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2025 Tennessee External Quality Review Technical Report, Tennessee. Division Of Tenncare. Mar 2026

2025 Tennessee External Quality Review Technical Report, Tennessee. Division Of Tenncare.

TennCare Additional Reports

No abstract provided.


Trail To Classroom: Digitizing Rocky Mountain Landscapes With 360 Video, Hanna Fontes Mar 2026

Trail To Classroom: Digitizing Rocky Mountain Landscapes With 360 Video, Hanna Fontes

SACAD: Scholarly Activities

Immersive media technologies are increasingly used in science education, yet they are often positioned as tools for passive observation rather than relational engagement. This qualitative study examines the use of 360-degree video as a relational, place-based pedagogical tool in learning. Using immersive landscape recordings from Rocky Mountain National Park, this research explores how 360-degree video can support student connection, empathy, and a sense of belonging to place. Learning activities were designed to prompt sensory observation, reflection, and meaning-making, encouraging students to engage emotionally and cognitively with the landscape rather than viewing it as a detached object of study. Data sources …


On Signifiable Computability: Part Iii: A Note On Unnameable Functions On Natural Numbers, Vladimir A. Kulyukin Mar 2026

On Signifiable Computability: Part Iii: A Note On Unnameable Functions On Natural Numbers, Vladimir A. Kulyukin

Computer Science Faculty and Staff Publications

A writing system 𝔚 on an alphabet 𝒜 is a tuple (ℜ,𝔐), where ℜ is a finite set of text formation rules and 𝔐 is a finite rule application mechanism that generates texts on 𝒜. A natural writing system forms natural language texts on an alphabet such as Sanskrit on Devanagari. An artificial writing system generates formal language texts on an alphabet such as Lisp on Unicode. Let ℕ ={0,1,2,…} be the set of natural numbers. A function on natural numbers 𝑓 :ℕ𝑘 ↦ ℕ, 0 < 𝑘 ∈ ℕ, is nameable by a writing system on an alphabet if, and only if, the system can generate a text on the alphabet that names f and no other function. We show that there exist functions on natural numbers unnameable in principle in that they cannot be named by any writing system on any alphabet. Our results imply the following computability-theoretic hierarchy of functions on natural numbers: computable ⊊ partially computable ⊊ nameable ⊊ 𝔉, where 𝔉 is the set of functions on ℕ.


In Vitro Pharmacological Evaluation Of Novel Cmpi Derivatives As Selective Positive Allosteric Modulators Of The Alpha4 Beta2 Nicotinic Acetylcholine Receptor, Josue Gaona, Nataly Sanchez, Wilder Felix, Nathalia Menegasso, Brisa Cea, Ganesh Thakur, Ayman K. Hamouda Mar 2026

In Vitro Pharmacological Evaluation Of Novel Cmpi Derivatives As Selective Positive Allosteric Modulators Of The Alpha4 Beta2 Nicotinic Acetylcholine Receptor, Josue Gaona, Nataly Sanchez, Wilder Felix, Nathalia Menegasso, Brisa Cea, Ganesh Thakur, Ayman K. Hamouda

School of Medicine Student Publications and Presentations

Nicotinic acetylcholine receptors (nAChRs) contribute to the pathogenesis of neurodegenerative diseases such as Parkinson’s disease (PD), where degeneration of dopaminergic and cholinergic neurons disrupts neurotransmission. The (α4)₃(β2)₂ nAChR subtype is expressed on affected neuronal populations and represents a promising therapeutic target. Positive allosteric modulators (PAMs) may enhance receptor function while preserving endogenous signaling. We evaluated chemical derivatives of CMPI [3-(2-chlorophenyl)-5-(5-methyl-1-(piperidin-4-yl)-1H-pyrazol-4-yl)isoxazol] as selective PAMs of (α4)₃(β2)₂ nAChRs. Two-electrode voltage-clamp recordings were performed in Xenopus laevis oocytes expressing defined receptor stoichiometries to assess potentiation and generate dose–response curves. Cytotoxicity was assessed in HEK cells using the MTT assay. Substitutions at the pyrazole …


Using Ensemble Disagreement To Stabilize Conformal Prediction Under Distribution Shift, Patrick D. Murphy Mar 2026

Using Ensemble Disagreement To Stabilize Conformal Prediction Under Distribution Shift, Patrick D. Murphy

