Digital Commons Network^™

Construction Of Hyperbranched Imprinted Nanomaterials For Selective Adsorption Of Cadmium (Ii), Sheng Nan Hu, Xinyu Zhang, Ming Guo, Shengchun Wu, Wenjun Lu

Turkish Journal of Chemistry

A hyperbranched ion-imprinted polymer (IIP) material containing multiple selective adsorption sites was synthesized using halloysite nanotubes, methyl acrylate, and ethylenediamine in the presence of a template ion [i.e. Cd (II) heavy metal]. The successful preparation of the Cd-IIP composition was confirmed by FT-IR, XRD, TEM, TGA, and elemental analysis. The polymers exhibited good adsorption of Cd (II) with a maximum adsorption capacity of 64.37 mg·g–1. The imprinting factor (α) for Cd (II) was 2.62 and the selection factor (β) was 1.78, indicating a specific adsorption of Cd (II) ion. The selection coefficients of Cd-IIP for Cd (II)/Pb (II), Cd (II)/Cu …

Transdermal Delivery System To Release Phthalocyanine Photosensitizers For The Potential Treatment Of Skin Cancer With Pdt, Meryem Çamur Demi̇r, Fatma Kurşun Baysak, Caner Yahya Boyar, Ali̇han Toksoy, Fati̇h Algi

Turkish Journal of Chemistry

This research aims to examine the transdermal release of water-soluble indium and zinc metallo phthalocyanine (InPc and ZnPc) compounds from the poly(vinyl alcohol) (PVA) membrane and the cytotoxicity effect of these Pcs on normal mouse fibroblasts (L929 fibroblast) and human melanoma (SK-MEL-30) cells. For this purpose, the effects of temperature, pH, drug concentration and membrane thickness on transdermal release were investigated in order to obtain the optimum transdermal release profile by preparing PVA membranes with different thicknesses and crosslinked by heat treatment. Optimum drug release was found to be 85.36% using 6 µm thick PVA membrane at 37 ± 0.5 …

Graphene Aerogels: Part 1 - Derived From Graphene Oxide And Thermally Reduced Graphene Oxide Via Supercritical Carbon Dioxide Drying, Meryem Samanci, Ayşe Bayrakçeken

Turkish Journal of Chemistry

Graphene aerogels have become promising materials in many areas of industry, especially in energy applications due to their superior physical and electrochemical properties. Generally, graphene oxide (GO)-derived aerogels (A) are synthesized by using the hydrothermal method. In this study, both GO and reduced graphene oxide (RGO)-derived aerogels were synthesized by using the sol-gel method coupled with the supercritical carbon dioxide (SCCO2) drying process. It aims to examine the changes in the structure of the final aerogel by changing the amount (0.25–0.5–1% wt.) and type of graphene-based precursor materials used in the synthesis. Physical characterizations of graphene aerogels were conducted using …

Graphene Aerogels: Part 2 - Derived From Commercial Graphene And Chemically Reduced Graphene Oxide Via Supercritical Carbon Dioxide Drying, Meryem Samanci, Ayşe Bayrakçeken

Turkish Journal of Chemistry

Graphene aerogels (GAs), the most important class of carbonaceous aerogels, have attracted attention of many researchers due to their superior physical and chemical properties. In this study, commercial graphene (GR) and chemically reduced graphene oxide (RGO) were used as graphene-based precursor materials, unlike graphene oxide (GO), which is widely used in the literature in GA synthesis. GAs were synthesized using the sol-gel technique and dried with supercritical carbon dioxide (SCCO2). In addition, graphene-based materials were used in different ratios and their distribution in the aerogel matrix and its effect on surface properties were investigated. In addition, the synthesized GAs were …

Sensitive And Accurate Determination Of Oil-Soluble And Water-Soluble Organosulfur Compounds In Garlic Matrix Using Reversed Phase-High Performance Liquid Chromatography, Ümmügülsüm Polat Korkunç, Buse Tuğba Zaman, Sezgi̇n Bakirdere, Emine Karakuş

