Engineering Commons^™

Lignocellulosic And Cellulosic Beads For Affinity And Immunoaffinity Chromatography Of High Molecular Weight Protiens, William H. Velander

Department of Chemical and Biomolecular Engineering: Patents

Improved cellulosic beads for use as supports in bioaffinity chromatography are produced by dissolution of cellulose in a chaotropic cellulose solvent, formation of the dissolved cellulose into droplets, and immersion of the droplets into a non-solvent capable of solvent interchange with the cellulose solvent to form generally spherical porous cellulose beads of narrow particle size distribution. The beads formed are preferably made with cellulose having a degree of polymerization between 100 and 200, and the resulting beads when saturated with water without drying contain between 1% and 7% cellulose by weight and have a particle size of at least about …

Pulping Of Sisal Fibres: Effects Of Chemical Concentration, Na-Zs03/Na2c03 Ratio And Fibre To Chemical Ratio, J Katima

Tanzania Journal of Engineering and Technology (TJET)

This paper reports on pulping of hard fibres extracted from the leaves Of agave sisalana using sodium sulphite buffered with sodium carbonate as pulping chemical. The cooking was carried Out at 1680Cfor a cooking period of 6 hours, with varying chemical concentration, sodium sulphite to sodium carbonate ratio and fibre to chemical ratio. The results show thar boll! the pulp yield and pulp viscosity decæase with increasing chemi- cal concentration, whereas Kappa number of pulp decreases to a limit of about 16.45. Brightness increases significantly with an increase in the ra- rio of Na2S03/Na2C03. The pulp yield obtained indicated the …

An Alternative Method Of Interfacing A Dc Motor To A Microprocessor For Mo- Tion Control, M Selekwa

Tanzania Journal of Engineering and Technology (TJET)

A Simple and cheap alternative method Of interfacing a permanent mag- net dc motor to a motion control using switch- ing transistor motor drivers is presented. This method involves the use Of very few transistor-transistor logic (TTL) devices and a 555 timer to pro- duce a pulse width modulated (P WM) signal which is required by the mo- ror driver. The motor driver in this case should be of an H-bridge type. Like other methods currently in use, it relieves the MPU of all timing func- tions which are necessary in the generation of P WM signals. The present method, …

Oxidation Of Pollutants In A Batch Recirculation Bioreactor With Immobilized Microorganisms, Jongtai Jung

Dissertations

The purpose of this work was to study bio-oxidative destruction of several substrates in an immobilized cell batch bioreactor in recirculation configuration. This system was used in three cases: a series of substrates usually used as monomers, ethylene glycol and its tetramer, and phenol under magnetic irradiation. In addition, kinetic studies were performed and experimental versus predicted results compared.

The substances styrene, methyl methacrylate (MMA), and β-hydroxybutyric acid (HBA), common monomers, were biologically treated using an acclimated mixed microbial community immobilized in calcium alginate gel. A comparison of biodegradation rates (3.3, 9.4, and 15 ppm/hr for styrene, MMA, and HBA, …

Removal Of Vapors From Air By Selective Membrane Processes, Junseok Cha

Dissertations

The behaviors of different membrane modules for the selective removal and recovery of water vapor and some volatile organic compounds (VOCs) from N₂ have been studied. For the selective permeation-based removal of water vapor from N₂, a polymeric water-swollen gel membrane in the form of Cuprophan hollow fiber was employed. A thin film composite type rubbery membrane module was studied for the selective removal of VOCs like toluene or methanol from N₂ by permeation. The usefulness of pore-condensation phenomenon-based removal of toluene or xylene from N₂ was explored using a microporous ceramic tubular membrane.

The …

Engineering Analysis Of A Packed-Bed Biofilter For Removal Of Volatile Organic Compound (Voc) Emissions, Zarook M. Shareefdeen

Dissertations

This study dealt with removal of VOC emissions from airstreams using an evolving new technology which is known as biofiltration. The basis of this technology is biodegradation of VOCs in biofilms formed around porous solids which are placed in packed-bed reactors.

