Digital Commons Network^™

Ultrasound Assisted One-Pot Synthesis Of Benzo-Fused Indole-4, 9-Dinones From 1,4-Naphthoquinone And Α-Aminoacetals, Quang H. Luu, Jorge D. Guerra, Cecilio M. Castañeda, Manuel A. Martinez, Jong Saunders, Benjamin A. Garcia, Brenda V. Gonzales, Anushritha R. Aidunuthula, Shizue Mito

School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry)

A one-pot synthesis of benzo[f]indole-4,9-diones from 1,4-naphthoquinone with α-aminoacetals has been developed. This method provides a straightforward synthesis of benzo[f]indole-4,9-diones via intramolecular nucleophilic attack of aminoquinones to aldehydes under mild reaction conditions. The detailed mechanism was also investigated.

Alluvial Sedimentation Associated With Logging In Low Gradient Watersheds In Desoto National Forest, Mississippi, Andrew W. Simmons

Master's Theses

Forestry and related businesses are an important factor of Mississippi’s economy, contributing between $11 and $14 billion annually (Mississippi Forestry Commission, 2006). The timber industry is not only important in Mississippi but is an important sector of the economy throughout the Gulf Coast region. While providing positive economic benefits to the region, the forestry industry can also negatively affect soil properties, hillslope stability, and increase sedimentation rates in local streams and rivers. The aim of this research is to determine if forestry removal causes an increase of soil erosion and how it affects floodplain sedimentation in the low gradient watershed …

The Scripture Of Helices, Jessica M. Ramer

Master's Theses

This thesis comprises poems written during my two years of study for the Master of Arts Degree in English with a creative writing emphasis. The majority of the poems are written in either a received or contemporary form, although a substantial minority are written in free verse. Many of the poems deal with extreme circumstances such as combat and imprisonment. Others address family stresses due to birth, death, remarriage, and clashes of values. Some poems have a religious emphasis while others are firmly rooted in the natural world. All, however, are explorations of human nature.

Fire And Fuels: Vegetation Change Over Time In The Zuni Mountains, New Mexico, Luke Wylie

Master's Theses

The Zuni Mountains are a region that has been dramatically changed by human interference. Anthropogenically, fire suppression practices have allowed a buildup of fuels and caused a change in the fire-adapted ponderosa pine ecosystem such that the new ecosystem now incorporates many fire-intolerant species. As a result, the low-severity fires that the ecosystem once depended on to regenerate the forest are much reduced, and these low-severity fires are now replaced by crown-level infernos that threaten the forest and nearby towns. In order to combat these effects, land managers are implementing fuel reduction practices and are striving to better understand the …

Expander Graphs And Coding Theory, Michael C. Dowling Jr.

All Dissertations

Expander graphs are highly connected sparse graphs which lie at the interface of many different fields of study. For example, they play important roles in prime sieves, cryptography, compressive sensing, metric embedding, and coding theory to name a few. This thesis focuses on the connections between sparse graphs and coding theory. It is a major challenge to explicitly construct sparse graphs with good expansion properties, for example Ramanujan graphs. Nevertheless, explicit constructions do exist, and in this thesis, we survey many of these constructions up to this point including a new construction which slightly improves on an earlier edge expansion …

Exploiting Stiffness Nonlinearities To Improve The Performance Of Galloping Flow Energy Harvesters, Ali H. Alhadidi

All Dissertations

Fluid-structure coupling mechanisms such as galloping and wake galloping have recently emerged as effective methods to develop scalable flow energy harvesters (FEHs) that can be used to power remote sensors and sensor networks. The oper-ation concept of these devices is based on coupling the pressure forces culminating from the motion of the fluid past a mechanical oscillator to its natural modes of vibration. As a result, the mechanical oscillator undergoes large-amplitude motions that can be transformed into electricity by utilizing an electromechanical transduc-tion mechanism, which is generally piezoelectric or electromagnetic in nature. Due to their scalability and design simplicity, FEHs …

