Engineering Commons^™

A Multi-Analytical Approach To Understand The Chemistry Of Fe-Minerals In Feed Coals And Ashes, Marcos L.S. Oliveira, Frans Waanders, Luis F.O. Silva, Andre Jasper, Carlos H. Sampaio, Dursman Mchabe, Rachel S. Hatch, James C. Hower

Coal Combustion and Gasification Products Journal Archive

Seven feed coals used in the Brazilian power generation industry were obtained and subsequently analysed together with fly ash and bottom ash from a major Brazilian power plant. The samples were investigated by means of room temperature FeMo¨ssbauer analyses, X-ray diffraction, Raman spectroscopy, scanning electron microscope and petrographic analysis. In addition, nanometer-sized crystalline phases in coals and ashes were characterised using an energy-dispersive X-ray spectrometer and a high-resolution transmission electron microscope. The major identified Fe-bearing minerals in the coals were found to be actinolite, ankerite, chalcopyrite, chlorite, goethite, illite, ilmenite, magnesioferrite, natrojarosite, pyrite, pyrrhotite, and siderite; whilst in the fly …

The Leachability Of Major Elements At Different Stages Of Weathering In Dry Disposed Coal Fly Ash, S.A. Akinyemi, A. Akinlua, W.M. Gitari, R.O. Akinyeye, L.F. Petrik

Coal Combustion and Gasification Products Journal Archive

Large quantities of solid residue are generated by coal-fired power stations in many parts of the World. The disposal and management of the unused fly ash remains a major problem to the environment. The weathered dry disposed ash cores comprise of major element constituents such as Al, Si, Ca, Mg, Fe, Mn, Na+ and K+. The mobility patterns and mineralogical associations of major elements in weathered dry disposed ash dumps aged 1-year-old, 8-year-old and 20-year-old from a coalfired power station in South Africa were investigated using a modified sequential extraction scheme. The extraction sequence was as follows: (1) water soluble, …

Solubility Of Fe2(Oh)3cl (Pure-Iron End-Member Of Hibbingite) In Nacl And Na2so4 Brines, Martin Nemer, Yongliang Xiong, Ahmed Ismail, Je-Hun Jang

United States Department of Energy: Publications

Pure-iron end-member hibbingite, Fe₂(OH)₃Cl(s), may be important to geological repositories in salt formations, as it may be a dominant corrosion product of steel waste canisters in an anoxic environment in Na–Cl- and Na–Mg–Cl-dominated brines. In this study, the solubility of Fe₂(OH)₃Cl(s), the pure-iron endmember of hibbingite (Fe^II, Mg)₂(OH)₃Cl(s), and Fe(OH)₂(s) in 0.04 m to 6 m NaCl brines has been determined. For the reaction

Fe₂ (OH)₃Cl(s) + 3H⁺↔ 3H₂O + 2Fe²⁺ + Cl⁻,

the …

Feasibility Of Wastewater Reuse For Fish Production In Small Communities In A Developing World Setting, Joshua James Girard

USF Tampa Graduate Theses and Dissertations

Eradicating poverty, malnutrition, and the burden of disease have been included as three of the major issues facing the world. The United Nation member countries, having set forth the Millennium Development Goals, have committed themselves to solving these problems. Two major factors which affect solutions to these problems are increasing water stress and implementing improved sanitation. Integration of tilapia aquaculture and reuse of wastewater has been suggested as a solution which addresses both of these factors. The objective of this study is to examine the feasibility, and explore the benefits and drawbacks, to implementing small community wastewater fed (WWF) aquaculture …

Irrigation District Turnouts, Charles M. Burt

BioResource and Agricultural Engineering

This is meant to be a very quick, roughly written primer on irrigation district turnout selection. It by no means covers all of the details, but it might help out. ITRC offers flow measurement classes, with online registration at www.itrc.org. We have also done testing on quite a few designs over the years, but the work was almost all confidential in nature.

Microbial And Mineralogical Characterizations Of Soils Collected From The Deep Biosphere Of The Former Homestake Gold Mine, South Dakota, Gurdeep Rastogi, Shariff Osman, Ravi K. Kukkadapu, Mark Engelhard, Parag A. Vaishampayan, Gary L. Andersen, Rajesh K. Sani

United States Department of Energy: Publications

A microbial census on deep biosphere (1.34 km depth) microbial communities was performed in two soil samples collected from the Ross and number 6Winze sites of the former Homestake gold mine, Lead, South Dakota using high-density 16S microarrays (PhyloChip). Soil mineralogical characterization was carried out using X-ray diffraction, X-ray photoelectron, and Mössbauer spectroscopic techniques which demonstrated silicates and iron minerals (phyllosilicates and clays) in both samples. Microarray data revealed extensive bacterial diversity in soils and detected the largest number of taxa in Proteobacteria phylum followed by Firmicutes and Actinobacteria. The archael communities in the deep gold mine environments were …

