Digital Commons Network^™

Model Unification: A Systematic Approach For The Cluster Expansion, Kolten Barfuss

Theses and Dissertations

A systematic approach for model unification of cluster expansion models is developed and demonstrated. The method builds on previous work with the Manifold Boundary Approximation Method (MBAM) to identify supremal models. The work is motivated by the exercise of unifying cluster expansion models – characterized by Π matrices – for two binary alloys that share one atomic species to form a model for the ternary alloy. The result is the Supremal Π Algorithm, a systematic unification algorithm that relies on an MBAM-informed understanding of models and on the singular value decomposition. The algorithm yields ΠΛ, a Π matrix for the …

Highly Skilled First-Generation Immigrant Kenyan Women’S Lived Experiences With Workplace Integration Strategies In California, Lily Quiette Otieno

Walden Dissertations and Doctoral Studies

Unlocking the potential of highly skilled first-generation immigrant women in the workplace is critical in an era of globalization and multiculturalism. The social problem is that organizations face challenges integrating highly skilled first-generation immigrant women into the U.S. workforce due to a limited understanding of effective workplace integration strategies. The purpose of this qualitative phenomenological study was to explore the lived experiences of highly skilled first-generation Kenyan women with workplace integration strategies in California. The study was grounded in Graen and Uhl-Bien’s leader-member exchange theory and Crenshaw’s intersectionality theory to understand how leadership relationships and intersecting identities shaped workplace experiences. …

Psychometric Properties Of A Newly Developed Self-Report Scale To Determine The Relationship Between Retained Primary Reflexes And Behavioral Signs And Symptoms In An Adult Population, Joan Marie Macmillan

Walden Dissertations and Doctoral Studies

Many adults suffer from mental health issues, often caused by retained primary reflexes. There are current gaps in the literature surrounding primary reflex assessment methods. The purpose of this quantitative psychometric study was to evaluate the psychometric properties of a new behavioral self-assessment scale used to identify retained primary reflexes from behavioral indicators, while also determining if statistically significant relationships exist among study variables. The theoretical foundation for this cross-sectional study was based on the neurodevelopmental and neurobehavioral work of Melillo, while conceptually benefiting from several neuroplasticity related frameworks, such as those developed by Ayres, Bach-y-Rita, and Masgutova. The self-report …

Early Childhood Educators’ Experiences Teaching Literacy Acquisition Skills, Dena Renee Crews

Walden Dissertations and Doctoral Studies

The problem investigated through this study was that early childhood educators struggle to help students with literacy acquisition skills in a Title 1 elementary school. The purpose of this qualitative study was to investigate early childhood educators’ experiences with the challenges of teaching literacy acquisition skills and their suggestions for improving resources and training for teaching literacy acquisition skills. The study was grounded in Clay’s emergent literacy theory and Bronfenbrenner’s ecological systems theory. For this basic qualitative design, semistructured interviews with 14 participants were conducted with the following themes emerging: Early childhood educators were challenged due to (a) students’ background …

Teacher Voices In Ethnic Studies: Bridging Policy And Practice Through Educator Insights In California, Isiah Peter Iniguez

LMU Theses and Dissertations

This study explores ethnic studies teachers’ perceptions of implementing ethnic studies as a required course in California. This study used both critical pedagogy (Freire , 1970) and pedagogical content knowledge (PCK; Shulman, 1986) as theoretical frameworks. Through interviews with thirteen ethnic studies teachers across California, this research uncovered the pedagogical demands, implementation challenges, and transformative potential of ethnic studies education. The findings illuminated a fundamental tension between ethnic studies’ community-centered nature and pressures toward standardization. Teachers emphasized that ethnic studies had to be rooted in community, describing powerful outcomes when the curriculum reflected students’ identities, local histories, and lived experiences. …

Revised Draft Final Butte Priority Soils Operable Unit (Bpsou) Unreclaimed (Ur) Sites New And Mahoney (Ur-23) Construction Completion Report (Ccr), Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Revised Draft Final Butte Priority Soils Operable Unit (Bpsou) Unreclaimed (Ur) Sites New And Mahoney (Ur-23) Construction Completion Report (Ccr), Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Histopathology Image Classification Using Machine Learning, Mohammed H. Alali

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Histopathology image classification is a critical component of cancer diagnosis. However, the gigapixel scale of Whole-Slide Images (WSIs) and the high variability in tissue staining and scanner quality across medical centers present significant computational challenges. This dissertation proposes a comprehensive machine learning framework to address these challenges, bridging the gap between theoretical models and practical clinical deployment.