Experimental Assessment Of Mouse Sociability Using An Automated Image Processing Approach, Frency Varghese, Jessica A. Burket, Andrew D. Benson, Stephen I. Deutsch, Christian W. Zemlin

Electrical & Computer Engineering Faculty Publications

Mouse is the preferred model organism for testing drugs designed to increase sociability. We present a method to quantify mouse sociability in which the test mouse is placed in a standardized apparatus and relevant behaviors are assessed in three different sessions (called session I, II, and III). The apparatus has three compartments (see Figure 1), the left and right compartments contain an inverted cup which can house a mouse (called “stimulus mouse”). In session I, the test mouse is placed in the cage and its mobility is characterized by the number of transitions made between compartments. In session II, a …

Early Filing And Functional Claiming, Paul Gugliuzza

Faculty Scholarship

A major problem in the patent system is that many patents claim far more than the patentee actually invented. In his perceptive article, Ready for Patenting, Mark Lemley argues that this overclaiming is caused in part by legal doctrines that encourage inventors to file a patent application as early as possible, often before — or even instead of — building their invention. Patents issued from early-filed applications, Lemley argues, tend to be overly broad because the applicant does not yet know how the invention actually works.

This response essay, part of the Boston University Law Review’s symposium on Notice Failure …

Patent Uncertainty: Toward A Framework With Applications, Keith N. Hylton

Faculty Scholarship

There are three essential sources of uncertainty in the patent system: perceived uncertainty due to selective sampling (“statistical artefact uncertainty”), inherent uncertainty, and strategic uncertainty. It is only the strategic uncertainty source that should be of concern to reformers. With respect to this source, uncertainty in the patent system is largely a function of two variables: the degree of inherent abstraction associated with the patent, and the degree to which the patent provides notice of its scope. The maximal degree of uncertainty is observed in the category of abstract patents with poor notice, a category dominated today by software patents. …

Investigation Of How Hydrogen Bonding Affects The Enantiomeric Excess Of Pig Liver Esterase Promoted Hydrolysis Of Pro-Chiral Substrates, Jacob E. Pruett

Honors Theses

Pig Liver Esterase is a cost effective enzyme for ester hydrolysis. In our group, it is vital for creating chiral molecules for the synthesis of unnatural amino acids of potential biological importance. It has been previously found that the enantiomeric excess (%ee) of the PLE hydrolysis reaction increases drastically with the addition of co-solvents that are able to both accept and donate hydrogen bonds. This research endeavors to see if substrates of enhanced hydrogen bonding ability also increase the stereoselectivity of PLE hydrolyses. Diester malonate was covalently linked with a furan ring in both the third and second position from …

A Chemical Sensor For Cyanide, Rachel E. Lambert

Honors Theses

The cyanide ion and its gaseous form, hydrogen cyanide, are extremely toxic. Cyanide impairs cellular respiration by inhibiting cytochrome c oxidase, an enzyme in the electron transport chain, leading to cell death.

In a previous study, we synthesized an optical sensor that detects cyanide selectively. The aim of this project is to increase the sensitivity of this sensor. This can be achieved by utilizing the unique spectroscopic properties of lanthanide ions.

The lanthanide metal (europium or terbium) was added to a coumarin-glycine chemodosimeter in a DMSO solvent system. The sensor was titrated with several monodentate analytes including, nitrate, octylamine, 1-pentanethiol, …

A Review And Application Of Aviation Forecasting For Airport Planners, Robert Sims

Theses and Dissertations

Forecasting is a common method of predicting facility requirements at airports. Statistical methods used in forecasting are often simple and do not require advanced statistical analysis. However, while forecasting methodologies may be simple, the assumptions necessary for those methodologies to work correctly are not always properly addressed. For example, linear regression is often used as a method of generating aviation forecasts but is reliant on the correct selection of independent variables. In order for a forecaster to produce a reliable forecast, care must be taken to select appropriate variable and comply with any additional assumptions of the methodology they select. …