Mineralogy And Leaching Characteristics Of Coal Ash From A Major Brazilian Power Plant, Luis F.O. Silva, Colin R. Ward, James C. Hower, Maria Izquierdo, Frans Waanders, Marcos L.S. Oliveira, Zhongsheng Li, Rachel S. Hatch, Xavier Querol

Coal Combustion and Gasification Products Journal Archive

The feed coals, fly ashes and bottom ashes collected from seven different units in a major Brazilian PF power plant have been subjected to comprehensive mineralogical, geochemical, and petrographic studies, to investigate the links between feed coal and ash characteristics. Ashes from two of the units were collected while the coal was being co-fired with oil as part of the boiler start-up procedure, allowing the impact of oil co-firing on ash characteristics also to be evaluated. High proportions of unburnt carbon and high proportions of retained sulphur were found in the fly ashes produced during oil co-firing, probably reflecting less …

Increasing Productivity In Irrigated Agriculture: Agronomic Constraints And Hydrological Realities, Chris Perry, Pasquale Steduto, Richard C. Allen, Charles M. Burt

BioResource and Agricultural Engineering

Irrigation is widely criticised as a profligate and wasteful user of water, especially in watershort areas. Improvements to irrigation management are proposed as a way of increasing agricultural production and reducing the demand for water. The terminology for this debate is often flawed, failing to clarify the actual disposition of water used in irrigation into evaporation, transpiration, and return flows that may, depending on local conditions, be recoverable. Once the various flows are properly identified, the existing literature suggests that the scope for saving consumptive use of water through advanced irrigation technologies is often limited. Further, the interactions between evaporation …

Farming Systems Education: Case Study Of Swedish Test Pilots, Lennart Salomonsson, Anna Nilsson, Sofia Palmer, Adam Roigart, Charles A. Francis

Department of Agronomy and Horticulture: Faculty Publications

We describe and analyze a pedagogical experiment that introduced a broad and holistic perspective on complete farming systems, systemic learning tools, and a participatory learning strategy at an early stage in agronomy education. The paper describes the adventure of three students, who came from a conventional agronomy program at the Swedish University of Agricultural Sciences (SLU), who were frustrated with the lack of integrated approaches to the study of agricultural systems and a strong focus on molecular-level processes in their first year of education. They encountered a narrow focus in most courses and the overall curricula of agricultural education that …

Challenges In Earth System Modelling: Approaches And Applications, D.J. Erickson Ill, Robert J. Oglesby, S. Elliott, W. Steffen, G. Brasseur

United States Department of Energy: Publications

Earth system modelling has taken on increasing importance over the past several years. These models are being used to address an increasing number of environmental and global change problems of societal concern (e.g. Adams et al., 1998; Easterling et al., 2000; Foley et al., 2003). Perhaps most commonly known is the application to possible greenhouse-gas induced warming (Hoffman et al., 2005). Other compelling problems include the climatic effects of land use changes, aerosols (including sulphate emissions, and smoke from biomass burning; Erickson et al., 1995; Oglesby et al., 1999), changing trace gas fluxes, interactions and feedbacks with the global carbon …

Agricultural Systems: Agroecology And Rural Innovations For Development [Book Review], Charles A. Francis

Department of Agronomy and Horticulture: Faculty Publications

To welcome yet another book on sustainable development, a reviewer must look for what is unique and what adds value to the volumes already published. In Agricultural Systems, editors Sieglinde Snapp and Barry Pound have assembled a collection of chapters that goes beyond the usual praise and criticism of the green revolution and the focus on economic development. Their book provides a first-hand story by people with lengthy experiences in the field, especially in Africa, who have developed and tested grassroots, participatory development approaches. The result is a valuable set of principles, strategies and case studies that paint a new …

Intellectual Property Management In Health And Agricultural Innovation: A Handbook Of Best Practices, Vol. 2, Anatole Krattiger, Richard T. Mahoney, Lita Nelsen, Jennifer A. Thomson, Alan B. Bennett, Kanikaram Satyanarayana, Gregory D. Graff, Carlos Fernandez, Stanley Kowalski

Law Faculty Scholarship

Prepared by and for policy-makers, leaders of public sector research establishments, technology transfer professionals, licensing executives, and scientists, this online resource offers up-to-date information and strategies for utilizing the power of both intellectual property and the public domain. Emphasis is placed on advancing innovation in health and agriculture, though many of the principles outlined here are broadly applicable across technology fields. Eschewing ideological debates and general proclamations, the authors always keep their eye on the practical side of IP management. The site is based on a comprehensive Handbook and Executive Guide that provide substantive discussions and analysis of the opportunities …

