Engineering Commons^™

Direct Chip Attachment (Dca) With Electrically Conductive Adhesives, Ravi F. Saraf

Department of Chemical and Biomolecular Engineering: Patents

A simple process for card assembly by Direct Chip Attachment (DCA) uses electrically conductive adhesives. Two methods create the same intermediate wafer product with a layer of insulative thermoplastic and conductive thermoplastic bumps. After sawing or dicing the wafer to form the chips, the chips are adhered to chip carriers with conductive pads which match the conductive thermoplastic bumps, using heat and pressure. Chips may be easily removed and replaced using heat.

Direct Chip Attachment (Dca) With Electrically Conductive Adhesives, Ravi F. Saraf

Department of Chemical and Biomolecular Engineering: Patents

A simple process for card assembly by Direct Chip Attachment (DCA) uses electrically conductive adhesives. Two methods create the same intermediate wafer product with a layer of insulative thermoplastic and conductive thermoplastic bumps. After sawing or dicing the wafer to form the chips, the chips are adhered to chip carriers with conductive pads which match the conductive thermoplastic bumps, using heat and pressure. Chips may be easily removed and replaced using heat.

Analysis Of Combustion-Driven Acoustics, Leonie Boshoff-Mostert, Hendrik J. Viljoen

Papers in Reaction Kinetics

Combustion-driven acoustic oscillations are investigated by performing a onedimensional stability analysis of a burner-stabilized premixed flame. In contrast to other investigators, no initial acoustic wave is assumed in the analysis; the downstream acoustic field results from flame instability. Two models are considered: the thermodiffusive model (uncoupled model) and the fully coupled thermodiffusive-hydrodynamic model. The fully coupled problem exhibits instability at a much lower critical Lewis number than the uncoupled problem.

Kinetics Of Phase Transition In An Anticlinic Liquid Crystal Induced By A Uniform Temperature Field: Growth In One Dimension, X. Y. Wang, Jian-Feng Li, Eliezer Gurarie, S. Fan, Thein Kyu, S. S. Keast, Charles Rosenblatt

College of Polymer Science and Polymer Engineering

It is experimentally demonstrated that a transition from a synclinic to an anticlinic liquid crystal phase occurs via stable domain wall propagation after quenching in a uniform temperature field. Such a one-dimensional growth may be explained in terms of a nonlinear diffusion equation. The experiment provides the first example of free, one-dimensional growth in a system subjected to a pure and uniform temperature field.

Molecular Modelling Studies Of Acetylcholinesterase, Charilaos E. Linaras

Dissertations

The controversial role of electrostatic interactions in the process of steering of acetylcholine into the active site of acetylcholinesterases was investigated in this study. A novel methodology was implemented to simulate the process of recognition of acetylcholine by Torpedo Californica and both wild type and charge neutralized mutated Human AChE. The obtained results suggest the important role of coulombic interactions in the steering process. The steering process of selected irreversible AChE inhibitors was also simulated supporting the role of electrostatic interactions in the recognition process.

A novel methodology was also employed to model the covalent adducts of Torpedo Californica and …

Diffusivities Of N-Alkanes In Silicalite By Steady-State Single-Crystal Membrane Technique, Orhan Talu, Matthew S. Sun, Dhananjai B. Shah

Chemical & Biomedical Engineering Faculty Publications

A novel experimental technique that measures the diffusive flux through a single-crystal membrane (SCM) was developed and tested. Unlike all other macroscopic techniques that depend on a transient response, SCM is used under steady-state conditions, which results in a wide range of applicability from 10⁻² to 10⁻¹¹ cm²/s. Phenomenological equations for the steady-state data analysis were developed. The variation of driving force over the diffusion path is included in the model. As required by thermodynamics, the micropore concentration is given as a function of surface-excess amount adsorbed and gas density. The membrane configuration measures diffusivity in …

Studies Of Surface Electrochemistry And Electrocatalysis At Atomic And Molecule Level, Shigang Sun

Journal of Electrochemistry

The main progresses achieved during last few years in our research group concerning studies of surface electrochemistry and electrocatalysis were reviewed in this present paper. Four topics were described: 1) the surface electrochemistry and model electrocatalysis of metal single crystal planes, 2) the electrocatalytic reaction mechanism and the control of reaction pathways at molecule level, 3) the reaction kinetics of electrooxidation of small organic molecules, and 4) the relationship between the properties and the surface chemical states of electrocatalyst. This review lays in emphasis on the demonstration of the results as well as the research direction of surface electrochemistry and …