A detailed model describing steady state biofiltration of single and mixed VOCs was developed, and experimentally validated. The model takes into account biodegradation kinetics, the effect of oxygen, kinetic interactions among structurally similar compounds, and mass transfer from the gas phase to the biolayer. It was found that oxygen (a factor neglected in all previous studies) plays a very …

Biological Denitrification : Fundamental Kinetic Studies, And Process Analysis For Sequencing Batch Reactor Operation, Jun-Hsien Wang

Dissertations

This study dealt with a detailed investigation of biological denitrification of nitrate and nitrite by a pure culture of Pseudomonas denitrificans (ATCC 13867), under anaerobic conditions.

In the first part of the study, the kinetics of denitrification were studied in serum-bottle experiments. It was found that reduction of both nitrate and nitrite follows inhibitory expressions of the Andrews type. It was also found that when nitrite is present at levels above 15 mg/L, nitrite and nitrate are involved in a cross-inhibitory, non-competitive, interaction pattern. Analysis of the kinetic data has shown that the culture used has severe maintenance requirements, which …

A Study Of The Biofiltration Process Under Shock-Loading Conditions, Helen Androutsopoulou

Theses

Biofiltration is a new technology for treating airstreams contaminated with emissions of volatile organic compounds (VOCs). It employs porous particles which are placed in reactors, in packed-bed configurations, after appropriate microorganisms have been immobilized on the solid support.

Biofiltration involves complex processes, and is not yet well understood. In this thesis the response of biofilter units to quantitative and qualitative changes in the inlet airstreams was examined. Steady state data were also analyzed through the use of an existing detailed model.

Experiments were performed with two small-scale biofilters, and with ethanol and butanol as model compounds. Each biofilter was dedicated …

Unzippable Polymer Mask For Screening Operations, Ravi F. Saraf

Department of Chemical and Biomolecular Engineering: Patents

The present invention relates to a dry process for forming patterns on a substrate. More particularly, the process contemplates coating an unzippable polymer film with a small amount of desirable UV if required on a substrate; laser ablating said film into a desired pattern or mask; screening a conductive or resistive paste onto the substrate through the ablated features of said mask; heating said substrate and mask to the unzipping temperature of said mask; and, vaporizing said mask and UV absorbing dye if present leaving behind the solid of said conductive or resistive past adhered to the substrate in the …

Electroless Metal Adhesion To Organic Dielectric Material With Phase Separated Morphology, Ravi F. Saraf

Department of Chemical and Biomolecular Engineering: Patents

Improved adhesion of electroless metal deposited on an organic dielectric layer with phase separated morphology is accomplished by the spontaneous formation of a morphologically and topographically rough surface. In one embodiment a ternary solution of a polar solvent and two polymer precursors of the same polymer which are separable in two phases of different order are cast in film on a substrate and heated to form two phases of different order to spontaneously produce a rough surface. Upon exposure to an alkaline solution, one phase is etched at a faster rate than the other. Seeding and electroless deposition of a …

The Affects Of Butyl Acetate And Acetone On Plexiglass, Tracy E. Downs

Opportunities for Undergraduate Research Experience Program (OURE)

The actions that solvents take on polymers was the focus of the summer 1993 research. There were two goals: one was to measure the distances between the cracks that formed in the plexiglass and two was to determine the time of arrival of the cracks. Two solvents, butyl acetate and acetone were used to generate data on polymethyl methacrylate (PMNA/Plexiglass).

The measurement of the time of arrival of a crack was another goal. This quantity is related to the growth of the fractures. This was difficult since only a localized portion of the plexiglass sample could be viewed.

Skin Effects Due To Perforations -- A Study Of Analysis Techniques, Jon Michael Gibbs

Opportunities for Undergraduate Research Experience Program (OURE)

Until 1991, two methods could be used to evaluate the skin effect due to perforations, the Brons and Marting Method and the Harris Method. Due to the simplicity of the technique, the Brons and Marting Method has been the preferred method of use in the petroleum industry. However, with the recent development of a third technique to evaluate the skin effect due to perforations, the need has arisen to evaluate each of these techniques to determine which method is the most accurate under given conditions. This paper reviews and compares each of the three methods for evaluating the perforations skin. …

An Extension Of Pdxi Data Models To Include Process Control Data, Joseph D. Graber

Opportunities for Undergraduate Research Experience Program (OURE)

The results described herein have culminated into the creation of an object model which extends an existing engineering data model to include process control data. The existing data model is described in Volume I of the deliverables for the Process Data Exchange Institute (PDXI) Data File Interchange Format Project. This object model was created using the OMTooP software package on Sun Stations in the Intelligent Systems Center(ISC) of the University of Missouri--Rolla (UMR). It expands on the classes of signal port, control element, and control system.

