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Methylene Blue Dye Removal In Aqueous Solution Using Synthesized Mncuo2 Nanocomposite: Thermodynamic And Kinetic Studies, Sara Mohammed Hassan, Ahlam M. Farhan Jul 2026

Methylene Blue Dye Removal In Aqueous Solution Using Synthesized Mncuo2 Nanocomposite: Thermodynamic And Kinetic Studies, Sara Mohammed Hassan, Ahlam M. Farhan

Baghdad Science Journal

This work reports the preparation of manganese and cupper Hybrid Oxide nanocomposites by a green synthesis method. The material was characterized by X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), and Transmission Electron Microscopy (TEM). Brunauer–Emmett–Teller (BET) surface area measurements The synthesized materials were examined for their dye adsorption performance through the removal of basic methylene blue (MB) as a model compound from water. Various adsorption parameters were investigated, such as adsorbent dosage, contact time, solution pH, and temperature. Mesoporous MnCuO2 nanocomposites displayed satisfactory results, with rapid adsorption occurring and the use of low-concentration sorbents and contact times …

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A Waste-To-Fuel Approach: Utilizing Parkia Speciosa Peel Extract For Green Synthesis Of Zno Nanocatalyst, Nurul Zannah Siregar, Vivi Sisca, Isalmi Aziz, Wulandari Wulandari, Dicky Annas Jul 2026

A Waste-To-Fuel Approach: Utilizing Parkia Speciosa Peel Extract For Green Synthesis Of Zno Nanocatalyst, Nurul Zannah Siregar, Vivi Sisca, Isalmi Aziz, Wulandari Wulandari, Dicky Annas

Baghdad Science Journal

Biodiesel can be made by a transesterification reaction using a ZnO catalyst. This research aims to synthesize and characterize the ZnO catalyst and test its activity in producing biodiesel from waste cooking oil. ZnO was synthesized by the one-pot phytosynthesis method by adding petai peel (Parkia speciosa Hassk). ZnO catalyst size 42.9 nm. The resulting surface area and pore size are 7.629 m2/g and 1.693 nm, respectively. The particle size and constituent components of the ZnO catalyst are 93.21 nm with 82.3% (Zn) and 17.7% (O). FTIR spectra confirmed the formation of metal-oxide stretching at wave number 511 …

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Synthesis, Characterization, And Biological Evaluation Of A New Azo Dye Ligand 1-[2,4,6-Trihydroxy-3-(2-Hydroxy-Phenylazo)-Phenyl-Ethanone] And Its Complexes With Co(Ii), Ni(Ii), Cu(Ii), Zn(Ii), And Cd(Ii), Ban Hasan Al-Agele, Areej Kamal Assim Aldabbagh Jul 2026

Synthesis, Characterization, And Biological Evaluation Of A New Azo Dye Ligand 1-[2,4,6-Trihydroxy-3-(2-Hydroxy-Phenylazo)-Phenyl-Ethanone] And Its Complexes With Co(Ii), Ni(Ii), Cu(Ii), Zn(Ii), And Cd(Ii), Ban Hasan Al-Agele, Areej Kamal Assim Aldabbagh

Baghdad Science Journal

1-[2,4,6-trihydroxy-3-(2-hydroxy-phenylazo)-phenyl-ethanone] is a new azo dye ligand (H2L), which was used to form a number of new azo dye-metal complexes by reaction with salt chlorides of Co, Ni, Cu, Zn and Cd(II). The complexes were characterized using mass spectroscopy, infrared analysis, ultraviolet-visible spectrophotometry, 1H-, 13C-NMR spectroscopy, conductivity, magnetic susceptibility, DSC, TGA, C.H.N., metal content, and melting point. The results highlighted the ligand's trigonal behavior and that all the complexes yielded tetrahedral geometry, with the exception of Co and Ni, which produced octahedral geometry. They are all non-electrolytic. The compounds' capacity to function as antioxidants was used …

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K-12 Teachers’ Perspectives On The Adoption Of Virtual Reality And Augmented Reality Technology In Classroom Instruction, Breanna Mckenley Jul 2026

