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Potential Driven Polyelectrolyte Adsorption Onto Monolayer Modified Electrodes, Mark Anderson, Weslie Sanders
Potential Driven Polyelectrolyte Adsorption Onto Monolayer Modified Electrodes, Mark Anderson, Weslie Sanders
Mark R. Anderson
Preparation of interfacial structures by molecular self-assembly has been actively studied for many years. Well-defined modified interfaces can be used to study fundamental interfacial properties, or they can be used in different practical applications. To broaden the utility of interfaces prepared by molecular self-assembly, monolayers containing terminal functionality are frequently used. These interfaces have structural and physical properties that can be controlled by both the identity of the functionalization as well as the ensemble structure of the modified interface. This suggests that the chemical and physical properties of an interface can be designed and/or controlled to some extent by altering …
Selective Formation Of A Symmetric Sc3n@C78 Bisadduct: Adduct Docking Controlled By An Internal Trimetallic Nitride Cluster, Ting Cai, Liaosa Xu, Chunying Shu, Hunter Champion, Jonathan Reid, Clemins Anklin, Mark Anderson, Harry Gibson, Harry Dorn
Selective Formation Of A Symmetric Sc3n@C78 Bisadduct: Adduct Docking Controlled By An Internal Trimetallic Nitride Cluster, Ting Cai, Liaosa Xu, Chunying Shu, Hunter Champion, Jonathan Reid, Clemins Anklin, Mark Anderson, Harry Gibson, Harry Dorn
Mark R. Anderson
In this paper we report a regioselective Bingel−Hirsch reaction of Sc3N@C78 yielding a single mono- and a dominate bis-ethyl malonate derivative for the first time. The Cs-symmetric monoadduct 1 and C2v-symmetric bisadduct 2 were isolated by HPLC and characterized by MS, UV−vis, and NMR spectroscopy. The symmetric bisadduct 2 clearly demonstrate the remarkable regioselectivity control exerted by the encapsulated Sc3N cluster. We have employed a LUMO electron density surface computational approach to predict multiadduct docking sites on the ellipsoidal fullerene cage surface.