The Development Of Equipment Specification Form From The Pdxi Data Models, Justin M. Juengel

Opportunities for Undergraduate Research Experience Program (OURE)

The project has culminated in the development of a simplistic working model, based upon the existing data model created by the Process Data Exchange Institute (PDXI). This data model is depicted in Volume 1 of the deliverables for the PDXI Data File Interchange Format Project. The working model, based in part on the Planning Level Model and the Heat Transfer Model [1] of the overall data model, was then used to create an equipment specification form (Fig 1) for a heat exchanger, partially utilizing the standards set forth by the Tubular Exchanger Manufacturers Association (TEMA).

Solvent Recovery For An Extraction Process, Denise C. Ratcliff

Opportunities for Undergraduate Research Experience Program (OURE)

The solvent recovery project involves the recovery of a valuable solute, acetic acid, from a spend solvent stream generated in a laboratory extraction experiment. The majority of this project’s efforts center on the simulation of a ten-stage distillation column that will recover the acid. These simulation results will then be used to specify the ancillary process equipment needed for this distillation process.

Automation Of Process Data Management, Stephen C. Chadwick

Opportunities for Undergraduate Research Experience Program (OURE)

The project goal is to create an automated system for managing data that describes a chemical process. The data is both graphical, such as piping and instrumentation diagrams, and numerical, such as pipe schedule and diameter. AutoLisp and C++ programs were developed and tested to simplify the creation of the automated system.

Fixed Site Facilitated Transport Of Oxygen And Nitrogen Through Plasma Polymer Films, Chad Dunnegan

Opportunities for Undergraduate Research Experience Program (OURE)

A method of preparing plasma polymer films, in which metal chelate molecules are incorporated, is briefly outlined. The chemical reactivity of metal chelate molecules is preserved so that they may ”facilitate” the transport of oxygen molecules through the membrane. The method for testing permeability of the films is presented and results are analyzed with respect to the dual mode sorption model, applied to fixed site facilitated transport.

Forced Convective Diffusion And Interphase Heat And Mass Transfer: Computations Of Radial Functions, Temperature And Concentration Fields, And Presentation Of Local And Average Nusselt And Sherwood Numbers, Stephen Myers, X B. Reed Jr., N. Y. Shah, A. E. Penn

Opportunities for Undergraduate Research Experience Program (OURE)

Theoretical calculations have been carried out for forced convective transport for uniform streaming and uniaxial and biaxial extensional axisymmetric flows past single spheres. Homogeneous and heterogeneous chemical reactions, both of first and of second order have also been or are presently being treated. Orthogonality and other properties of Legendre functions have been used, together with introduction of an eigenfunction expansion, to reduce the mathematical description from a partial differential equation with variable coefficients, which is nonlinear for homogeneous second order chemical reactions, to a system of coupled ordinary differential equations for the radial modes. The numerical solutions of the latter …

Effect Of Culture Conditions, Donor Age, And Injection Site On In Vitro Development Of Dna Microinjected Porcine Zygotes, M A. Hajdu, J W. Knight, R S. Cansecot, R L. Krisher, William H. Velander, R E. Pearson, F C. Gwazdauskas

Papers in Biotechnology

A series of experiments evaluated development of porcine zygotes microinjected with DNA in three culture media and two incubation temperatures, from postpubertal and prepubertal donors, and between zygotes injected with DNA into the pronucleus and the cytoplasm. Zygotes recovered from 36 postpubertal gilts in Exp. 1 were injected and cultured in modified NCSU-23, modified NCSU-37, and CZB media at 37°C or 39°C for 7 d. In Exp. 2, zygotes were collected from postpubertal or prepubertal gilts, microinjected with DNA, and cultured in modified NCSU-23. In Exp. 3 superovulated prepubertal gilts had DNA injected into the cytoplasm or pronucleus of zygotes. …