Study On The Synthesis And Electrochemical Behavior Of Poly (Quinonoid-Disulfide), Xiaohui Tang, Xiuwu Sun, Yongfang Li, Shibi Fang

Journal of Electrochemistry

Organic polydisulfide containing quinonoid structure was synthesized by chloromethylation, oxidation by nitric acid, and condensation polymerization with sodium disulfide. The effect of quinonoid structure on the electrochemical behavior of organic polydisulfide was investigated with cyclic voltammetry and chargedischarge measurement. The result shows that quinonoid struture mainly affects the positions of redox peaks of organic polydisulfide, open circuit voltage and discharge platform voltage of cell with the organic polydisulfide as cathode.

The Investigations Of Surface Treatment Methods And Characterization Of Oxide Films On Ab5 Based Metal Hydride Electrodes Ⅰ. New NiRich Treatment Methods And Photoelectrochemical Characterization Of Oxide Films, Junmin Nan, Yong Yang, Jun Li, Zugeng Lin

Journal of Electrochemistry

Two simple and efficient surface treatment methods for AB₅ type hydrogen storage alloys were developed. The results of X-ray photoelectron spectroscopy (XPS) and cyclic voltammetric (CV) experiments showed that the hydrogen storage alloys treated by two different methods had Ni rich surface layer so that the performances of the electrodes were improved after treatment. The characterization of the oxide films which formed on the surface of electrodes through potentiodynamic oxidation with the help of photoelectrochemical microscopy (PEM) were done. The anodic photocurrent and the cathodic photocurrent related to the oxidation of hydrogen and the reduction of oxygen on the …

A Study On Heterogeneous Indirect Electrosynthesis Of Benzaldehyde, Daobao Chu, Changjian Lin, Huashui Lin, Jianguang Tan

Journal of Electrochemistry

Heterogeneous indirect electrosynthesis process of benzaldehyde has been investigated using cyclic voltammetry and polarization curves. An optimum condition for preparation of benzaldehyde by indirect electrooxidation of toluenc with redox Mn³⁺/Mn²⁺ is given in this paper. Electrolytic regeneration Mn³⁺ are made at Pt/Ti anode in “slurry” MnSO₄/H₂SO₄ medium. Current efficiency for electrolytic regeneration Mn³⁺  was maintained over 88% by “double cyclic way”.

Investigation Of Methanol Anode Electrooxidation Catalysts, Gangyao Wen, Ying Zhang, Zhenglong Yang, Changzhi Li

Journal of Electrochemistry

A series of catalysts, Pt-WO₃/C, Pt/Ru/C and Pt-Ru-WO₃/C were prepared by chemical reduction deposition. Electrocatalytic oxidation of methanolon different catalyst/Nafion membrane electrodes was studies by voltammetry and current-potential polarization. The results indicated that the catalytic activity order of different catalysts is as follows: Pt-Ru-WO₃/C > Pt-Ru/C > Pt-WO₃/C. At the same time, influences of methanol concentrations and catalyst proportion on performances of anodes were also studies.

Progresses In Surface Electrochemistry And Electrocatalysis ——A Review On The 1997 Joint International Meeting Of Electrochemistry And 97' International Meeting Of Surface Electrochemistry, Shigang Sun

Journal of Electrochemistry

The progresses in surface electrochemistry and electrocatalsis reported in the 1997 joint international meeting of electrochemistry and in the 97′ international meeting of surface electrochemistry were reviewed. The main trends described in this paper consisted of 7 aspects: 1) the studies employing single crystal electrodes, 2) the development of in situ methods of diverse spectroscpoy, 3) the innovation of new research techniques, 4) the preparaton of electrocatalyst of high performances, 5) the quantitative studies on kinetics of electrocatalytic reactions, 6) the investigation on the dynamic processes of surface by timeresolved methods, and 7) the theoretical modeling and simulation of surface …

Phase Equilibria Of A Nematic And Smectic-A Mixture, Hao-Wen Chiu, Thein Kyu

College of Polymer Science and Polymer Engineering

A phase diagram of a mixture consisting of nematic and smectic liquid crystals has been calculated self-consistently by combining Flory-Huggins (FH) theory for isotropic mixing and Maier-Saupe-McMillan (MSM) theory for smectic-A ordering. However, the MSM theory can be deduced to the original Maier-Saupe (MS) theory for nematic ordering. To describe the phase transitions involving induced smectic phase and nematic + smectic equilibrium, two nematic and two smectic order parameters for the nematic/smectic mixtures have been coupled through the normalized partition function and the orientation distribution function. Self-consistent numerical solution has been sought in establishing nematic/smectic phase diagrams involving (i) phase …

