Digital Commons Network^™

The Potential Importance Of Microenvironment On Polymer Bound Chemical Reagents, Nathan Joseph Halsteter

Theses and Dissertations

In this thesis will provide a brief history of polymer bound reagents, their uses, and advancements. The importance of polymer microenvironments will be explored using a model kinetic resolution reaction utilizing polymer bound reagents to observe how changes in a polymer’s microenvironment effects the yield and selectivity of a reaction. It was found that there are copious factors that affect polymer bound reagents, and no direct conclusion could be drawn from the study.

Impact Of Participation In Extracurricular Activities On Female Students’ Motivation, Noha Ibrahim

Theses and Dissertations

This study investigated the impact of extracurricular activities (ECAs) on academic motivation among female high school students at a semi-governmental international school in the UAE. It addressed three research questions: (1) the effect of ECA participation on academic motivation, (2) students’ perceptions of how these activities influence their motivation, and (3) teachers’ perspectives on their impact. I conducted this action research in a school of 4,500 K-12 students predominantly local and from high-income backgrounds with an international teaching staff. Participants included grade 11 and 12 female students (ages 16–18) enrolled in one of four clubs (Reading, International, Sports, and Art) …

As Iron Sharpens Iron: Intentional Near-Peer Mentorship In The Collegiate Applied Studio, Morgan Smith Owen

Theses and Dissertations

Undergraduate students struggle to adjust to the expectations of university music programs. Mentoring programs are consistently cited as tools to build social capital and academic success, but there are few documented studies of mentoring applied directly to the traditional model of conservatory music instruction. Effective near-peer mentoring can build musicianship skills and develop accountability, establishing stronger practice routines and easing the transition to collegiate music study for younger students. This case study examines three models of mentorship to identify ways to create an intentional mentorship program within the applied studio, regardless of scale or specific form of instruction.

Characteristics Of Individuals Who Desired A Mentor But Did Not Have One: A Nationally Representative Study, Kenzie Delposen

Theses and Dissertations

Youth are experiencing increased mental health challenges due to the parallel increase in loneliness and social isolation. Mentorship has emerged as a potential solution to reduce social isolation and provide support, guidance, and encouragement to young people. The context of the mentoring relationship positively impacts adolescent lives by promoting a safe, stable, nurturing relationship (SSNR) to reinforce the intrinsic motivation to connect with others. However, many young people lack these relationships despite indicating that there were times when they wanted one (Garringer & Banning, 2023). Access to mentorship is influenced by factors such as racial or ethnic background, socioeconomic status …

Transgressive Desire And Women’S Liberation In The British Strike Bildungsroman, Carl Clinton Sweat

Theses and Dissertations

This dissertation examines the intersection of gender and class identity in British proletarian Bildungsromane set during the General Strike of 1926 and the Miners’ Strike of 1984/5, referred to collectively as “Strike Bildungsromane.” These prolonged industrial conflicts temporarily disrupted the gender division of labor that had hitherto been a defining aspect of pit village life. This development encouraged proletarian writers of the interwar and post-war periods to consider coalfield women as political agents, capable of subverting their preordained roles within the private sphere. These moments of subtle subversion are critical to the General Strike novels explored in this study, …

An Investigation Of The Impact Of Child-Centered Play Therapy Facilitated Through A Virtual Playroom On Disruptive Behaviors: A Single-Case Research Design, Keeland Kelley Lodato

Theses and Dissertations

This multi-manuscript dissertation comprises two interconnected articles that collectively explore facilitating Child-centered play therapy (CCPT) through telemental health (TMH) using a virtual playroom. Chapter Three includes a qualitative manuscript using thematic analysis to understand the experiences of eight counseling students who participated in a training where they learned how to create and utilize a virtual playroom, followed by a virtual play session with elementary-aged children. The results from this study provided six emergent themes and subthemes. Chapter Four includes a quantitative manuscript using a single-case research design. More specifically, this study used a reversal design to investigate the impact of …

Reactivity Of Redox-Active Carboranyl Diphosphines And Carboranyl Diphosphoniums: Metal-Free Pathways For Small Molecule Activations And Transformations, Amanda Lynn Humphries

