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You'll Loan Nothing And Be Happy, Becky Chambers Jan 2026

You'll Loan Nothing And Be Happy, Becky Chambers

Minnesota Journal of Law, Science & Technology

Digital lending of eBooks offers flexibility to patrons, but it also exacerbates the existential threats libraries face. Libraries cannot own eBooks—they can only license and lend them on publishers’ terms—which means libraries are paying more for less. This is known as the “digital lending problem.” Access to older books is even more limited, as publishers and copyright holders rarely offer them as eBooks, creating the “20th century book problem.” These problems are chilling libraries’ creative approaches to digital lending and are further exacerbated by the Trump Administration’s attacks on libraries and the continuing effects of the COVID-19 pandemic. These developments …


Hyperscalers In The Heartland: How A Climate-First Framework Can Incentivize Sustainable Data Center Development And Grid Decarbonization, Eli Dotson Jan 2026

Hyperscalers In The Heartland: How A Climate-First Framework Can Incentivize Sustainable Data Center Development And Grid Decarbonization, Eli Dotson

Minnesota Journal of Law, Science & Technology

This Note proceeds in three parts. Part II surveys the rise of AI and hyperscale data centers, the technical and legal challenges their loads pose, and the evolving policy landscape, both nationwide and in Minnesota. Part III argues that Minnesota should build on its emerging data center framework in two ways. First, the PUC should institutionalize the framework’s most promising features by setting a “clean energy floor” to ensure that data centers contribute to, rather than prevent, the decarbonization of Minnesota’s grid. Second, the PUC should create an additional “distributed flexibility pathway” by forcing utilities to consider alternative ways of …


259th Annual Cornish Report Of The Selectmen And Other Town Officers For The Year Ending December 31, 2025, Cornish, New Hampshire, Cornish Town Representatives Jan 2026

259th Annual Cornish Report Of The Selectmen And Other Town Officers For The Year Ending December 31, 2025, Cornish, New Hampshire, Cornish Town Representatives

Cornish, NH Annual Reports

This is an annual report containing vital statistics for a town/city in the state of New Hampshire.


Annual Report Of The Town Officers Of The Town Of Columbia, New Hampshire For The Year Ending December 31, 2025 Including The Report Of The School Directors, Columbia Town Representatives Jan 2026

Annual Report Of The Town Officers Of The Town Of Columbia, New Hampshire For The Year Ending December 31, 2025 Including The Report Of The School Directors, Columbia Town Representatives

Columbia, NH Annual Reports

This is an annual report containing vital statistics for a town/city in the state of New Hampshire.


Dr. David M. Lowry Papers - Accession 1906, David Michael Lowry Jan 2026

Dr. David M. Lowry Papers - Accession 1906, David Michael Lowry

Manuscript Collection

The Dr. David Lowry Papers document the life and career of Dr. David Michael Lowry (1938-2025), an organist, musicologist, and music professor at Winthrop University from 1965 to 2011. Lowry was Professor of Music Emeritus at Winthrop and helped establish the York County Choral Society in 1981, serving as its artistic director for 31 years.

The collection consists of biographical and family materials, correspondence, certificates, church and recital programs, newspaper clippings, musical scores, photographs, physical media, and artifacts. Materials document Lowry’s education, teaching career, musical performances, research, and professional accomplishments. The collection includes numerous musical scores and research materials relating …


"Art, Esthetics, Ideal": An Ethics For Literary Translators In The Age Of Translating Machines, Gabriel González Núñez Jan 2026

"Art, Esthetics, Ideal": An Ethics For Literary Translators In The Age Of Translating Machines, Gabriel González Núñez

Writing and Language Studies Faculty Publications

The advent of effective machine translation has raised several issues for translators, including the question of how a human translator ought to translate in this age of translating machines. In this context of new ethical questions, the present essay argues that an answer may be found in Pedro Figari’s (1912) philosophical essay on esthetics. Following Figari, the current essay argues that literary translation is art, that as such it can produce an esthetic emotion on readers and that the purpose of such art and esthetics is an ideal in the form of the continuous betterment of the human condition.