Frontal Chromatography Of Proteins. Effect Of Axial Dispersion On Column Performance, G. A. Heeter, Athanasios I. Liapis

Chemical and Biochemical Engineering Faculty Research & Creative Works

A mathematical model describing the dynamic adsorption of proteins in columns packed with spherical porous adsorbent particles is used to study the effect of axial dispersion on the performance of chromatographic systems. The values of the axial dispersion coefficient, D(L), are estimated from a correlation based on a model describing axial dispersion in packed beds that provides satisfactory results when compared with experiment. Simulations of frontal chromatography in systems including axial dispersion and in systems without axial dispersion are made and compared to determine the effect of axial dispersion on the efficiency of the adsorption process; also, the system parameters …

Computer Simulations Of Branched Alkanes: The Effect Of Side Chain And Its Position On Rheological Behavior, Richard L. Rowley, Tapani A. Pakkanen, Maija Lahtela, Mikko Linnolahti

Faculty Publications

Nonequilibrium molecular dynamics simulations have been performed on model fluids representing eicosane isomers in order to investigate the effect of branching and side chain position on fluid rheology. A heterogeneous, united-atom model with 20 Lennard-Jones interaction sites located at carbon centers was used to model the fluids. Vibrations and bond rotations were frozen, but torsional rotation was included. It was found that viscosity increases significantly from the n-alkane structure to a branch on carbon 2, but the movement of the branch along the carbon backbone has a smaller increasing than decreasing effect. The size of the group in a branched …

Derivation Of An Analytical Model To Calculate Junction Depth In Hgcdte Photodiodes, Stacy H. Gleixner, H. G. Robinson, C. R. Helms

Faculty Publications

Presents an enhanced analytical model to calculate junction depth and Hg interstitial profile during n-on-p junction formation in HgCdTe photodiodes. Detailed information on the enhanced model; Function of the model; Information on HgCdTe; Detailed information on how the model was obtained.

A Study Of Piezoelectric Orthorhombic Ta2O5, B. R. Jooste, Hendrik J. Viljoen

Hendrik J. Viljoen Publications

In 1985 it was first reported that monoclinic Ta₂O₅ has piezoelectric properties comparable to ZnO. In this work we report on the deposition, characterization, and qualitative assessment of the piezoelectric behavior of orthorhombic Ta₂O₅. Reactive magnetron sputtering was used to deposit thin films of Ta₂O₅ onto substrates of 316L stainless steel. Without substrate heating the crystallinity was poor. A rapid thermal anneal improved the crystallinity. The orthorhombic phase was dominantly present on all substrates. The piezoelectric property was qualitatively assessed, including a high temperature test at 650 °C.

Introduction To Pollution Prevention Concepts In Freshman Chemistry Through Simulations And Hypermidia, Aniraban Bhaumik

Theses

As citizens of the 20th century, a key issue we all are aware of is degradation of the environment. In the interest of teaching the environmental issues to freshmen engineers, this study develops a computer aided learning/teaching (CAL/T) tool.

This CAL/T tool consists of Internet based multimedia courseware and intelligent simulations. The courseware assembles the fundamentals of chemistry associated with current environmental issues such as air pollution, stratospheric ozone layer depletion and environmentally sensitive or 'clean' manufacturing. The courseware targets early and comprehensive understanding of pollution prevention concepts with a focus on environmentally friendly manufacturing. The courseware includes: on-line text, …

Development And Characteristics Of Carbon Nitride Thin Solid Films For Advanced Coating Applications, Muhammad A. Hussain

Theses

Carbon nitride films were synthesized on silicon substrate by reactive magnetron sputtering of graphite target in an environment of Ar and nitrogen gas. The performance of a negative carbon ion source was also investigated to use the source in negative ion-beam-assisted deposition. These films were synthesized at room temperature at a constant pressure of 5 mtorr and at 300 Watts R.17 power, but at different composition of nitrogen in Ar-N₂ gas mixture ranging from 0-53 percent. The films deposited were microscopically smooth, amorphous and their properties found to be varied with nitrogen composition in plasma. The deposition rate was …