Theses and Dissertations

Transition metal catalysis has been an integral part of synthetic chemistry for its ability to selectively activate strong substrate bonds, promoting numerous crucial transformations. Despite their utility, the precious metals that are often employed in these catalytic reactions suffer from several drawbacks (including high toxicity, low natural abundance, high costs, and low sustainability), increasing the motivation to design suitable metal-free alternatives. Towards this end, several ambiphilic main-group systems have been devised to show metal-like reactivity, such as carbenes, borylenes, and Frustrated Lewis Pairs. This manuscript will describe the ambiphilic reactivity of carborane-based phosphorus compounds, highlighting the unique metallomimetic reactivity that …

Characterizing Dissolved Organic Matter Composition In A Southeastern United States Watershed, Gwendolyn Marcelette Hopper

Theses and Dissertations

Dissolved organic matter (DOM) has important roles in many biogeochemical cycles. DOM is primarily composed of dissolved organic carbon (DOC), nitrogen, and phosphorus, and the processing of DOM is important for nutrient regulation and carbon cycling. In the coastal plains of the southeastern United States, there are many rivers and streams known as “blackwaters” with exceptionally high concentrations of chromophoric dissolved organic matter (CDOM) leached from terrestrial soils, coinciding with a region experiencing some of the nation’s highest rates of development. As changes in land use and climate continue to occur, DOM composition from natural to anthropogenically impacted systems can …

The Dialogic Self: Persius Satires 4 And Oikeiosis In Stoic Philosophy, William Michael Dodd

Theses and Dissertations

Though acknowledging that Persius alludes to Horace so frequently that he creates a dialogue with his elder, many commentators fail to see that Persius would challenge his predecessor. Especially evident in Satire 4, Persius' challenge to Horace stems from the younger poet's Stoicism, which philosophy he sees Horace as lampooning throughout the elder poet's Satires. Persius not only defends his Stoicism in Satires 4 but also engages with perceived weaknesses in the Epicureanism he finds in Horace. For instance, instead of the Epicurean version of natural law Persius finds in Horace, which conceives of human ties as contractual, the younger …

Determination Of Structure-Function Relationships In Hybrid Catalysts On Metal Oxide Supports, Joseph John Kuchta

Theses and Dissertations

Transition metal catalysis has revolutionized chemical synthesis, enabling efficient and selective transformations critical to the pharmaceutical, agricultural, and materials industries. However, traditional methods often rely on expensive, non-sustainable metals and harsh reaction conditions that generate significant waste. This dissertation explores a series of innovations aimed at bridging the gap between homogeneous and heterogeneous catalysis through the development of hybrid catalysts. These systems combine the molecular precision of homogeneous catalysts with the stability and practicality of heterogeneous supports, offering a pathway to more sustainable and scalable catalytic processes.

The first area of focus investigates nickel-based hybrid catalysts as a cost-effective and …

What We Don’T Know Can Hurt Them: An Examination Of Culture-Centered Pedagogy In A Diverse Elementary School, Kelly Dale Hogan

Theses and Dissertations

This qualitative action research study examined a growing cultural divide at an elementary school with a significant teacher diversity gap, best described as a discrepancy between the number of White educators compared to the number of students of color within an educational setting. Surveys were utilized to understand teachers’ cultural competency, and then all participants engaged in a book study intervention focused on culture-centered pedagogy. The study concluded with exit interviews between participants and the researcher to gauge how perceptions of working with diverse student populations progressed throughout the study. Survey responses, book study field notes, and interview transcripts were …

‘If You Design For The Future To Treat Of Witches:' Diabolic Service Magicians, Astrologers, And Witchcraft In John Dunton's Athenian Mercury, 1690-1697, Lauren Rebecca Rowe

Theses and Dissertations

Originating in the print stands of seventeenth-century London, the Athenian Mercury enjoyed a nearly miraculous seven-year run time as the most well-known and successful anonymous question and answer periodical of its time. Conceptualized and produced by bookseller John Dunton, the Mercury existed as an interface for intellectual discourse readily accessible to men and women. Kept entirely anonymous on the part of the author and reader, the intellectually curious could write questions to the Mercury and receive answers in turn on a vast variety of subjects twice a week. Aside from the more expected queries on science, love, mathematics, and religion, …

Irish Teachers’ Perceptions Of Immigrant Students: Exploring How Culturally Responsive Pedagogy Affects Biases, Metacognition, And Inclusive Teaching Practices, Dorothy Widener Alton