First, to manage the massive dimensionality and noise inherent in WSIs, this research develops a robust feature extraction methodology. The pipeline implements a stringent tile filtering technique to eliminate physical artifacts and resolve severe class imbalances. It integrates ConvNeXt alongside an attention-based pooling …

Cohomological Support Varieties Along Ring Maps, Ryan Watson

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Inspired by Quillen’s geometric approach to study group cohomology, Avramov introduced the theory of support varieties to study finite modules over local complete intersection rings. Geometric properties of the variety encode important homological information, and this theory has been a useful tool in studying complete intersection rings leading to many advances in local commutative algebra. By the work of several authors, this theory has now been expanded to encompass any noetherian local ring. Notably, Pollitz developed the theory of cohomological support varieties over Koszul complexes and used them to answer a question of Dwyer, Greenlees, and Iyengar regarding the structure …

Development And Flight Of Stratospheric Missions For Hard X-Ray Polarimetry And Hard X-Ray Spectroscopy, Ephraim Gau

Arts & Sciences Graduate Student Theses and Dissertations

The recent launches of the {\it Imaging X-ray Polarimetry Explorer} ({\it IXPE}\,) and {\it XRISM} have provided significant advances to the realms of polarization and high-resolution spectroscopy in X-ray astrophysics. However, both of these satellite missions conduct measurements in the soft X-rays, below 10 keV. To obtain a complete picture of any astrophysical source, we must extend these capabilities to the hard X-rays, above 10 keV, as well. Thus, in my graduate work, I have directed my efforts in these two regimes: measuring the polarization of hard X-rays with {\it XL-Calibur}, and improving the energy resolution of hard X-ray telescopes …

Some Closure On The Relation Between Cfg And Peg, Nathan J. Bulloch

Theses and Dissertations

We work toward a practical, unified language formalism for structurally recursive languages by expressing the mathematical theories underlying context-free grammars with lookahead (CFGLA) in the Rocq theorem prover and leveraging CFGLA semantics to analyze interactions between between recursion and negative lookahead. We give examples of grammars with left-recursive negation cycles for the parsing expression grammar (PEG) variant due to Medeiros et al. and for the translation from PEG to CFGLA due to Miyazaki and Minamide. To study the interaction between left recursion and negative lookahead in a PEG context, we introduce FPEG, a left-recursive extension of PEG with Fitting semantics.

Computational And Experimental Analysis Of Oleanolic Acid As An Allosteric Activator Of Sirt1, Emrah Sariyer, Eda Dokumacioğlu, Hati̇ce İskender

Turkish Journal of Chemistry

Sirtuin 1 (SIRT1) is a member of the sirtuin protein family and the biological effects of SIRT1 encompass various areas such as the ageing process, metabolism regulation, and cellular stress response. SIRT1 activators are compounds that enhance the activity of SIRT1 enzyme. These activators can be natural or synthetic compounds and have the potential to provide health benefits by augmenting the biological effects of SIRT1. Oleanolic acid (OA) is a triterpenoid compound that has antiinflammatory, antioxidant, and glucose and lipid metabolism-regulating properties naturally found in many plants. The aim of the present study was to investigate the effect of OA …

Investigation Of The Enzyme-Inhibitory, Antibacterial, And Anticancer Properties Of Metal Phthalocyanines, Meryem Topal, Fevzi̇ Topal, Firat Yilmaz, Esra Bulut Atalay, Ümi̇t Muhammet Koçyi̇ği̇t, Emre Güzel

Turkish Journal of Chemistry

In this study, the enzyme inhibitory, antibacterial, and anticancer activities of a phthalonitrile derivative and its metal phthalocyanines (Pcs; indium, zinc, copper, cobalt, and manganese; 1–6) were investigated. The cobalt and manganese Pcs were synthesized for the first time in this study. The inhibitory activities of the symmetric Pcs, which were expected to interact with acetylcholinesterase (AChE) and butyrylcholinesterase (BChE) via their 4-(isopropylbenzyl)oxy substituents through host–guest interactions, were investigated. More selective inhibition of AChE than BChE was observed for these compounds. For AChE, CoPc was identified as the most potent inhibitor (IC50 = 14.81 nM), whereas for BChE, InPc was …

