Digital Commons Network^™

Stimuli-Responsive Phosphate Hydrogel: A Study On Swelling Behavior, Mechanical Properties, And Application In Expansion Microscopy, Yokly Leng, Collin N. Britten, Fatema Tarannum, Kayla Foley, Christopher Billings, Yingtao Liu, Keisha B. Walters

Chemical Engineering Faculty Publications and Presentations

Phosphorus-based stimuli-responsive hydrogels have potential in a wide range of applications due to their ionizable phosphorus groups, biocompatibility, and tunable swelling capacity utilizing hydrogel design parameters and external stimuli. In this study, poly(2-methacryloyloxyethyl phosphate) (PMOEP) hydrogels were synthesized via aqueous activators regenerated by electron transfer atomic transfer radical polymerization using ascorbic acid as the reducing agent. Swelling and deswelling behaviors of PMOEP hydrogels were examined in different salt solutions, pH conditions, and temperatures. The degree of swelling in salt solutions followed CaCl₂ < MgCl₂ < KCl < NaCl with a decrease in swelling rate at higher concentrations until reaching a saturation point. In water, the degree of swelling increased significantly around neutral pH and remained constant at basic pH values. The effects of polymerization conditions, including pH, temperature (30, 40, 50 °C), and MOEP concentration (40, 50, 60% v/v MOEP/H₂O), on the hydrogel swelling behavior in various salt solutions were also investigated. PMOEP hydrogels …

Localized Hermite Method Of Approximate Particular Solutions, Kwesi Acheampong

Dissertations

A localized Hermite method of approximate particular solutions (LHMAPS) is presented in this dissertation. This method is designed to improve the accuracy of the localized method of approximate particular solutions (LMAPS) for solving partial differential equations. LMAPS is a strong-form method that defines local radial basis function approximations to the solution values at a group of collocation points before applying the differential operator to this approximation function. Based on the LMAPS's local scheme, LHMAPS seeks Hermite-type local approximations based on both function values and derivatives. Numerical experiments validate the superior accuracy of the proposed method to the LMAPS by solving …

Analysis And Tritrophic Associations Of Bats, Bat Flies, And Laboulbeniales Microfungi In Kenya, Ally Willis

Masters Theses & Specialist Projects

Bats (Chiroptera) are host to diverse lineages of ectoparasitic arthropods including ticks, mites, fleas, bat bugs, and bat flies (Arthropoda). Streblidae and Nycteribiidae are families in the dipteran superfamily Hippoboscoidea, and these hematophagous ectoparasites and their host associations are relatively well studied in the American tropics but not as well in east Africa. One of the main properties of host-parasite systems is host specificity, with some Eastern Hemisphere species (Nycteribiidae) appearing to display a lower level. The morphology of bat flies may drive (or be the result of) niche partitioning on the landscape of the host. Streblid bat flies in …

Contaminant Transport Mechanisms And Source Tracking In Karst Groundwater Systems Under Agricultural Land Use, Shreya Pandey

Masters Theses & Specialist Projects

Karst areas in general face severe groundwater contamination problems that can degrade their water quality. In comparison to other landscapes, groundwater within karst regions is more susceptible to contamination. The situation gets worse when agriculture is practiced in these karst regions, because the nutrients and bacteria like nitrates and E. coli (Escherichia coli) are released into the groundwater systems which contaminate the water quality of those karst groundwater systems. This research aims to study the impacts of these contaminants, specifically nitrates and E. coli., by identifying the contaminant transport mechanisms and source tracking of these contaminants in the groundwater under …

Climate-Smart Agriculture In Southern Kenya: An Assessment Of Factors Influencing Crop Development And Productivity, Matthew Bowers

Masters Theses & Specialist Projects

Globally, the adverse effects of climate change are forcing farmers to adapt their practices or risk crop failures. Throughout Sub-Saharan Africa, agriculture is the largest source of food, income, and employment, so threats such as climate change can put millions of lives and livelihoods in peril if modifications are not made to the existing system. Climate-Smart Agriculture (CSA) is a potential solution, as CSA techniques aim to increase the productivity and resilience of land affected by climate change. While CSA is a relatively new conceptual approach, many traditional and Indigenous techniques can be considered “climate-smart”. Understanding what biotic and abiotic …

Development And Application Of The Sinkhole Hazard Risk Index To Inform Karst Policy And Mitigation Planning, Meghan Puente