Theses and Dissertations

Abstract The purpose of this paper is to describe a qualitative, reflective action research study that examined if learning and reflecting on culturally responsive pedagogy (CRP) affected Irish post-primary teachers’ perceptions of immigrant students, metacognition of biases, teaching practices, and inclusivity of these marginalized students. Qualitative data consisted of administering an online survey to post-primary teachers across Ireland, chosen by convenience sampling. In addition, I conducted an in-depth reflective survey before, during, and after providing CRP literature to four select participants, selected by purposive and snowball sampling. Data was analyzed by coding and observing emerging patterns to identify overarching themes …

Investigating The Impact Of Cross-Loadings On Model Fit And Mediation Inferences In The Latent Mediator Model, Qiulin Lu

Theses and Dissertations

Cross-loadings are a common phenomenon in psychological research. Extant studies have focused primarily on measurement models, like confirmatory factor analysis (CFA), and have shown that omitted cross-loadings can bias the inter-factor correlation. These results suggest that omitted cross-loadings might likewise bias structural paths in other structural equation models (SEMs), but this area remains under-investigated. Such an effect could impact the evaluation of third variable effects, like mediation, when estimated in a SEM framework.

This study addresses this gap by examining the effects of cross-loadings in single, latent mediator model in a simulation study. The performances of conventional SEM and Bayesian …

Moderation Amid Resistance: African American Advocacy, Educational Equity, And School Desegregation In Botetourt County, Virginia, Katherine Blanton

Theses and Dissertations

This dissertation examines the historical and social dynamics surrounding African American education in Botetourt County, Virginia preceding, during, and following court ordered desegregation. Using historiography, the researcher incorporated archival resources, interviews, and oral histories to examine the African American leadership of the County Wide League and their steadfast commitment to provide equal educational opportunities for African American children in Botetourt County. Set against the history of southern segregation, white school boards, and massive resistance to the 1954 U.S. Supreme Court decision to desegregate in Brown v. Board of Education, the historiography represents the moderate stance of the County in …

A Study Of Ci3t Implementation: Middle School Ela Teachers' Perceptions Of Tier 1 Academic Practices On Student Performance, Martha Kathryn Jenkinson

Theses and Dissertations

The purpose of this mixed methods action research study was to understand teachers’ perceptions of Ci3T tier 1 academic practices following the first year of implementation. Tier 1 instruction, delivered primarily by classroom teachers, is meant to meet the needs of a majority of students. Understanding teachers’ perceptions of program implementation, as well as reviewing student data to seek impacts of Ci3T on student learning, are important considerations when deciding how to improve the system. This study focused on the experiences and perceptions of English Language Arts teachers and Special Education teachers who work in ELA classes.

Data were gathered …

Utilizing Culturally Responsive Teaching Practices In The Classroom, Lindsey Nicole Finley

Theses and Dissertations

This research study aimed to address the impact of teaching concepts of culturally responsive pedagogy on teachers’ understanding of their implicit biases. Additionally, it examined the impact that professional development training utilizing culturally responsive teaching (CRT) methods have on teachers working with multilingual learners (MLs). The research questions were: (1) What is the impact of teaching concepts of culturally responsive pedagogy on teachers' understanding of their implicit biases? and (2) What is the impact of intentional, ongoing professional development utilizing CRT methods for teachers working with multilingual learners? This study used a theoretical framework of culture centered pedagogies such as …

Latinx Parent Acculturation And Acculturative Stress: Impact On Family Functioning And Youth Well-Being, Julie Nguyen

Theses and Dissertations

Research has demonstrated that acculturation and acculturative stress can influence family dynamics and Latinx youth well-being. Guided by the Family Stress Model, the current study aimed to assess a latent measurement model of acculturation and examine the relationship between acculturation and acculturative stress and how acculturative stress is related to family processes and youth adjustment. Data included 898 youth and 630 parents from the SOL Youth study. Structural equation modeling was used to assess a latent two-factor measurement model of acculturation and its relation to parental acculturative stress as well as how parental acculturative stress is related to family functioning …

Exploring The Sense Of Community And Perceived Professional Learning Of Multigrade Teachers In Cohort-Based Online Community Of Practice Sessions: An Action Research, Paola Franco-Oudri

