Digital Commons Network^™

Metal-Free Photoredox Catalysis For The S-Trifluoromethylation Of Thiols, Raheemat Rafiu, Puspa Aryal, V. Prakash Reddy

Chemistry Faculty Research & Creative Works

The S-trifluoromethylation of thiols is accomplished using a simple and cost-effective organic catalyst (diacetyl) along with a bench-stable and environmentally friendly trifluoro methylating reagent (Langloi's reagent). Under optimized conditions (2.5 equivalents of Langlois reagent, Blue LED irradiation, 48-h reaction time at room temperature), the reaction yielded up to 81% S-trifluoro methylated product. This method's high yields, compatibility with a broad substrate scope (aliphatic, heteroaromatic, and aromatic thiols), and environmentally friendly conditions demonstrate its potential for broader synthetic applications. In contrast to traditional methods that rely on organometallic catalysts and environmentally hazardous reagents, this novel photoredox catalysis method offers a more …

Characterizing The Transient Emission Of Particles And Gases From A Single Puff Of Electronic Cigarette Smoke, Kashala Fabrice Kapiamba, Steven Achterberg, Ta Chun Lin, Philip D. Whitefield, Yue-Wern Huang, Yang Wang

Chemistry Faculty Research & Creative Works

This study employed high-time-resolution systems to examine the transient properties of aerosols and gases emitted from electronic cigarette (EC) puffs. Using a fast aerosol sizer, we measured particle size distributions (PSDs) across various EC brands (JUUL, VUSE, VOOPOO), revealing sizes ranging from 5 to 1000 nm at concentrations of 107 to 1010 cm-3. Most aerosols were found to be in the ultrafine range (below 100 nm), with JUUL-, VUSE-, and VOOPOO-producing aerosols with geometric mean sizes of 19.9, 47.3, and 29.4 nm, respectively. Applying the International Commission on Radiological Protection (ICRP) deposition model and assuming no further evolution of aerosols …

Formation Of Hydrocarbons And Carbon Oxides In Mxene Reactions With Water Under Varying Oxidative Conditions, Shuohan Huang, Guanglei Xiang, Vadym Mochalin

Chemistry Faculty Research & Creative Works

Titanium carbide / carbonitride MXenes have garnered significant attention due to their remarkable properties, versatile solution processability, and broad range of potential applications. However, when exposed to the environment, MXenes are susceptible to degradation, which ultimately leads to the formation of metal oxides, a process that may be regarded as either disadvantageous or beneficial, depending on the application of a MXene and our knowledge about the underlying mechanisms. Therefore, it is very important to understand the reactivity of MXenes in different environments and conditions. Although researchers have made efforts to understand MXene degradation in air and water, our knowledge of …

Instantaneous Hydrolysis Of Methyl Paraoxon Nerve Agent Simulant Is Catalyzed By Nontoxic Aminoguanidine Imines, Emmanuel Kingsley Darkwah, Puspa Aryal, Chi Zhang, Charles B. Musgrave, William A. Goddard, V. Prakash Reddy

Chemistry Faculty Research & Creative Works

Exposure to organophosphate-based nerve agents and pesticides poses health and security threats to civilians, soldiers, and first responders. Thus, there is a need to develop effective decontamination agents that are nonhazardous to human health. To address this, we demonstrate that instantaneous hydrolysis of methyl paraoxon (Me-POX), a nerve agent simulant, can be achieved in the presence of aminoguanidine imines at pH 10: ● the pyridine-4-aldehyde aminoguanidine-imine (1) and ● the 2,3-butanedione aminoguanidine-imine (2). The hydrolysis of Me-POX under these conditions is substantially faster than that of the state-of-the-art decontaminating agent, Dekon-139 (2,3-butanedione oxime, potassium salt). Furthermore, Dekon-139 shows adverse effects …

Synthesis And Characterization Of Free Radical Scavenging Dendrimer Nanogels Via Cross-Linking Reaction-Enabled Flash Nanoprecipitation, Lin Qi, Da Huang, Huari Kou, Anna Chernatynskaya, Nuran Ercal, Hu Yang