K-12 Teachers’ Perspectives On The Adoption Of Virtual Reality And Augmented Reality Technology In Classroom Instruction, Breanna Mckenley

Walden Dissertations and Doctoral Studies

The problem addressed in this basic qualitative study was that although some K–12 teachers have access to virtual reality (VR) and augmented reality (AR) technologies, these tools are not widely accepted or adopted for classroom instruction. Guided by the technology acceptance model, the purpose of the study was to explore K–12 teachers’ perspectives on their willingness to incorporate VR/AR, the perceived usefulness and ease of use of these technologies, and the challenges they encounter or anticipate during the adoption process. Semistructured interviews were conducted with 10 K-12 teachers from public, charter, and private schools in the United States who had …

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From Chromosomes To Precision Therapy: Clinical Cytogenetics And Cytogenomics In The Era Of Genomic Medicine, Jinglan Liu Jul 2026

From Chromosomes To Precision Therapy: Clinical Cytogenetics And Cytogenomics In The Era Of Genomic Medicine, Jinglan Liu

Department of Pathology, Anatomy, and Cell Biology Faculty Papers

No abstract provided.

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Under Pressure: Negative Urgency And Disordered Eating In The Context Of Parental Differential Support, Hamide Gozu, Jenna K. Rieder Jul 2026

Under Pressure: Negative Urgency And Disordered Eating In The Context Of Parental Differential Support, Hamide Gozu, Jenna K. Rieder

College of Humanities and Sciences Faculty Papers

Disordered eating behaviors are prevalent in emerging adulthood and may be shaped by family dynamics. This study examined associations among maternal and paternal differential support, weight-shape concerns, and binge eating and compensatory behaviors in emerging adulthood, while testing the moderating role of negative urgency. Participants were 517 emerging adults from across the United States (ages 18-29; M = 22.60, SD = 3.81; 76% female). Participants reported on parental differential support, weight-shape concerns, eating behaviors, and negative urgency. Using moderated-mediation analyses, we found that weight-shape concerns mediated associations between differential support and eating behaviors. Unequal maternal support and paternal favoritism showed …

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Tinyml-Based Embedded Vision System For Ic Detection In Microcontroller Manufacturing, Mark M. Pallones, King Harold A. Recto, Rynne Daven A. Barrios Jul 2026

Tinyml-Based Embedded Vision System For Ic Detection In Microcontroller Manufacturing, Mark M. Pallones, King Harold A. Recto, Rynne Daven A. Barrios

Electronics, Computer, and Communications Engineering Faculty Publications

Mixing of microcontroller unit (MCU) integrated circuits (ICs) during the final testing stage of semiconductor manufacturing can lead to material waste, production delays, and customer dissatisfaction. This issue often occurs when standard JEDEC Matrix Trays (JMTs) are reused without confirming that all ICs have been removed after testing, a process typically performed through manual inspection and therefore susceptible to human error due to high test volumes, small IC package sizes, and visual similarity between IC packages and tray surfaces. This study develops an automated IC Detection Test System using embedded vision to determine whether JMT trays are empty prior to …

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Zno-Functionalized Cotton Textiles With Enhanced Antibacterial Activity, Moisture Management, And Wear Comfort, Md Ariful Islam, Md Mehedi Hassan, Md Tanvir Hossain, Jakir Hossain Ridoy, Ahasan Habib Jul 2026

Zno-Functionalized Cotton Textiles With Enhanced Antibacterial Activity, Moisture Management, And Wear Comfort, Md Ariful Islam, Md Mehedi Hassan, Md Tanvir Hossain, Jakir Hossain Ridoy, Ahasan Habib

Michigan Tech Publications

Nowadays, cotton textiles with metal oxide nanoparticle functionality exhibit promising antibacterial applications; although many aspects have been tested, fabric comfort and moisture-related performance have not been sufficiently explored. In this study, cotton (twill) fabric has been functionalized by synthesizing ZnO nanoparticles (ZnO NPs) via a controlled exhaustion process followed by thermal fixation. The synthesized nanoparticles are characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD), whereas scanning electron microscopy (SEM) proves the surface morphology. Antibacterial evaluation shows effective activity against Staphylococcus aureus and Escherichia coli, with a large inhibition zone (35-36 mm) and a ∼99% reduction in bacterial …