Turkish Journal of Chemistry

Garlic is in the family Liliaceae and has many different constituents such as organic sulfur compounds, amino acids, carbohydrates, minerals, and vitamins. In this work, a simple, sensitive, and accurate analytical method was developed for the determination of selected organosulfur compounds (OSCs) in garlic bulbs using reversed phase-high performance liquid chromatography (RP-HPLC). Oil-soluble and water-soluble OSCs were extracted from the garlic samples via acetonitrile and deionized water, respectively. The OSCs were separated on a Phenomenex C18 (250 mm, 4 mm, 5mm) column and the monitoring was performed with a UV detector at 220 nm. An isocratic mobile phase comprising of …

Berkely Pit Repository Cost Comparison, Josh Bryson

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Block Copolymers And Chirality: Interplay Between Conformations And Structures, Natalie Buchanan

Theses

Block copolymers can exhibit chirality at three different length scales – molecular chirality at the residue scale, conformational chirality at the molecular scale, and structural chirality at the mesoscale from the self-assembly of thousands of molecules. Unique morphologies have been formed due to chirality transfer, a phenomenon where chirality at smaller length scales imparts chirality to larger length scales. However, chirality does not always transfer, with chiral blocks existing in an achiral phase due to chiral frustration. The thermodynamics of the effects of chirality on block copolymer self-assembly is not well understood. This work demonstrates that coarse-grained models can effectively …

Designing For Deployable, Secure, And Generic Machine Learning Systems, Li-Yun Wang

Dissertations and Theses

Machine learning systems have catalyzed numerous image-centric applications owing to the significant achievements of machine learning algorithms and models. While these systems have showcased the efficacy of machine learning models, certain challenges persist, such as machine learning system design and security vulnerabilities inherent in deep neural networks. Moreover, the deployment of deep neural network models remains a significant hurdle. This dissertation introduces a multimedia prototyping framework tailored for visual analytical applications, improving the reusability of video analysis software tools with minimal performance overhead. Furthermore, we present novel image-processing techniques designed to bolster the robustness of deep neural networks and propose …

Lmcrot: An Enhanced Protein Crotonylation Site Predictor By Leveraging An Interpretable Window-Level Embedding From A Transformer-Based Protein Language Model, Pawel Pratyush, Soufia Bahmani, Suresh Pokharel, Hamid D. Ismail, Dukka Bahadur

Michigan Tech Publications

MOTIVATION: Recent advancements in natural language processing have highlighted the effectiveness of global contextualized representations from Protein Language Models (pLMs) in numerous downstream tasks. Nonetheless, strategies to encode the site-of-interest leveraging pLMs for per-residue prediction tasks, such as crotonylation (Kcr) prediction, remain largely uncharted. RESULTS: Herein, we adopt a range of approaches for utilizing pLMs by experimenting with different input sequence types (full-length protein sequence versus window sequence), assessing the implications of utilizing per-residue embedding of the site-of-interest as well as embeddings of window residues centered around it. Building upon these insights, we developed a novel residual ConvBiLSTM network designed …

Developing An Aerosol Database For Understanding Aerosols' Effects On Atmospheric Processes And For Hel Research And Applications, Therese Michelle Parkes

Honors Capstone Projects and Theses

No abstract provided.

A Climatology Of North American Monsoon Precipitation Over Arizona From Mrms Data, Greta Graeler, Mark Sinclair, Curtis N. James

Publications

The North American Monsoon (NAM) is a seasonal shift in pressure and wind which accounts for over half of the southwest’s annual precipitation. North-central Arizona has variable terrain which influences the location and intensity of convective storms. Severe weather such as strong winds, lightning, and hail can cause loss of life, property, and fires. High spatial and temporal resolution data along with reanalysis data is used to identify convective cells and their motion for the 2015 to 2022 NAM seasons. The heaviest precipitation in north-central Arizona is found over the Bradshaw Mountains and is most active in July and August. …

Statistical Genetic Approaches To Investigate Genotype-By-Environment Interaction: Review And Novel Extension Of Models, Vincent P. Diego, Eron G. Manusov, Marcio Almeida, Sandra Laston, David Ortiz, John Blangero, Sarah Williams-Blangero