Chemistry Faculty Research & Creative Works

This work reports the development and evaluation of dendrimer-based nanogels based on Poly amidoamine (PAMAM) dendrimer generation 5, engineered to act as a carrier with reactive oxygen species (ROS)-scavenging capabilities. We developed a cross-linking reaction-enabled flash nanoprecipitation method in which the cross-linking reaction occurs during the flash nanoprecipitation process to form a cross-linked nanostructure. Using this approach, an N-hydroxy succinimide (NHS)-functionalized ROS-responsive thioketal cross-linker (TK-NHS) was synthesized and utilized to cross-link DAB-core PAMAM dendrimer G5, resulting in the formation of G5-TK nanogels. The resulting nanogels were characterized using dynamic light scattering and transmission electron microscopy, and their cytocompatibility, irritancy, cellular …

Pla-Based Bone Tissue Engineering Scaffolds Incorporating Hydroxyapatite And Bioactive Glass Using Digital Light Processing, Engin Gepek, Fateme Fayyazbakhsh, Lev Suliandziga, Vadym Mochalin, Osman Iyibilgin, Yue-Wern Huang, Ming C. Leu

Chemistry Faculty Research & Creative Works

Bone tissue engineering (BTE) aims to repair bone defects using biocompatible materials with tailored geometries and pore structures, providing appropriate mechanical support and control over biodegradation kinetics to promote bone growth. In this study, we utilized digital light processing (DLP) 3D printing to fabricate scaffolds with varying pore sizes using polymer–ceramic slurries composed of polylactic acid (PLA) as the main polymer matrix, incorporated with hydroxyapatite (HA) and bioactive borate glass (BBG) at various ratios. We studied the effect of composition on rheological behavior, printability, mechanical properties, bioactivity, degradation rate, and biocompatibility. While HA increased viscosity and reduced printing accuracy, it …

Unveiling Pseudocapacitance: A Kinetic Treatment Of The Pseudocapacitive Biosensor, Rokas Gerulskis, Egor Baiarashov, Maryam Karimi, Wassim El Housseini, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

A kinetic framework is introduced for a pseudocapacitive potentiometric biosensor. Mathematical derivation and kinetic modeling demonstrate that experimentally observed linearity in analyte-OCP response arises from a dynamic equilibrium between competing redox reactions on a single electrode. This system can be expanded to develop a new generation of biosensors.

Mechanical And Thermal Characterization Of Additively Manufactured Carbon/Nylon 12 And Carbon/Peek Composites, Matik Heskin, Bradley Deuser, Thomas P. Schuman, K. Chandrashekhara, John Bayldon, Jeff Degrange, Steven Patterson, Neiko Levenhagen

Chemistry Faculty Research & Creative Works

This study explores additive manufacturing of carbon fiber-reinforced thermoplastic composites using the Composite-Based Additive Manufacturing (CBAM) process. Carbon/Nylon 12 and Carbon/PEEK composites were fabricated and evaluated through mechanical (compression, tensile, flexural, and impact) and thermal (DSC and TGA) tests. Carbon/PEEK exhibited superior mechanical performance, with 97.5% higher tensile strength, 79.8% higher elastic modulus, and 59.6% higher flexural strength compared to Carbon/Nylon 12. Thermal testing showed that Carbon/PEEK had higher thermal stability, beginning degradation at 350 °C versus 298 °C for Carbon/Nylon. These results indicate that CBAM-fabricated Carbon/PEEK composites are suitable for applications requiring high strength and temperature resistance.

Electrochemically Active Molybdenum Phosphate With Open-Framework Structure, Sutapa Bhattacharya, Milad Aghayi-Anaraki, Nikolay Gerasimchuk, Steven P. Kelley, Amitava Choudhury

Chemistry Faculty Research & Creative Works

Somewhat less investigated, lithium ion containing molybdenum phosphate compounds are synthesized via simple template free hydrothermal method. Single-crystal X-ray diffraction (SCXRD) study reveals that the compounds Li_0.89Mo₂O_1.89F_0.11(PO₄)2(H₂PO₄)·xH₂O (x ≈1) and Li₃Mo₂O₂(PO₄)₃·xH₂O (x ≈1) crystallize in monoclinic C2/m and C2/c space group, respectively. The structures are built of alternate corner-sharing of MoO₆ octahedra and PO₄ tetrahedra forming layers, which are pillared by phosphate groups creating a 3D framework with channels. These …

Atomistic Mechanisms Of Ti3alc2 Etching: Oxidation, Surface Stability, And Selectivity, Valentina Nesterova, Ana Maria Stratulat, Walter Malone, Vadym Mochalin, Majid Beidaghi, Konstantin Klyukin

