Engineering Commons^™

Modeling Adsorption Of Cane Sugar Colorant In Packed-Bed Ion Exchangers, Hugh Anthony Broadhurst

LSU Master's Theses

The removal of cane sugar solution colorant by packed-bed ion exchangers was modeled using a linear driving force (LDF) adsorption model. Adsorption of colorant is of interest to the developers of the White Sugar Mill (WSM) process as it is a complex subject. The problem is that color is an indiscrete mixture of many components making it difficult to measure and even more challenging to model. Colorant formation was investigated using gel permeation chromatography (GPC) with the objective of developing a method to define pseudo-components representative of cane sugar solution colorants. WSM is a process for producing white sugar directly …

The Effects Of Rock And Fluids Characteristics On Reservoir Wettability, Chandra S. Vijapurapu

LSU Master's Theses

Wettability is the ability of a fluid to spread or adhere on a rock surface in the presence of other immiscible fluids. Knowledge of wettability is important to decide what production strategy needs to be employed for optimum oil recovery. Wettability is affected by rock mineralogy, rock surface roughness, and brine compositions. Previous studies have dealt with solid-liquid-vapor systems and those involving wettability characterization in solid-liquid-liquid systems have used contact angle techniques known to have reproducibility problems. In this study, a new technique called the Dual-Drop-Dual-Crystal (DDDC) Technique has been used to characterize wettability in terms of dynamic contact angles. …

Slab-Geometry Molecular Dynamics Simulations: Development And Application To Calculation Of Activity Coefficients, Interfacial Electrochemistry, And Ion Channel Transport, Paul S. Crozier

Theses and Dissertations

Methods of slab-geometry molecular dynamics computer simulation were tested, compared, and applied to the prediction of activity coefficients, interfacial electrochemistry characterization, and ion transport through a model biological channel-membrane structure. The charged-sheets, 2-D Ewald, corrected 3-D Ewald, and corrected particle-particle-particle-mesh (P3M) methods were compared for efficiency and applicability to slab-geometry electrolyte systems with discrete water molecules. The P3M method was preferred for long-range force calculation in the problems of interest and was used throughout.

The osmotic molecular dynamics method (OMD) was applied to the prediction of liquid mixture activity coefficients for six binary systems: methanol/n-hexane, n-hexane/n-pentane, methanol/water, chloroform/acetone, n-hexane/chloroform, methanol/ …

Best Available Treatment Technologies Applied To Groundwater Circulation Wells, Andrew Curtis Elmore, Thomas Graff

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Groundwater circulation wells (GCWs) are a quasi-in-situ method for remediating groundwater in areas where remediation techniques that limit the water available for municipal, domestic, industrial, or agricultural purposes are inappropriate. The inherently resource-conservative nature of groundwater circulation wells is also philosophically appealing in today's culture, which is supportive of green technologies. Groundwater circulation wells involve the circulation of groundwater through a dual screen well, with treatment occurring between the screens. The wells are specifically designed so that one well screen draws in groundwater and the second returns the groundwater after it has been treated within the well. Historically, the treatment …

A Unified Theory On Residual Oil Saturation And Irreducible Water Saturation, Nick P. Valenti, R. M. Valenti, Leonard Koederitz

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

In many mature fields, there is a growing debate as to how much of the remaining oil is mobile in the unswept regions versus immobile in the swept regions. Log measured oil saturations behind the flood front are substantially lower than the residual oil saturations measured from special core analysis. In order to explain this contradiction, data from several fields is analyzed with special emphasis on capillary pressure. The concept of irreducible water saturation, connate water saturation, residual oil saturation and "critical water saturation" are discussed. The conclusions which are supported by experiment and theory, have substantial commercial implications concerning …

Incorporation Of Cerium And Neodymium In A Uranyl Hydroxide Solid, Chang-Soo Kim, David J. Wronkiewicz, R. J. Finch, E. C. Buck

Electrical and Computer Engineering Faculty Research & Creative Works

The migration behavior of radionuclides in a nuclear-waste repository will be influenced, in part, by their equilibrium solubilities in the presence of radionuclide-bearing solids and/or adsorption affinities as trace components onto the surfaces of solid host phases. Uranium phases that precipitate on the surface of altered spent nuclear fuel may thus influence the mobility of radionuclides released in the near-field environment, since by proximity, these will be the first phases that the radionuclides encounter following their release from the spent fuel matrix. We have evaluated the potential for incorporating radionuclides into crystalline compounds by precipitating uranyl phases from aqueous solutions …