School of Medicine Publications

Statistical genetic models of genotype-by-environment (G×E) interaction can be divided into two general classes, one on G×E interaction in response to dichotomous environments (e.g., sex, disease-affection status, or presence/absence of an exposure) and the other in response to continuous environments (e.g., physical activity, nutritional measurements, or continuous socioeconomic measures). Here we develop a novel model to jointly account for dichotomous and continuous environments. We develop the model in terms of a joint genotype-by-sex (for the dichotomous environment) and genotype-by-social determinants of health (SDoH; for the continuous environment). Using this model, we show how a depression variable, as measured by the …

Combining Acoustic Telemetry With Archival Tagging To Investigate The Spatial Dynamic Of The Understudied Pollack, Pollachius Pollachius, Marine Gonse, Martial Laurans, Justus Magin, Tina Odaka, Jean Marc Delouis, Stéphane Martin, François Garren, Coline Lazard, Mickael Drogou, Thomas Stamp, Peter Davies, Alice Hall, Emma Sheehan, Mathieu Woillez

School of Biological and Marine Sciences

Combining fish tracking methods is a promising way of leveraging the strengths of each approach while mitigating their individual weaknesses. Acoustic telemetry provides presence information as the fish move within receiver range, eliminating the need for tag recovery. Archival tags, on the other hand, record environmental variables on tag retrieval, enabling continuous path reconstruction of a fish beyond coastal regions. This study capitalizes on the combination of both methods for geolocating pollack, Pollachius pollachius, an understudied species of the northeast Atlantic, where declining stocks are raising concern. Essential knowledge of population structure and connectivity between essential habitats is critically lacking …

Table Of Contents, The Editors

Coal Geology & Exploration

No abstract provided.

Response Mechanism Characteristics Of Mining-Induced Fault Activation, Sun Wenbin, Hao Jianbang, Dai Xianzheng, Kong Lingjun

Coal Geology & Exploration

In the process of coal mining, mining-induced stress perturbation is a key factor leading to fault activation, which is a primary challenge faced by safe coal mining. Fault activation is prone to induce geological disasters such as rock bursts and floor water inrushes of coal mines. Furthermore, it poses a serious threat to mining safety. Using the Flac^3D software for numerical simulations and similar material simulation experiments, this study established a model for faults’ stress-displacement responses under coal mining to analyze the mechanisms behind the evolution of fault structure zones in the process of coal mining. Key findings are …

Laws Of Changes In The Energy Of Gas Hydrate-Bearing Coals Under Different Confining Pressures And Saturations, Zhu Wei, Gao Xia, Zhang Baoyong, Wu Qiang

Coal Geology & Exploration

Gas hydration for the solidification of coal seams susceptible to outbursts is a novel technology used to prevent coal and gas outbursts by reducing gas pressure and enhancing coal strength. However, an unclear understanding of the failure characteristics and the energy dissipation law of gas hydrate-bearing coals under different confining pressures and saturations leads to the lack of a theoretical basis for the prevention of dynamic disasters such as field coal and gas outbursts in deep mines. Based on the deviatoric stress-strain curves obtained using triaxial compression tests, this study calculated and analyzed the laws of changes in energy of …

Fracture Propagation Mechanism In Directional Perforation And Hydraulic Fracturing Of Coal Seam Horizontal Wells, Pang Tao, Jiang Zaibing, Hui Jiangtao, Jia Bingyi

Coal Geology & Exploration

Horizontal well perforation and fracturing in complex coal-bearing strata are key to increasing coal seam permeability and enhancing gas extraction efficiency, with the formation structure and perforation location determining fracture propagation. Considering the characteristics of formation structure and perforation locations, a fracturing geological model is established. Based on the finite element method, a numerical model is constructed to study the effects of perforation location, formation conditions, and the difference between vertical stress and horizontal stress on fracture perforation. Engineering verification is conducted, and construction suggestions are proposed. Key findings are as follows: There are three scenarios for the perforation locations: …

An Intelligent Water Source Discrimination Method For Water Inrushes From Coal Seam Roofs In The Inner Mongolia-Shaanxi Border Region, Wang Hao, Sun Junqing, Zeng Yifan, Shang Hongbo, Wang Tiantian, Qiao Wei