Nucleophilic Cyclization Of N-Propargylated Pyrazole-5-Carboxylates: Synthesis Of Pyrazolo[1,5-A]Pyrazin-4(5h)-One Derivatives, Meli̇k Firat Mengeş, Meltem Tan Uygun

Turkish Journal of Chemistry

Cyclization reactions are among the most important and widely used methods for synthesizing biologically active fused heterocyclic compounds. In the present study, pyrazolopyrazinone derivatives (10a–i) were synthesized from N-propargylated pyrazoles via nucleophilic cyclization with hydrazine hydrate under a nitrogen atmosphere. Nuclear magnetic resonance (NMR) spectral analyses confirmed that ring closure proceeded in a manner consistent with the formation of a six-membered pyrazinone moiety. In addition, the pyrazolotriazepinone derivative 15c was synthesized using an alternative approach. In this method, substitution with chloroacetone was first carried out, followed by ring closure with hydrazine hydrate, affording a seven-membered triazepinone system. Comparison of the …

Sensitive Stripping Voltammetric Determination Of An Anthracene–Isatin Schiff Base In Biological Samples, Gökçe Öztürk, İrem Gökgöz, Emi̇ne Arslan, Eli̇f Şi̇şman, İnci̇ Seli̇n Doğan, Di̇lek Kul, Fatma Ağin

Turkish Journal of Chemistry

​In the present study, the electrochemical behavior and quantitative determination of the Schiff base 3-[(anthracen-2-yl)imino]-5-nitro-1,3-dihydro-2H-indol-2-one (ANT) were investigated for the first time using voltammetric techniques at a glassy carbon electrode. The effects of solvent composition, pH, and scan rate on the redox behavior of ANT were systematically evaluated. The compound exhibited an irreversible oxidation process governed by adsorption-controlled kinetics. Quantitative analysis was conducted using differential pulse stripping voltammetry (AdS-DPV) and square-wave stripping voltammetry (AdS-SWV) under optimized conditions. Both methods exhibited linear responses over the concentration range of 0.2–8.0 μM, with limits of detection of 0.0366 μM and 0.0433 μM for …

Influence Of Precursor Synthesis Temperature And Hydrothermal Alkaline Medium On Agglomeration And Crystal Phase Of Barium Titanate Nanoparticles, Murat Özen

Turkish Journal of Chemistry

Phase‑pure, cube‑like barium titanate (BaTiO3) nanoparticles were synthesized via hydrothermal treatment of a single‑source barium-titanium peroxo-hydroxide precursor. Precursor solutions prepared at room temperature, 0 °C, and –10 °C with various storage times exhibited Ba/Ti molar ratios ranging from 0.66 to 1.05 as determined by X-ray fluorescence. Cooling the precursor solution to –10 °C effectively suppressed the polymerization of Ti-O-Ti, yielding near‑ideal stoichiometry and finer precursor particles. Subsequent hydrothermal processing in NH4OH, KOH, and NaOH (0.5–10 M, 100–200 °C) revealed the strong dependence of agglomeration and morphology on the alkaline medium. While NH4OH and KOH resulted in severe agglomeration and the …

Templating Effect Of Neutral Dithiane Ligands On The Self-Assembly Of Cationic Au(I)-Phosphine Units, Farzane Osanlou, Abdollah Neshat, Mohammad Reza Yousefshahi, Vaclav Eigner, Michal Dusek, Shahram Seidi

Turkish Journal of Chemistry

The interactions between the dinuclear Au(I) precursor (dppm)Au2Cl2 and neutral sulfur-containing dithianes (specifically 1,3- and 1,4-dithiane) were examined in the presence of NH₄PF₆. Although these sulfur-based ligands were initially employed to facilitate the formation of mixed phosphine/sulfur Au(I) complexes, single-crystal X-ray diffraction analysis revealed the unexpected generation of multinuclear Au(I) assemblies exclusively coordinated by phosphine ligands. When 1,3-dithiane was present, a trinuclear Au(I) complex was isolated, characterized by a central four-coordinate Au(I) center exhibiting a distorted see-saw geometry, flanked by two terminal Au(I) centers with T-shaped coordination environments. Importantly, the dithiane ligand did not coordinate directly to the gold centers …

