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Full-Text Articles in Engineering
Corrosion Case Study On Pipeline, Kangze Ren
Corrosion Case Study On Pipeline, Kangze Ren
Corrosion Research
The Kashagan pipeline leaks were likely caused by sulfur stress corrosion cracking, a combined corrosion mechanism developed by the presence of high pressure, the high level of hydrogen sulfide(the main "ingredient" of sour gas), and poor metallurgical choice. Improper welding and poor metallurgical examination were blamed for causing the leaking issue. The purpose of the current review is to raise the alarm about the inappropriate corrosion management of Kashagan oil production and its societal and environmental consequences.
Corrosion Case Study On Automobile, Grace Ajayi, Xinran Pan, Geethu Sasikala, Marshall S. Yang
Corrosion Case Study On Automobile, Grace Ajayi, Xinran Pan, Geethu Sasikala, Marshall S. Yang
Chemistry Publications
No abstract provided.
A Computational Investigation Of The Interstitial Oxidation Thermodynamics Of A Mo-Nb-Ta-W High Entropy Alloy Beyond The Dilute Regime, Adib J. Samin
A Computational Investigation Of The Interstitial Oxidation Thermodynamics Of A Mo-Nb-Ta-W High Entropy Alloy Beyond The Dilute Regime, Adib J. Samin
Faculty Publications
High entropy alloys (HEAs) are promising candidates for high-temperature structural material applications. Oxidation is a major factor that must be accounted for when designing such materials and it is thus important to study the oxidation behavior of HEAs to enable the optimum design of next generation materials. In this study, the thermodynamic behavior of interstitial oxygen in a Mo-Nb-Ta-W high entropy alloy was explored beyond the dilute limit. This was accomplished by sampling configurations of the HEA and HEA-oxygen systems from an isothermal–isobaric ensemble using a series of first-principle-based Monte Carlo simulations. It was found that the interstitial oxygen had …
The Effect Of Flinak Molten Salt Corrosion On The Hardness Of Hastelloy N, David Kok
The Effect Of Flinak Molten Salt Corrosion On The Hardness Of Hastelloy N, David Kok
Honors Program Projects
The desire to reduce pollution caused by electricity production has led to a call for the replacement of conventional fossil fuel power plants. In order to fulfill this goal, a large amount of new nuclear reactors is required, and this provides the opportunity to put new and innovative reactor designs into production. The Molten Salt Reactor (MSR) is one of the most promising concepts, but a suitable combination of molten salt and container material needs to be found to reduce the potential for corrosion before the concept can be put into production. FLiNaK molten salt and the nickel-based alloy Hastelloy …
Cysteine As An Eco-Friendly Corrosion Inhibitor, Hany A. Elazab Dr
Cysteine As An Eco-Friendly Corrosion Inhibitor, Hany A. Elazab Dr
Chemical Engineering
In this paper, the aim was finding the most efficient corrosion inhibitor for mild steel placed in a 0.5M Sulfuric acid. The comparison was implemented between Cysteine (an eco-friendly corrosion inhibitor) and 4 different Ions-Cysteine Inhibitors (Copper- Cysteine, Nickel-Cysteine, Iron-Cysteine, and Cobalt-Cysteine). The solutions were prepared and evaluated while placed with a working electrode of mild steel with a copper rod attached to its end. To determine the best eco-friendly corrosion inhibitors two experiments were implemented: Electrochemical Impedance Spectra, and Linear Polarization. By the end of the experiment it was found that Copper- Cysteine was the most efficient eco-friendly corrosion …
Review Of Corrosion Aspects Of Compression Ignition Engine Parts Using Biodiesel Blends, B. Singh, John Korstad, Y. C. Sharma
Review Of Corrosion Aspects Of Compression Ignition Engine Parts Using Biodiesel Blends, B. Singh, John Korstad, Y. C. Sharma
College of Science and Engineering Faculty Research and Scholarship
This paper reviews the effects of corrosion on the engine parts that come in contact with a newly developed biodiesel fuel and its petrodiesel blend. Copper, aluminum, copper alloys (bronze), and elastomers caused significant levels of corrosiveness in biodiesel and biodiesel blend as opposed to low corrosion with petrodiesel. Specimens of stainless steel showed significant resistance to corrosion in biodiesel samples as compared to copper, aluminum, and copper alloys, but the level of corrosion was still higher than that in petrodiesel. Common methods adopted for measurement of corrosion include weight loss through static emersion tests, and electrochemical techniques by electrochemical …
Electrochemical Investigation Of Chromium Nanocarbide Coated Ti-6al-4v And Co-Cr-Mo Alloy Substrates, Viswanathan Swaminathan, Haitong Zeng, Daniel Lawrynowicz, Zongtao Zhang, Jeremy L. Gilbert
Electrochemical Investigation Of Chromium Nanocarbide Coated Ti-6al-4v And Co-Cr-Mo Alloy Substrates, Viswanathan Swaminathan, Haitong Zeng, Daniel Lawrynowicz, Zongtao Zhang, Jeremy L. Gilbert
Biomedical and Chemical Engineering - All Scholarship
This study investigated the electrochemical behavior of chromium nano-carbide cermet coating applied on Ti–6Al–4V and Co–Cr–Mo alloys for potential application as wear and corrosion resistant bearing surfaces. The cermet coating consisted of a highly heterogeneous combination of carbides embedded in a metal matrix. The main factors studied were the effect of substrate (Ti–6Al–4V vs. Co–Cr–Mo), solution conditions (physiological vs. 1 M H2O2 of pH 2), time of immersion (1 vs. 24 h) and post coating treatments (passivation and gamma sterilization). The coatings were produced with high velocity oxygen fuel (HVOF) thermal spray technique at atmospheric conditions to …