Masters Theses & Specialist Projects

Sinkholes are geologic hazards that occur in karst landscapes and can be highly destructive and costly. Sinkhole mitigation plans and development policies are nonexistent at the federal level within the United States and vary significantly at the state level. The lack of a unified standard for sinkhole mitigation planning is partly due to a lack of available data and resources needed to assess sinkhole risk. While there are established sinkhole assessments within the literature, they focus more on the detection and prediction of sinkholes rather than a holistic approach to risk assessment. The goal of this study is to create …

Application Of Agent-Based Simulation And Game Theory In Evaluating Implementation Of Whole Genome Sequencing In Treating Lung Cancer, Fateme Ghalenoei

Master's Theses

Cancer, particularly lung cancer, presents significant diagnostic and economic challenges globally. Timely diagnosis and cost management play pivotal roles in treatment success. A biomarker is any measurable molecule in blood, bodily fluids, or tissues, indicating the potential presence of an abnormal bodily process, condition, or disease. Biomarker testing is a laboratory test in oncology that is used in the selection of targeted cancer treatments and to help avoid ineffective treatments. Whole Genome Sequencing (WGS), is a biomarker test which while more comprehensive, comes at a higher cost. This study proposes an agent-based simulation model within a game-theoretic framework to examine …

The Evolution Of A Response To Smoke Within The Arthropoda, Adam Miles

Masters Theses & Specialist Projects

Many animals have a survival instinct to flee in response to fire, but do they respond to smoke alone? Many arthropods respond to fire or smoke by moving in the opposite direction (a negative taxis) to obtain shelter. At the species level, taxa that have adapted a behavioral response to fire increase their fitness. This response behavior has been observed in many terrestrial arthropods. Still, the behavior is currently unknown for marine, aquatic, or cave arthropods, which are atypically exposed to smoke or fire. This project assesses how often behavioral adaptation to smoke avoidance may have evolved within Arthropoda. Twenty-two …

Parameter Estimation For Stroke Patients Using Brain Ct Perfusion Imaging With Deep Temporal Convolutional Neural Network, Shake Ibna Abir

Masters Theses & Specialist Projects

Acute ischemic stroke, caused by cerebral artery blockage, is a leading cause of long-term disability and mortality. Effective management relies on accurate, timely assessments from neuroimaging data. Computed tomography perfusion (CTP) imaging is crucial in evaluating stroke patients, offering detailed maps of cerebral perfusion to identify irreversibly damaged tissue and at-risk areas. This detailed assessment is essential for informed therapeutic decisions.

Key perfusion parameters derived from CTP imaging, including cerebral blood volume (CBV), cerebral blood flow (CBF), time to peak (TTP), and mean transit time (MTT), are crucial for understanding the extent and nature of cerebral ischemia, providing valuable insights …

Assessing Regional Responsibility Of Plecoptera (Stoneflies) Across Two U.S. Fish And Wildlife Service Regions, Josie Griffith

Masters Theses & Specialist Projects

Developing an objective metric to designate taxa that are the responsibility of the region is imperative for the proper allocation of conservation funding. This project focused on stoneflies (Order Plecoptera), an imperiled group of aquatic insects at the global scale, in two U.S. Fish and Wildlife Service regions. At the regional scale, a baseline designation of Regional Species of Greatest Conservation Need (RSGCN) was applied to each species where their range included at least 75% of states within either the Midwestern or Northeastern regions. Two sets of data were accumulated for each RSGCN. One, distributional information was collected from valid …

Unrefined And Milled Ilmenite As A Cost-Effective Photocatalyst For Uv-Assisted Destruction And Mineralization Of Pfas, Eustace Y. Fernando, Zhiming Zhang

Henry M. Rowan College of Engineering Departmental Research

Per- and polyfluoroalkyl substances (PFAS) are fluorinated and refractory pollutants that are ubiquitous in industrial wastewater. Photocatalytic destruction of such pollutants with catalysts such as TiO2 and ZnO is an attractive avenue for removal of PFAS, but refined forms of such photocatalysts are expensive. This study, for the first time, utilized milled unrefined raw mineral ilmenite, coupled to UV-C irradiation to achieve mineralization of the two model PFAS compounds perfluorooctanoic acid (PFOA) and perfluoro octane sulfonic acid (PFOS). Results obtained using a bench-scale photocatalytic reactor system demonstrated rapid removal kinetics of PFAS compounds (>90% removal in less than 10 …

Dean's Research Newsletter, August 2024, Neil W. Schluger

SOM Dean's Research Newsletter

No abstract provided.