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Elucidation Of Spin-Hamiltonian Parameters Via Spectroscopy, Magnetization, And Computation, Joshua C. Mengell Jul 2026

Elucidation Of Spin-Hamiltonian Parameters Via Spectroscopy, Magnetization, And Computation, Joshua C. Mengell

Chemistry and Chemical Biology ETDs

Molecular Quantum Information Science (QIS) is fundamentally concerned with using spin-systems as quantum bits (qubits) or as sensors. Prerequisite to using molecular systems for QIS applications, it must be understood how one can design molecules with bespoke magnetic characteristics. Herein we study various paramagnetic molecular compounds, describing their complex magnetic characteristics using a spin-Hamiltonian formalism. We utilize various (sometimes novel) methods for determining these spin-Hamiltonian parameters. Many of these molecules possess magnetic characteristics, which make them attractive as qubits or for sensing applications. These characteristics include higher total spin-states (qudits—ST>1/2), forbidden interstate electronic transitions, systems of spatially distant …

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Exploring The Nature And Role Of Local Cation Ordering In Disordered Rock Salt Cathodes For Li- And Na-Ion Batteries, You Wang Jul 2026

Exploring The Nature And Role Of Local Cation Ordering In Disordered Rock Salt Cathodes For Li- And Na-Ion Batteries, You Wang

Chemistry and Chemical Biology ETDs

Cation-disordered rock-salt (DRX) cathodes provide a highly tunable platform for next-generation Li- and Na-ion batteries, but their electrochemical behavior is strongly influenced by local structural features hidden in average crystal structures. This dissertation systematically investigates local cation ordering in Li- and Na-based DRX cathodes to understand its effects on Li+/Na+ transport, redox activity, structural evolution, and electrochemical performance. In Li-based systems, Raman spectroscopy and electrochemical analysis reveal that local layered cation ordering in Mn- and Fe-based DRX cathodes is closely correlated with electrochemical behavior. Over-stoichiometric Li-based DRX oxyfluorides further demonstrate that excess Li can regulate local cation ordering, improve Li+ …

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Examining Conditional Indirect Media Effects Through Normative Perceptions: The Role Of Traditional Family Gender Role Expectations And Stigmatizing Beliefs In Human Papillomavirus Vaccination, Moonsun Choi Jul 2026

Examining Conditional Indirect Media Effects Through Normative Perceptions: The Role Of Traditional Family Gender Role Expectations And Stigmatizing Beliefs In Human Papillomavirus Vaccination, Moonsun Choi

Communication ETDs

This dissertation examines how indirect media effects operate through normative perceptions within a gendered and stigmatized health context of HPV vaccination. Specifically, this study investigates how these normative mediation processes are conditioned by traditional family gender role expectations at the norm formation stage and stigmatizing beliefs about HPV vaccination at the normative influence stage. A cross-sectional survey was conducted with mothers of children aged 9 – 12 in the United States in June 2025. The key findings show that while gendered perceptions of HPV vaccination persist, the underlying normative mechanism operated in similar ways across gender-referent contexts. Injunctive norms were …

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Uv Damage Mapping Reveals Different Impacts Of Xpd Mutations On Global Genomic And Transcription-Coupled Dna Repair, Allyson Hoag Jul 2026

Uv Damage Mapping Reveals Different Impacts Of Xpd Mutations On Global Genomic And Transcription-Coupled Dna Repair, Allyson Hoag

Biomedical Sciences ETDs

Nucleotide Excision Repair (NER) is a fundamental cellular process that removes bulky and helical distorting lesions from the genome through the separate responses of its two subpathways – global genomic (GG-NER) and transcription coupled (TC-NER) DNA repair. The pathways converge with the recruitment of the TFIIH complex, a key step that is mediated by the translocase and helicase activities of  its XPD subunit. Germline mutations in XPD result in the clinical disorders, Xeroderma Pigmentosum (XP) and XP combined with Cockayne Syndrome (XP/CS). The goal of this thesis was to understand if XPD XP and XP/CS mutations differentially impact GG-NER and …