Optimizing Cloud-Service Performance: Efficient Resource Provisioning Via Optimal Workload Allocation, Zhuoyao Wang

Electrical and Computer Engineering ETDs

Cloud computing is being widely accepted and utilized in the business world. From the perspective of businesses utilizing the cloud, it is critical to meet their customers' requirements by achieving service-level-objectives. Hence, the ability to accurately characterize and optimize cloud-service performance is of great importance. In this dissertation, a stochastic multi-tenant framework is proposed to model the service of customer requests in a cloud infrastructure composed of heterogeneous virtual machines (VMs). The proposed framework addresses the critical concepts and characteristics in the cloud, including virtualization, multi-tenancy, heterogeneity of VMs, VM isolation for the purpose of security and/or performance guarantee and …

Bayesian Models For Repeated Measures Data Using Markov Chain Monte Carlo Methods, Yuanzhi Li

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Bayesian models for repeated measures data are fitted to three different data an analysis projects. Markov Chain Monte Carlo (MCMC) methodology is applied to each case with Gibbs sampling and/or an adaptive Metropolis-Hastings (MH) algorithm used to simulate the posterior distribution of parameters. We implement a Bayesian model with different variance-covariance structures to an audit fee data set. Block structures and linear models for variances are used to examine the linear trend and different behaviors before and after regulatory change during year 2004-2005. We proposed a Bayesian hierarchical model with latent teacher effects, to determine whether teacher professional development (PD) …

An Economic Analysis Of Factors Affecting Pre-Weaned Dairy Calf Growth And Profit Optimization In Dairy Calf Operations, Vincent T. Hess

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This study was an extension of a study submitted in April 2014 by Sheldon D. Holt entitled “Ambient Temperature, Calf Intakes, and Weight Gains on Preweaned Dairy Calves”.

A major component in a profitable dairy operation is the raising of female calves as replacement heifers; but since no direct income is generated by calf raising alone, it is often overlooked as a potential profit area on a dairy farm. Calf management practices that ultimately impact milk productivity and reproductive performance during a heifer’s lifetime begin at birth. This study examines the effect of calf starter intake on calf growth, measuring …

Cluster-Based Salient Object Detection Using K-Means Merging And Keypoint Separation With Rectangular Centers, Robert Buck

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The explosion of internet traffic, advent of social media sites such as Facebook and Twitter, and increased availability of digital cameras has saturated life with images and videos. Never before has it been so important to sift quickly through large amounts of digital information. Salient Object Detection (SOD) is a computer vision topic that finds methods to locate important objects in pictures. SOD has proven to be helpful in numerous applications such as image forgery detection and traffic sign recognition. In this thesis, I outline a novel SOD technique to automatically isolate important objects from the background in images.

Visualization Of Three-Dimensional Models From Multiple Texel Images Created From Fused Ladar/Digital Imagery, Cody C. Killpack

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The ability to create three-dimensional (3D) images offers a wide variety of solutions to meet ever increasing consumer demands. As popularity for 3D cinema and television continues to grow, 3D images will remain an important area of research and development. While there are a variety of ways to create a 3D model, textel images are quickly become the preferred solution that has been captured with a texel camera. The combination of multiple texel images taken around a scene can be used to form a texel model. Offering both visual and dimensional accuracy, texel models are becoming invaluable tools for disaster …

Epistemic Beliefs Of Middle And High School Students In A Problem-Based, Scientific Inquiry Unit: An Exploratory, Mixed Methods Study, Jiangyue Gu

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Epistemic beliefs are individuals’ beliefs about the nature of knowledge, how knowledge is constructed, and how knowledge can be justified. This study employed a mixed-methods approach to examine: (a) middle and high school students’ self-reported epistemic beliefs (quantitative) and epistemic beliefs revealed from practice (qualitative) during a problem-based, scientific inquiry unit, (b) How do middle and high school students’ epistemic beliefs contribute to the construction of students’ problem solving processes, and (c) how and why do students’ epistemic beliefs change by engaging in PBL.