Transient Body Force Effects On The Dryout And Rewet Of A Heated Capillary Structure, Michael K. Reagan

Theses and Dissertations

A transient, one-dimensional numerical code was developed to model the liquid flow in a non-uniformly heated, axial square groove. The groove was subjected to transient body forces up to approximately 0.51 m/s² . Axial variation in meniscus levels, shear stress and heat transfer between the groove wall and the liquid, axial conduction through the liquid, evaporation and body forces were accounted for in the model. Dryout and rewet of the groove were allowed; the front location was determined using conservation of mass and linear extrapolation. A physical experiment was performed with a stainless steel plate into which eight square …

First Shell Substitution Effects: Diglyeidyl Ether Of Bisphenol A Cured With 4,4'-Diaminodiphenylmethane, Hossein Noureddini, Delmar C. Timm

Papers in Molecular Chemistry

First shell substitution effects were incorporated into a kinetic reaction model descriptive of the polymerization of an epoxy resin formulated from diglycidyl ether of bisphenol A and 4,4'-diaminodiphenylmethane. Analysis of populaiion density distribution dynamics for the hardener and several oligomers in the sol fraction showed that the reactivity of secondary amino hydrogens is less than the reactivity of primary amino hydrogens.

Sporomorphs And Palynological Interpretations Of Lower Oligocene Strata From The Eastern Gulf Coast, U.S.A., Lisa M. Reeves

Opportunities for Undergraduate Research Experience Program (OURE)

The Vicksburg Group in the eastern Gulf Coast of the United States belongs to one of the most complete and continuous Paleogene strata in the world. Previous studies in this region have neglected the rich palynomorph assemblages of the Lower Oligocene units of the Vicksburg Group. Four samples from Wayne County Mississippi were analyzed for palynological information on the Vicksburg Group. The initial objective of the study was to understand the principles of palynology and the basis for sporomorph identification. A minimum of 300 specimens were counted per slide to determine the distribution of sporomorphs in the sediments. Two hundred …

Interactive Multimedia Applications For The Correlations Of Petroleum Fluids Properties, Herman Smith Iii

Opportunities for Undergraduate Research Experience Program (OURE)

Interactive Multimedia Applications for the Correlations of Petroleum Fluids Properties is a truly interactive and multimedia computer application designed to better help students taking the class "The Properties of Petroleum Fluids", Petroleum Engineering 141. This computer program incorporates error and information voice messages, control over three different computer applications (HyperCard 2.2, Mathcad V3.1, and DeskPaint™ V3.2), three-dimensional multi-coloration, pop-up graphics, directional buttons, object/label-oriented programming, and floating palettes. This creates one computer application to calculate petroleum properties versus the use of multiple, often crowded graphs.

Development Of A Bill Of Materials From The Pdxi Data Models, Bryan A. Stanford

Opportunities for Undergraduate Research Experience Program (OURE)

The research on the development of a bill of materials has resulted in the construction of a portion of the working data model, as designed in theory by the Process Data Exchange Institute (PDXI). The theoretical object model can be found in The PDXI Data Models [1]. It was necessary to develop this working data model in order to be able to produce the bill of materials. The bill of materials was created with the help of the software package Paradox for Windows (version 4.0).

High-Pressure Wateijet Technology: A Review And Design Of High-Pressure Hybrid Drillbits, Azmi Zainal Adnan

Opportunities for Undergraduate Research Experience Program (OURE)

The petroleum industry has seen many technological advances since oil was first discovered in the 19th century. Some of the current technological advances in the industry include cuttings transport, drillbit design, logging, and horizontal and directional drilling. Currently, research projects are being done at UMR to find ways to further reduce drilling costs and develop new technology that could improve the drilling effectiveness. One such project is the development of high- pressure waterjet / hybrid bits to replace the conventional mechanical drillbits. In this design, the advantages of waterjet penetration are combined with those of mechanical teeth cutting action..