Adult-Onset T-Cell Acute Lymphoblastic Lymphoma-Leukemia Presenting With Petechial Rash: A Case Report., Kelly Kimball, Vissy Elad, Edward J Hamad, Christopher Wasco

Oncology Articles

T-cell acute lymphoblastic lymphoma-leukemia (T-ALL) is a rare neoplastic disease with presenting symptoms that are often non-specific. As such, accurate diagnosis requires high clinical suspicion and assessment of bone marrow aspirate with flow cytometry and morphology. While remission is achievable in most patients, the five-year survival rate is only 48% despite treatment. The standard chemotherapy regimen is referred to as hyper-CVAD, where CVAD stands for cyclophosphamide, vincristine sulfate, Adriamycin (doxorubicin), methotrexate, and dexamethasone. In this study, we describe a 38-year-old female who presented with atraumatic abdominal bruising and a petechial rash on the upper and lower extremities. Imaging revealed a …

Landuse And Microplastic Transport In Karst Groundwater Of South-Central Kentucky, Katie Norman

Masters Theses & Specialist Projects

Groundwater in karst areas is susceptible to contamination from various sources of pollution. Microplastics are a prevalent source of pollution entering groundwater. This study examines karst groundwater in three areas of investigation. One point of interest is an area that is impacted by urban activities, the Lost River Groundwater Basin, which includes water drainage from the City of Bowling Green, Kentucky. Another study location is Great Onyx (GO) Spring, which is a part of the Great Onyx Groundwater Basin located in Mammoth Cave National Park, Kentucky, and that is relatively unimpacted by urban activities. The third point of interest is …

Development And Evaluation Of An Instrument For Exploring Achievement Emotions Of General Chemistry Students: General Chemistry Achievement Emotions Questionnaire, Alexander Graves

Dissertations

General Chemistry, a course that is required for many STEM degree programs, is often perceived as a difficult and stress-inducing course by students. One aspect of a student’s course experiences that can be measured are achievement emotions. Emotions that students can experience that can affect and are affected by academic performance are called achievement emotions. Achievement emotions, such as anxiety, have been extensively studied in recent years in relation to student performance and retention in different courses. Instruments that have been developed to measure achievement emotions in broad academic settings. However, achievement emotions have been determined to be domain-specific, meaning …

Proceedings Of The 2024 Berry Summer Thesis Institute, University Of Dayton. University Honors Program, Magdelyn Stewart, Noah Clemens, Sarah Theewis, Henry Salisbury, Kevin Johnston, Adin Stoller, Meggie Bailey, Erin T. Flaherty, Adelyn Hughes, Marc Nya

Proceedings of the Berry Summer Thesis Institute (2013-Present)

Thanks to a gift from the Berry Family Foundation and the Berry family, the University Honors Program launched the Berry Summer Thesis Institute in 2012. The institute introduces students in the University Honors Program to intensive research, scholarship opportunities and professional development. Each student pursues a 12-week summer thesis research project under the guidance of a UD faculty mentor. This contains the product of the students' research.

Contents:

Testing the Influence of Lithology and Ice Sheet Dynamics on Waterfall Formation in Hocking Hills State Park // Magdelyn Stewart

Step-Rate Manipulation for Improved Performance: A Review// Noah Clemens

Alfred Rosenberg: An …

Covid-19 Prevention Behaviors And Dietary Habits Among Undergraduate Students: A Health Belief Model Approach, Doreen Liou

Department of Nutrition and Food Studies Scholarship and Creative Works

Physical and social disruptions resulted from the COVID-19 pandemic, affecting young adults in higher education. The purpose of this survey research is to unveil COVID-19 related beliefs using the Health Belief Model, and COVID-19 prevention behaviors, including self-reported fruit and vegetable consumption among university students. A cross-sectional survey was administered to 304 male and female undergraduate students from diverse ethnic backgrounds and majors at a New Jersey state university using convenience sampling. Variables measured included frequency of COVID-19 prevention behaviors (e.g.: wearing indoor mask, handwashing), and consumption of fruit and vegetables (dark green and orange vegetables) over the previous week. …

Diseases Of Cannabis Sativa And The Epidemiology And Molecular Diversity Of Neofusicoccum Parvum, Hannah V. Zima

Graduate Theses and Dissertations

Cannabis sativa has been an underutilized agricultural resource in the United States, largely due to federal regulations distinguishing marijuana from hemp. In 2018, Congress passed a Farm Bill, which defined hemp as C. sativa containing a tetrahydrocannabinol (THC) level of no more than 0.3%. As a result, commercial hemp production began in most states in 2019, including Arkansas, and was accompanied by numerous challenges like diseases and pests. The research on the epidemiology of diseases affecting C. sativa is limited, and understanding the pathogens is in its early stages in the U.S. For this study, an initial disease survey was …

