Engineering Commons^™

Effect Of Antibody Orientation On Immunosorbent, Anuradha Subramanian, William H. Velander

Papers in Biotechnology

The impact of antibody orientation on immunosorbent efficiency was quantitatively assessed. A pH-dependent murine monoclonal antibody (Mab) against human protein C (hPC), recombinant hPC (rhPC) and two different immobilization chemistries and matrices were used as model systems. The lysyl groups of the rhPC were covalently modified with an acetic acid ester of N-hydroxysuccinimide and this modified rhPC was used as a Fab masking agent (FMA). The FMA was used to mask the antigen bind-ing regions (Fab) of the Mab prior to and during covalent immobilization. Thereafter, the residual active sites of the support were in-activated and the FMA was removed. …

Measurement And Analysis Of Oxygen/Nitrogen/5a-Zeolite Adsorption Equilibria For Air Separation, Orhan Talu, Jianmin Li, Ravi Kumar, Paul M. Mathias, J. Douglas Moyer Jr, Joan M. Schork

Chemical & Biomedical Engineering Faculty Publications

Multicomponent adsorption equilibrium data are essential for the reliable design of processes and equipment for gas separation by adsorption. We discuss techniques for the measurement and analysis of multicomponent adsorption equilibrium data, and present a comprehensive set of equilibrium data for the adsorption of oxygen and nitrogen on 5A-zeolite.

Effects Of Structural And Kinetic Parameters On The Performance Of Chromatographic Columns Packed With Perfusive And Purely Diffusive Adsorbent Particles, G. A. Heeter, Athanasios I. Liapis

Chemical and Biochemical Engineering Faculty Research & Creative Works

A mathematical model describing dynamic adsorption in columns with spherical bidisperse perfusive or spherical bidisperse purely diffusive adsorbent particles is used to study the effects of the structural parameters of the adsorbent particles and of the parameters of the adsorption mechanism on the performance of chromatographic systems involving the adsorption of bovine serum albumin onto anion-exchange porous adsorbent particles. Four structural parameters are studied: the particle diameter, d(p), the macropore void fraction, ε(p), the microparticle diameter, d(m) and the parameter φ which affects the value of the permeability of the adsorbent particle. Two parameters of the adsorption mechanism are studied: …

An Esr Study Of Free Radicals In Electroreduction Process Of Allyl Alcohol, Jindong Zhang, Yafei Kuang, Shukun Huang, Naixian Xie, Fengzhen Wang, Dewen Chen

Journal of Electrochemistry

Electrochemical-ESR technique with spin trap phenyl-t-butyl nitrone(PBN)was used to study the intermediates of electroreduction of allyl alcohol at platinized platinum electrode in acidic alcohol-aqua solution. Hydrogen and allyl group and(or)propyl group radicals were identified by a hyperfine spectrum of the radical adducts, and that provided a direct evidence for the presence of these radicals in the electroreduction of allyl alcohol.

A Study On Solid Polymer Electrolyte Fuel Cell, Hongfeng Xu, Ming Han, Baolian Yi, Xinge Zhang, Shanhai Ge

Journal of Electrochemistry

Solid polymer electrolyte fuel cell (SPEFC) show promise of a high level of performance in the present fuel cell. In this paper, we report the method of SPEFC electrode preparation,and the effects of temperature, pressure and gas flow rate on the performance.

A Study On Electrochemical Oxidation Of Reduced Nicotinamide Coenzyme Nadh In Organic Media, Fangzu Yang, Huihuang Wu, Shukai Xu, Shaomin Zhou

Journal of Electrochemistry

The behaviour of electrochemical oxidation of the reduced nicotinamide coenzyme NADH on glassy carbon was studied and some kinetic parameters were measured by means of voltammometry in the N-dimethylformamide (DMF) and 1,4-dioxane media respectively. The eletrochemical oxidation of NADH shows completely irriversable both in the two solvents,and the diagnostic experiments support that the process involves a fast chemical step.The oxidation rate and the diffusion coefficient of NADH in DMP are smaller than those in 1,4-dioxane, but the response current is more stable in DMF. The experimental results are discussed by solvent effects.