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Mapping And Modeling Threat-Evoked Brain States After Early Life Adversity, Taylor W. Uselman Jul 2026

Mapping And Modeling Threat-Evoked Brain States After Early Life Adversity, Taylor W. Uselman

Biomedical Sciences ETDs

Early life adversity (ELA) increases lifelong neuropsychiatric vulnerability. Yet how ELA reorganizes brain-wide activity and circuit coordination across later experience remains unclear. This dissertation tests the hypothesis that ELA alters adult brain-wide activity and responses to threat through disrupted coordination among neural systems that regulate emotional experience, including prefrontal-limbic and monoaminergic systems. Longitudinal manganese-enhanced MRI of adult mice exposed to standard or fragmented early care, combined with computational processing and statistical modeling, quantified brain states before, during, and long after innate predator threat. These studies established that acute threat evokes large-scale, distributed brain activity that evolves over time. ELA potentiates …

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Prenatal Alcohol Exposure Induces Vulnerability To Mild Stress Through Heightened Limbic Glial Activation And Cytokine Release, Justine R. Zimmerly Jul 2026

Prenatal Alcohol Exposure Induces Vulnerability To Mild Stress Through Heightened Limbic Glial Activation And Cytokine Release, Justine R. Zimmerly

Biomedical Sciences ETDs

Fetal alcohol spectrum disorder (FASD) results from prenatal alcohol exposure (PAE) and is linked to development of mood disorders, which in turn are driven by dysregulation of the sympathetic nervous system, the neuroendocrine hypothalamic-pituitary-adrenal (HPA) axis, and the central nervous system (CNS) neuroimmune response to stressors. PAE alters brain glial activation and proinflammatory cytokine expression through secondary challenges such as psychological stressors. The goals of the experiments presented in this dissertation were to 1) examine peripheral glucocorticoid receptor function following mild acute stress in adult PAE offspring, 2) characterize a sensitized cytokine stress response in the hippocampus, medial prefrontal cortex, …

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Multiscale Network Modeling Of Native And Modified Photosynthetic Light-Harvesting Complexes, Zane E. Armijo Jul 2026

Multiscale Network Modeling Of Native And Modified Photosynthetic Light-Harvesting Complexes, Zane E. Armijo

Chemical and Biological Engineering ETDs

Photosynthetic light-harvesting complexes harvest solar energy and direct electronic excitations toward reaction centers with exceptional efficiency. This dissertation models the Fenna--Matthews--Olson complex of green sulfur bacteria, coupled to the PscA1 reaction center, as a chromophoric network. Forster resonance energy transfer theory, validated against numerically exact hierarchical equations of motion, was implemented in kinetic Monte Carlo simulations to resolve fine-grained excitation-transport pathways. The predicted charge-transfer efficiency of 77\% agrees with experiment, with the FMO2 monomer and its gateway pigment governing interfacial transfer. Systematic single, multi, and symmetry-preserving site removals, interpreted through Mobius inversion, identify critical pigments and show that cooperative effects …

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Impact Of Gas Interactions With Nano Porous Geological Material In The Presence Of Water Vapor, Matthew D. Powell Jul 2026

Impact Of Gas Interactions With Nano Porous Geological Material In The Presence Of Water Vapor, Matthew D. Powell

Chemical and Biological Engineering ETDs

Predicting gas transport in nanoporous geological material requires understanding competitive adsorption and transport under humid conditions. However, most adsorption studies rely on single-component equilibrium measurements that do not capture these effects. This dissertation develops an experimental methodology to directly quantify multicomponent gas adsorption and breakthrough behavior under controlled relative humidity. The method was first applied to the Kr/Xe–N2–H2O system, where it resolved competitive adsorption behavior in humid porous media and produced a bivariate model relating noble gas adsorption to noble gas partial pressure and water saturation. The methodology was then extended to the CO2–N2 H2O system. Results showed that water …