Voc Removal From Nitrogen By A Membrane-Based Combined Absorption-Stripping Process, Boya Xia

Theses

A regenerative membrane-based absorption process has been extensively studied to remove volatile organic compounds (VOCs) from air/N₂ using silicone oil as absorbent. The absorbent liquid is regenerated by applying vacuum in a membrane-based stripper. In this process, there are no flooding, loading and entrainment, which limit the gas/liquid flow rate in the traditional absorption process. In the present study, attention has been focused on the removal of volatile component(s) from binary gas mixtures such as methanol-N₂, and toluene-N₂, and from a model multicomponent mixture of gasoline vapor constituents and nitrogen. The process performance was tested …

Removal Of Vocs From Superfactant-Flushed Wastewater By Membrane Based Modified Pervaporation Process, Anirban Das

Theses

An aqueous solution of a volatile organic compound (VOC) e.g. trichloroethylene (TCE) is passed through the bores of hydrophobic microporous polypropylene hollow fibers having a plasma polymerized silicone coating on the fiber outside diameter; a vacuum is maintained on the shell side of the fiber to remove the VOC and recover it by condensation. Process performance has been obtained over a range of feed flow rates, concentrations of VOC and the surfactant (sodium dodecyl sulfate (SDS)). In solutions without surfactant or low surfactant concentrations, the pores are not wetted and remain gas-filled. The VOC is stripped from the solution into …

Birkman Screening And The Covariance Of The Fluid Velocity Of Fixed Beds, Ashok S. Sangani, Donald L. Koch, Reghan J. Hill

Biomedical and Chemical Engineering - All Scholarship

The phenomenon of Brinkman screening, whereby the fluid velocity disturbance produced by each particle in a fixed bed is attenuated by the forces that the fluid exerts on surrounding particles, plays a crucial role in limiting the range of velocity correlations in porous media and fixed beds. Koch and Brady [J. Fluid Mech. 154, 399 (1985)] showed theoretically that Brinkman screening leads to a finite hydrodynamic diffusion coefficient for fluid phase tracers in dilute fixed beds. In this Letter, we present the results of two simulation techniques (lattice-Boltzmann method and a multipole method) confirming the screening of the fluid velocity …

Fuel Cells, Frederick J. Munster Jr.

Maine Collection

Fuel Cells

by Frederick J. Munster Jr.

Edited by: Mr. Christopher Carroll

Maine Department of Economic Development, Augusta, Maine, 1998.

Contents: Hydrogen / Hydrogen Safety / Electrolysis / Electrolyzers / History of Fuel Cells / How Fuel Cells Operate / Fuel Cell Types / Fuel Cell Electrochemistry / Power Systems / Fuel Cells in Transportation / Hydrogen Powered Internal Combustion Engines / Home, Garden, Education and Industry / For More Information / Glossary / References

Dynamic Analysis Of Unidirectional Pressure Infiltration Of Porous Preforms By Pure Metals, Dhiman K. Biswas, Jorge E. Gatica, Surendra N. Tewari

Chemical & Biomedical Engineering Faculty Publications

Unidirectional pressure infiltration of porous preforms by molten metals is investigated numerically. A phenomenological model to describe fluid flow and transport phenomena during infiltration of fibrous preforms by a metal is formulated. The model describes the dynamics of the infiltration process, the temperature distribution, and solid fraction distribution. The numerical results are compared against classical asymptotic analyses and experimental results. This comparison shows that end effects may become important and render asymptotic results unreliable for realistic samples. Fiber volume fraction and initial temperature appear as the factors most strongly influencing infiltration. Metal superheating affects not only the length of the …

Improving The Jar Slake, Slake Index, And Slake Durability Tests For Shales, Paul M. Santi

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This study proposes modifications to three shale durability tests to improve reproducibility, reduce the level of effort required, and better correlate the test to actual slaking characteristics. Modifications to the jar slake test reduced test variability by one-third, offering a substantial improvement in consistency, with only a slight loss in the ability of the test to predict slake durability. Analysis showed that slake index test error could be reduced or at least pinpointed by testing groups of samples, rather than single samples. Furthermore, the wet-sieving procedure should be more carefully defined. Analysis of correlations between single- and multiple-cycle slake durability …

Investigation Of A Complex Reaction Network: I. Experiments In A High-Pressure Trickle-Bed Reactor, M. R. Khadilkar, Y. Jiang, M. (Muthanna) H. Al-Dahhan, M. P. Duduković, S. K. Chou, G. Ahmed, R. Kahney

