulation system's thermophysical package has been evaluated using the study of a subprocess consisting of various rotational equipment modules.

In this work, the Chao-Seader liquid phase activity coefficient model has been reinstalled in conjunction with the original …

Process For Recovering Terephthalic Acid From Waste Polyethylene Terephthalate, Richard A. Lamparter, Bruce A. Barna, David R. Johnsrud

Michigan Tech Patents

Terephthalic acid (TPA) is recovered from used polyethylene terephthalate beverage containers by reacting comminuted containers in a reaction zone with an aqueous medium containing ammonium hydroxide at elevated temperatures and pressures to form a water soluble diammonium salt of TP A, separating any undissolved solids from the reaction product, acidifying the remaining reaction product to liberate TP A, and separating the precipitated TPA. A portion of the liquid remaining after separation of TPA can be mixed with lime or slaked lime, the resulting mixture treated in an ammonia stripper to remove ammonia therefrom and the ammonia overheads from the stripper …

The Effect Of Single Electrolytes On The Vapor-Liquid Equilibrium Of Mixed Solvents, Peggy Tomasula

Dissertations

A group-contribution model for the prediction of salt-effects on the vapor-liquid equilibria of multicomponent electrolytic solutions containing a single electrolyte is presented. Coulombic interactions are represented through a Pitzer term. Solvation effects and short-range interactions are represented through a UNIQUAC-type expression. An ion-size, a solvation and three ion-solvent interaction parameters per salt-solvent binary are required for multicomponent predictions.

All parameters are obtained only through the correlation of binary salt-solvent osmotic coefficient and vapor-pressure depression data at 25°C, in most cases, and binary solvent VLE data. The salt-solvent binary data were correlated with an average percent error in CD of 2.5 …

Ternary Ion Exchange In Fixed Beds : Equilibrium And Dynamics, David W. H. Roth

Dissertations

A model was developed to simulate ion exchange within fixed beds for ternary systems. Models of the fluid phase material balance, phase equilibria, and diffusion of ions through the film and within the resin phase incorporated the latest advances in ion exchange theory. The separate model elements were combined after testing into an overall general model. Non-linear regression support programs were developed to estimate equilibrium parameters and resin phase diffusion coefficients.

A computer program was developed to estimate axial dispersion coefficients from experimental data. General correlations derived from literature sources were tested, and axial dispersion terms were included in the …

Shear Induced Anisotropy In The Rheology Of Solids Dispersions, Nicholas G. Triantafillopoulos

Masters Theses

Under strong hydrodynamic forces, solids dispersions could no longer be considered isotropic fluid s but rather two-phase systems. The continuous (dispersing) phase was only sheared in side an effective gap determined in a Couette flow device by the presence of solid (dispersed) phase in to suspension. Three parameters, the effective gap, percent gap reduction and the relative shear volume, were incorporated to account for the influence of solids in the rheology of their suspension.

The objectives of this study were: (1) to investigate the role of solids volumetric concentration, particle size, nominal gap and continuous phase viscosity on Hercules Hi-Shear …

A Structural Study Of Some (H6-Arene)Ml2, First Row, Group Viii, Transition Metal Complexes And Their Derivatives, Stuart Kevin Janikowski

Theses and Dissertations

The structures of five organonickel compounds were determined using x-ray diffraction techniques. This study was conducted to ascertain the relationships between the compound's structures, bonding, and chemical properties. The first structural evidence for discrete complexes containing Ni-SiX3 bonds is (h6-mesitylene)Ni(SiCl3)2 and presented. The compounds (h6-toluene)Ni(SiF3)2, crystallize in space group P21/c with Z = 2. The lattice constants at 23° C are: a = 9.056(2), b = 14.426(1), c = 13. 3 0 3 ( 2) ~, {J = 10 0. 6 9 ( 1 )0 , and a = 11. 3 5 5 ( 3) , b = 11.268(4), c …

Kinetic Modeling Of A Laminar-Flow Reactor, Shih-Hsin Chang

Dissertations

The laminar-flow reactor considering radial dispersion for a species incurring first-order homogeneous (bulk) and heterogeneous (wall) chemical reactions was mathematically modeled. The equation was solved both analytically, and by the Crank-Nicolson finite-difference technique.

The response surface method was used to obtain the optimum values of the two rate constants. The optimum values interact because the wall and bulk reactions proceed in parallel. Varied reactor diameters serve to decouple the bulk and wall reactions to locate the true values of the rate constants.

Four dimensionless variables were defined and used to characterize the reacting system. In addition, their values were shown …