Master's Theses

Semantic segmentation of eelgrass from drone imagery is crucial for coastal habitat monitoring, restoration, and management, as these habitats continue to see rapid changes due to climate change and human influence. However, the reliability of generalizing a deployed classification model relies on both high-accuracy segmentation as well as robust uncertainty quantification that holds up when conditions change over years or locations. Conformal prediction (CP) is a method that converts a classifier's output into prediction sets with a guaranteed average coverage level for in-distribution data. However, the “vanilla” conformal score can often under-cover in hard or out-of-distribution (OOD) regions under drift. …


Mechanistic Framework Of Wood Decomposition In Post-Storm Vegetative Debris Piles Using Continuous Quality Theory, Thomas T. Lee Mar 2026

Mechanistic Framework Of Wood Decomposition In Post-Storm Vegetative Debris Piles Using Continuous Quality Theory, Thomas T. Lee

Master's Theses

Storm events generate significant quantities of vegetative debris composed of wood, branches, twigs, and other organic materials. Efficient post-storm resource recovery and carbon accounting depend on reliable predictions of decomposition within these large, heterogeneous debris piles. While small-scale wood decay is well studied, decomposition dynamics within multi-layer debris piles remain poorly characterized, limiting municipalities' ability to estimate material longevity and resource recovery potential.

To address this gap, this study develops the WOOD_DK (Wood Organic Oxidation and DegraDation Kinetics) model, a preliminary, exploratory one-dimensional multilayer decomposition framework simulating coupled temperature, moisture, oxygen, and carbon dynamics in MATLAB. Microbial decomposition follows Continuous …


Neurosymbolic Counterpoint Generation, Paul D. Jarski Mar 2026

Neurosymbolic Counterpoint Generation, Paul D. Jarski

Master's Theses

Recent advancements in generative artificial intelligence have revolutionized music generation, yet research has predominantly focused on raw audio synthesis over music in symbolic form, i.e. a score. This thesis presents the first neurosymbolic model designed to generate imitative Renaissance counterpoint in symbolic (MIDI) format. By leveraging an autoregressive Transformer architecture, this research explores the capacity of deep learning models to manage independent voices and strict stylistic constraints.

We compare multiple data representation strategies with distinct tokenization methods. The proposed model incorporates a symbolic component that enforces fundamental contrapuntal rules. Additionally, this thesis contributes a preprocessed dataset of Renaissance polyphony, in …


A Simulation Framework For Edge Lane Roads And Bicycle Shared Roadways, Nick Sauciur Mar 2026

A Simulation Framework For Edge Lane Roads And Bicycle Shared Roadways, Nick Sauciur

Master's Theses

Edge Lane Roads, also referred to as Advisory Bike Lanes, are a shared roadway treatment that designates space for cyclists while allowing flexible use of the roadway by motorists. They are commonly applied on lower speed corridors and can be used both where roadway width is limited and where agencies seek to manage vehicle speeds, clarify cyclist positioning, or improve shared roadway operations. The configuration provides visually designated space for cyclists while allowing motorists to encroach into that space when yielding to opposing traffic. Although interest in these facilities is growing in North America, quantitative tools for evaluating their operational …


Beyond Artifacts And Fossils: Exploring The Contributions And Socioeconomic Impacts Of Montana’S Museums And Paleontological Tourism, Emma Keinath-Lopez, Elena Bigart, Glenna Hartman, Kara Grau, Ava Worbets, Melissa Weddell Mar 2026

Beyond Artifacts And Fossils: Exploring The Contributions And Socioeconomic Impacts Of Montana’S Museums And Paleontological Tourism, Emma Keinath-Lopez, Elena Bigart, Glenna Hartman, Kara Grau, Ava Worbets, Melissa Weddell

Institute for Tourism and Recreation Research Publications

This study explores how Montana’s museums, including those along the Montana Dinosaur Trail, influence communities, economies, and visitor experiences in a post-pandemic environment. Through mixed methods—511 visitor surveys at 44 museums and 18 interviews with museum professionals— this research provides a holistic understanding of museum operations, visitor motivations, and community impacts.


Law And The Self-Coordinating Market Idea, Sanjukta Paul Mar 2026

Law And The Self-Coordinating Market Idea, Sanjukta Paul

Articles

Much of the focus of the live Symposium was on comparing existing scholarship associated with two intellectual communities. I have no objection to that enterprise in the abstract, though I think it is a bit premature where law and political economy (LPE) is concerned and sets up an apples-to-oranges comparison to the decades-old streams of work and thinking in law and economics (L&E). But I would rather use the privilege of the space in this written Symposium to sketch what I believe is the ultimate substantive nub of contestation in this conversation about the core subject matter of “the economy” …


A Unified Methodological Framework For Generating Digital Twins Of Multi Class Uncrewed Systems (Uxs), Sai Raghava Pathuri Mar 2026

A Unified Methodological Framework For Generating Digital Twins Of Multi Class Uncrewed Systems (Uxs), Sai Raghava Pathuri

Shelby Hall Graduate Research Forum Presentations

No abstract provided.