Coal Geology & Exploration

Water hazard on the coal seam proof induced by high-intensity coal mining are increasingly prominent in the Inner Mongolia-Shaanxi border region. The effective, accurate water-source discrimination of the water inrushes is the key to water hazard prevention. This study investigated three typical mines in the Inner Mongolia-Shaanxi border region. To this end, principal component analysis (PCA) was employed to extract principal components from 80 groups of groundwater samples. Then, with inorganic indicators K⁺+Na⁺, Ca²⁺, Mg²⁺, Cl⁻, SO₄ ²⁻, HCO₃ ⁻ and TDS and organic indicators UV_{254 …}

Sulphate Contamination In An Abandoned Coal Mine In Light Of Mining Effects, Qi Yueming, Zhou Pei, Zhou Lai, Jiang Dan, Yang Yuqing, Liu Yanzhuo

Coal Geology & Exploration

Abandoned high-sulfur coal mines will become deeply buried acid-producing contamination sites, posing hazards to adjacent aquifers and surrounding environments. Furthermore, mining effects and the complex spatial distribution of abandoned mines complicate the assessment of the contamination processes and degrees in adjacent aquifers. Focusing on a certain abandoned coal mine, this study examined the migration characteristics of SO₄ ²⁻ pollution in acid mine drainage using numerical simulations by taking sulfate (SO₄ ²⁻) as the characteristic contaminant and considering the effects of the fractures formed by the mining of multiple coal seams on the aquifer structure. Furthermore, it analyzed …

Three-Dimensional Forward Modeling Using The Transient Electromagnetic Method Under Complex Terrains And The Analysis Of Terrain Effects, Qu Shaobo, Zhu Jiao, Jiang Zhihai, Li Maofei, He Zhilong

Coal Geology & Exploration

The ground-based transient electromagnetic method (TEM), with unique advantages, has been extensively applied for hydrogeological exploration in coal mines. However, in field exploration, complex terrains tend to cause variations in geometric shapes of transmitting sources and deviations in signals received, reducing exploration accuracy. Hence, by integrating theoretical analysis and numerical simulations with the analysis of actual terrain data, this study systematically investigated the response characteristics of electrical- and magnetic-source TEM fields under complex terrains. Using the vector finite-element electromagnetic forward modeling technique based on second-order backward Euler discretization, this study delved into the laws of influence of peak and valley …

Exploring The Detection Performance Of Different Array Configurations For Multi-Electrode Resistivity Method Tomography Using A 2.5d Finite Element Method, Zhao Rongchun, Lyu Yuzeng, Zhang Zhi, Wei Liuye, Pan Hongxu

Coal Geology & Exploration

Multi-electrode resistivity method is equipped with various electrode array configurations. Due to their different electrode arrangements, various electrode array configurations tend to exhibit significantly varying detection effects under different survey environments. Hence, to achieve satisfactory detection effects using high-resolution electrical resistivity tomography, it is necessary to explore the strategy for choosing appropriate array configurations targeting different objects in practical work. Given the high applicability of the method, its forward and inversion calculations remain a critical task. Based on the differential equations to be satisfied by the point source potential in a three-dimensional structure, this study derived the variational problem to …

Research On Path Planning Methods For Underground Roadheader Robots, Zhang Xuhui, Zheng Xili, Yang Wenjuan, Li Yuyang, Ma Bing, Dong Zheng, Chen Xin

Coal Geology & Exploration

In order to solve the problems of difficulty and low efficiency in the movement of robotic roadheaders under conditions of non-full-section roadways in coal mines, the characteristics of unstructured environments in coal mines and the motion characteristics of robotic roadheaders were analyzed, and a path planning method for robotic roadheaders based on deep reinforcement learning was proposed. The tunnel environment was constructed in real time using depth cameras, a virtual model for detecting roadheader-tunnel collisions was established, collision detection was performed in a virtual environment using the hierarchical bounding box method, and an obstacle avoidance strategy under the restrictions of …

Intelligent Identification Method For Overburden Three Zones Of A Goaf, Li Jianwen, Zhao Wen, Wu Zhenkun, Xu Xiaobing, Wang Qingtao, Duan Longchen

