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Safe Use Of Hydrogen Peroxide In The Organic Lab, Patrick Dussault
Safe Use Of Hydrogen Peroxide In The Organic Lab, Patrick Dussault
Organic Peroxides: Safety Issues
The article describes good practices for use of hydrogen peroxide (H2O2) in an organic lab setting. Major headings include:
Leading references; Toxicity; Physical properties; Chemical properties; Stability and incompatibilities; Confinement/pressure; and, References to accidents involving H2O2.
Working With Organic Peroxides In The Academic Lab, Patrick Dussault
Working With Organic Peroxides In The Academic Lab, Patrick Dussault
Organic Peroxides: Safety Issues
ABSTRACT: The following is a brief introduction to peroxide safety from the viewpoint of a synthetic chemist. Major topics include: classes of organic peroxides; peroxide reactivity; hazard identification and minimization; reaction monitoring; and, hazards associated with auto-oxidation of peroxidizable solvents.
KEYWORDS: peroxide, hydroperoxide, hydroperoxyacetal, ozonide, perester, dihydroperoxide, monoperoxyacetal, active oxygen, peroxide strips, TLC indicator, self-accelerating decomposition, radical, exothermicity, transition metals.
CONTENTS: 1. Literature resources 2. Major classes of peroxides 3. Basis for peroxide reactivity 4. Determining reactivity and minimizing hazards a. Steps to take before an experiment b. Minimizing hazard during reactions c. Monitoring reactions d. Working with isolated peroxides …