Your Voice Matters Subtitle: First-Year Writing And Social Justice, Jackie Hendricks, Amy J. Lueck, Loring Pfeiffer, Maura Tarnoff Jan 2026

Your Voice Matters Subtitle: First-Year Writing And Social Justice, Jackie Hendricks, Amy J. Lueck, Loring Pfeiffer, Maura Tarnoff

OER for Social Justice Grant

Your Voice Matters: First-Year Writing and Social Justice frames writing as both an intellectual and community-oriented practice rooted in identity, audience awareness, and ethical engagement. Beginning with personal ways of knowing and the social construction of language, the text advances through public writing for social change, research methods grounded in justice, rigorous source collection and analysis, and strategies for making scholarly conversation visible and meaningful to real audiences. By foregrounding positionality, linguistic justice, and multi-modal strategies for public communication, this book equips students with the critical tools and reflective practices necessary for producing purposeful, public-facing writing.


Influence Of A Structured Strength Program On Sport-Related Outcomes In Female Lacrosse Players, Taylor R. Howard Jan 2026

Influence Of A Structured Strength Program On Sport-Related Outcomes In Female Lacrosse Players, Taylor R. Howard

UNF Graduate Theses and Dissertations

Per the National Collegiate Athletic Association (NCAA), approximately 30,000 individuals participate in collegiate lacrosse in the United States, roughly 13,000 being women. Participation beyond the NCAA has increased substantially in the National Association of Intercollegiate Athletics (NAIA), National Junior College Athletics Association (NJCAA), the Women’s Club Lacrosse Association (WCLA), and high school programs nationwide.  As women’s lacrosse continues to grow, strength and conditioning programs at the collegiate level have become pervasive to enhance athletic performance. However, limited research exists examining the impact of strength training on physical performance in women’s lacrosse.

The purpose of this study was to investigate the …


A Preliminary Investigation Of Research Collaboration Through Scientific Paper Co-Authorship In The Gulf Of Mexico, Juliet Vallejo, Evelyn Roozee, Dongkyu Kim, Andrew M. Song, Christopher A. Gabler, Jasper R. De Vries, Antonia Sohns, Gordon M. Hickey, Owen Temby Jan 2026

A Preliminary Investigation Of Research Collaboration Through Scientific Paper Co-Authorship In The Gulf Of Mexico, Juliet Vallejo, Evelyn Roozee, Dongkyu Kim, Andrew M. Song, Christopher A. Gabler, Jasper R. De Vries, Antonia Sohns, Gordon M. Hickey, Owen Temby

School of Earth, Environmental, & Marine Sciences Faculty Publications

It is well known that publications with collaborators from external institutions increase citations. This effect scales with spatial distance. There are also many barriers to long-distance collaborations, including linguistic differences, funding constraints, and the incremental costs of remote collaboration. This paper uses the Gulf of Mexico as a case study to examine long-distance research collaboration because it consists of three countries with diverse development levels and two prominent diplomatic languages, within a singular regional ecosystem of tremendous natural and economic value. This paper uses bibliometric network analysis to examine scientific research article co-authorship in the Gulf of Mexico from 2000 …


Histochemical Alteration, Protein Nitration, And Antioxidant Expression In Oysters As Early Warning Indicators For Microplastic Contamination In The Texas Gulf Coast, Rebecca Muñiz, Md Faisal Amin, Md. Saydur Rahman Jan 2026

Histochemical Alteration, Protein Nitration, And Antioxidant Expression In Oysters As Early Warning Indicators For Microplastic Contamination In The Texas Gulf Coast, Rebecca Muñiz, Md Faisal Amin, Md. Saydur Rahman

School of Earth, Environmental, & Marine Sciences Faculty Publications

Microplastics are widely distributed in aquatic environments and have been detected in numerous organisms. Marine bivalves are among the most affected aquatic organisms by microplastics due to their filter-feeding behavior. In this study, 60 oysters were collected from two sites along the Texas Gulf Coast. Fourier transform infrared (FTIR) spectroscopy and Nile red staining were used to detect microplastics in oyster (Crassostrea virginica) tissues. We compared field and laboratory samples collected after a two-week depuration period to identify differences in the shape and size of microplastics in oyster tissues. Results from the field sites showed a large number of microplastics, …


Possible Reconsideration To The Library Of Congress Classification System’S Liberal Placements Of African American Psychology And African American Social Science, Eddie Hughes Jan 2026

Possible Reconsideration To The Library Of Congress Classification System’S Liberal Placements Of African American Psychology And African American Social Science, Eddie Hughes

Southern University and A&M College: John B. Cade Library Publications

The Library of Congress Classification (LCC), developed by Herbert Putnam in 1897, remains the predominant system for organizing materials in U.S. academic libraries. By integrating innovations with earlier classification systems by Charles Cutter and Melvil Dewey, the LCC divides human knowledge into 21 classes, each represented by alphabetic codes. While Psychology is classified under BF and social sciences under HQ, materials on African American Psychology and African American Social Science are primarily cataloged under Class E—History of America—specifically E185.625 and E185.86. This placement raises critical questions about the appropriateness of categorizing these subjects as historical rather than disciplinary. Given African …