Twenty-one middle and high school students participated in a summer science class to investigate local water …

The Mh-2 Core From Project Hotspot: Description, Geologic Interpretation, And Significance To Geothermal Exploration In The Western Snake River Plain, Idaho, Jerome A. Varriale

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Harnessing the earth’s natural heat generation as an energy resource has seen increased interest in recent history. While geothermal energy is a sustainable, low-carbon emitting, and viable source of energy in certain regions, large upfront risks, including costs of exploration and deep well drilling, have kept private sector investment at bay. Lowering the risks to capital investment that are inherent to subsurface exploration can help to assuage investors and bring this well-known energy-generating technology to the masses.

A blind potential geothermal system was encountered while drilling the MH2 science drill hole, on Mountain Home Air Force Base, Idaho. The MH-2 …

Efficient Device To Device Communications Underlaying Heterogeneous Networks, Xue Chen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Device-to-Device communications have the great potential to bring significant performance boost to the conventional heterogeneous network by reusing cellular resources. In cellular networks, Device-to-Device communication is defined as two user equipments in a close range communicating directly with each other without going through the base station, thus offloading cellular traffic from cellular networks. In addition to improve network spectral efficiency, D2D communication can also improve energy efficiency and user experience.

However, the co-existence of D2D communication on the same spectrum with cellular users can cause severe interference to the primary cellular users. Thus the performance of cellular users must be …

Evapotranspiration Estimation: A Study Of Methods In The Western United States, Clayton S. Lewis

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Theoretical water use of well-watered vegetation in the western United States was investigated by comparing a gridded dataset developed from satellite and ground instruments to weather stations representative of irrigated agricultural conditions. Since wetter environments are cooler and therefore subject to lower levels of evaporation than the same scenario with warmer temperatures, models derived from dryland and often populated areas overestimate potential plant needs in semi-arid or arid conditions. Evaluation of the model revealed an acceptable fit for air temperatures and solar radiation but with less confidence in humidity and wind speeds. Ultimately, the last two parameters were minor components …

Separation Of Points And Interval Estimation In Mixed Dose-Response Curves With Selective Component Labeling, Darl D. Flake Ii

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Dose-response experiments are those that involve giving subjects different amounts of a treatment and observing the outcome. For example, plants may be given fertilizer and their growth could be measured or cancer patients could be given different doses of chemotherapy and their response could be monitored. These experiments are used to understand the relationship between the amount of, and response to, the treatment. Logistic regression models are often used to summarize data from these types of experiments. The dose-response experiment that motivated this dissertation involved treating a grain-pest with a pesticide. Some of the beetles had genes that made them …

Investigating The Effect Of Carbon Nanotube Functionalization In A Polydimethylsiloxane Composite Through Use Of A Stepped Bar Apparatus, Matthew I. Ralphs

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Thermal interface materials (TIMs) are used in transporting heat away from a circuit or electronic module. Composite materials are a popular research area for TIMs because they allow the desired properties to be joined in a composite to take advantage of the best properties from all the constituents involved. The composite selected for this study uses carbon nanotubes (CNT) as the filler and an elastomeric polymer for the matrix, specifically a multiwalled carbon nanotube (MWCNT) / polydimethylsiloxane (PDMS) composite. This study looks at chemical modification (functionalization) of the CNTin an effort to produce a better bond between the CNT and …

Thermal Property Measurement Of Thin Fibers By Complementary Methods, Troy Robert Munro

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Thin fibers are prevalent in many engineering materials. Measuring how well heat transfers in such small fibers can be difficult to determine, and previous methods have led to erroneous results. This dissertation details three proposed methods to improve the measurement of the thermal conductivity, thermal diffusivity, and volumetric heat capacity of thin fibers. Of particular interest is natural and synthetic spider silks because previously published values of the natural silk thermal conductivity was similar to copper, an excellent thermal conductor.