Theses and Dissertations

The purpose of this action research was to explore the influence of cohort-based, online Community of Practice sessions on the sense of community and perceived professional learning of multigrade teachers in a faith-based, private school system in North America. Approximately 25% of teachers in the Seventh-day Adventist school system are multigrade elementary teachers and teach three or more grade levels in the same classroom. Multigrade teachers often have limited access to traditional professional development (PD) options because of distance, cost, and staffing limitations, but furthermore, traditional PD programs do not address the needs and realities of small, multigrade schools. Additionally, …

Hardware Accelerated Simulation Of Buck Converters Using Physics-Informed Neural Networks, James Clayton Crews

Theses and Dissertations

Physics-informed neural networks (PINNs) are an emerging machine learning method for learning the behavior of physical systems described by governing differential equations. Dc-dc power-electronic converters are used in a variety of industry applications such as motor drives or power supplies where real-time simulation is critical for control and safety. This thesis investigates physics-informed machine learning as an approach to develop a real-time digital twin for dc-dc power converters. Traditional numerical integration methods are used to approximate discretized behavior, and the results are compared with a trained PINN model. Modern ML frameworks (such as PyTorch and TensorFlow/Keras) are used to quickly …

A Mixed Methods Study Exploring The Lived Experience Of Shared Trauma In Psychiatric Nurses During Covid-19, April Lynne Hutto

Theses and Dissertations

Introduction: Psychiatric nurses (PNs) had a unique lived experience of shared trauma (ST) during the COVID-19 pandemic. These nurses experienced the same traumatic event, COVID-19, with associated trauma symptoms as their patients. This mixed methods study aims to triangulate data on ST in PNs using a quantitative and qualitative study. Methods: PN (N=24) completed a semi-structured interview during the summer and fall of 2024. A quantitative study PN (N=552) in spring 2023, using the Shared Trauma and Professional Posttraumatic Growth (STPPG) inventory, was completed with descriptive and inferential statistics using SAS 9.4. A thematic analysis of the interviews was completed …

A Spatial Examination Of Colonial Anglican Landscapes In The South Carolina Lowcountry, Madeleine Paige Blaze

Theses and Dissertations

This thesis project will focus on the early colonial landscape of the South Carolina Lowcountry to analyze the placement of Anglican churches that were built between 1700 and 1730. My research will expand on previous analysis of the Anglican landscape to incorporate additional components that will aid in a better understanding of regional organization. To do so, I will incorporate a landscape archaeology theoretical frame that will allow my research questions to be explored. This project will also include GIS analysis to examine spatial visualizations, navigation paths, and colonial relationships to understand the Church’s early interactions with and on the …

A Mixed Methods Examination Of Interdisciplinary Strategies For Addressing Trauma And Chronic Pain In Group Therapy, Kara Marceil Schneider

Theses and Dissertations

Chronic pain and trauma are distinct yet interconnected public health concerns, each significantly affecting physical, psychological, and social well-being. The comorbidity of these conditions highlights a critical need for integrated treatment approaches. This dissertation explores interdisciplinary strategies that merge group counseling and physical therapy to address trauma symptomology and chronic pain within a group therapy setting. Grounded in the biopsychosocial model, somatic therapy principles, and the gate control theory of pain, this multi-manuscript dissertation employs a mixed methods design to examine counselor experiences, intervention feasibility, and participant outcomes.

The Impact Of Social Emotional Learning (Sel) Lessons On Students’ Mental Health Surrounding Standardized Testing, Margaret Denning

Theses and Dissertations

This qualitative action research examined the emotional impacts of standardized testing on 4th and 5th graders and the effects of targeted social-emotional learning lessons in a Title 1 school. Pre- and post-intervention data were gathered through surveys (Children’s Test Anxiety Scale) and focus group interviews. By employing thematic and narrative analysis, findings revealed significant initial cognitive anxiety, physical symptoms, and difficulties in self-regulation. Following the SEL intervention, the data indicated that students exhibited improved emotional resilience, reduced anxiety symptoms, and enhanced coping skills. Although the SEL interventions enhanced overall emotional well-being, anxiety was not fully eliminated. This study highlights the …

Explorations In Extremal Combinatorics: Graph Spectra, Codegree Squared Sum Of Hypergraphs And Lin-Lu-Yau Ricci Curvature, George Henry Brooks

