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Mole Street Journal, December 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

A Topological Approach To Molecular Chirality, Erica Flapan

Pomona Faculty Publications and Research

Topology is the study of deformations of geometric figures. Chemistry is the study of molecular structures. At first glance these fields seem to have nothing in common. But let’s take a closer look to see how these fields come together in the study of molecular symmetries.

Multiple Benzene-Formation Paths In A Fuel-Rich Cyclohexane Flame, Wenjun Li, Matthew Law, Phillip Westmoreland, Tina Kasper, Nils Hansen, Katharina Kohse-Höinghaus

United States Department of Energy: Publications

Detailed data and modeling of cyclohexane flames establish that a mixture of pathways contributes to benzene formation and that this mixture changes with stoichiometry. Mole-fraction profiles are mapped for more than 40 species in a fuel-rich, premixed flat flame (Φ = 2.0, cyclohexane/O₂/30% Ar, 30 Torr, 50.0 cm/s) using molecular-beam mass spectrometry with VUV-photoionization at the Advanced Light Source of the Lawrence Berkeley National Laboratory. The use of a newly constructed set of reactions leads to an excellent simulation of this flame and an earlier stoichiometric flame (M.E. Law et al., Proc. Combust. Inst. 31 (2007) 565–573), …

Prehistoric Plant Procurement, Food Production, And Land Use In Southwestern Tamaulipas, Mexico, John Hanselka

All Theses and Dissertations (ETDs)

In this dissertation, I examine plant use, food production, and land use in the Ocampo region of southwestern Tamaulipas, northeastern Mexico. In the early 1950s Richard S. MacNeish excavated in a series of dry cave sites within the study area and discovered evidence for the local adoption of domesticated plants and the subsequent development of a mixed foraging-farming economy that persisted for millennia, before culminating in the establishment of settled farming villages. This research remains central to discussions of early Mesoamerican agriculture. However, the spectrum of land use and wild plant utilization over the prehistoric sequence remains poorly understood, as …

New Synthetic Methodologies For The Construction And Optimization Of Natural Products, Amir E. Wahba

Electronic Theses and Dissertations

Toxicity associated with bioactive natural products is considered as a major obstacle in the process of drug discovery. Manzamine A (MA) is one such candidate that requires optimization to overcome the toxicity problem. The manzamine alkaloids represents a unique class of natural products that have shown a diverse range of bioactivities including antimicrobial, antiparasitic, cytotoxicity, anti-inflammatory, pesticidial, and was shown to possess activity against HIV-1 and AIDS opportunistic infections. The greatest potential for the manzamine alkaloids appears to be against malaria and neuroinflammation. Experimental and modeling studies suggested that the planer ?-carboline moiety can act as DNA intercalator and hence …

Synthesis Of Molecular Containers Based On Modifications Of Resorcin(4)Arene And Calix(4)Arene, Anupama Makineni

Masters Theses

This research work was mainly focused on the synthesis of molecular containers based on modifications ofresorcin[4]arene and calix[4]arene.

The modifications of resorcin[ 4 ]arene include the attempts to attach a phthalimide featured linker onto the phenol hydroxyl groups of resorcin[4]arene. A few halogen leaving groups were used, including fluorine, chlorine, and bromine. The substitution with tetraflorophthalimide resulted in a mixture of regio-isomeric products, whereas for 4,5-dichloro- and 4,5-dibromophthalimides, no desired substitution product was formed. It was, however, discovered that both 4,5-dichloro- and 4,5-dibromophthalimides forms monoclinic crystals. The second modification of resorcin[4]arene focused on functionalizations of both upper and lower rims …

Evaluating Methods For Optimizing Classification Success From Otolith Tracers For Spotted Seatrout (Cynoscion Nebulosus) In The Chesapeake Bay, Stacy Kavita Beharry

OES Theses and Dissertations

Identifying the natal sources of fish is an important step in understanding its population dynamics. Adult recruits are often sourced from multiple nursery areas, with good quality locations contributing disproportionately more fish to the adult stock. Because population persistence is strongly influenced by nursery habitat, methods that correctly identify the source of recruits are necessary for effective management. Within the last decade, otolith chemistry signatures have been increasingly used as a natural marker to delineate fish from a mixture of nursery sources. Despite the widespread use of otolith trace element and stable isotope ratios as habitat markers, the statistical approaches …