Study On The Growth Process Of Lead Dioxide On Lead-Antimony Electrodes By Impedance Tracing Method, Guolin Wei, Hongxin Yang, Jiarong Wang

Journal of Electrochemistry

The growth process of PbO₂ formed by the oxidation of PbSO₄ in the anodic film on lead-(1,3,5,7)wt% antimony electrodes was investigated with impedance tracing method of single frequency and the current-time transient method. The influence of antimony on this process was studied.The simulation curves obtained for capacity-time transients fit the experimental results very well. It has been shown that the mentioned growth process is a two-dimentional instantaneous nucleation and growth process. Antimony will inhibit the growth of PbO₂ nucleus but enhance its nucleation.

Fabrication Of Double Side Fully Metallized Plated Thru-Holes, In Polymer Structures, Without Seeding Or Photoprocess, Ravi F. Saraf

Department of Chemical and Biomolecular Engineering: Patents

The present invention is directed to a process of a method for the full metallization of thru-holes in a polymer structure comprising the steps of applying a film-forming amount of a conductive polymer-metal composite paste to a metal cathode; bonding a patterned polymer structure to said paste; subjecting said polymer structure to an electrolytic plating bath for a time sufficient to fully metallize thru-hole surfaces in said patterned polymer structure and removing the structure from the cathode assembly. The fully metallized thru-hole polymer structure can then be cleaned and polished to produce a finished product.

Direct Chip Attachment (Dca) With Electrically Conductive Adhesives, Ravi F. Saraf

Department of Chemical and Biomolecular Engineering: Patents

A simple process for card assembly by Direct Chip Attachment (DCA) uses electrically conductive adhesives. Two methods create the same intermediate wafer product with a layer of insulative thermoplastic and conductive thermoplastic bumps. After sawing or dicing the wafer to form the chips, the chips are adhered to chip carriers with conductive pads which match the conductive thermoplastic bumps, using heat and pressure. Chips may be easily removed and replaced using heat.

Sulfur Tolerant Bimetallic Zeolitic Reforming Catalysts, Gustavo F. Larsen

Department of Chemical and Biomolecular Engineering: Patents

New compositions of matter comprise a metal from the group consisting of platinum, rhodium and palladium, a metal from the first row of Group VIII of the Periodic Table and a nonacidic L-zeolite. A preferred composition is Pt--Ni/KL-zeolite. Such catalysts are prepared by coimpregnation of the zeolite with the metals. Methods of using the catalysts in reforming, aromatization or dehydrogenation are provided.

Characterization Of The Si/Sio2 Interface Formed By Remote Plasma Enhanced Chemical Vapor Deposition From Sih4/N2O With Or Without Chlorine Addition, Young-Bae Park, Xiaodong Li, Shi-Woo Rhee

Faculty Publications

The Si/SiO₂interface formed by remote plasma enhanced chemical vapor deposition (RPECVD) at low temperature with SiH₄/N₂O or SiH₄/N₂O/Cl₂ was studied and compared with thermal oxidation. The interface of the CVD SiO₂ without chlorine addition is rougher than that with chlorine addition. But the surface roughness of CVD SiO₂ films increases with chlorine addition. The thermal oxidation induces strong interface strains, and the strains generated by the CVD SiO₂ without chlorine addition are stronger and are distributed more nonuniformly than those by the chlorinated SiO₂. …

Polyelectrolyte Dna Conjugation And Genetic Transformation Of An Animal , William H. Velander

Department of Chemical and Biomolecular Engineering: Patents

Improved cellulosic beads for use as supports in bioaffinity chromatography are produced by dissolution of cellulose in a chaotropic cellulose solvent, formation of the dissolved cellulose into droplets, and immersion of the droplets into a non-solvent capable of solvent interchange with the cellulose solvent to form generally spherical porous cellulose beads of narrow particle size distribution. The beads formed are preferably made with cellulose having a degree of polymerization between 100 and 200, and the resulting beads when saturated with water without drying contain between 1% and 7% cellulose by weight and have a particle size of at least about …