The three methods developed are the improved transient electrothermal technique (which was redeveloped to include radiation and convection heat losses …

Development Of A Three-Dimensional High-Order Strand-Grids Approach, Oisin Tong

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The strand-Cartesian grid approach is a unique method of generating and computing fluid dynamic simulations. The strand-Cartesian approach provides highly desirable qualities of fully-automatic grid generation and high accuracy. This work focuses on development of a high-accuracy methodology (high-order scheme) on strand grids for two and three dimensions.

In this work, the high-order scheme is extended to high-Reynolds number computations in both two and three dimensions with the Spalart-Allmaras turbulence model and the Menter SST turbulence model. In addition, a simple limiter is explored to allow the high-order scheme to accurately predict discontinuous flows.

Extensive verification and validation is conducted …

A Spatiotemporal Mountain Pine Beetle Outbreak Model Predicting Severity, Cycle Period, And Invasion Speed, Jacob P. Duncan

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The mountain pine beetle (MPB, Dendroctonus ponderosae), a tree-killing bark beetle, has historically been part of the normal disturbance regime in lodgepole pine (Pinus contorta) forests. In recent years, warm winters and summers have allowed MPB populations to achieve synchronous emergence and successful attacks, resulting in widespread population outbreaks and resultant tree mortality across western North America. We develop an age-structured forest demographic model that incorporates temperature-dependent MPB infestations: the Susceptible-Infested-Juvenile (SIJ) model. Stability of equilibria is analyzed as a function of population growth rates, and indicates the existence of periodic outbreaks that intensify as growth rates …

An Automatic Algorithm For Textured Digital Elevation Model Formation Using Aerial Texel Swaths, Taylor C. Bybee

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The process of creating a 3D terrain map of an area is a challenging, computationally intensive task. There are two main camps of established methods doing this, with varying degrees of accuracy and cost. Using the established methods, there is a trade-off between accuracy and cost. The first method involves using many aerial images to detect disparity between points in the images. This is a difficult task as it requires a lot of computer processing with varying degrees of reliability. In addition, this method does not make any direct distance measurements. Secondly, using high-precision and high-cost lasers and positioning equipment, …

Aligning Conservation Goals And Management Objectives For Bonneville Cutthroat Trout (Oncorhynchus Clarki Utah) In The Logan River, Utah, Harrison E. Mohn

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Rivers are often managed without informed knowledge of how sportfish use different areas of the river to reproduce, and rarely take into account the relationship between fish movement and how they are distributed within the river when making management decisions. The population of native Bonneville cutthroat trout (Oncorhynchus clarki utah) within the Logan River is the largest documented population remaining for this imperiled species, and still maintains extremely high numbers of fish in the upper river. Currently, fishing is not allowed in the upper 20 kilometers of the Logan River watershed during spawning, based on the assumption that …

Intraspecific Variation In The Response Of Elymus Elymoides To Competition From Bromus Tectorum, Rebecca K. Mann

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

In the western United States, thousands of acres of degraded rangelands are dominated by aggressive invasive species such as cheatgrass (Bromus tectorum), and are seeded by managers with native plants in an attempt to restore species diversity, wildlife habitat, and ecosystem services. There are many options for obtaining seeds of native plants; for instance, they can be collected from the region where restoration is to occur, or they may be purchased through commercial producers. For a given plant species, managers may also select seeds from unique subspecies, cultivars, and populations. Genetic differentiation among these within-species groups can not only affect …

Atp Usage In The Dark-Operative Protochlorophyllide Oxidoreductase, Mark S. Soffe

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Chlorophylls are essential pigment molecules that function in photosynthesis, and serve to aid in utilizing energy from sunlight to power cellular processes in plants, and other organisms. To make chlorophyll, photosynthetic organisms devote an abundance of resources and energy to ensure their appropriate construction. This process of making chlorophylls is highlighted by the penultimate step in the pathway—the conversion of protochlorophyllide (Pchlide) to chlorophyllide a (Chlide).

This conversion can be mediated in two different ways, depending on the type of organism. The first method incorporates the use of a light-activated system called the light-dependent protochlorophyllide oxidoreductase (LPOR). This system, as …