Estimation Of Diffusion Coefficient Of Lithium In Carbon Using Ac Impedance Technique, Qingzhi Guo, Venkat R. Subramanian, John W. Weidner, Ralph E. White

Faculty Publications

The validity of estimating the solid phase diffusion coefficient, D_s, of a lithium intercalation electrode from impedance measurement by a modified electrochemical impedance spectroscopy (EIS) method is studied. A macroscopic porous electrode model and concentrated electrolyte theory are used to simulate the synthetic impedance data. The modified EIS method is applied for estimating D_s. The influence of parameters such as the exchange current density, radius of active material particle, solid phase conductivity, porosity, volume fraction of inert material, and thickness of the porous carbon intercalation electrode, the solution phase diffusion coefficient, and transference number, on the …

Using Sputter Deposition To Increase Co Tolerance In A Proton-Exchange Membrane Fuel Cell, Andrew T. Haug, Ralph E. White, John W. Weidner, Wayne Huang, Steven Shi, Narender Rana, Stephan Grunow, Timothy C. Stoner, Alain E. Kaloyeros

Faculty Publications

Placing a layer of Ru atop a Pt anode increases the carbon monoxide tolerance of proton-exchange membrane fuel cells when oxygen is added to the fuel stream. Sputter-deposited Ru filter anodes composed of a single Ru layer and three Ru layers separated by Nafion-carbon ink, respectively, were compared to Pt, Pt:Ru alloy, and an ink-based Ru filter anodes. The amount of Pt in each anode was 0.15 mg/cm² and the amount of Ru in each Ru-containing anode was 0.080 mg/cm². For an anode feed consisting of hydrogen, 200 ppm CO, and 2% O₂ (in the form …

Increasing Proton Exchange Membrane Fuel Cell Catalyst Effectiveness Through Sputter Deposition, Andrew T. Haug, Ralph E. White, John W. Weidner, Wayne Huang, Steven Shi, Timothy Stoner, Narender Rana

Faculty Publications

Sputter deposition has been investigated as a tool for manufacturing proton-exchange membrane fuel cell (PEMFC) electrodes with improved performance and catalyst utilization vs. ink-based electrodes. Sputter-depositing a single layer of Pt on the gas diffusion layer provided better performance (0.28 A/cm² at 0.6 V) than sputtering the Pt directly onto a Nafion membrane (0.065 A/cm² at 0.6 V) and equaled the performance of the baseline for an equivalent Pt loading. Sputter-depositing alternating layers of Pt and Nafion-carbon ink (NCI) onto the membrane did not increase the performance over the baseline as measured in amperes per centimeter squared due …

Simulating Shape Changes During Electrodeposition: Primary And Secondary Current Distribution, Venkat R. Subramanian, Ralph E. White

Faculty Publications

A technique based on the analytical method of lines is presented for predicting shape changes during electrodeposition. The technique is presented for both primary and secondary current distributions. The method presented does not require iterations for nonlinear Butler-Volmer boundary conditions or changing electrode shapes. The technique is based on a semianalytical method developed earlier for predicting current distributions in electrochemical cells. This technique is attractive because it provides a symbolic solution for the Laplace equation, and hence requires less computation time to perform case studies.

Electrochemical Filtering Of Co From Fuel-Cell Reformate, Balasubramanian Lakshmanan, Wayne Huang, John W. Weidner

Faculty Publications

A proton exchange membrane fuel cell was used as a flow reactor for continuous preferential oxidation of CO over H2 from 1.0% CO in H2 under pulse-potential control. By varying the pulse profile ~e.g., on-time, off-time, pulse potential! the CO and H2 oxidation currents were varied independently. The improvement in faradaic selectivity between CO and H2 oxidation results from the promotion of CO adsorption during the off ~i.e., open-circuit! portion of the pulse. Therefore, during the on portion CO oxidation was preferred while the surface was covered with CO.