Anion Induced Blue To Purple Transition In Bacteriorhodopsin, Mrunalini Pattarkine, Anil K. Singh

Faculty Works

Purple membrane (PM, λ" role="presentation">λmax" role="presentation">max 570 nm) of H. halobium on treatment with sulphuric acid changes its colour to blue (λ" role="presentation">λmax" role="presentation">max 608 nm). The purple chromophore can be regenerated from the blue chromophore by exogeneous addition of anions such as CI−" role="presentation">− and HPO42−" role="presentation">2−4. Chloride ion is found to be more effective than the dibasic phosphate ion in regenerating the purple chromophore. Nevertheless, one thing common to the anion regeneration is that both CI−" role="presentation">− and HPO42−" role="presentation">2−4 show marked pH effect. At pH 1.0 the efficiency of …

Emulsion Liquid Membrane Removal Of Arsenic And Strontium From Wastewater : An Experimental And Theoretical Study, Ding-Wei Zhou

Dissertations

The emulsion liquid membrane (ELM) technique has been successfully applied on the removal of arsenic (As) from metallurgical wastewater and the removal of strontium (Sr) horn radioactive wastewater. This study consisted of experimental work and mathematical modeling.

Extraction of arsenic by an emulsion liquid membrane was firstly investigated. The liquid membrane used was composed of 2-ethylhexyl alcohol (2EHA) as the extractant, ECA436OJ as the surfactant, and Exxsol D-8O solvent (or heptane) the diluent. The sulfuric acid and sodium hydroxide solutions were use I as the external and internal phases, respectively. The arsenic removal efficiency reached 92% within 15 minutes in …

Removal Of Vocs From Waste Gas Streams By Cyclic Membrane Separation Techniques, Gordana Obuskovic

Theses

In this study, new separation techniques called Flow Swing Membrane Absorption Permeation (FSMABP) and Flow Swing Membrane Permeation (FSMP) were used for the removal of the volatile organic compounds (VOCs). In both cases, processes are cyclic in terms of feed flow while desorption of the VOCs is constantly taking place. The transport mechanism in the FSMABP process is selective permeation followed by absorption of the VOCs into the stagnant nonvolatile absorbent liquid on the shell side of the membrane module and then desorption through a similar polymeric membrane. In the FSMP process, VOCs selectively permeate through the membrane into the …

Mass Transfer Of Pryene Between A Solid Phase And Oil/Water Suspensions, Sachin Ashok Purekar

Theses

This study dealt with understanding the partitioning of pyrene between water and mineral oil, and the mass transfer of pyrene from solid particles to oil/water suspensions.

It was found that when pyrene is dissolved in mineral oil, the amount transferred to water is negligible even after 10 days of phase contact.

Glass beads and sand were used as model solid phases to simulate soil and PAH (pyrene)-contaminated industrial sludges.

The transfer of pyrene from glass beads to mineral oil when no water phase is present was quantified. Mass transfer coefficients, and their dependence on the rate of environment shaking were …

Status Of The Research And Development For Fuel Cell Technology Abroad, Naichao Li, Baolian Yi

Journal of Electrochemistry

Status of the research and development for fuel cell technology abroad was overviewed, and at the aim of accelerating the research and development for fuel cell technology in China, the corresponding stategy for our country was recommended.

Electrocatalytic Oxidation Of Some C2 Compounds (Alcohols, Aldehydes, And Carboxylic Acids) On A Pt/SbAd Electrod, Hong Li, Lincai Jiang, Xiong Jiang

Journal of Electrochemistry

The electrocatalytic oxidation behavior of some C₂ compounds(alcohols, aldehydes and carboxylic acids) on a Pt/Sb_ad electrode prepared in-situ or ex-situ UPD was investigated using pontential sweep and rotating disc electrode methods. It is confirmed that Pt/Sb_ad electrode show the most electrocatalytical active to the oxidation of aldehyde functional group and only a little activity to the oxidation of hydroxyl group, but no activity for the oxidation of carboxyl group.