Intellectual Property Management In Health And Agricultural Innovation: Executive Guide, Anatole Krattiger, Richard T. Mahoney, Lita Nelsen, Jennifer A. Thomson, Alan B. Bennett, Kanikaram Satyanarayana, Gregory D. Graff, Carlos Fernandez, Stanley Kowalski

Law Faculty Scholarship

Prepared by and for policy-makers, leaders of public sector research establishments, technology transfer professionals, licensing executives, and scientists, this online resource offers up-to-date information and strategies for utilizing the power of both intellectual property and the public domain. Emphasis is placed on advancing innovation in health and agriculture, though many of the principles outlined here are broadly applicable across technology fields. Eschewing ideological debates and general proclamations, the authors always keep their eye on the practical side of IP management. The site is based on a comprehensive Handbook and Executive Guide that provide substantive discussions and analysis of the opportunities …

Intellectual Property Management In Health And Agricultural Innovation: A Handbook Of Best Practices, Vol. 1, Anatole Krattiger, Richard T. Mahoney, Lita Nelsen, Jennifer A. Thomson, Alan B. Bennett, Kanikaram Satyanarayana, Gregory D. Graff, Carlos Fernandez, Stanley Kowalski

Law Faculty Scholarship

Prepared by and for policy-makers, leaders of public sector research establishments, technology transfer professionals, licensing executives, and scientists, this online resource offers up-to-date information and strategies for utilizing the power of both intellectual property and the public domain. Emphasis is placed on advancing innovation in health and agriculture, though many of the principles outlined here are broadly applicable across technology fields. Eschewing ideological debates and general proclamations, the authors always keep their eye on the practical side of IP management. The site is based on a comprehensive Handbook and Executive Guide that provide substantive discussions and analysis of the opportunities …

Rational Risk/Benefit Analysis Of Genetically Modified Crops, Stanley P. Kowalski

Law Faculty Scholarship

Safety concerns over the use of molecular biotechnology in the improvement of crops has generated substantial, heated and confusing debates, often driven by ideology and hysterics. Modification of crops is not new, and biotechnology (in its broadest sense) has been used for over a century to accelerate the development of new crops for food, feed and fibre, so as to meet the demands of a growing global community. The introduction of crops developed via molecular biotechnology [Genetically Modified Crops (GMCs)] represents the latest step in this inexorable innovative progression of technology. However, misinformed concern has led to a broad embrace …

Volumetric Water Pricing, Charles M. Burt

BioResource and Agricultural Engineering

This document discusses the concept of volumetric pricing for irrigation water, including:

1. The justification for paying volumetrically

2. The challenge of charging volumetrically

3. Characteristics of volumetric charges and influencing factors

4. Examples of irrigation projects with volumetric charges

5. A summary of necessary conditions for volumetric billing

Addressing Our Global Water Future, Center For Strategic And International Studies (Csis), Sandia National Laboratories

United States Department of Energy: Publications

This White Paper addresses the growing global challenges of dealing with the devastating effects of increasing water scarcity and declining water quality. Across the planet, in developing and developed regions alike, poor governance and mismanagement of natural resources coupled with rising population growth, increasing urbanization, and economic development have led to a growing imbalance between water supply and demand. This imbalance is reaching crisis proportions in many regions. It will have even more significant consequences for economic development, stability and security unless the there is a more dramatic and urgent international response. Several international forums have arisen to address just …

Potential Of Multivariate Quantitative Methods For Delineation And Visualization Of Ecoregions, William Hargrove, Forrest Hoffman

United States Department of Energy: Publications

Multivariate clustering based on fine spatial resolution maps of elevation, temperature, precipitation, soil characteristics, and solar inputs has been used at several specified levels of division to produce a spectrum of quantitative ecoregion maps for the conterminous United States. The coarse ecoregion divisions accurately capture intuitively-understood regional environmental differences, whereas the finer divisions highlight local condition gradients, ecotones, and clines. Such statistically generated ecoregions can be produced based on user-selected continuous variables, allowing customized regions to be delineated for any specific problem. By creating an objective ecoregion classification, the ecoregion concept is removed from the limitations of human subjectivity, making …

Global Optical Lightning Flash Rates Determined With The Forte Satellite, Tracy E. Light, Sean M. Davis, William Boeck, Abram Jacobson, David Suszcynsky