Chemistry Faculty Research & Creative Works

Mechanisms governing MAX-phase etching set the properties and stability of resulting MXenes, yet the details of this complex process remain poorly understood. Combining thermodynamic analysis of surface chemistries with ab initio molecular dynamics and enhanced free-energy sampling, we directly model elementary steps at the MAX/etching solution interface. We find that purely thermodynamic analysis overestimates etching selectivity, which is governed by the kinetics of elementary reaction steps. Our calculations reveal that initial exposure to water drives localized, thermodynamically favored edge oxidation that seeds MXene-like terminations into the uppermost layers of Ti₃AlC₂ with oxygen occupying the interlayer space between …

Charge Your Clients: Payable Secure Computation And Its Applications, Cong Zhang, Liqiang Peng, Weiran Liu, Shuaishuai Li, Meng Hao, Lei Zhang, Dongdai Lin

Research Collection School Of Computing and Information Systems

The online realm has witnessed a surge in the buying and selling of data, prompting the emergence of dedicated data marketplaces. These platforms cater to servers (sellers), enabling them to set prices for access to their data, and clients (buyers), who can subsequently purchase these data, thereby streamlining and facilitating such transactions. However, the current data market is primarily confronted with the following issues. Firstly, they fail to protect client privacy, presupposing that clients submit their queries in plaintext. Secondly, these models are susceptible to being impacted by malicious client behavior, for example, enabling clients to potentially engage in arbitrage …

The Gradient Puppeteer: Adversarial Domination In Gradient Leakage Attacks Through Model Poisoning, Kunlan Xiang, Haomiao Yang, Meng Hao, Shaofeng Li, Haoxin Wang, Zikang Ding, Wenbo Jiang, Tianwei Zhang

Research Collection School Of Computing and Information Systems

In Federated Learning (FL), clients share gradients with a central server while keeping their data local. However, malicious servers could deliberately manipulate the models to reconstruct clients' data from shared gradients, posing significant privacy risks. Although such Active Gradient Leakage Attacks (AGLAs) have been widely studied, they suffer from two severe limitations: 1) coverage: no existing AGLAs can reconstruct all samples in a batch from the shared gradients; 2) stealthiness: no existing AGLAs can evade principled checks of clients. In this paper, we address these limitations with two core contributions. First, we introduce a new theoretical analysis approach, which uniformly …

Fuzzing Drones For Anomaly Detection: A Systematic Literature Review, Vikas Kumar Malviya, Wei Minn, Lwin Khin Shar, Lingxiao Jiang

Research Collection School Of Computing and Information Systems

Drones, also referred to as Unmanned Aerial Vehicles (UAVs), are becoming popular today due to their uses in different fields and recent technological advancements which provide easy control of UAVs via mobile apps. However, UAVs may contain vulnerabilities or software bugs that cause serious safety and security concerns. For example, the communication protocol used by the UAV may contain authentication and authorization vulnerabilities, which may be exploited by attackers to gain remote access over the UAV. Drones must therefore undergo extensive testing before being released or deployed to identify and fix any software bugs or security vulnerabilities. Fuzzing is one …

A Review Of Chinese Sentiment Analysis: Subjects, Methods, And Trends, Zhaoxia Wang, Donghao Huang, Jingfeng Cui, Xinyue Zhang, Seng-Beng Ho, Erik Cambria

Research Collection School Of Computing and Information Systems

Sentiment analysis has emerged as a prominent research domain within the realm of natural language processing, garnering increasing attention and a growing body of literature. While numerous literature reviews have examined sentiment analysis techniques, methods, topics and applications, there remains a gap in the literature concerning thematic trends and research methodologies in sentiment analysis, particularly in the context of Chinese text. This study addresses this gap by presenting a comprehensive survey dedicated to the progression of research subjects, methods and trends in sentiment analysis of Chinese text. Employing a framework that combines keyword co-occurrence analysis with a sophisticated community detection …

Graphite Particles Modified By Zno Atomic Layer Deposition For Li-Ion Battery Anodes, Ahmad Helaley, Han Yu, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Graphite, with a modest specific capacity of 372 mA h g−1, is a stable material for lithium-ion battery anodes. However, its capacity is inadequate to meet the growing power demands because the formation of an irregular solid electrolyte interphase (SEI) can result in unstable performance. In this research, we used a few cycles of atomic layer deposition (ALD) to deposit ZnO on graphite particles as an anode with improved electrochemical stability. Transmission electron microscopy revealed that ZnO was in the form of nanoparticles due to the inert surface properties of graphite and only a few cycles of ALD. Electrochemical characterization …