Detecting Bitstream-Level Fpga Trojans With An Snn, Kylie Arnett Mar 2026

Detecting Bitstream-Level Fpga Trojans With An Snn, Kylie Arnett

Shelby Hall Graduate Research Forum Presentations

Limited research has been conducted on SNNs for FPGA Trojan detection. FPGA design is often handled by manufacturers outside the U.S. FPGA manufactures outsource production to third-party foundries. This multi-step process introduces security vulnerabilities and increases risk of Hardware Trojan insertion.

Key Questions: To what extent can an FPGA be manipulated at the bitstream level to enable or disable encryption algorithms?

Can SNNs accurately detect the presence of Trojans within an FPGA?


Bridging The Distance: Expanding Access To Mental Health Services In School, Griffin Gallagher, Arayah St John, Kaylie Svir Mar 2026

Bridging The Distance: Expanding Access To Mental Health Services In School, Griffin Gallagher, Arayah St John, Kaylie Svir

Master of Social Work Student Policy Advocacy Briefs

All students should have equitable access to mental health services in schools. In Minnesota, there has been an 11% increase in students experiencing long-term mental health challenges since 2016, and only 1 in 5 students receive the assistance they need. Students are experiencing a lack of access to mental health services in schools due to barriers of cost, transportation, shortage of support staff, and stigma. When mental health services are not provided in schools, this results in a decrease in school attendance, higher dropout rates, and negative school environments, affecting the long-term outcomes and needs of the child. Mental health …


When You're Just Not "Indian" Enough: The Erosion Of Tribal Sovereignty In State V. Nobles And The Case For Deference To Tribes On Questions Of Indian Status, Daniel G. Sullivan Mar 2026

When You're Just Not "Indian" Enough: The Erosion Of Tribal Sovereignty In State V. Nobles And The Case For Deference To Tribes On Questions Of Indian Status, Daniel G. Sullivan

North Carolina Law Review

No abstract provided.


Teaching On The Clock, Michael Burla Do Mar 2026

Teaching On The Clock, Michael Burla Do

Faculty Development Tips

No abstract provided.


The Emerging And Evolving Evidence Supporting Creatine As An Ergogenic Aid: History And Applications, Chad Kerksick, Drew Gonzalez, Jeffrey Stout, Scott Forbes, Darren Candow, Tim Ziegenfuss, Ronald Marshall, René Schwesig, Richard Kreider Mar 2026

The Emerging And Evolving Evidence Supporting Creatine As An Ergogenic Aid: History And Applications, Chad Kerksick, Drew Gonzalez, Jeffrey Stout, Scott Forbes, Darren Candow, Tim Ziegenfuss, Ronald Marshall, René Schwesig, Richard Kreider

Faculty Scholarship

Background

Creatine is one of the most extensively studied ergogenic aids, with over three decades of research supporting its role in exercise performance, recovery, and health.

Methods

This narrative review summarizes the historical development of creatine supplementation and evaluates evidence regarding its mechanisms, efficacy across active, athletic populations (e.g. strength, endurance, team-sport), and tactical (e.g. military, law enforcement) populations, and its safety profile.

Results

The evidence suggests that creatine enhances phosphocreatine resynthesis and cellular energy availability, resulting in consistent improvements in high-intensity exercise performance, training adaptations, lean body mass, strength, and power. Additional findings indicate that creatine may attenuate exercise-induced …


Analyzing Access To Livelihood Opportunities Among Migrants, Refugees And Asylum-Seekers In Egypt, Sara Sadek, Nada Hegazy, Shaimaa Gheith, Mahmoud Mansour Mar 2026

Analyzing Access To Livelihood Opportunities Among Migrants, Refugees And Asylum-Seekers In Egypt, Sara Sadek, Nada Hegazy, Shaimaa Gheith, Mahmoud Mansour