Vanadium’S Journey From Essential Trace Metal To Emerging Environmental Pollutant In The Anthropocene Era, Tanu Arora, Nivedita Agnihotri, Mohammad Azam

Turkish Journal of Chemistry

Vanadium, previously considered a minor trace element, is gaining global environmental attention due to its expanding applications in metallurgy, energy storage, catalysis, and agriculture. With this rise in its industrial and technological uses, however, anthropogenic emissions of vanadium into the atmosphere, soils, and water bodies have also escalated. Unlike many heavy metals, vanadium exhibits complex redox behavior, primarily existing as V(IV) and V(V) species, which significantly impacts its environmental mobility, bioavailability, and toxicity. Vanadium exhibits complex behavior that necessitates an integrated research approach to better understand its various roles in scientific fields. This review summarizes the current knowledge on vanadium’s …

The Impact Paradox: Mixed-Methods Evaluation Of National Institute Of Health And Care Research Funding For Intellectual Disability Research In The Uk, Rohit Shankar, Richard Laugharne, Sarah Lennard, Samuel Tromans, Nathan Goddard, Madeline Dale, Ruth Bishop, Nathan Johnson, Maxine Hough

Peninsula Medical School

BackgroundPeople with intellectual disability experience substantialhealth inequities, including higher multimorbidity, increasedhealthcare utilisation and markedly reduced life expectancy.High-quality research is essential to address these disparities.The National Institute for Health and Care Research (NIHR)funded Research Delivery Network provides the infrastructure/expertise/support needed to deliver NIHR-funded studies, andsupports studies funded by a non-commercial/industry partner. However, the effectiveness of NIHR-funded studies versusthose supported in driving impactful intellectual disabilityresearch remains unclear.AimsTo evaluate and compare the outcomes of NIHR-funded andsupported intellectual disability research.MethodAll NIHR studies (funded/supported) relating to intellectualdisability (2010–2020) were identified through systematicregister searches. Primary outcomes included publicationrates and impact on local, national and international clinicalguidelines. …

Enhancing Lane Detection In Autonomous Vehicles Using Data Augmentation For Adverse Environmental Conditions, Rutvikkumar Dave

Electronic Theses and Dissertations 2020 - Present

To make sure that self-driving and connected automobile technologies are safe and work well, it’s really important that they can correctly identify lanes. But lane detection Algorithms typically have a hard time working well when the weather is bad, such when it rains, fogs, or goes too fast. The circumstances cause visual distortions that make existing computer vision systems less reliable, which makes it harder requires autonomous navigation systems to work well. This paper introduces a comprehensive lane detection system that integrates synthetic Weather-informed data augmentation combined with a Weather-aware Temporal Lane Detection Network (WTLDNet) to make it easier for …

Holding The Line: The Existential Threat To Dei Language And Values, Terrance Fitzsimmons, Larry Martinez, Jennifer Bishop, Darryl Rice, Florence Villesèche

Psychology Faculty Publications and Presentations

Purpose – This article critically analyses and critiques the operationalisation of the Trump administration’s anti- DEI policies on Diversity, Equity and Inclusion (DEI) initiatives in the United States of America and beyond. It specifically examines the attempt to silence DEI scholarship and practice, assessing the broader implications for social justice and global progress towards equity. The article also positions these attacks as an existential threat to DEI scholarship, scholars and practitioners, with the potential to reverse progress made since the adoption of the Universal Declaration of Human Rights in 1948. The article serves as a call to action, urging the …

Identifying Skill Gaps And Upskilling Priorities For C-Level Executives Using The Analytic Hierarchy Process (Ahp) Analysis, Mohamed Riyazhkhan, Mohsin Aziz, Krishna Murthy, Abdul Azeez K M, George Anthony Fernando

Journal of Global Management Research

C-level executives, or chief-level executives, play a significant role in corporate development, and their roles and responsibilities are essential for sustaining organizational effectiveness in an increasingly competitive business environment. They also constitute a fundamental component of organizational management systems (Julie & Emory, 2006). In this research, data were collected exclusively from C-level or C-suite executives (CEO, CFO, COO, and CHRO) from leading corporations in Oman and India. This study investigates three representative cases related to managerial functions across various corporate organizations. The first case examines the job descriptions associated with C-level executives, the second case explores the identification of skill …

Create @ State 2026, Arkansas State University - Jonesboro

Create@State

Proceedings for 2026

Music Enhances Theta Brainwave Activity Regardless Of Tuning Frequency, Robert Somerville, Davis Raz, Jettson Yarborough, Luc-Shalom Kouame

Liberty University Research Week

No abstract provided.