Experimental Investigation Of Heat Transfer Behavior In Spouted Bed Reactors Under Different Operating Conditions, Hasan A. Abdulwahab, Abbas J. Sultan, Amer A. Abdulrahman, Hasan Sh Majdi, Haydar A.S. Aljaafari, Zahraa W. Hasan, Laith S. Sabri, Bashar J. Kadhim, Jamal M. Ali, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Abstract: Spouted bed reactors (SBRs) are highly valued for their effectiveness in chemical and biochemical processes due to their mixing and heat transfer capabilities. Understanding the heat transfer mechanisms in these reactors is necessary. This research delves into the heat transfer behavior of SBRs, which plays a role in enhancing their performance under operational conditions. The study conducted experiments to measure the heat transfer coefficient (HTC) at varying gas velocities (ranging from 0.32 to 0.74 m/s) at radial positions (r/R = 0, ±0.28, ±0.56, and ±0.85) and axial levels (H/D = 0.8, 2.1, and 3.5) within the spouted bed (SB) …

Florida’S Shift From Swing State To Republican Solid State, Alex Alonso Toledo

Honors Undergraduate Theses

This thesis seeks to understand better the changes in Florida’s recent state-level politics. Florida has recently been considered a competitive state on the national political stage, but in the last few years, it has favored the Republican Party. Using publicly-available data and information from databases allows me to lay the foundation for investigating the shift towards the Republican Party in the state. It is important to research this topic to show why specific political strategies adopted can cause significant changes in the political environment, thereby affecting how the public views and supports political parties.

Evaluating Coffee And Caffeine Intake In Adults With Cardiovascular Disease: A Comparative Literature Review, Adam Harrington

Honors Undergraduate Theses

Coffee is among the most commonly consumed beverages worldwide, and its bioactive components, including caffeine, affect the cardiovascular system through multiple physiological mechanisms. Patients with cardiovascular disease are typically advised to limit coffee and caffeine consumption because of potential cardiovascular harm, but emerging research challenges this recommendation. This review evaluates recent evidence regarding consumption of whole coffee, caffeine, or decaffeinated coffee in adults with established cardiovascular disease. Database searches conducted across three platforms for studies published after December 2021 yielded 360 records. Following screening against inclusion criteria, 11 studies were reviewed included in the final review. The studies showed variable …

Road Dependence And Inventory Challenges: A Case Study Of Danone Brazil’S Dairy Supply Chain., Karollyne Nakanishi

Business ETD Collections

The research examines the Danone Brazil raw milk supply chain through the Poços de Caldas factory which operates with more than 1,200 employees and functions as a key facility in Latin America. The research investigates two main questions about how Brazilian road-based transportation affects raw milk inventory stability and which localized tools or emerging technologies would enhance supply reliability.

The research design combined survey data from 42 participants with three interviews. The study reveals that stockouts and overstock and waste occur frequently because of poor road conditions and seasonal disruptions and limited local autonomy which results in monthly milk rejection …

Retention Strategies Of Disney+ In Saturated Streaming Markets: A Case Study Of Ireland., Suelen Aleixo Matos

Business ETD Collections

The global streaming video-on-demand (SVOD) industry has undergone rapid transformation in recent years, with Disney+ emerging as a major competitor following its launch in 2019. Despite achieving exceptionally fast subscriber growth in its early stages, the platform now faces increasing retention challenges in mature and saturated markets such as Ireland, where competition and subscription fatigue have become key constraints on further expansion. Evidence from the Irish market indicates high levels of subscription penetration alongside stabilising or declining growth rates, with increasing patterns of subscription cycling and service cancellation driven by cost sensitivity, underuse, and the availability of multiple competing platforms. …

Optimising Student Recruitment And Brand Awareness At Icot College Through Culturally Targeted Advertising And Social Media Strategies., Uchral Ganbold

Business ETD Collections

In today’s competitive higher education landscape, institutions increasingly rely on digital marketing strategies to attract and retain international students. ICOT College, an English Language Training provider in Ireland, faces challenges in recruiting and engaging a diverse international student base due to limited culturally tailored advertising and underutilisation of social media platforms. The global education sector has become more competitive following COVID-19, with students adopting more selective and research-driven approaches when choosing institutions. However, ICOT’s current marketing approach remains largely generic, lacking localisation, targeted messaging, and interactive digital engagement. This reduces its effectiveness in connecting with key international markets and weakens …

Countries As Laboratories: Reflections On Sierra Leone’S Amended Anti-Human Trafficking Law, Andrea L. Dennis

Scholarly Works

Sierra Leone’s improved anti-trafficking laws align with global norms, but enforcement remains weak due to socio-economic realities and Western deterrence mismatches, limiting effective prosecution despite recent legislative reforms.