Detection Of Fungicide Resistance In Population Of Corynespora Cassiicola From Arkansas Soybean And Cotton Fields, Rafael Zaia

Graduate Theses and Dissertations

Target spot, caused by the fungus Corynespora cassiicola, has reemerged since 2016 as an economically important disease on soybean and cotton across the Southern U.S. The quinone outside inhibitors (QoI) and succinate dehydrogenase inhibitors (SDHI) are important fungicide classes used to control foliar diseases in soybean and cotton. The efficacy of these products is rapidly decreasing, impacting control, and causing significant yield losses. The overall objective of this study was to determine the risks associated with chemical control by screening fungicide sensitivity, evaluating target site alterations, and analysis of disease control efficacy and yield response of fungicides for soybean in …

Interactive Effects Between Bluetongue Virus Infection And Insecticide Exposures In Culicoides Sonorensis, Parker Mullins

Graduate Theses and Dissertations

Culicoides biting midges are common pests around the world of humans, livestock, and wildlife. In addition to nuisance blood feeding, they are also able to transmit pathogens to their hosts like bluetongue virus (BTV) and African horse sickness virus, which can be damaging in terms of both production economics and animal welfare. In order to protect humans and livestock from biting pests like Culicoides, a wide array of interventions is recommended, but chemical insecticides and repellent use are ubiquitous. For a multitude of reasons ranging from natural weathering of applied insecticides to the increase in resistance-associated mutations and behaviors in …

Impact Of Equipment Type On Measured Particle Size Of Civil Engineering Materials, Tanner Turben

Graduate Theses and Dissertations

Particle size analysis (PSA) captures the size distribution of fine-grained or emulsified materials with particles generally smaller than 1000 microns. Asphalt emulsions and many other civil engineering materials do not leverage PSA for material specifications or acceptance despite the insight into material performance and quality gained through understanding the particle size. The objectives of this study are to compare PSA measurement principles by testing 13 civil engineering materials by laser diffraction, Coulter counter, and microscopy and to develop a draft standard procedure for asphalt emulsion PSA. Asphalt emulsions, cementitious materials, sands, clays, and biological samples were selected to represent a …

Fungal Pathogen Control And Microbial Ecology: Insights From Soybean Seed Production, Samantha Rigo Segalin

Graduate Theses and Dissertations

This study evaluated the effects of planting date (PD), seed vigor, and chemical seed treatments on the plant stand and yield of two soybean cultivars with different maturity groups (MGs) across four locations in Arkansas from 2018 to 2021. Early planting in early May (early PD) led to higher plant stands and yields compared to late planting in early June (late PD). The interaction between planting date and cultivar was significant, with both cultivars showing higher plant stands on early planting dates. Seed vigor and seed treatment also significantly impacted plant populations; high-vigor seeds planted early resulted in better stands …

Letters To Whiteness: Reflections On A White Artist-Educator Identity Through Dialectical Materialism, Richard Peterson

Graduate Theses and Dissertations

In this thesis, I reflect on my identity and experience as a white male and an artisteducator through a lens of critical whiteness and dialectical materialism. I utilize creative writing, and storytelling to speak more metaphorically about my own experiences and feelings in relation to whiteness to understand how I now operate as an artist-educator. Through dialectical materialism, I break down the social change described within the stories of growing up in the United States and intergenerational relationships with other white male figures, displaying more intricate ways I understand how similarities and differences change over time within the white identity …

Developing A Controlled Traffic (Tramline) Farming System, Department Of Primary Industries And Regional Development, Western Australia

Grains and other field crops factsheets

Controlled traffic farming (CTF) is a farming system built on permanent wheel tracks where the crop zone and traffic lanes are permanently separated. It can improve profitability and sustainability.

Implements for seeding, spraying, spreading and harvesting have a particular span, or multiple of it, and all wheel tracks are confined to specific traffic lanes.

CTF increases profit by more yield, better grain quality, improved operation timeliness, and reduced costs. The environment can improve, with less nutrient leaching, less water erosion, better water infiltration, and less greenhouse gas emission. Implementation needs a clear, long-term plan, and prioritisation of soil health.