Improving Staff Perceptions Of Effective Communication Through Frequent Micro-Team Huddles: A Quality Improvement Initiative, Sara Krslovic Jan 2026

Improving Staff Perceptions Of Effective Communication Through Frequent Micro-Team Huddles: A Quality Improvement Initiative, Sara Krslovic

Master's Theses and Capstones

Abstract 

Background: Effective communication among interdisciplinary team members is essential for safe, coordinated patient care. An outpatient primary care clinic identified inconsistent and non-inclusive communication within assigned micro-teams, particularly between nurses and providers, creating an opportunity to implement a structured communication strategy.

Local Problem: Communication within micro-teams lacked a standardized process, and nurses were often excluded from routine communication with providers. Prior to implementation, no formal micro-team huddles had occurred within the previous six months.

Methods: A four-week quality improvement initiative was conducted using the Plan-Do-Study-Act (PDSA) framework. Weekly, micro-team huddles were implemented between nurses, providers, and the medical assistant …


Implementing A Nurse Re-Education Program To Promote Timely Use Of The Jada® System In The Postpartum Hemorrhage Cascade: A Quality Improvement Project, Maegan E. Doody Jan 2026

Implementing A Nurse Re-Education Program To Promote Timely Use Of The Jada® System In The Postpartum Hemorrhage Cascade: A Quality Improvement Project, Maegan E. Doody

Master's Theses and Capstones

Background: Postpartum hemorrhage (PPH), defined as blood loss greater than 1,000 mL after delivery, is a leading cause of maternal morbidity in the United States. Identification of risk factors and timely intervention are critical to improving maternal outcomes after delivery. First-line interventions include manual uterine massage, uterotonic medications, and antifibrinolytic medications; however, when bleeding is not well controlled, the Jada® System (Jada) is a newer vacuum-induced hemorrhage control device with a high efficacy and safety profile, particularly when implemented earlier in the hemorrhage cascade.

Local Problem: In 2025, the annual rate of PPH within the microsystem was 7.29%, …


Reducing Readmissions For Copd Through Improved Education: A Gap Analysis, Raphael Gaughan Jan 2026

Reducing Readmissions For Copd Through Improved Education: A Gap Analysis, Raphael Gaughan

Master's Theses and Capstones

No abstract provided.


Promoting Equitable Access To Postpartum Hemorrhage Education: A Quality Improvement Project Using Educational Interventions For Night Shift Nurses, Michelle Stella Jan 2026

Promoting Equitable Access To Postpartum Hemorrhage Education: A Quality Improvement Project Using Educational Interventions For Night Shift Nurses, Michelle Stella

Master's Theses and Capstones

Abstract

Background: Postpartum hemorrhage (PPH) is a serious condition that can lead to maternal morbidity or mortality following the birth of their child. It is important for nurses to be properly educated to manage this condition quickly and efficiently. Night shift nurses often face barriers to accessing educational opportunities during their shift because most education is tailored to daytime hours.

Local Problem: At the project site facility, night shift nurses perceived inconsistent access to education compared to day shift nurses. This gap highlighted the need for more flexible educational modalities to meet the needs of night shift nurses.

Methods: This …


Enhancing Patient Safety And Team Communication Via Standardized Unit Handoff Tools In Inpatient Rehabilitation, Julia Rae Before Jan 2026

Enhancing Patient Safety And Team Communication Via Standardized Unit Handoff Tools In Inpatient Rehabilitation, Julia Rae Before

Master's Theses and Capstones

Abstract

Background: Interdisciplinary safety huddles in healthcare are used to facilitate staff communication, voice patient safety concerns and identify high acuity patients, as well as identify current unit issues that need resolution. Using characteristics of safety huddles, revising patient report sheets to include pertinent safety information often shared during huddles may lead to an increase in staff perception of communication as well as awareness to patient safety concerns. Within an in-patient rehabilitation hospital, anonymous staff reports indicated dissatisfaction with interprofessional communication and microsystem data revealed increased events of adverse patient outcomes and safety concerns. Baseline data indicated inconsistent patient handoff …


A Patient-Centered Approach To Improving Patient And Family Education On Perioperative Processes To Reduce Anxiety: A Quality Improvement Initiative, Ashley Lauren Doherty Jan 2026

A Patient-Centered Approach To Improving Patient And Family Education On Perioperative Processes To Reduce Anxiety: A Quality Improvement Initiative, Ashley Lauren Doherty

Master's Theses and Capstones

Background: Perioperative anxiety is common among surgical patients and their family members. Anxiety may be increased by uncertainty and limited understanding of the surgical experience. Improving perioperative education may enhance understanding, reduce anxiety, and support a more patient and family centered surgical experience.