Theses and Dissertations

This dissertation explores a variety of extremal problems in spectral graph theory, hypergraph Tur\'an theory in the $\ell_2$-norm, and Lin-Lu-Yau Ricci curvature. We begin by studying the maximization of linear combinations of eigenvalues in relation to the adjacency matrix of a graph. For a graph $G$ on $n$ vertices, we order its eigenvalues $\lambda_1 \geq \dots \geq \lambda_n$. First, we study a generalization of the maximum spread. Specifically, we consider the $(i,j)$-spread, defined as $\lambda_{i+1}-\lambda_{n-j}$, and aim to maximize that quantity over all simple graphs on $n$ vertices. We establish asymptotic bounds for all $i,j\geq 0$ and identify infinitely many …

Combining Remote Sensing And Field Sampling To Assess Microphytobenthos Distribution In The North Inlet Estuary, South Carolina, Joseph Carmine Mcguinn

Theses and Dissertations

The study of microphytobenthos (MPB) distributions in mudflat ecosystems is critical for understanding coastal ecosystem health and resilience. This research integrates high-resolution multispectral imagery and elevation data to predict chlorophyll-a concentrations in mudflats within the North Inlet estuary, South Carolina. Using statistical analyses, MSAVI was identified as the most effective spectral index for chlorophyll-a prediction, and a regression model was generated for this index, finding significant correlation with elevation. Temporal and spatial patterns of chlorophyll-a distributions were explored through predictive rasters, revealing significant relationships between MPB abundance and microtopography. These findings demonstrate the value of remote sensing for …

Developing Mathematical Thinking And Reasoning For Students With Disabilities Through Professional Learning Communities, Dawn Pilotti

Theses and Dissertations

Professional learning communities (PLCs) are designed to improve learning outcomes for all students through educator collaboration. Guided by systems theory and supported by social cognitive, social practice and change theories, this longitudinal participatory action research study explored the development of an interdepartmental PLC, and its impact on mathematics teachers’ practices and students’ performance. Additionally, this study explored the relationship between participation in the PLC and participants’ collective efficacy. The study was conducted at a school for students with learning disabilities. The PLC included Grade 5 and Grade 6 mathematics teachers, occupational therapists, speech and language pathologists, a mathematics specialist, reading …

Mo Isotopes In The Aleutian And Costa Rican Arcs: Source Variability And Juvenile Crust Formation, Ekaterina Rojas Kolomiets

Theses and Dissertations

Chemical and physical transfer between the surface, lithosphere and asthenosphere at subduction zones leads to arc magmatism and continental crust (CC) production. Subduction zones magmas and associated volcanic products sample a variety of magmatic sources that contribute to their chemical compositions in various proportions. This dissertation contributes to the study of subduction zones magmatism by assessing the relative role of subduction inputs (sediments, altered oceanic crust – AOC – and serpentinite) as flux agents in the arc magmatism and in CC formation in subduction zones under the scope of Mo isotope systematics.

I present the first Mo isotope analyses form …

Deprivation And Threat As Predictors Of Executive Functioning And Emotion Regulation In Early Adolescence: The Protective Role Of School Support, Abigail Best De Arellano

Theses and Dissertations

Childhood adversity (CA) impacts a large proportion of US youth with far reaching consequences for development and subsequent health outcomes (McLaughlin et al., 2012). Given the widespread impact of CA, it is imperative to understand how these exposures impact development, as well as identify opportunities for intervention. McLaughlin and Sheridan (2016) proposed the Dimensional Model of Adversity of Psychopathology (DMAP), providing a framework for understanding the heterogeneity of outcomes related to exposure to CA. DMAP emphasizes that deprivation (i.e., lack of expected cognitive or social stimulation) and environmental threat (i.e., exposure to harm or the threat of harm) impacts youth …

Exploring The Self-Assembly Of Functional Bis-Urea Macrocycles: M-Terphenyl Bis Urea Macrocycles And Triphenylamine Bis-Urea Macrocycles, Gamage Isuri Pramodya Wijesekera

Theses and Dissertations

Porous materials have gained significant attention due to their diverse applications in catalysis, separation, and molecular storage. Among them, self-assembled macrocycles represent a unique class of functional materials that leverage non-covalent interactions to form well-defined architectures with pores of controlled size. This thesis explores the design, synthesis, and self-assembly of bis-urea macrocycles in both solid-state and solution-phase environments, with a particular focus on supramolecular polymerization mechanisms and the emergence of kinetically trapped states.

The first chapter of this thesis presents a detailed overview of self-assembled porous materials, categorizing them based on pore dimensions and discussing their significance in catalysis, separation, …