Faculty Journal Articles

The study “Access to livelihood opportunities among migrants, refugees and asylum- seekers in Egypt,” was conducted under the framework of the Egyptian Migration Hub (EHUB) project. It focused on underscoring the prospects of challenges with regards to the employment of such groups in the informal labor economy in Egypt considering the current limitations in the legal framework. The study adopted a qualitative method including 46 KIIs and 46 FGDs conducted in three governorates: Greater Cairo, Alexandria and Damietta. In December 2024 the law 164 governing refugee and asylum issues in Egypt was enacted with Article 18 stipulating the right to …


Portable Ice Cube Maker, Ayden Ziegler, Emiliano Hansen, Wyatt Engdahl, Dane Hansen Mar 2026

Portable Ice Cube Maker, Ayden Ziegler, Emiliano Hansen, Wyatt Engdahl, Dane Hansen

Mechanical Engineering

This Final Design Report outlines the senior design project undertaken by a team of mechanical engineering students at California Polytechnic State University, San Luis Obispo, for the development of a portable backpacking ice cube maker. The project aims to design, build, and test a lightweight, compact device that produces ice cubes for backpackers in remote outdoor environments. The goal is to create a functional prototype that is durable, user-friendly, and suitable for backcountry use. This document details background research, project objectives, and project plan, and current design status.


Measuring Plantar Flexor Voluntary Activation And Maximal Voluntary Contraction In A Portable, Seated Method: A Validity And Reliability Study, Molly E. Coventry, Andrea B. Mosler, Paola T. Chivers, Brady D. Green, Ebonie K. Rio, Myles C. Murphy Mar 2026

Measuring Plantar Flexor Voluntary Activation And Maximal Voluntary Contraction In A Portable, Seated Method: A Validity And Reliability Study, Molly E. Coventry, Andrea B. Mosler, Paola T. Chivers, Brady D. Green, Ebonie K. Rio, Myles C. Murphy

Research outputs 2022 to 2026

Background: Voluntary activation testing quantifies the ability of the motor nervous system to produce maximal force. Laboratory assessment of ankle plantar flexor voluntary activation is common, but field testing in practical settings is limited by equipment portability. We aimed to compare plantar flexor voluntary activation and maximal voluntary contraction (MVC) using a portable device with a standardised laboratory method and evaluate the test–retest reliability of the portable protocol. Methods: We performed a pseudo-randomised, crossover design. Participants completed two protocols: (1) portable force plate testing and (2) a laboratory-based isokinetic dynamometer. Voluntary activation was assessed using twitch interpolation via tibial nerve …


A High-Fidelity Multimodal Synthetic Dataset Generation Framework For Off-Road Unstructured Terrain Navigation Training Of Autonomous Robots, Liyana Wijayathunga, Dulitha Dabare, Alexander Rassau, Douglas Chai, Syed Mohammed Shamsul Islam Mar 2026

A High-Fidelity Multimodal Synthetic Dataset Generation Framework For Off-Road Unstructured Terrain Navigation Training Of Autonomous Robots, Liyana Wijayathunga, Dulitha Dabare, Alexander Rassau, Douglas Chai, Syed Mohammed Shamsul Islam

Research outputs 2022 to 2026

The success of deep learning methods in a wide range of application areas has inspired many recent developments in the urban and off-road autonomous navigation domain. In particular, techniques for semantic scene understanding, a key aspect of the navigation pipeline, have been researched extensively, resulting in many real-world and synthetic datasets. However, in comparison to urban semantic segmentation datasets, the availability of datasets for off-road environments remains sparse. In this paper, we aim to overcome this challenge by introducing a methodology capable of efficiently generating photorealistic synthetic datasets for off-road environments with support for multiple sensor modalities. The developed approach …


Remedying Copyright For Indigenous Australians: A Stolen Generations Perspective, Elizabeth Serventy, Koutras Mar 2026

Remedying Copyright For Indigenous Australians: A Stolen Generations Perspective, Elizabeth Serventy, Koutras

Research outputs 2022 to 2026

This study presents a Judicial Intersectionality method that incorporates knowledge from arts, humanities, natural sciences, and social sciences. It aims to examine how historical legal, political, and social injustices against Indigenous Australians have persisted in various spheres. When considering the Stolen Generations period, attention is directed on addressing the existing insufficient copyright rights and enhancing future legal results for Indigenous artists. In order to achieve that objective, a unique and distinct copyright system is regarded as the most suitable resolution. Philosophically and pragmatically, this approach was aligned with the Australian Government's 2023 Referendum, which aimed to grant constitutional status to …