Anodic Behavior Of Ti In Koh Solutions: Ellipsometric And Micro-Raman Spectroscopy Studies, A. Prusi, Lj. Arsov, Bala Haran, Branko N. Popov

Faculty Publications

Anodic formation of oxide films on titanium surfaces, in various concentrations of aqueous KOH solutions, have been studied using ellipsometry and micro-Raman spectroscopy. By in situ ellipsometric measurements the coefficient of film thickness growth and indexes of refraction of anodic oxide films have been determined. The voltage at which the oxide film breaks down is strongly dependent on the KOH concentration. Further, the solution concentration strongly influences the potential at which the oxide film is transformed from the amorphous state to crystalline form. Using micro-Raman spectroscopy four crystalline forms of titanium oxides, namely, anatase, brookite, corundum, and rutile, have been …

Study Of Sn-Coated Graphite As Anode Material For Secondary Lithium-Ion Batteries, Basker Veeraraghavan, Anand Durairajan, Bala Haran, Branko N. Popov, Ronald Guidotti

Faculty Publications

Tin-graphite composites have been developed as an alternate anode material for Li-ion batteries using an autocatalytic deposition technique. The specific discharge capacity, coulombic efficiency, rate capability behavior, and cycle life of Sn-C composites has been studied using a variety of electrochemical methods. The amount of tin loading and the heating temperature have a significant effect on the composite performance. The synthesis conditions and Sn loading on graphite have been optimized to obtain the maximum reversible capacity for the composite electrode. Heating the composite converts it from amorphous to crystalline form. Apart from higher capacity, Sn-graphite composites possesses higher coulombic efficiency, …

Modeling The Effects Of Electrode Composition And Pore Structure On The Performance Of Electrochemical Capacitors, Changqing Lin, Branko N. Popov, Harry J. Ploehn

Faculty Publications

This work presents a mathematical model for charge/discharge of electrochemical capacitors that explicitly accounts for particle-packing effects in a composite electrochemical capacitor consisting of hydrous RuO₂ nanoparticles dispersed within porous activated carbon. The model is also used to investigate the effect of nonuniform distributions of salt in the electrolyte phase of the electrode in the context of dilute solution theory. We use the model to compare the performance of capacitors with electrodes made from different activated carbons and to investigate the effects of varying carbon content and discharge current density. Even at low discharge current density, concentration polarization in …

Modeling The Effects Of Electrode Composition And Pore Structure On The Performance Of Electrochemical Capacitors, Changqing Lin, Branko N. Popov, Harry J. Ploehn

Faculty Publications

This work presents a mathematical model for charge/discharge of electrochemical capacitors that explicitly accounts for particle-packing effects in a composite electrochemical capacitor consisting of hydrous RuO₂ nanoparticles dispersed within porous activated carbon. The model is also used to investigate the effect of nonuniform distributions of salt in the electrolyte phase of the electrode in the context of dilute solution theory. We use the model to compare the performance of capacitors with electrodes made from different activated carbons and to investigate the effects of varying carbon content and discharge current density. Even at low discharge current density, concentration polarization in …

High Resolution Modeling Of Transport In Porous Media, Guangli Liu

LSU Doctoral Dissertations

This dissertation presents research on the pore-level modeling of transport in porous media. The focus of this work is on high-resolution modeling, a rigorous approach that represents detailed geometry and first-principle physics at the streamline scale. Three major topics are presented in this dissertation: an efficient approach for solving Stokes flow in essentially arbitrary disordered porous media, high-resolution versus network simulations of dispersion phenomena, and a stochastic model for solving interfacial mass transfer from source spheres in porous media. First an approach was developed for solving the Stokes flow problem in a comparatively large, very heterogeneous two-dimensional porous media with …

Numerical Study Of Water Coning Control With Downhole Water Sink (Dws) Completions In Vertical And Horizontal Wells, Solomon Ovueferaye Inikori

LSU Doctoral Dissertations

Approximately 2.5 billion dollars is spent annually to solve the problem of produced water in oil and gas wells. Downhole Water Sink (DWS) technology is one industry solution to control water coning in oil wells. DWS technology involves the segregated production of oil and water through separate completions with zonal isolation packer. However, several problems have been experienced in the application of the technology in watered-out oil wells. This study identified two factors that could aid in a better modeling of the technology in old vertical wells – inclusion of capillary transition pressures and relative permeability hysteresis. It also identified …

Experimental Evaluation Of Control Fluid Fallback During Off-Bottom Well Control In Vertical And Deviated Wells, Fernando Sebastian Flores-Avila