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Mechanisms Of Advanced And Energy Efficient Wastewater Treatment Technologies, Derek Belka Jul 2026

Mechanisms Of Advanced And Energy Efficient Wastewater Treatment Technologies, Derek Belka

Civil Engineering ETDs

This dissertation combines meta-omics, microbial ecology, and hydrodynamic analysis to explore mechanisms of enhanced biological phosphorus removal (EBPR) and aerobic granular sludge (AGS) in municipal wastewater treatment. Metagenomic and functional gene profiling of a laboratory sequencing batch reactor fed with amino acids and proteins, and with a low abundance of known polyphosphate-accumulating organisms (PAOs), revealed abundant Herpetosiphonaceae and Dermatophilaceae families possessed key PAO metabolic traits, including phosphate scavenging, anaerobic carbon pathways, and ppk2 gene variants aligned with established PAOs. These findings suggest amino acid-driven EBPR can occur via previously unrecognized taxa, challenging current engineering assumptions and highlighting the need for …

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Wildfire Impacts On Fluvial Hydrology From Watershed To National Scales, Paige G. Tunby Jul 2026

Wildfire Impacts On Fluvial Hydrology From Watershed To National Scales, Paige G. Tunby

Civil Engineering ETDs

Wildfires alter the water quantity and quality in downstream river networks. Fires promote biodiversity, maintain habitat, and provide many ecosystem services in a fire-adapted landscape. However, changes in the natural fire regimes can alter ecosystem function and threaten the water security of impacted downstream communities. The magnitude, timing, and persistence of these impacts are difficult to predict due to the lack of high-resolution datasets with adequate coverage to evaluate spatiotemporal trends after a fire. This dissertation moves us beyond the status quo to evaluate post-fire fluvial responses across scales, from the event-scale impacts after the Hermit’s Peak-Calf Canyon wildfire in …

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Myeloid Mmp14 Couples Extracellular Proteolysis To Inflammatory And Metabolic Remodeling During Obesity, Long J Shao, Fathima Elizondo, Feng Gao, Elizabeth L Lieu, Bharati Reddi, Maryam Elizondo, Iqbal Mahmud, Kristin Eckel-Mahan, Philipp E Scherer, Xin Ge, Huaizhu Wu, Sean Hartig, Kai Sun Jul 2026

Myeloid Mmp14 Couples Extracellular Proteolysis To Inflammatory And Metabolic Remodeling During Obesity, Long J Shao, Fathima Elizondo, Feng Gao, Elizabeth L Lieu, Bharati Reddi, Maryam Elizondo, Iqbal Mahmud, Kristin Eckel-Mahan, Philipp E Scherer, Xin Ge, Huaizhu Wu, Sean Hartig, Kai Sun

The Brown Foundation: Institute of Molecular Medicine

Macrophages orchestrate tissue remodeling, inflammation, and metabolic dysfunction in obesity, but the role of macrophage-intrinsic extracellular proteolysis in immunometabolic regulation remains unclear. Matrix metalloproteinase-14 (MMP14), a membrane-bound protease, is strongly induced during monocyte-to-macrophage differentiation and further elevated in adipose tissue macrophages from high-fat diet (HFD)-fed mice. Pharmacological inhibition or myeloid-specific deletion of Mmp14 impaired macrophage differentiation, proliferation, migration, phagocytosis, and inflammatory activation in response to obesity-associated adipose tissue signals. Mechanistically, MMP14 promoted inflammatory programming by increasing endotrophin generation and enhancing TLR4-NFκB signaling. MMP14 also reprogrammed macrophage lipid metabolism by suppressing lipolysis and promoting lipid accumulation, altering metabolic communication with neighboring …

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Good Impressions At Work: Exploring Gendered Labor In The Middle Rio Grande, Nm Ad 1100-1500, William F. Marquardt Jul 2026

Good Impressions At Work: Exploring Gendered Labor In The Middle Rio Grande, Nm Ad 1100-1500, William F. Marquardt