Effect Of A 6-Week Structured Exercise Intervention On Tnf-Α During The Chronic Recovery Phase Of A Burn Injury Compared To Regular Daily Activities: A Pilot Randomised Cross-Over Trial, Tyler Jerome Osborne, Grant Rowe, Dale W. Edgar, Mark Fear, Fiona M. Wood, Timothy Fairchild, Brook Galna, Pippa Kenworthy, Brad Wall Mar 2026

Effect Of A 6-Week Structured Exercise Intervention On Tnf-Α During The Chronic Recovery Phase Of A Burn Injury Compared To Regular Daily Activities: A Pilot Randomised Cross-Over Trial, Tyler Jerome Osborne, Grant Rowe, Dale W. Edgar, Mark Fear, Fiona M. Wood, Timothy Fairchild, Brook Galna, Pippa Kenworthy, Brad Wall

Research outputs 2022 to 2026

Background: Burn injury induces a prolonged inflammatory response that may contribute to long-term metabolic dysfunction. Exercise is known to reduce inflammation in various clinical populations; however, its effect on chronic post-burn inflammation remains unclear. This crossover trial investigated the impact of a 6-week exercise intervention on tumour necrosis factor-alpha (TNF-α) in adults with non-severe burns sustained more than one year prior. Methods: Twenty-one participants were randomised to complete either a 6-week exercise program or a control period first, separated by a 4-week washout. The exercise program comprised three supervised sessions per week of combined resistance and cardiovascular training. Primary (TNF-α) …


Physical Fitness And Executive Functions In Early Childhood: A Systematic Review Of Recent Evidence, Nemanja Lakicevic, Marko Manojlovic, Elena Chichinina, Apollinaria Chursina, Kristina Tarasova, Ewan Thomas, Yuming Zhong, Antonino Bianco, Patrik Drid Mar 2026

Physical Fitness And Executive Functions In Early Childhood: A Systematic Review Of Recent Evidence, Nemanja Lakicevic, Marko Manojlovic, Elena Chichinina, Apollinaria Chursina, Kristina Tarasova, Ewan Thomas, Yuming Zhong, Antonino Bianco, Patrik Drid

Research outputs 2022 to 2026

Background Optimizing physical fitness (PF) and developing executive functions (EFs) is of great importance in preschool children. The link between PF, obtained through repetitive physical activity, and EFs is gaining increasing attention in recent years and we sought to systematically search the literature on the relationship between PF and EFs in preschool children published in the last five years. Methods Web of Science, Scopus, and PubMed were databases searched for the relevant literature. Original studies written in English and published in peer-reviewed journals including healthy children aged 3–6 years who were simultaneously tested for PF and EFs were considered eligible. …


Explainable Artificial Intelligence Models For Detecting Suspicious Bank Transactions, Narasimha Kumar Narasapuram, Syed Afaq Ali Shah, Mohd Fairuz Shiratuddin, Ferdous Sohel Mar 2026

Explainable Artificial Intelligence Models For Detecting Suspicious Bank Transactions, Narasimha Kumar Narasapuram, Syed Afaq Ali Shah, Mohd Fairuz Shiratuddin, Ferdous Sohel

Research outputs 2022 to 2026

Detecting financial crime is a complex challenge due to evolving criminal strategies and fragmented detection systems, particularly in the areas of money laundering and fraud. While it is easy to implement, traditional rule-based approaches lack adaptability to new threats, and machine learning models, though more effective, often function as opaque "black boxes," limiting their practical use in regulated domains like banking, where interpretability and accountability are essential. This research presents a novel framework that combines intrinsic and post-hoc XAI techniques to detect suspicious bank transactions. Intrinsic methods provide model-inherent transparency, while post-hoc methods offer behavior-level explanations, enabling robust cross-verification of …


Optimizing Agility Training In Team Sport Players—The Role Of Perception-Action Coupling: A Systematic Review With Multi-Level Meta-Analysis, Zhiwei Zhao, Yuhang Liu, Kai Xu Mar 2026

Optimizing Agility Training In Team Sport Players—The Role Of Perception-Action Coupling: A Systematic Review With Multi-Level Meta-Analysis, Zhiwei Zhao, Yuhang Liu, Kai Xu

Research outputs 2022 to 2026

Agility, characterized by rapid whole-body movement in response to external stimuli, is a key performance determinant in team sports owing to its reliance on perception-action coupling. Despite its importance, existing evidence on training effects is disproportionately focused on change-of-direction ability, overlooking the perceptual-cognitive demands of true agility. This systematic review therefore sought to quantify the effects of agility-specific training, examine moderators and establish dose-response model in team-sport players, while accounting for perception-action coupling. Following PRISMA 2020 guidelines, systematic searches were conducted in Web of Science, Scopus and PubMed for peer-reviewed English-language studies. Risk of bias was appraised using a modified …