Inhibition And Nucleic Acid Binding Studies Of The Carboxyltransferase Component Of Bacterial Acetyl-Coa Carboxylase, Brian Benson

LSU Doctoral Dissertations

Acetyl-CoA carboxylase is an essential enzyme, as it catalyzes the first committed and regulated step in fatty-acid biosynthesis in all organisms excepting few Archaea and Eubacteria. Acetyl-CoA carboxylase from gram-negative and gram-positive bacteria is a multifunctional enzyme composed of three separate proteins. The carboxyltransferase subunit catalyzes the transfer of a carboxyl group from carboxybiotin to acetyl-CoA, forming malonyl-CoA. The crystal structure of the Escherichia coli (E. coli) carboxyltransferase component of acetyl-CoA carboxylase revealed a unique Zn-domain, presumed to mediate nucleic acid binding, that is absent in the eukaryotic enzyme. Notably, the Zn-domain, adjacent to the active site of carboxyltransferase, makes …

Investigating Student Understanding Of The Law Of Conservation Of Matter, Shirley Lynn Tremel

Dissertations and Theses

The purpose of this study was to gather information about how students learn the foundational concept of conservation of matter during a non-chemistry unit on the rock cycle. The unit covered the rock cycle, rock types, and the law of conservation of matter and took place in a sixth grade classroom of 30 students. A mixed methods, quasi-experimental, pre-post, delayed post design was used to measure student understanding of the concept of conservation of matter as it relates to the rock cycle. Students made significant learning gains from pre-test to post-test and showed mastery in less complex subject areas, but …

Application Of Scanning Probe Microscopy For New Physical Measurements And Studies Of Surface Chemical Reactions Of Materials At The Molecular Level, Stephanie Loletha Daniels

LSU Doctoral Dissertations

Scanning probe microscopy (SPM) provides unique capabilities for surface visualization and measurements that reach atomic and molecular dimensions. My research focus is directed toward applying and developing new measurements for analytical and surface chemistry with SPM. Two distinct goals based on studies with atomic force microscopy (AFM) will be described within this dissertation. The primary goal was to develop and apply a new AFM imaging mode for ultrasensitive measurements of the superparamagnetic properties of proteins. Magnetic sample modulation (MSM)-AFM, has capabilities to investigate and map the magnetic response of nanomaterials with unprecedented spatial resolution. The second goal was to apply …

Contrasting View On Asphaltene And Human Cardiac Troponin I: A Surface Chemistry And Spectroscopy Perspective, Jhony Orbulescu

Open Access Dissertations

Surface chemistry has proven in the recent years that it could be used for a variety of applications. In the current work, the surface chemistry and spectroscopic techniques are used to emphasize their great potential in aggregation studies of UG8 asphaltene and the contrasting results for a surface chemistry perspective for the human cardiac troponin I. The first part of the work focuses on the influence of different spreading solvents on the aggregation of UG8 asphaltene and their comparison to the literature on the topic. It is shown that the surface chemistry approach employed in the current work has significant …

Mole Street Journal, November 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Mole Street Journal, October 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Mole Street Journal, September 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Impact Of Interdisciplinary Undergraduate Research In Mathematics And Biology On The Development Of A New Course Integrating Five Stem Disciplines, Lester Caudill, April L. Hill, Kathy Hoke, Ovidiu Z. Lipan

Department of Math & Statistics Faculty Publications

Funded by innovative programs at the National Science Foundation and the Howard Hughes Medical Institute, University of Richmond faculty in biology, chemistry, mathematics, physics, and computer science teamed up to offer first- and second-year students the opportunity to contribute to vibrant, interdisciplinary research projects. The result was not only good science but also good science that motivated and informed course development. Here, we describe four recent undergraduate research projects involving students and faculty in biology, physics, mathematics, and computer science and how each contributed in significant ways to the conception and implementation of our new Integrated Quantitative Science course, a …