At …

Effects Of Time Of Deoxyribonucleic Acid Microinjection On Gene Detection And In Vitro Development Of Bovine Embryos, A.E T. Sparks, R S. Canseco, C G. Russell, J L. Johnson, H D. Moll, William H. Velander, Francis C. Gwazdauskas

Papers in Biotechnology

In vivo fertilized embryos were surgically collected from superovulated dairy cows to evaluate microinjection on embryo development and utilized the polymerase chain reaction technique for selection of transgenic embryos. Seventy-two percent of the embryos with visible pronuclei or nuclei were microinjected with DNA, and the remaining 28% served as uninjected controls. All embryos were cocultured with bovine oviductal epithelial cells. Mean final development scores of embryos within the same initial cell stage at collection were unaffected by microinjection. After 144 h of culture, 45% of the microinjected embryos developed to the morula or blastocyst stage. The transgene was detected in …

Reaction Kinetics Analyses Of Amine-Cured Epoxies: First Shell Substitution Effects, Hossein Noureddini, C Q. Zhang, Delmar C. Timm

Papers in Reaction Kinetics

Kinetic reaction theory was used to model first shell substitution effects for several amine-cured epoxy resins, subject to the constraint of intermolecular reactions. Moment analysis will allow numerical simulations to be extended beyond the gel point. Functionalities for several chemical moieties were correlated as a function of conversion. Simulations also incorporated population density distribution dynamics. Analyses of several oligomers clearly demonstrated the dependency of oligomeric weight fractions on first shell substitution effects and conversion. The ratio of rate constants for reactions of secondary amino hydrogens relative to reactions of primary amino hydrogens ranged from 0.5 to 1.2 for the resins …

A Shock Tube Study Of Aerodynamic Heating Of Gaps In A Cylinder Subjected To Supersonic Cross Flow, Douglas D. High

Theses and Dissertations

The effects of localized aerodynamic heating in cylinder expansion gaps positioned in cross flow were investigated in a shock tube. For this study, Mach number and Reynolds number were varied from 1.04 to 1.38 and 5 x 105 to 9 x 105, respectively. The cylinder was instrumented with quick response time thermocouples positioned on the surface of the cylinder, the wall of the gap, and the gap floor. Gap aspect ratios varied from 1.23 to 3.69. Pressure gauges were used to measure wave shock speeds, pressure ratios, and transient pressure conditions. Surface temperatures were measured and converted to heat fluxes …

Morphological Composite Materials Formed From Different Precursors, Ravi F. Saraf

Department of Chemical and Biomolecular Engineering: Patents

A method of producing a multiphase polymer is disclosed whereby the phases have the same chemical structure but have different morphological states and thus different properties. This is achieved by forming a mixture of precursors of the polymer, at least one of the precursors having a reaction rate higher than the other precursor or precursors in the mixture. The precursor having the highest reaction rate is then converted to obtain a composite of a polymer and the precursors that are not polymerized. This mixture might also be formed by mixing a soluble polymer with its precursor. The polymer/precursor composite is …

Formation Of Plasma Polymer Thin Films Containing Reactive Metal Chelate Sites, J. M. Skelly, Nicholas C. Morosoff, V. T. Stannett, A. L. Crumbliss

Chemical and Biochemical Engineering Faculty Research & Creative Works

We report here the successful incorporation of chemically active Co2+ and Ni2+ centers into plasma polymer thin films. Metal center incorporation was accomplished by simultaneous plasma polymerization of sublimed Co2+ or Ni2+ complexes with gaseous "comonomers" or Ar. The metal complexes include N,N′-bis(salicylidene)-1,2-phenylenediaminecobalt(II) (CoSalophen), N,N′-bis(salicylidene)ethylenediaminecobalt(II) (CoSalen), N,N′-bis(3-fluorosalicylidene)ethylenediaminecobalt(II) (CoFluomine), meso-tetraphenylporphyrinatocobalt(II) (CoTPP), meso-tetraphenylporphine (TPP), and meso-tetraphenylporphyrinatonickel(II) (NiTPP). Modification to the metal complex structure was observed by IR and UV-vis spectroscopies. IR spectra of plasma polymer films containing the Schiff's base complexes, prepared using Ar as a carrier gas, contained a band at 2190 cm−1, which can be attributed to nitrile group formation, …