Corrosion And Dissolution Protection Of A Conductive Silver/Polymer Composite, Ravi F. Saraf
Corrosion And Dissolution Protection Of A Conductive Silver/Polymer Composite, Ravi F. Saraf
Department of Chemical and Biomolecular Engineering: Patents
A conductive composite is described containing silver particles and a polymer which covers each silver particle and wherein a heterocyclic organic compound containing nitrogen such as benzotriazole (BTA) is present to reduce Ag dissolution and ion mobility by forming a water insoluble complex with the Ag ion. The invention overcomes the problem of silver dissolution or corrosion a conductive composite as a result of normal high Ag ion mobility in the presence of moisture and an electric field
Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn-Ni-Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko N. Popov
Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn-Ni-Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko N. Popov
Faculty Publications
A new Zn-Ni-Cd plating process was developed which offers a unique way of controlling and optimizing the Ni and Cd contents in the final deposit. Zinc-nickel-cadmium alloy was deposited from a 0.5 M NiSO4 + 0.2 M ZnSO4 bath in the presence of 0.015 M CdSO4 and 1 g/L nonyl phenyl polyethylene oxide. Using this process a Zn-Ni-Cd ternary alloy, with a higher nickel content as compared to that obtained from conventional Zn-Ni baths, was synthesized. The Zn-Ni-Cd alloy coatings deposited from an electrolyte containing 0.015 M (0.3%) CdSO4 has a Zn to Ni ratio of …
Characterization Of Hydrogen Permeation Through Zinc-Nickel Alloys Under Corroding Conditions: Mathematical Model And Experimental Study, M. Ramasubramanian, Branko N. Popov, Ralph E. White
Characterization Of Hydrogen Permeation Through Zinc-Nickel Alloys Under Corroding Conditions: Mathematical Model And Experimental Study, M. Ramasubramanian, Branko N. Popov, Ralph E. White
Faculty Publications
A mathematical model was developed for the characterization of hydrogen permeation into metals and alloys under corroding conditions. The model requires a knowledge of the corrosion rate of the given metal or alloy in solutions of various H+ concentrations. It provides quantitative values of rate constants of the hydrogen discharge, recombination, and adsorption reactions. This model can serve as a diagnostic criterion for determining the effectiveness of various metals and alloys as hydrogen permeation inhibitors and can be used for evaluation of hydrogen entry inhibition efficiency. Experiments were carried out to study the effectiveness of thin layers of electrodeposited …
Comparing Electrochemical Impedance Spectroscopy Methods For Estimating The Degree Of Delamination Of Organic Coatings On Steel, S. A. Mccluney, S. N. Popova, Branko N. Popov, Ralph E. White, R. B. Griffin
Comparing Electrochemical Impedance Spectroscopy Methods For Estimating The Degree Of Delamination Of Organic Coatings On Steel, S. A. Mccluney, S. N. Popova, Branko N. Popov, Ralph E. White, R. B. Griffin
Faculty Publications
Electrochemical impedance spectroscopy (EIS) was used to evaluate the degree of delamination of the epoxy primer Uniprime ED-41 electrocoated on phosphate-treated cold-rolled steel in 3.5% NaCl exposed to air. Specimens with coating thicknesses of 20.3 and 20.8 µm and surface areas of 78.5 cm2 were used. Coating parameters were obtained using a circuit-analog model. The area of delamination was estimated using several EIS parameters, including the pore resistance and the break point frequency. These values were compared to the corroded area determined visually. All methods considered exhibited a strong correlation over some or all of the range of …
A Mathematical Model For The Initial Corrosion Rate Of A Porous Layer On A Rotating Disk Electrode, William E. Ryan, Ralph E. White, S. L. Kelly
A Mathematical Model For The Initial Corrosion Rate Of A Porous Layer On A Rotating Disk Electrode, William E. Ryan, Ralph E. White, S. L. Kelly
Faculty Publications
A mathematical model is presented for the initial corrosion rate of a porous layer on a rotating disk electrode. The model is used to predict the corrosion potential and corrosion current density for a porous electrode made of pure iron in aerated caustic solutions. The dependence of these predictions on some of the properties of the porous layer is presented. It is shown that the corrosion rate depends significantly on the specific surface area of the porous electrode.
The Anodic Dissolution Of Tungsten, James W. Johnson, Cheng-Hsiao Wu
The Anodic Dissolution Of Tungsten, James W. Johnson, Cheng-Hsiao Wu
Chemical and Biochemical Engineering Faculty Research & Creative Works
The anodic dissolution of tungsten was studied in H2SO4-K2SO4 solutions (pH = -2 to 2.5) and K2SO4-K2CO3-KOH solutions (pH = 11.5 to 14.5) at 25 C. Faradaic efficiency studies in basic solutions showed the metal to be oxidized to the +6 state. In acid solutions, a thick protective film of yellow WO3 was formed. Polarization curves possessed linear Tafel regions (slope ~ 2.3 RT/F) at potentials slightly more positive than the rest potentials. An anodic dissolution mechanism is proposed which involves a surface film …