Anthropology ETDs

This dissertation investigates changes in the gendered division of labor among potters in the Middle Rio Grande Valley, New Mexico (MRG) between A.D. 1100 and 1500. During this time, diverse groups coalesced into some of the largest communities seen in the region until the industrial era. New architectural, technological, religious, and trade practices emerged to help knit these communities together during a dynamic period of change. Pottery making practices changed alongside other developments transforming from manufacture for local consumption to surplus production for exchange. Previous research on gendered divisions of labor have largely portrayed gendered labor as static rather than …

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Algorithmic Sculpting Of Complex Fused Silica Surfaces For Nondestructive, Mode-Matched Cavity Quantum Electrodynamics: Adaptive Co2 Milling And Simulation-Guided Ultrafast Inscription, From Fiber Fabry-Perot Cavities To Monolithic Architectures, Meagan E. Parker Jul 2026

Algorithmic Sculpting Of Complex Fused Silica Surfaces For Nondestructive, Mode-Matched Cavity Quantum Electrodynamics: Adaptive Co2 Milling And Simulation-Guided Ultrafast Inscription, From Fiber Fabry-Perot Cavities To Monolithic Architectures, Meagan E. Parker

Optical Science and Engineering ETDs

Quantum sensors achieve exceptional measurement sensitivity through coherent, well-isolated quantum systems, but practical deployment is hindered by destructive readouts that require repeated state preparation and create long system dead times. Optical cavities enable continuous, nondestructive measurements with minimal back-action, yet integrating high-finesse cavities into scalable quantum devices remains limited by existing fabrication methods. To overcome these constraints, an adaptive CO₂ laser-milling platform was developed. Guided by glass thermodynamics and melt dynamics, this closed-loop system uses in-situ phase-shifting interferometry to sculpt complex fused-silica surfaces with sub-nanometer root-mean-square roughness. The platform was validated by fabricating extended-length fiber Fabry–Pérot cavities and monolithic micro-cavity …

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3d Electromagnetic Simulations Of A 1.6 Cell S-Band Photoinjector: Emittance Studies For Electron Microscopy, Trudy Bolin Jul 2026

3d Electromagnetic Simulations Of A 1.6 Cell S-Band Photoinjector: Emittance Studies For Electron Microscopy, Trudy Bolin

Electrical and Computer Engineering ETDs

Modern beam-based materials research demands electron sources with increasingly precise time resolution, high brightness, and stability. For example, there are various instruments across the U.S. dedicated to ultrafast electron diffraction (UED), but fewer are dedicated to ultrafast electron microscopy (UEM), which demands beam stability. Modeling femtosecond electron bunches with ultra-low emittance < 50 nm-rad inside a 1.6-cell S-band (2856 MHz) rf photoinjector with full 3D electromagnetic simulations can require high-performance computing (HPC) environments due to the scale disparity between the macroscopic cavity geometry and the femtosecond-scale bunch kinematics. To enable optimization in a desktop computing environment, this work presents a streamlined 3D electromagnetic Particle-in-Cell (PIC) simulation framework optimized for 400-femtosecond bunch regimes. The covariance method was employed to study emittance properties for electron bunch counts ranging from thousands to millions and has successfully resolved highly transient, pure rf phase-space rotations, such as a localized energy-spread minimum occurring at the gun exit iris. To overcome the computational cost of these simulations, a machine-learning-based Bayesian optimization approach was deployed to construct multi-objective Pareto fronts from sparse datasets. Because the simulation software is scalable from desktop to HPC facilities, the framework is ready for experiments at the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory (LBNL).

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Impacts Of Agricultural Microplastics On The Growth Of Marine Phytoplankton In Monterey Bay, Olivia A. Pawlyk Jul 2026

Impacts Of Agricultural Microplastics On The Growth Of Marine Phytoplankton In Monterey Bay, Olivia A. Pawlyk