The experimental results show that the activity of the Pt/Sb_ad electrode prepared by ex-situ UPD is higher than that prepared by in-situ UPD.

The limitations of the …

Electrocatalytic Reduction Of Nitrite In The Presence Of Complex Of Cobalt(Ⅱ) And 1,10 Phenanthroline, Jian Tong, Xiaojun Dang, Hulin Li

Journal of Electrochemistry

The electrochemistry of cobalt(Ⅱ)-1,10-phenanthroline Co(Phen)₂²⁺ complex and its ability to electrocatalyze the reduction of nitrite were studied, we found that this complex could act as a catalyst in alkaline or neutral solution for nitrite reduction. We have investigated the effect of the complex composition on electrocatalytic ability. The effects of pH value, complex concentration, regeneration and activation of electrocatalyst on the catalytic current have been studied and discussed.

The Reduction Of Oxygen To Hydrogen Peroxide In An Acidic Trickle Bed Cell Using Graphite Chip Cathode, Zhaoe Lu, Guanyong Zhang, Tiangeng Zhong, Guonu Fang

Journal of Electrochemistry

The authors investigated the electrochemical reduction of oxygen to hydrogen peroxide in 0.05 mol/L H₂SO₄ solution by the trickle bed electrode using graphite chip. The bed dimension was 14×5×0.6 cm. The current efficiency and the concentration of H₂O₂ in the catholyte were determined at various current strengths and various rates of adding the electrolyte. The proper current was 0.15 A. i.e. the current density was 2.1 mA/cm² vertical cross section area of the bed. The concentration of H₂O₂ reached 7×10^-3 mol/L with the current efficiency of 0.2. If the …

Multi-Component Perfusion Chromatography In Fixed Bed And Periodic Counter Current Column Operation, G. A. Heeter, Athanasios I. Liapis

Chemical and Biochemical Engineering Faculty Research & Creative Works

A mathematical model of multi-component dynamic adsorption in columns with spherical perfusive and spherical purely diffusive adsorbent particles with a bidisperse porous structure is constructed, solved, and used to study the performance of a binary adsorption system in a single-column fixed-bed process and in a two-column periodic countercurrent process in which the adsorbent is equally distributed over two beds. The total length of the two-column periodic counter-current system is equal to the length of the single-column fixed-bed system. The performance of fixed-bed and periodic counter-current systems with both perfusive and purely diffusive adsorbent particles is examined for different values of …

Experimental And Theoretical Study Of Vibrations Of A Cantilevered Beam Using A Zno Piezoelectric Sensor, B. R. Jooste, Hendrik J. Viljoen, S. L. Rohde, N. F. J. Van Rensburg

Hendrik J. Viljoen Publications

Piezoelectric sensors can measure vibrations of solid structures very accurately. A model of a cantilevered beam, with a ZnO film on one side is presented. Both viscous and internal damping are considered. The output of the sensor is modeled and matched with experimental results by adjusting the damping parameters. A theoretical formulation for damage is introduced. Experimental results for a damaged beam confirm the shift in frequencies to lower values. The model is used to identify the extent of the damage.

Behavior And Performance Of Adsorptive Natural Gas Storage Cylinders During Discharge, K. J. Chang, Orhan Talu

Chemical & Biomedical Engineering Faculty Publications

Adsorbed natural gas (ANG) has the potential to replace compressed natural gas in mobile storage applications, such as in vehicles. Although a substantial research effort has been devoted to ANG, very few studies evaluate the impact of heat of adsorption on system performance. This paper concentrates on the impact of heat of adsorption on ANG performance during discharge, while the gas outflow rate is dictated by the energy demand of the application. The temperature drop and performance loss was measured with commercially available ANG cylinders under realistic conditions. Data show as high as a 37°C temperature drop at …