Pleural Metastases From Acral Lentiginous Melanoma Diagnosed By Medical Thoracoscopy, Ad Rian Chong, Khai Lip Ng, Nai-Chien Huan, Nur Husna Mohd Aminudin, Fazilah Hassan, Kasuma Mohamed Nordin Mar 2026

Pleural Metastases From Acral Lentiginous Melanoma Diagnosed By Medical Thoracoscopy, Ad Rian Chong, Khai Lip Ng, Nai-Chien Huan, Nur Husna Mohd Aminudin, Fazilah Hassan, Kasuma Mohamed Nordin

Research outputs 2022 to 2026

Acral lentiginous melanoma (ALM) with pleural metastases is rare and under-recognised. We report an 86-year-old woman with progressive dyspnoea and pleuritic chest pain. 18 months ago, she was diagnosed with stage IIC ALM of the right heel, and was treated with wide local excision, but she declined adjuvant therapy. Imaging demonstrated a large left pleural effusion with diffuse pleural thickening, pulmonary mass, and hepatic metastases. Brownish pleural fluid, along with thoracoscopic identification of multiple pigmented nodules, led to a histologically confirmed diagnosis. Talc pleurodesis was performed for symptom control, and best supportive care was pursued. This case highlights the diagnostic …


The Indian Law Aunties, Torey Dolan Mar 2026

The Indian Law Aunties, Torey Dolan

UMKC Law Review

No abstract provided.


Resisting Overcompliance, Meera E. Deo Mar 2026

Resisting Overcompliance, Meera E. Deo

UMKC Law Review

No abstract provided.


Mentorship Practices And Perceptions Of Nursing Faculty At The Aga Khan University In Uganda: A Qualitative Study, Mary Namuguzi, Sarah Nakaziba, Shamim Namukasa, Carolyne Namukwaya, Dinah Kassaman, Arnold Mwanzu, Jackline Estomihi Kiwelu, Duncan Osuka, Nazahed Mkiramweni, Ahmed Sarki Mar 2026

Mentorship Practices And Perceptions Of Nursing Faculty At The Aga Khan University In Uganda: A Qualitative Study, Mary Namuguzi, Sarah Nakaziba, Shamim Namukasa, Carolyne Namukwaya, Dinah Kassaman, Arnold Mwanzu, Jackline Estomihi Kiwelu, Duncan Osuka, Nazahed Mkiramweni, Ahmed Sarki

School of Nursing & Midwifery, East Africa

Background Mentorship of new faculty helps to reduce the challenges associated with their new roles, as some lack knowledge of teaching pedagogies. This study assessed the mentorship experiences regarding practices and perceptions of new nursing and midwifery faculty at the Aga Khan University School of Nursing and Midwifery (SONAM) in Uganda.

Methodology This study used a phenomenological design. Data were collected in semistructured interviews with 11 participants, and data saturation was reached. Data were organized with NVivo 12 Pro and analyzed using framework analysis.

Findings The main themes that emerged were mentorship practices, perceptions about mentorship, and proposed mentorship guidelines. …


Synthesis And Structures Of Ru(Ii)-P-Cymene Sandwich Complexes With Electron-Withdrawing Cyclopentadienyl Ligands, Uttam R. Pokharel, Sean Parkin, John P. Selegue Mar 2026

Synthesis And Structures Of Ru(Ii)-P-Cymene Sandwich Complexes With Electron-Withdrawing Cyclopentadienyl Ligands, Uttam R. Pokharel, Sean Parkin, John P. Selegue

Chemistry Faculty Publications

A modular synthetic route has been developed to prepare a new series of cationic ruthenium(II) complexes with electron-withdrawing 1,2-diacylcyclopentadienyl ligands. The 2-acyl-6-hydroxyfulvenes were synthesized from cyclopentadienide and acyl chlorides and converted to Tl(I) cyclopentadienyl salts using Tl2SO4/KOH. Transmetalation with [Ru(η6-p-cymene)(μ-Cl)Cl]2 followed by PF6− metathesis gives the complexes [Ru{η5-1,2-C5H3(CO–R)2}(η6-p-cymene)][PF6] (R = t-Bu, p-Tol, p-ClC6H4, p-IC6H4) in moderate to high yields. The new compounds were characterized by NMR and IR spectroscopy; mass spectrometry …