United States Department of Energy: Publications

Using FORTE photodiode detector (PDD) observations of lightning, we have determined the geographic distribution of nighttime flash rate density. We estimate the PDD flash detection efficiency to be 62% for total lightning through comparison to lightning observations by the TRMM satellite's Lightning Imaging Sensor (LIS), using cases in which FORTE and TRMM viewed the same storm. We present here both seasonal and total flash rate maps. We examine some characteristics of the optical emissions of lightning in both high and low flash rate environments, and find that while lightning occurs less frequently over ocean, oceanic lightning flashes are somewhat more …

Water Delivery Service As A Determinant Of Irrigation Project Performance, Stuart W. Styles, M. A. Marino

BioResource and Agricultural Engineering

Performance of an irrigation system is represented by its measured levels of achievement in terms of one or several parameters that are chosen as indicators of the system’s goals. The purpose of this paper is to utilize and refine a set of evaluation indicators that can be used to describe the irrigation performance for sixteen international irrigation projects in less-developed countries. The irrigation performance of many international irrigation projects in less-developed countries has been reported as poor. The cause of the poor irrigation performance has been blamed on technical, financial, managerial, social, and/or institutional causes. This study is specifically designed …

Extraction Of Silymarin Compounds From Milk Thistle (Silybum Marianum) Seed Using Hot, Liquid Water As The Solvent, J.F. Alvarez Barreto

Inquiry: The University of Arkansas Undergraduate Research Journal

High value specialty chemicals are usually obtained from natural products by extracting with generally regarded as safe (GRAS) solvents. Because organic solvents are quite often used, high operating and disposal costs often occur. When compared to traditional solvents, water can be viewed as an interesting alternative because of its low operating and disposal costs. Milk thistle contains compounds (taxifolin, silychristin, silydianin, silybinin A and silybinin B) that display hepatoxic protection properties. This paper examines the batch extraction of silymarin compounds from milk thistle seed meal in 50'C, 70'C, 85'C and 100'C water as a function of time. For taxifolin, silychristin, …

Problems Of Irrigation In Developing Countries, Phillip Z. Kirpich, Dorota Z. Haman, Stuart W. Styles

BioResource and Agricultural Engineering

This paper describes the crucial importance of irrigated agriculture to developing countries and to the world as a whole. This is followed by a summary of key problems that restrict and diminish the benefits of irrigated agriculture. Solution of these problems will above all require a holistic approach and will require changes in the institutions involved. These institutions include those of the developing countries, of the developed countries that provide aid, and of the international financing and technical-assistance agencies. Engineers in the developed countries have had, and will continue to have, a leading role but will need some redirection. ASCE …

Modern Water Control And Management Practices In Irrigation: Impact On Performance, Charles M. Burt, Stuart W. Styles

BioResource and Agricultural Engineering

This research addressed the basic questions of what levels of water delivery service are presently provided by irrigation projects having some aspect of modernization; what hardware and software features impact those levels of service; whether modern water control and management practices in irrigation make a positive difference in performance; and what universal lessons can be learned and applied.

Nest Material As A Delivery Method For Avicides: Preliminary Tests With African Weaver Finches, Stephen A. Shumake, Peter J. Savarie

Vertebrate Pest Conference Proceedings: 17th (1996)

To evaluate the potential of using nesting material as a medium for avicide delivery, five organophosphates (Dasanit^®, Volaton^®, fenthion, parathion, and Cyanophos^®) were tested on small groups of paired male-female quelea (n = 4 to 9). Toxicants were presented to each pair of birds on five 13-cm strands of cotton string after a preliminary screening for male nest weaving behavior. Tested concentrations ranged from 100% technical grade to 0.003 % compound diluted with acetone. Dasanit^® was found to be the most effective candidate with some lethal effects noted at 0.012%. An optimal concentration …

Techniques And Expertise In Wildlife Damage Control: A Survey Among The National Animal Damage Control Association (Nadca) Membership, Dallas R. Virchow, J. Russell Mason

Vertebrate Pest Conference Proceedings: 17th (1996)

The membership of the National Animal Damage Control Association (NADCA) was surveyed during 1995 to collect information about specialty fields, preferred methods and experience. Respondents had broad experience that included 44 species or species groups. Members reported firsthand experience with an average of 17.6 different species and 2.9 vertebrate groups. Forty-three percent indicated that their specialization was among carnivores. In this group, coyotes, Canis latrans (45%), raccoon, Procyon lotor (23%) and skunk (13%) were most frequently mentioned. Members reporting carnivore experience had firsthand experience with an average of five different species. Rural and urban members did not significantly differ in …

Bulletin 3929 - Irrigation In Western Australia, K S. Cole

Bulletins - 3000 - 3999

Irrigation is essential in many parts of the world to produce essential food and profitable cash crops. Generally, those areas of land with less than 360 mm of rain spread over a distinct wet season of several months cannot grow crops for food or cash on rainfall alone. Then irrigation becomes necessary unless some peculiarity such as an oasis exists.