Master's Theses

Agricultural plastics are an emerging source of microplastics (MPs) to coastal marine environments, yet their effects on marine phytoplankton remain poorly understood. In coastal regions surrounding Monterey Bay (California, USA), plastic mulch used in agriculture can fragment into MPs during weathering and removal, entering marine waters via runoff and wind transport. This study investigated the effects of environmentally relevant concentrations of agricultural MPs on the growth and physiology of four marine phytoplankton species: two harmful algal bloom (HAB) taxa (Alexandrium sp. and Pseudo-nitzschia multiseries) and two non-HAB taxa (Thalassiosira sp. and Prorocentrum sp.). Each species was cultured independently and exposed …

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Establishing Thermal Bleaching Thresholds For Montastraea Cavernosa On Florida’S Coral Reef, Olivia Faris Jul 2026

Establishing Thermal Bleaching Thresholds For Montastraea Cavernosa On Florida’S Coral Reef, Olivia Faris

Electronic Theses and Dissertations

Marine heatwaves are increasing in frequency and duration, with widespread bleaching events and mortality impacts observed on Florida’s Coral Reef. However, thermal bleaching thresholds for corals in Southeast Florida are not well established, limiting the ability to forecast or manage response to thermal stress events in the region. This study was designed to establish bleaching thresholds for Montastraea cavernosa, a reef-building stony coral, in Southeast Florida. Ex-situ experiments were conducted where triplicate M. cavernosa fragments of multiple genotypes were exposed to acute thermal stress or held at intermediate temperatures to simulate chronic stress. Thermal performance curves based on photosynthetic …

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Ionophore-Based Plga Nanosensor For Selective Ion Detection And Imaging, Zhiyu Tang Jul 2026

Ionophore-Based Plga Nanosensor For Selective Ion Detection And Imaging, Zhiyu Tang

Electronic Theses and Dissertations

Accurate detection of electrolyte ions is essential for biological research, disease diagnosis, and the investigation of cellular function. In this study, we developed ionophore-based PLGA nanosensors for the optical detection of biologically important ions. The nanosensors were prepared by encapsulating ionophores, chromoionophore III, and ion exchangers within PLGA nanoparticles. The resulting nanosensors showed uniform morphology, good colloidal stability, and concentration-dependent optical responses toward Na⁺, K⁺, and Ca²⁺ over the range of 10⁻⁶ to 10⁻¹ M. Reversible fluorescence responses under repeated ion concentration changes confirmed the stability and robustness of the sensors. The nanosensors also demonstrated reliable analytical performance for K⁺ …

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Assessment Of Anaerobic Co-Digestion Of High Strength Organic Feedstocks Diverted From Landfills, Sumaiya Sharmin Jul 2026

Assessment Of Anaerobic Co-Digestion Of High Strength Organic Feedstocks Diverted From Landfills, Sumaiya Sharmin

Electronic Theses and Dissertations

The increasing generation of high-strength organic wastes such as food waste and fats, oils, and grease (FOG) presents challenges for landfill capacity and waste management. Anaerobic co-digestion offers a sustainable alternative by converting these wastes into renewable energy and nutrient-rich digestate. This study evaluated the co-digestion performance of single fruit waste residuals and mixed food waste with wastewater sludge to identify substrate combinations that maximize methane production while maintaining process stability. Laboratory-scale batch experiments were conducted under mesophilic conditions using thickened waste activated sludge (TWAS) with varying proportions of food waste and co-substrates, including seaweed, aquatic weed, grease trap waste, …

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Neural And Computational Mechanisms Of Effort Under The Pressure Of A Deadline, M. Andrea Pisauro, Daniele Pollicino, Lucy Fisher, Matthew A. J. Apps Jul 2026

Neural And Computational Mechanisms Of Effort Under The Pressure Of A Deadline, M. Andrea Pisauro, Daniele Pollicino, Lucy Fisher, Matthew A. J. Apps

School of Psychology

Deadlines fundamentally shape motivation. Research examining effort-based choices finds effort is an avoided cost. However, this overlooks how making progress on longer-term goals to be reached before deadlines motivate people to exert high effort for little immediate reward. Here, we test a framework where motivation depends on deadline pressure (work remaining / time remaining). Across four studies we use computational modelling examining decisions when physical effort makes progress on goals with deadlines. In support of the hypotheses, deadline pressure significantly impacts decision-making, shifting people from avoiding effort, to seeking the progress it makes. Using ultra-high-field fMRI, we show that functionally …