Local Problem: A Post-Anesthesia Care Unit (PACU) identified knowledge gaps in patient and family education about the perioperative process. The existing waiting room bulletin board was outdated and provided limited information. PACU nurses observed anxiety-related behaviors and confusion among patients and family members about the perioperative process. Patient satisfaction surveys routinely collected by the hospital also demonstrated …


Enhancing Safety And Efficiency In Cardiac Admission Handoffs Through Implementation Of An I-Pass Checklist: A Quality Improvement Project, Soraia D. Barros Jan 2026

Enhancing Safety And Efficiency In Cardiac Admission Handoffs Through Implementation Of An I-Pass Checklist: A Quality Improvement Project, Soraia D. Barros

Master's Theses and Capstones

Abstract

Background: Effective care handoff is a necessary step for maintaining patient safety during hospitalizations. The goal of this quality improvement project was to improve the completeness of information, particularly cardiac-related, provided by the ED staff to the CSSU nurses. The implementation involved the creation of a cardiac checklist and applying it to the pre-existing I-PASS forms used during asynchronous handoff.

Local Problem: The macrosystem implemented an updated system for handoffs between the ED and CSSU by substituting an over-the-phone report with a faxed I-PASS sheet. The result, as identified by the CSSU staff, is that reports contain undetailed patient …


Property Rights V. Taxpayer Rights: The Battle Over Tax Foreclosures, Stewart E. Sterk Jan 2026

Property Rights V. Taxpayer Rights: The Battle Over Tax Foreclosures, Stewart E. Sterk

Articles

No abstract provided.


Increasing Patient Feedback Survey Completions Through Patient-Centered Nursing Communication: A Quality Improvement Project, Lindsey E. Pawlowski Jan 2026

Increasing Patient Feedback Survey Completions Through Patient-Centered Nursing Communication: A Quality Improvement Project, Lindsey E. Pawlowski

Master's Theses and Capstones

Background: Patient feedback is essential to providing the best possible nursing care. Positive patient experiences can impact overall patient satisfaction, loyalty, and trust.

Local Problem: On a pediatric unit at a New England hospital, an assessment of the microsystem revealed that there was a low number of monthly patient feedback survey completions, which limited insight into patient experiences.

Aim Statement: The primary aim of this project was to increase the number of monthly National Research Corporation (NRC) surveys to ten by June 30, 2026.

Methods: This quality improvement project was guided by the Plan-Do-Study-Act (PDSA) model. The first stage of …


Increasing Nursing Perceptions On Advanced Directives Through Education To Promote Patient Centered Care, Michelle Strong Jan 2026

Increasing Nursing Perceptions On Advanced Directives Through Education To Promote Patient Centered Care, Michelle Strong

Master's Theses and Capstones

No abstract provided.


Incorporating Structured Safety Huddles To Improve Nursing Communication And Reduce Medical-Surgical Inpatient Fall Rates: A Quality Improvement Project, Alexia K. Leonard Jan 2026

Incorporating Structured Safety Huddles To Improve Nursing Communication And Reduce Medical-Surgical Inpatient Fall Rates: A Quality Improvement Project, Alexia K. Leonard

Master's Theses and Capstones

BACKGROUND: Patient falls are a significant concern for patient safety in the acute care setting and are typically connected to inadequate communication during shift transitions. Bedside shift report is considered the standard of care, however, barriers are still present when shifting patient care responsibilities among nursing staff. A literature review identified standardized safety huddles as an evidence-based practice to improve areas of communication, teamwork, situational awareness, and patient safety. This quality improvement (QI) project concentrated on the implementation of a standardized evening safety huddle in order to improve nursing communication and reduce patient falls on an inpatient medical-surgical/telemetry unit. METHODS: …


Improving Telemetry Alarm Fatigue By Reducing Perception Of Noise Through Education: A Quality Improvement Project, Emma Bergeron Jan 2026

Improving Telemetry Alarm Fatigue By Reducing Perception Of Noise Through Education: A Quality Improvement Project, Emma Bergeron

Master's Theses and Capstones

Background: The perception of excess telemetry noise has a negative impact on nursing staff workflow, emotional stress, physical stress, and alarm fatigue. This can create a distressing workplace, interrupt the ability to answer telemetry alarms in an appropriate amount of time, and further worsen alarm fatigue in nursing staff.