LSU Doctoral Dissertations

This study measured the liquid fallback during simulated blowout conditions. The purpose of the study was to establish a basis for developing a procedure for controlling blowouts that relies on the accumulation of liquid kill fluid injected while the well continues to flow. The results from experiments performed with air, water, 10.5 ppg and 12.0 ppg mud in an experimental 48 ft flow loop at 0°, 20°, 40°, 60° and 75° deviation angles from the vertical, as well as results from full-scale experiments performed with natural gas and water based drilling fluid in a vertical 2787-foot deep research well, are …

Evaluation Of The Hydrocarbon Potential In Low-Salinity Shaly Sand, Fnu Kurniawan

LSU Master's Theses

This research utilizes reservoir data from an oilfield in Indonesia, which is characterized by shaly sand and low salinity formation water. Both low salinity and shaliness reduce the resistivity contrast between oil and water. The aim of this research was to build a comprehensive interpretation algorithm to evaluate the shaly-sand reservoir in a low salinity formation water using limited well log data. Shaly-sand interpretation is still evolving with numerous researchers conducting investigations of the clay minerals effect on rock conductivity through theoretical and experimental approach. These investigations can be loosely divided into either Fractional Shale Volume models or the Cation …

Analytical Model To Control Off - Bottom Blowouts Utilizing The Concept Of Simultaneous Dynamic Seal And Bullheading, Victor Gerardo Vallejo-Arrieta

LSU Doctoral Dissertations

The current methods for off - bottom control of blowouts involve pumping kill fluid into the well through an injection string. These are the dynamic kill and the momentum kill. The dynamic kill, which is based on the steady state system analysis approach, and the momentum kill, that is loosely based on the Newton's Second Law of Motion, have been used extensively in off-bottom control of actual blowouts. A comprehensive study of these two concepts was performed. The review included an analytical analysis of the published design techniques for both of these methods. The application of these techniques to several …

Nonlinear State And Parameter Estimation And Model Predictive Control Of Nitrogen Purification Columns, Shoujun Bian

LSU Master's Theses

High-purity distillation columns are highly nonlinear systems. Nonlinear Model Predictive Control of these columns is challenging. The complexity of a first-principles model of a multi-stage distillation column, which involves a large number of differential and algebraic equations, makes Model Predictive Control computationally expensive. This thesis has focused on Nonlinear Model Predictive Control based on a simplified wave model of a distillation column; the simplified wave model consists of only one ordinary differential equation along with several algebraic equations. The predictive capability of the nonlinear wave model can be improved significantly through the application of nonlinear state estimation. Off-line estimation by …

The Effects Of Local Hydrodynamics On Mass Transfer In Disordered Porous Media, Gang Guo

LSU Doctoral Dissertations

Interfacial mass transfer in disordered media was studied experimentally and numerically. The dissolution of solid benzoic acid spheres in packed columns showed the existence of spatial variations in mass transfer coefficients in monodisperse and polydisperse packings at the same overall Peclet number. The concept of a local Peclet number (single-particle average) was introduced to quantify the effect of local hydrodynamics on local mass transfer. Correlations between Sherwood number and Peclet number having the form Sh_i=A·(x_iPe)^m were used to quantify data from various sites in each packing. These experiments also showed that the exponent m varies …

Log-Derived Cation Exchange Capacity Of Shaly Sands : Application To Hydrocarbon Detection And Drilling Optimization, Gamze Ipek

LSU Doctoral Dissertations

Researchers at Louisiana State University, LSU, have introduced several petrophysical models expressing the electric properties of shaly sands. These models, to be used for hydrocarbon detection, are based on the Waxman and Smits concept of supplementing the water conductivity with a clay counterions conductivity. The LSU models also utilize the Dual Water theory, which relates each conductivity term to a particular type of water, free and bound, each occupying a specific volume of the total pore space. The main difference between these models and the other shaly sand models is that the counterion conductivity is represented by a hypothetical sodium …

Mechanism Of The Nicofe Ternary Alloy Deposition, Yun Zhuang

LSU Doctoral Dissertations

Electrodeposited NiCoFe ternary alloys are of interest for their magnetic and thermophysical properties. The reaction rates and resulting composition and current efficiency are often determined empirically, due to a lack of understanding of the electrodeposition mechanism and coupled mass transport. Therefore, the effects of electrolyte concentration, bulk pH and solution agitation are studied over a wide range of applied current densities to investigate the interrelated behavior of the partial reaction rates. The Fe rate during alloy deposition is independent of Co2+ and Fe2+ bulk concentrations, but is enhanced compared with its single metal rate. Both catalytic and inhibiting effects are …