Impact Of Interdisciplinary Undergraduate Research In Mathematics And Biology On The Development Of A New Course Integrating Five Stem Disciplines, Lester Caudill, April L. Hill, Kathy Hoke, Ovidiu Z. Lipan

Biology Faculty Publications

Funded by innovative programs at the National Science Foundation and the Howard Hughes Medical Institute, University of Richmond faculty in biology, chemistry, mathematics, physics, and computer science teamed up to offer first- and second-year students the opportunity to contribute to vibrant, interdisciplinary research projects. The result was not only good science but also good science that motivated and informed course development. Here, we describe four recent undergraduate research projects involving students and faculty in biology, physics, mathematics, and computer science and how each contributed in significant ways to the conception and implementation of our new Integrated Quantitative Science course, a …

Mole Street Journal, August 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Creative Exercises In General Chemistry: A Student-Centered Assessment, Scott E. Lewis, Janet L. Shaw, Kathryn A. Freeman

Faculty Articles

Creative exercises (CEs) are a form of assessment in which students are given a prompt and asked to write down as many distinct, correct, and relevant facts about the prompt as they can. Students receive credit for each fact that they include that is related to the prompt and distinct from the other facts they list. With CEs, students have an opportunity to demonstrate their knowledge and the opportunity to select the information that they believe is related to the prompt. In addition, CEs encourage students to connect concepts because any relevant information presented can assist them in completing the …

Mole Street Journal, July 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Locating The Accretion Footprint On A Herbig Ae Star: Mwc 480, C A. Grady, K Hamaguchi, G Schneider, B Stecklum, B E. Woodgate, J E. Mccleary, G M. Williger, M L. Sitko, F Menard, Th. Henning, Sean D. Brittain

Publications

Accretion is a fundamental process which establishes the dynamics of the protoplanetary disk and the final properties of the forming star. In solar-type stars, the star–disk coupling is determined by the magnetic field structure, which is responsible for funneling material from the disk midplane to higher latitudes on the star. Here, we use pan-chromatic data for the Herbig Ae star MWC 480 to address whether similar processes occur in intermediatemass stars. MWC 480 has X-ray emission typical of actively accreting Herbig Ae stars, but with ∼10× more photoelectric absorption than expected from optical and FUV data. We consider three sources …

Study On Energy Absorption Behaviors Of Hydrophobic Mesoporous Materials, Zhongyuan Sun

Theses and Dissertations - UTB/UTPA

Nanoporous energy absorption system has been developed tremendously as an advanced energy storage system in recent years. This research is to optimize the mesoporous energy absorption matrixes via surface treatment to find out the optimum conditions for higher energy conversion efficiency. Five mesoporous silica matrixes with pore size in a range of 3 to 31.6 nm were investigated. Six alkylchlorosilanes were used as the modification reagents. The results showed that the energy absorption density via pressure-induced infiltration is as high as 8.0 J/g which is 100 times larger than that of conventional energy absorption materials. The controllability of the energy …

Mole Street Journal, June 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Utpa Commencement – Summer 2010, University Of Texas-Pan American

Edinburg Archives - Legacy Commencement Programs

No abstract provided.

Mole Street Journal, May 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Mole Street Journal, April 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Organic Chemistry Preconceptions And Their Correlation To Student Success, Jodie T. Wasacz

Dissertations

When general chemistry students register for organic chemistry, they often have a negative connotation associated with the topic. It has been observed that students talk as if they are experts in what organic chemistry is and exactly how hard it is when many of them have had very little background on the subject. Some students do not even know what topics organic chemistry encompasses. By establishing a framework of where their preconceptions come from and what they are, instructors, will have a better understanding of how to address preconceptions when beginning an organic chemistry course, or perhaps even before. Furthermore, …

Mole Street Journal, March 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Mole Street Journal, February 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

Mole Street Journal, January 2010, University Of Arkansas, Fayetteville. Dept. Of Chemistry And Biochemistry

Mole Street Journal

No abstract provided.

In Situ Perturbation Experiments: Natural Venting Sites, Spatial/Temporal Gradients In Ocean Ph, Manipulative In Situ Pco2 Perturbations, Jp Barry, Jm Hall-Spencer, T Tyrell

School of Biological and Marine Sciences

No abstract provided.