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Chemical Engineering

University of South Carolina

2006

Articles 1 - 5 of 5

Full-Text Articles in Engineering

Fabrication And Characterization Of Poly(Propylene Fumarate) Scaffolds With Controlled Pore Structures Using 3-Dimensional Printing And Injection Molding, Kee-Won Lee, Shanfeng Wang, Lichun Lu, Esmaiel Jabbari, Bradford L. Currier, Michael J. Yaszemski Oct 2006

Fabrication And Characterization Of Poly(Propylene Fumarate) Scaffolds With Controlled Pore Structures Using 3-Dimensional Printing And Injection Molding, Kee-Won Lee, Shanfeng Wang, Lichun Lu, Esmaiel Jabbari, Bradford L. Currier, Michael J. Yaszemski

Faculty Publications

Poly(propylene fumarate) (PPF) is an injectable, biodegradable polymer that has been used for fabricating preformed scaffolds in tissue engineering applications because of in situ crosslinking characteristics. Aiming for understanding the effects of pore structure parameters on bone tissue ingrowth, 3-dimensional (3D) PPF scaffolds with controlled pore architecture have been produced in this study from computer-aided design (CAD) models. We have created original scaffold models with 3 pore sizes (300, 600, and 900 µm) and randomly closed 0%, 10%, 20%, or 30% of total pores from the original models in 3 planes. PPF scaffolds were fabricated by a series steps involving …

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High-Pressure Torsion-Induced Grain Growth In Electrodeposited Nanocrystalline Ni, X. Z. Liao, A. R. Kilmametov, R. Z. Valiev, Hongsheng Gao, Xiaodong Li, A. K. Mukherjee, J. F. Blingert, Y. T. Zhu Jan 2006

High-Pressure Torsion-Induced Grain Growth In Electrodeposited Nanocrystalline Ni, X. Z. Liao, A. R. Kilmametov, R. Z. Valiev, Hongsheng Gao, Xiaodong Li, A. K. Mukherjee, J. F. Blingert, Y. T. Zhu

Faculty Publications

Deformation-induced grain growth has been reported in nanocrystalline (nc) materials under indentation and severe cyclic loading, but not under any other deformation mode. This raises an issue on critical conditions for grain growth in nc materials. This study investigates deformation-induced grain growth in electrodeposited nc Ni during high-pressure torsion (HPT). Our results indicate that high stress and severe plastic deformation are required for inducing grain growth, and the upper limit of grain size is determined by the deformation mode and parameters. Also, texture evolution suggests that grain-boundary-mediated mechanisms played a significant role in accommodating HPT strain.

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Combinatorial Study Of Ni-Ti-Pt Ternary Metal Gate Electrodes On Hfo2 For The Advanced Gate Stack, K.-S. Chang, M. L. Green, J. Suehle, E. M. Vogel, H. Xiong, Jason R. Hattrick-Simpers, I. Takeuchi, O. Famodu, K. Ohmori, P. Ahmet, T. Chikyow, P. Majhi, B.-H. Lee, M. Gardner Jan 2006

Combinatorial Study Of Ni-Ti-Pt Ternary Metal Gate Electrodes On Hfo2 For The Advanced Gate Stack, K.-S. Chang, M. L. Green, J. Suehle, E. M. Vogel, H. Xiong, Jason R. Hattrick-Simpers, I. Takeuchi, O. Famodu, K. Ohmori, P. Ahmet, T. Chikyow, P. Majhi, B.-H. Lee, M. Gardner

Faculty Publications

The authors have fabricated combinatorial Ni–Ti–Pt ternary metal gate thin film libraries on HfO2 using magnetron co-sputtering to investigate flatband voltage shift (ΔVfb) , work function (Φm) , and leakage current density (JL) variations. A more negative ΔVfb is observed close to the Ti-rich corner than at the Ni- and Pt-rich corners, implying smaller Φm near the Ti-rich corners and higher Φm near the Ni- and Pt-rich corners. In addition, measured JL values can be explained consistently with the observed Φm variations. Combinatorial methodologies prove to be useful …

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Modeling Volume Changes In Porous Electrodes, Parthasarathy M. Gomadam, John W. Weidner Jan 2006

Modeling Volume Changes In Porous Electrodes, Parthasarathy M. Gomadam, John W. Weidner

Faculty Publications

A three-dimensional mathematical model is presented to describe volume changes in porous electrodes occurring during operation. Material conservation equations are used to derive governing relationships between electrode dimensions and porosity for deposition/precipitation, intercalation, and ionomer-based electrodes. By introducing a parameter, called the swelling coefficient, the relative magnitudes of the change in electrode dimensions and the change in porosity are determined. The swelling coefficient is design-dependent and measured experimentally for a given cell design. The model is general and forms a critical addition required to extend the existing porous electrode models to include volume change effects. For the special case of …

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Development Of An Electroless Method To Deposit Corrosion-Resistant Silicate Layers On Metallic Substrates, Swaminatha P. Kumaraguru, Basker Veeraraghavan, Branko N. Popov Jan 2006

Development Of An Electroless Method To Deposit Corrosion-Resistant Silicate Layers On Metallic Substrates, Swaminatha P. Kumaraguru, Basker Veeraraghavan, Branko N. Popov

Faculty Publications

A novel electroless method for depositing corrosion-resistant silicate layers on metallic substrates from aqueous solutions has been developed. The silicate layer was deposited from an aqueous solution of sodium silicate (3.22 weight ratio sodium silicate, 37.5% solution in water from PQ Corporation) and sodium borohydride. The technique is demonstrated by forming a passive film on galvanized steel. Deposition parameters such as concentration of the bath, temperature, and pH have been optimized based on the corrosion characteristics of the final coating. Studies on the coating reveal the formation of a very thin (5 nm) zinc disilicate layer followed by a much …

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