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A New Numerical Approach For Solving Caputo-Fabrizio Fractional Differential Equations, Manoj Kumar Jul 2026

A New Numerical Approach For Solving Caputo-Fabrizio Fractional Differential Equations, Manoj Kumar

Baghdad Science Journal

In this paper, we present a novel numerical scheme for solving fractional-order differential equations of the form ^CFD_t^η ψ ( t ) = f( t,ψ ( t ) ),ψ ( 0 ) = ψ 0,0 < η < 1,t∈[ 0,T ], where ^CFD_t^η denotes the Caputo-Fabrizio derivative operator. Further, we establish the stability and error analysis of the proposed scheme. We also extend this scheme for solving systems of fractional differential equations. Furthermore, we perform the several numerical simulations and present the results graphically. The obtained solutions are compared with those achieved through the well-known methods such as fractional Adams-Bashforth method and a new predictor-corrector method. It has been observed that the proposed method offers greater accuracy than these established methods. Hence, the proposed scheme can be utilized for the simulations of various fractional order differential equations, when the derivatives are considered in the Caputo-Fabrizio sense.

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Synthesis, Characterization, Molecular Docking, And Anticancer Activity Of Triazole-Derived Trinuclear Metal Complexes (Tat3), Eman M. Ramadthan, Khansaa Shakir Al-Nama, Ammar H. Al-Sabawi Jul 2026

Synthesis, Characterization, Molecular Docking, And Anticancer Activity Of Triazole-Derived Trinuclear Metal Complexes (Tat3), Eman M. Ramadthan, Khansaa Shakir Al-Nama, Ammar H. Al-Sabawi

Baghdad Science Journal

A novel series of trinuclear coordination complexes of Co(II), Ni(II), Cu(II), Zn(II), and Cd(II) was synthesized using a triazole-based ligand, namely 4-amino-5-((bis((4-amino-5-thioxo-4,5-dihydro-1H-1,2,4-triazol-3-yl)methyl)amino)methyl)-2H-1,2,4-triazole-3(4H)-thione, (TAT3) in an alcoholic medium. The obtained complexes were investigated using a comprehensive set of physicochemical and spectroscopic techniques, including CHNS elemental analysis, Fourier-transform infrared (FT-IR) spectroscopy, UV–visible spectroscopy, proton and carbon-13 nuclear magnetic resonance (1H and 13C-NMR), mass spectrometry, magnetic susceptibility measurements, and molar conductivity. Structural and surface morphology assessments were further carried out using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The spectroscopic and analytical data confirmed that …

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Synthesis, Spectroscopic Characterization, Biological And Computational Study For Some Metal Ions Complexes With Schiff - Mannich Base Ligand Derived From 1,3,4-Thiadiazole, Israa Rasheed Ghadhban, Shaymaa R. Baqer Jul 2026

Synthesis, Spectroscopic Characterization, Biological And Computational Study For Some Metal Ions Complexes With Schiff - Mannich Base Ligand Derived From 1,3,4-Thiadiazole, Israa Rasheed Ghadhban, Shaymaa R. Baqer

Baghdad Science Journal

A new Schiff–Mannich base ligand derived from 1,3,4-thiadiazole was synthesized via the reaction of 2-amino-5-mercapto-1,3,4-thiadiazole with sulfabenzamide and indoline in the presence of formaldehyde, yielding N–(4-((5-(2-oxoindolin-3-ylideneamino)-1,3,4-thiadiazol-2-ylthio)methylamino) phenyl thiolperoxy) benzamide (L). Six multivalent metal complexes were subsequently prepared with Co(II), Ni(II), Cu(II), Pd(II), Pt(IV), and Au(III) ions. The ligand and its complexes were characterized using various spectroscopic techniques, including FT-IR, UV-Vis, 1H NMR, and 13C NMR, while magnetic susceptibility and conductivity measurements were performed for the complexes. Infrared analysis revealed tetradentate coordination of the ligand to all metals, with octahedral geometries for most complexes and square planar geometries for …

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