Nucleation Initiated Spinodal Decomposition In A Polymerizing System, Thein Kyu, Jae Hyung Lee

College of Polymer Science and Polymer Engineering

Dynamics of phase separation in a polymerizing system, consisting of carboxyl terminated polybutadiene acrylonitrile/epoxy/methylene dianiline, was investigated by means of time-resolved light scattering. The initial length scale was found to decrease for some early periods of the reaction which has been explained in the context of nucleation initiated spinodal decomposition We have combined the Cahn-Hilliard kinetic equation and polymerization kinetics, and predicted the initial reduction of the length scale triggered by nucleation.

Experimental And Theoretical Study Of Vibrations Of A Cantilevered Beam Using A Zno Piezoelectric Sensor, B. R. Jooste, Hendrik J. Viljoen, S. L. Rohde, N. F. J. Van Rensburg

Hendrik J. Viljoen Publications

Piezoelectric sensors can measure vibrations of solid structures very accurately. A model of a cantilevered beam, with a ZnO film on one side is presented. Both viscous and internal damping are considered. The output of the sensor is modeled and matched with experimental results by adjusting the damping parameters. A theoretical formulation for damage is introduced. Experimental results for a damaged beam confirm the shift in frequencies to lower values. The model is used to identify the extent of the damage.

Extensive Study Of The Pvc Industry: Relation Of The Processing Time And Processing Temperature To The Degree Of Fusion, As Well As A Strategic Plan For Increasing Consumer Demand, Erick Jason Comeaux

Honors Capstones

No abstract provided.

Droplet Evaporation And Deformations In An Amplitude Modulated Ultrasonic Field, Nihad E. Daidzic, Rene Stadler, Adrian Melling

Aviation Department Publications

The aim of the report presented is the measurements of droplet oscillations.

The Effect Of Wet End Operations On Sizing Loss In Alkaline Papers, Suresh B. Cherukuri

Masters Theses

Changes in wet end of alkaline papermaking affect the size development as well as sizing loss. These changes include pH, alkalinity and type of filler used. Precipitated and ground varieties of carbonate fillers and the alkalinity associated with · them are believed to be the causes for the gradual sizing loss in alkaline papers due the accelerated hydrolysis reaction of sizing chemicals at higher alkalinity.

Precipitated and ground calcium carbonate fillers are used as fillers and compared to non carbonate filler such as kaolin clay for their response to size development and sizing loss at lower and higher alkalinity ranges …

Convection During Thermally Unstable Solidification Of Pb-Sn In A Magnetic Field, Hui Song, Surendra N. Tewari, H. C. Degroh Iii

Chemical & Biomedical Engineering Faculty Publications

Convection and macrosegregation in directionally solidified hypoeutectic Pb-38 wt pct Sn and hypereutectic Pb-64.5 wt pct Sn have been examined during upward and downward growth. Temperature fluctuations are observed along the length of the melt column during downward growth. With increasing Rayleigh number, these fluctuations change from none, to cyclic, to time periodic having multiple harmonics, and finally to random. At the higher convective driving force of 350 K temperature inversion, the transverse magnetic field decreased convective levels, strong random temperature fluctuations (flows) becoming smaller and periodic. The maximum field of 0.45 T was unable to completely eliminate convection. For …

Non-Markovian Brownian Motion In A Viscoelastic Fluid, V. S. Volkov, Arkadii I. Leonov

College of Polymer Science and Polymer Engineering

A theory of non-Markovian translational Brownian motion in a Maxwell fluid is developed. A universal kinetic equation for the joint probability distribution of position, velocity, and acceleration of a Brownian particle is derived directly from the extended dynamic equations for the system. Unlike the extended Fokker-Planck equation which corresponds to Mori-Kubo generalized Langevin equation and provides only with calculations of one-time moments, the universal kinetic equation obtained gives complete statistical description of the process. In particular, an exact generalized Fokker-Planck equation in the velocity space valid for any time instant is derived for the free non-Markovian Brownian motion. It shows …