Chemical and Biochemical Engineering Faculty Research & Creative Works

A High-Pressure Trickle-Bed Reactor Was Used to Achieve High Productivity and Selectivity for the Manufacture of a Key Herbicide Intermediate (Α-Aminomethyl-2-Furanmethanol (Amino Alcohol, AA) from Α-Nitromethyl-2-Furanmethanol (Nitro Alcohol, NA). Raney Nickel Catalysts of Varying Activity Were Prescreened for Suitability in Trickle-Bed Operation. the Effect of Operating Parameters Such as Reactant Feed Concentration, Liquid Mass Velocity, and Temperature on the Yield of Amino Alcohol (AA) for RNi-A Are Discussed. the Superiority of Trickle-Bed Reactors over Others Such as Semibatch and Batch Slurry Systems is Demonstrated. the AA Yield Increases with Decrease in Feed Reactant Concentration and Liquid Mass Velocity, as Well …

Modeling Partially Premixed Fast Chemical Reactions In Statistically Homogeneous Turbulent Flow Using One-Dimensional Equations Of Change, Yang Gi Kim, X. B. Reed

Chemical and Biochemical Engineering Faculty Research & Creative Works

A pseudospectral algorithm has been used to compute solutions u(x,t), Ax,t), B(x,t), and R(x,t) to one-dimensional equations of change incorporating the simple reaction A + B → R for statistically homogeneous random velocity and partially premixed reactant concentration fields. An initial turbulence Reynolds number of 400 has been used, together with Damkohler numbers of 102 and 103 for fast reactions and Schmidt numbers of 10-3, 1, and 102 to span a wide range of diffusivities. Evolving concentration profiles inform intuition in general and provide insight into the evolution of the single-point statistical measures in particular: (A), (B), (a2), (b2), (ab), …

Experimental Measurements And Simulation Of Mixing And Chemical Reaction In A Stirred Tank, Robertp Zipp, Gary Kent Patterson

Chemical and Biochemical Engineering Faculty Research & Creative Works

Effects of mixing on the rate of second-order chemical reactions have been studied by measuring the time-average degree of conversion at enough points in a steady-state, continuous-flow stirred reactor to provide comparisons with numerical simulations of the same reactions using a standard Reynolds-averaged turbulence simulation code with an added closure. The reactants were introduced in widely separated feed streams in order to provide a difficult test for the measurements and simulations. Concentration and segregation measurements were made with two fluorescence based methods - one remote and one using a fiber optic probe. The rates of mixing and reaction were simulated …

Optical Digital Fragmentation Measuring Systems -- Inherent Sources Of Error, Norbert H. Maerz, Wei Zhou

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Automated optical imaging systems of measuring fragmentation are increasingly being used in the mining, comminution, and materials handling industries. These methods have been well received in many of the industries involved. Considering that in many of these applications there are no alternative ways of sizing material, having even a rudimentary measurement of size distributions allows evaluations of explosive, blast design, detonator performance, crusher and milling performance, and material degradation due to transport.

Optical methods have inherent limitations, which reflect on accuracy, precision, and reproducibility of measurement results. This stems from the fact that there are myriads of variables, which affect …

Investigation Of A Complex Reaction Network: Ii. Kinetics, Mechanism And Parameter Estimation, Y. Jiang, M. R. Khadilkar, M. (Muthanna) H. Al-Dahhan, M. P. Duduković, S. K. Chou, G. Ahmed, R. Kahney

Chemical and Biochemical Engineering Faculty Research & Creative Works

Conventional Strategies for Discrimination of Intrinsic and Apparent Kinetics from Crushed- and Whole-Catalyst-Pellet Experimental Data, Respectively, Do Not Yield Satisfactory Results for the Reaction Network in the Manufacture of Α-Aminomethyl-2-Furanmethanol (Aminoalcohol) from Α-Nitromethyl-2-Furanmethanol (Nitroalcohol). Laboratory Trickle-Bed Reactor Tests in the Range of Concentration and Product Yield of Commercial Interest Are Utilized to Yield a Reasonable Set of Kinetic Parameters, Which Are Otherwise Unobtainable. This is Accomplished by Proposing a Reaction Network, a Plausible Mechanism, and Optimizing the Kinetic Parameters based on the Reactor-Model-Generated Performance Data to Fit Experimental Output Concentrations of All Species for the Entire Set of Experiments. a …