Local Problem: The local problem identified was the perception of telemetry noise and alarm fatigue. The purpose of this study was to assess the extent of alarm fatigue and perception of telemetry noise on the unit.

Methods: The study consisted of an assessment of the microsystem itself and the observed impact …


Promoting Safe And Effective Ciwa-Ar Protocol Adherence On An Inpatient Psychiatric Unit Through An Educational Reference Poster: A Quality Improvement Project, Kenan J. Gray Jan 2026

Promoting Safe And Effective Ciwa-Ar Protocol Adherence On An Inpatient Psychiatric Unit Through An Educational Reference Poster: A Quality Improvement Project, Kenan J. Gray

Master's Theses and Capstones

Abstract

Background: Alcohol withdrawal syndrome (AWS) can progress to seizures, delirium tremens, and autonomic instability. The Clinical Institute Withdrawal Assessment for Alcohol–Revised (CIWA-Ar) supports symptom-triggered AWS management, but safe use depends on timely nursing assessment, reassessment, and documentation.

Local Problem: On an adult inpatient psychiatric unit, chart audits identified CIWA-Ar protocol adherence gaps, including missed four-hour assessments and one-hour reassessments after lorazepam.

Methods: This quality improvement project used the Plan-Do-Study-Act model. Three educational reference posters were placed in high-visibility staff areas with QR-linked access to the facility’s AWS protocol and CIWA-Ar scoring guidelines. Outcomes were evaluated using pre- and post-intervention …


Improving Nurse Well-Being And Patient Safety Through A Structured Break Buddy System: A Quality Improvement Project, Elizabeth Harrington Jan 2026

Improving Nurse Well-Being And Patient Safety Through A Structured Break Buddy System: A Quality Improvement Project, Elizabeth Harrington

Master's Theses and Capstones

Abstract

Background: Nursing burnout has become an increasing concern due to heavy workloads, staffing shortages, and the inability of nurses to consistently take uninterrupted rest breaks during their shifts. Missed breaks contribute to fatigue, emotional exhaustion, decreased job satisfaction, and an increased risk of patient safety events. Evidence suggests that structured break interventions may improve opportunities for recovery during the workday.

Methods: A quality improvement (QI) project was conducted on a respiratory care unit at a midsized hospital in central New Hampshire using the Plan-Do-Study-Act (PDSA) framework. A microsystem assessment identified inconsistent break-taking as a significant gap. A five-question anonymous …


Introducing Education For Sensory Approaches In Mental Health-Related Emergency Department Visits: A Quality Improvement Project To Enhance Patient-Centered Care, Jesse O'Neill Jan 2026

Introducing Education For Sensory Approaches In Mental Health-Related Emergency Department Visits: A Quality Improvement Project To Enhance Patient-Centered Care, Jesse O'Neill

Master's Theses and Capstones

Background: Barriers to specialty care access have resulted in emergency departments (ED) operating as temporary psychiatric hold facilities for their communities. Patients boarding in the ED are demonstrated to use a disproportionate percentage of facility resources with minimal benefit to the patient. The Institute for Healthcare Improvement identifies the impact of the healthcare environment on patient outcomes and suggests staff training to foster trauma-informed practice culture (Schall et al., 2020).

Local Problem: High-stress healthcare environments can escalate maladaptive patient behaviors and the use of restrictive interventions. Traditional use of restrictive interventions lacks supportive evidence and contradicts person-centered care goals (Molloy …


Framing Migration And Legitimizing Power: A Critical Discourse Analysis Of Suella Braverman’S Illegal Migration Bill, Darren Pullen, Andy Brown, Gui Ying Annie Yang-Heim Jan 2026

Framing Migration And Legitimizing Power: A Critical Discourse Analysis Of Suella Braverman’S Illegal Migration Bill, Darren Pullen, Andy Brown, Gui Ying Annie Yang-Heim