Instructors’ Lived Experiences Of Using Authentic Assessments In College Calculus Courses Across The United States: A Phenomenological Study, Christy Kains

Liberty University Research Week

The purpose of this transcendental phenomenological study was to describe the lived experiences of instructors with authentic assessments in college calculus courses across the United States. The theory guiding this study was Astin’s student involvement theory, which provided a framework to study the involvement of students in higher education. The central research question for this study was: What are the lived experiences of instructors who utilize authentic assessments in college calculus courses across the United States? This study used a qualitative design following the transcendental phenomenological approach of Moustakas. The sample included 12 instructors from two-year and four-year colleges in …

Functional Genomics Of Streptococcus Mutans: Identifying Critical Genes For Oral Biofilm Formation, Cara E. Pirani

Create@State

Streptococcus mutans (S. mutans) is a pathogen found in the human oral cavity that plays a central role in the development of dental caries, or tooth decay. This pathogen thrives on the sugars consumed in the diet, contributing to the breakdown of tooth enamel, especially in the presence of poor oral hygiene. S. mutans produces a glycosyltransferase enzyme that converts sucrose into the polysaccharide glucan. Glucan allows the pathogen to attach to the enamel of the tooth and begin metabolizing the sugar on the teeth, resulting in lactic acid. The acid under the biofilm layer lowers the pH of the …

Assessment Of Total Cellular Protein Following Fatty Acid Treatment Using The Bca Assay, Carli B. Maguire

Create@State

Fatty acids can influence cellular metabolism and protein homeostasis, potentially altering total protein content within cell samples. Accurate quantification of total protein concentration is essential for standardization for further biochemical assays and ensuring reproducibility. In this study, adherent mammalian cells were treated with a defined fatty acid preparation under controlled culture conditions. Following treatment, whole-cell lysates were collected and total protein concentration was determined using the bicinchoninic acid (BCA) assay. The BCA assay is a colorimetric method based on the reduction of Cu²⁺ to Cu¹⁺ by peptide bonds under basic conditions, followed by formation of a purple-colored complex between bicinchoninic …

Robust Thermodynamic Analysis Of Flexible Protein-Ligand Binding Using Statistical Mechanics, Mitchell Dulaney

Create@State

Understanding how proteins bind small molecules is essential for accurate computational modeling of biological systems. However, calculating binding free energy (delta G), enthalpy (delta H), and entropy (delta S) becomes unreliable when proteins are flexible, and ligands are between multiple binding positions. This motion causes traditional computational methods to produce inconsistent thermodynamic values.

A computational workflow was implemented that included docking to predict likely binding positions, molecular dynamics simulations to sample how the protein and ligand move over time, and statistical mechanics analysis to calculate thermodynamic quantities. A new theoretical framework was developed and implemented in a custom program to …

Ma(1) Or White Noise?, Orithea Regn, Ferebee Tunno

Create@State

This project provides an over of testing an MA(1) process confidence interval while keeping the margin of error to a minimum, even for small sample sizes.

Comparison Of Levels Of Bmi, Stress, And Depression Of Women During The Prenatal Period Relative To Their Activity Levels, Kalayna King

Create@State

This study aimed to analyze the relationships between activity levels, Body Mass Index (BMI), stress levels, and depression symptoms in obese pregnant women in Arkansas. Two separate exercise intervention studies were combined in this analysis to ultimately give a sample size of 293 pregnant women who were randomized into standard of care group (control) and an exercise group (experimental) (n = 115 and n = 178, respectively). Women in the control groups were instructed to independently continue to follow the physical activity guidelines recommended by their gynecologist, whereas the experimental groups participated in a combination of aerobic and resistance exercise …