Another …

Assessing Soil Properties & Suitability For Optimized Irrigation Development In Sudan, Northern Africa, Suhib O. Hamid

Department of Agricultural and Biological Systems Engineering: Masters Project Reports

In Chapter 1, soil properties essential for efficient irrigation are thoroughly assessed. Factors such as soil texture, infiltration rates, and nutrient content are analyzed to provide insights into the selection of modern irrigation systems. Utilizing data collected from 3,192 locations through GPS and laboratory analyses, alongside sophisticated ranking systems, the research determines the most suitable irrigation methods for specific soil series. Findings highlight the remarkable efficiency of drip irrigation across various soil types, contrasting with the consistently lower performance of surface irrigation. The chapter emphasizes the significance of considering soil variability, evapotranspiration, and investment factors in selecting irrigation methods for …

Clemson Commencement Program, August 2024, Clemson University

Clemson Commencement Programs

No abstract provided.

New Ways Of Being White: White Families Striving To Raise Young Antiracists, Katie Kitchens

Education (PhD) Dissertations

In asking the questions “How are white families striving to create antiracist family cultures simultaneously resisting reifying white dominant culture, and how are white children making sense of their racial identities in those families?” I had the opportunity to deepen previously established relationships with three families asking similar questions. Our collective querying resulted in data collected using critical ethnographic methods rooted in culturally responsive methods including fieldwork, formal and informal conversations, and written narrative. Unique themes emerged from each family’s data, from which I drew three major theoretical conclusions: the importance of (1) Critical Consciousness (2) Antiracist Community, and (3) …

Why Are There So Many Definitions Of Eutrophication?, Alexandrine Pannard, Philippe Souchu, Christian Chauvin, Monique Delabuis, Chantal Gascuel-Odoux, Erik Jeppesen, Morgane Le Moal, Alain Ménesguen, Gilles Pinay, Nancy N. Rabalais, Yves Souchon, Elisabeth M. Gross

Faculty Publications

Because of the first observations in the 1900s of the oligotrophic and eutrophic states of lakes, researchers have been interested in the process that makes lakes become turbid because of high phytoplankton biomass. Definitions of eutrophication have multiplied and diversified since the mid-20th century, more than for any other ecological process. Reasons for the high number of definitions might be that the former ones did not sufficiently describe their causes and/or consequences. Global change is bringing eutrophication more into the spotlight than ever, highlighting the need to find consensus on a common definition, or at least to explain and clarify …

Key Uncertainties And Modeling Needs For Managing Living Marine Resources In The Future Arctic Ocean, Julia G. Mason, Andrea Bryndum-Buchholz, Juliano Palacios-Abrantes, Renuka Badhe, Isabella Morgante, Daniele Bianchi, Julia L. Blanchard, Jason D. Everett, Cheryl S. Harrison, Ryan F. Heneghan, Camilla Novaglio, Colleen M. Petrik

Faculty Publications

Emerging fishing activity due to melting ice and poleward species distribution shifts in the rapidly-warming Arctic Ocean challenges transboundary management and requires proactive governance. A 2021 moratorium on commercial fishing in the Arctic high seas provides a 16-year runway for improved scientific understanding. Given substantial knowledge gaps, characterizing areas of highest uncertainty is a key first step. Marine ecosystem model ensembles that project future fish distributions could inform management of future Arctic fisheries, but Arctic-specific variation has not yet been examined for global ensembles. We use the Fisheries and Marine Ecosystem Intercomparison Project ensemble driven by two Earth System Models …

Lactoferrin And Lysozyme To Promote Nutritional, Clinical And Enteric Recovery: A Protocol For A Factorial, Blinded, Placebo-Controlled Randomised Trial Among Children With Diarrhoea And Malnutrition (The Boresha Afya Trial), Ruchi Tiwari, Kirkby Tickell, Emily Yoshioka, Joyce Otieno, Adeel Shah, Barbra Richardson, Lucia Keter, Maureen Okello, Churchil Nyabinda, Indi Trehan

Paediatrics and Child Health, East Africa

Introduction: Children with moderate or severe wasting are at particularly high risk of recurrent or persistent diarrhoea, nutritional deterioration and death following a diarrhoeal episode. Lactoferrin and lysozyme are nutritional supplements that may reduce the risk of recurrent diarrhoeal episodes and accelerate nutritional recovery by treating or preventing underlying enteric infections and/or improving enteric function.

Methods and analysis: In this factorial, blinded, placebo-controlled randomised trial, we aim to determine the efficacy of lactoferrin and lysozyme supplementation in decreasing diarrhoea incidence and improving nutritional recovery in Kenyan children convalescing from comorbid diarrhoea and wasting. Six hundred children aged 6–24 months with …