Faculty Publications - College of Education

Language plays a crucial role in shaping public perceptions, reinforcing ideological dominance, and legitimizing government policies. The purpose of this paper is to analyze how linguistic and rhetorical strategies are used as a means to legitimize government authority and construct migrant identities.  This is achieved through an examination of the rhetorical strategies employed by the former UK Home Secretary, Suella Braverman in her speech on the Illegal Migration Bill. Using Critical Discourse Analysis (CDA) and the Sociolinguistic concepts of ideological positioning and social actor representation, this research investigates word choice, lexical framing, and ideological positioning to reinforce dominant migration narratives. …


Scope Of Microbial Transglutaminase For Site-Specific And Oriented Immobilization Of Native Antibodies From Various Host Species, Emily Beitello, Kwame Osei, Faith E. Breausche, Jon A. Friesen, Jeremy D. Driskell Jan 2026

Scope Of Microbial Transglutaminase For Site-Specific And Oriented Immobilization Of Native Antibodies From Various Host Species, Emily Beitello, Kwame Osei, Faith E. Breausche, Jon A. Friesen, Jeremy D. Driskell

Faculty Publications – Chemistry

Modification of antibodies to chemically couple labels or immobilization reagents is essential for developing biosensors. Typically, conjugation occurs through chemical methods that leverage reactive amines and thiols on native antibodies; however, this nonspecific approach can interfere with antibody function. Microbial transglutaminase (mTG) is an enzyme that has been used for site-specific conjugation of chemical modifiers to the Fc region of native antibodies, but thus far mTG-mediated conjugation has been limited to production of antibody-drug conjugates with human IgGs. Here, we assessed the scope and versatility of mTG to target IgGs, with the goal of site-specific conjugation to facilitate oriented …


Investigations Toward A Unified Reaction Pathway Of Thermal And Tbsotf-Mediated Oxidopyrylium-Alkene (5 + 2) Cycloadditions, Adam J. Youman, Samantha N. Rokey, Wentao Guo, Jacob P. Grabowski, Susanna N. Angles, Jacob J. Bulandr, Qing Sun, John R. Goodell, Dean J. Tantillo, T. Andrew Mitchell Jan 2026

Investigations Toward A Unified Reaction Pathway Of Thermal And Tbsotf-Mediated Oxidopyrylium-Alkene (5 + 2) Cycloadditions, Adam J. Youman, Samantha N. Rokey, Wentao Guo, Jacob P. Grabowski, Susanna N. Angles, Jacob J. Bulandr, Qing Sun, John R. Goodell, Dean J. Tantillo, T. Andrew Mitchell

Faculty Publications – Chemistry

Oxidopyrylium-based (5 + 2) cycloadditions are crucial reactions to construct seven-membered carbocycles containing an ether bridge (i.e. oxabicyclo[3.2.1]octanes). Intramolecular silyloxypyrone-based (5 + 2) cycloadditions were investigated and revealed several features: (1) the TBDPS thermal process proceeds via a zwitterionic oxidopyrylium intermediate similar to previously reported TBS variants; (2) the TBSOTf-mediated reaction proceeds through a cationic oxidopyrylium intermediate; (3) quantum chemical calculations predict a stepwise process for an electron-rich dipolarophile for each set of conditions. The thermal silyloxypyrone-based (5 + 2) cycloadditions were extremely dependent on the nature of the dipolarophile and the silyl transfer group. The TBDPS enhances the …


Ordo Ab Chao: Crystallographic Disorder As A Window Into Ionic Liquid Structure, Joseph Cooper, Marija Scheuren, Lara I. Teodoro, Christopher M. Butch, Raychell A. Jerdo, Kylie M. Allen, Mariana E. Toner, Matthias Zeller, Arsalan Mirjafari, Patrick C. Hillesheim Jan 2026

Ordo Ab Chao: Crystallographic Disorder As A Window Into Ionic Liquid Structure, Joseph Cooper, Marija Scheuren, Lara I. Teodoro, Christopher M. Butch, Raychell A. Jerdo, Kylie M. Allen, Mariana E. Toner, Matthias Zeller, Arsalan Mirjafari, Patrick C. Hillesheim

Faculty Publications – Chemistry

Despite being intended to resist crystallization, ionic liquids (ILs) quite frequently form solids, albeit with low melting points. The design motifs that lower melting points can leave measurable signatures in the solid state, manifesting as crystallographic disorder, and often give rise to metastable liquid states. While sometimes treated as experimental complications, such features provide a valuable window into the structural origins of IL phase behavior. Herein, we report a crystallographic study of a series of benzylated ILs that crystallize either directly or from long-lived supercooled melts. Single-crystal X-ray diffraction, supported by computational modeling and statistical analyses, provides structural evidence that …