Development Of Catalytic Processes For Aromatic Amides And Carboxylic Acids, Yujun Song

LSU Master's Theses

New catalysts were prepared and studied for: (1) a model amidation with a hindered amine, diethylamine (DEA), to N,N¡¯-diethyltoluamide (DEET); (2) the oxidation of m-xylene (MX) to DEET¡¯s alkylaromatic precursor, m-toluic acid (MTA). In both cases the goal was to reduce waste associated with current processes. Thermodynamic analyses showed that the amidation to produce DEET from MTA and DEA was an equilibrium limited reaction with equilibrium constants (Ke) less than 41 at temperatures below 320¡ÆC. The kinetics on silica-supported titanium (¥³) (triethanolaminato)-isopropoxide (Tyzor TE), calcium hydroxyapatites and silica supported tungsten heteropolyacids were studied using a continuous reactor. Both porous hydroxyapatites …

Numerical Reservoir Characterization Using Dimensionless Scale Numbers With Application In Upscaling, Djuro Novakovic

LSU Doctoral Dissertations

Dimensionless space provides a tool for analyzing the behavior of complex systems described by mathematical relationships. The limited application of dimensionless variables in numerical reservoir simulation and experimental design motivated the development of a complete set of dimensionless scaling groups. Inspectional analysis yielded 8 dimensionless groups completely describing the flow system. Further analysis of fluid interaction reduced the number of dimensionless groups to 7. The newly developed dimensionless equations and groups were used for analytical and numerical reservoir characterization, quantifying the behavior of differential and difference equations employed in fluid flow in three-dimensional porous media. The behavior of the dimensionless …

Dynamic Modeling And Analysis Of Oscillatory Bioreactors, Yongchun Zhang

LSU Doctoral Dissertations

Dynamic modeling of bioreactors is a challenging problem. The complexity of first principle models also make model validation and analysis very difficult and model-based controller design practically intractable. This thesis has focused on finding an effective tool for model dynamic analysis, construction of low-dimension model and simple and effective controller design. The validity of a biochemical reactor model often is evaluated by comparing transient responses to experimental data. Dynamic simulation can be rather inefficient and ineffective for analyzing bioreactor model. Bifurcation analysis is found to be a powerful tool for obtaining a more efficient and complete characterization of the model …

A Correlation Between The Optical And Mechanical Properties Of Novel Polysilane/Polysiloxane Nanocomposites, Sungho Lee

LSU Master's Theses

Polysilanes are ¥ò-conjugated conductive polymers with a one-dimensional Si backbone and organic substituted side chains. The conventional Wurtz-type coupling reaction has been used for preparing various alkyl substituted polysilanes, i.e. poly(di-n-hexyl)silane and poly(hexylmethyl)silane. For each polysilane examples with methoxy (-OCH3) and allyl (-CH2CH=CH2) end caps have been prepared. The solution UV absorption characteristics of the polysilanes at room temperature have been measured, from which the wavelength maximum of the UV-VIS absorption and the absorptivity have been obtained. Allyl end capped polysilanes have the same wavelength maximum as methoxy end capped polysilanes. However, the absorptivities of allyl end capped polysilanes are …

Thermal Rheological Analysis Of Cure Process Of Epoxy Prepreg, Liangfeng Sun

LSU Doctoral Dissertations

The cure process of epoxy prepreg used as composite pipe joints was studied by means of differential scanning calorimetry (DSC), Bohlin Rheometer and other techniques. Isothermal DSC measurements were conducted between 110 and 220 oC, at 10 oC intervals. The results show that the complete cure reaction could be achieved at oC. The isothermal cure process was simulated with the four-parameter autocatalytic model. Except in the late stage of cure reaction, the model agrees well with the experimental data, especially at high temperatures. To account for the effect of diffusion on the cure rate, a diffusion factor was introduced into …

Numerical Studies Of Reactive Polymer Flows In Porous Materials, Honggao Liu

LSU Doctoral Dissertations

This dissertation presents a new numerical model of reactive polymer flow in heterogeneous porous media. A moment representation of the log-normal polymer molecular weight distribution is used to model polymer as a multi-component species. Three leading moments are used to simulate the polymer transport and reaction processes in a two-dimensional porous medium. A new operator splitting technique that allows the moment equations for polymerization to be incorporated into a finite-difference transport model is developed. The novelty of this approach is the use of two different dependent variables (for the transport versus reaction parts of the problem). It is significant from …