Coal Geology & Exploration

In this paper, an intelligent identification method was proposed to ascertain overlying strata failure types and fracture development in the overlying strata of a goaf, and identify three zones (sagging zone, fractured zone and caving zone) quickly and accurately. This method is expected to be a basis in later development of goaf treatment plans. A coal mine goaf in Shandong Province was introduced for case study, where the Bayesian Online Changepoint Detection (BOCD) algorithm was employed to analyze the changes and response characteristics of the drilling fluid loss and drilling rate over the drilling process at the boundaries of three …

Edge Detection Of Low Illumination Image In Cutting Unit Of Shearer, Jia Pengtao, Jin Luwei, Wang Bin, Guo Fengjing, Li Na

Coal Geology & Exploration

In this paper, a fractional differentiation-based edge detection algorithm named Lif is proposed to address the edge detection problems of missing edge and fuzzy details in the cutting unit of shearers working in low-light underground environments. First, the initial fractional mask operator was built using a larger detection template according to the Grünwald-Letnikov definition of the fractional derivative. Then, the weight coefficients at various positions of the mask operator were determined according to the theory of Pascal’s triangle, and the mask operator was extended to four different directions. Finally, the mask operator was convolved with the image, and the local …

Exploring Dynamic Parameters And Tooth Structure Of Self-Propelled Borehole Repairing Drill Bits, Liu Yong, Li Yang, Wei Jianping, Yuan Yongwang, Dai Shuo, Li Linyu

Coal Geology & Exploration

Self-propelled borehole repairing drill bits provide an effective technique for repairing long boreholes that have failed. In order to further improve the borehole repair speed and gas drainage efficiency, based on the theory of jet recoil, the relationship between the jet recoil force and nozzle parameters was analyzed, and a theoretical model was established for rotational mechanics of self-propelled borehole repairing drill bits. Subsequently, the coal-breaking processes of drill bits with different tooth structures were simulated using LS-DYNA, the failure modes in coal mass broken by cutting teeth and the rules of variation in the volume of coal broken by …

Confronting Cosmetic Carcinogens: A Proposal Regarding The Dangers Of Talcum Powder, Rachael Howell

Helm's School of Government Conference - 2021-2024

The Federal Government needs to stop the import, export, mining, and distribution of talcum powder in the United States. This is an issue that affects all Americans, especially active-duty military members.

Since 2013, there have been over 38,000 lawsuits against Johnson & Johnson, which allege that their talcum-based baby powder caused cancer. The plaintiffs in the very first talc case in the U.S. have died. All four of the plaintiffs from a 2019 suit have died. Yet, the 2019 case has been reversed and remanded. The FDA has redacted the names of scientist(s) that conduct “safety tests” on talc samples. …

2024 Acssc Program, Acssc Planning Commitee

Annual Celebration for Student Scholarship and Creativity

No abstract provided.

Are Students Actually Learning What You Think They Are? An Exploration Into The Educational Outcomes Of Course Based Undergraduate Research Labs, Matilda Dumaine, Jacob Saadoun

Biology Presentations

It is important to understand whether students are acquiring intended educational objectives. A course-based undergraduate research experience (CURE) lab seeks to blend the logistical ease and accessibility of college courses with the educational benefits of research experiences. By employing inquiry-based teaching methods, CURE labs enable students to collaborate in a group setting under the guidance of a faculty member, engaging in hands-on research. This project studies how educational outcomes of CURE labs can be measured. CURE labs may improve anything from technical lab skills, to scientific literacy, to persistence in science. These short-, middle-, and long-term goals may be measured …

2024 Great Day Program, State University Of New York At Geneseo

GREAT Day Programs

SUNY Geneseo’s Eighteenth Annual GREAT Day. Geneseo Recognizing Excellence, Achievement & Talent Day is a college-wide symposium celebrating the creative and scholarly endeavors of our students.

Mapping Star Formation Histories In Nearby Galaxies To Source Lyman Continuum Photon Escape, Katie Kudla '24

Engineering & Physics Student Scholarship

Katie Kudla ’24, Physics major
Faculty Mentor: Dr. Joseph Ribaudo, Engineering and Physics