Transunion, Vermont Agency, And Statutory Damages Under Article Iii, Randy Beck

Scholarly Works

The Supreme Court concluded in TransUnion LLC v. Ramirez that a plaintiff may not sue to collect statutory damages under a statute like the Fair Credit Reporting Act (FCRA) simply because the defendant violated a right Congress conferred on the plaintiff. Instead, Article III requires the plaintiff to show that the statutory violation resulted in a “concrete” injury with “a ‘close relationship’ to a harm ‘traditionally’ recognized as providing a basis for a lawsuit in American courts.” The TransUnion Court made no effort to explain how its conclusion could be reconciled with Vermont Agency of Natural Resources v. United States …

Streamlining Digital Elevation Model Construction From Historical Aerial Photographs: The Impact Of Reference Elevation Data On Spatial Accuracy, Xin Hong, Christopher H. Roosevelt

All Works

This study proposes a streamlined workflow for producing historical digital elevation models (hDEMs) from scanned 1950s aerial photographs using structure-from-motion and multi-view-stereo (SfM-MVS) techniques along with co-registration methods. We also conducted a sensitivity analysis to assess the impact of DEM references with varying spatial resolutions on the SfM-MVS process and co-registration accuracy. The DEM references included a 30 m SRTM DEM (low resolution), a 12 m TanDEM-X DEM (medium resolution), and a 5 m DEM provided by the General Directorate of Mapping of the Ministry of National Defense, Republic of T & uuml;rkiye (high resolution). Results indicate that higher resolution …

Science Education In The Age Of Misinformation, Elissar Gerges

All Works

No abstract provided.

Zynfluencers: Decoding The New Wave Of Nicotine Culture On Tiktok, Abbie Walls, Page D. Dobbs, Susana Rodriguez Gongora

2025 Research Poster Competition

Significance: This research is crucial for understanding how ZYN, a leader in the rapidly growing nicotine pouch market, influences younger generations through platforms like TikTok. With the nicotine pouch industry projected to grow from $1.99 billion in 2022 to $22.98 billion by 2030, ZYNfluencers play a key role in shaping trends, building brand loyalty, and attracting new users. This phenomenon poses a challenge to tobacco control policies, as marketing strategies targeting youth—potentially with modified risk claims—could undermine efforts to limit nicotine's appeal. By examining ZYN’s impact on social media, this study highlights the need for updated regulations to address the …

University Students' Understanding And Utilization Of Food Labels: A Cross-Sectional Study, Sharifa Alblooshi, Linda Smail, Asya Aldayyani, Falak Zeb, Alia Ibrahim

All Works

Introduction: This study is aimed at investigating Zayed University students' knowledge, attitudes, and practices (KAPs) regarding food labels and at identifying key predictors of food label use through logistic regression analysis.Methods: This quantitative cross-sectional study used a validated questionnaire to elicit data on KAPs regarding the use of nutritional information and food labels. This study was conducted from January to May 2023 in the UAE among students from Zayed University. A total of 1153 students aged 18 and above from Zayed University participated in the study. They were recruited using snowball sampling. Descriptive statistics were obtained using the Statistical Package …

Designing Ai To Foster Acceptance: Do Freedom To Choose And Social Proof Impact Ai Attitudes Among British And Arab Populations?, Sameha Alshakhsi, Mohamed Basel Almourad, Areej Babkir, Dena Al-Thani, Ala Yankouskaya, Christian Montag, Raian Ali

All Works

This study examines the impact of two key AI modalities–freedom of choice (FoC) and social proof (SP)–on public attitudes toward AI, focusing on cultural differences between UK and Arab participants. FoC refers to the option of selecting a non-AI, possibly human, alternative, while SP means knowing that others have used AI without issues. Four scenarios were designed, combining the presence or absence of these modalities. The context was a customer service chatbot for a telecommunications company, familiar to all participants. A total of 639 participants (316 British and 323 Arab) were introduced to the modalities and then the scenarios in …

The Passing Of A Giant In Proteoglycan Research: Robert J. Linhardt (1953–2025), Renato V. Iozzo, Fuming Zhang, Paul L. Deangelis

Department of Pathology, Anatomy, and Cell Biology Faculty Papers

No abstract provided.

Historic Rock Hill Collection - Accession 1844, Historic Rock Hill, Rock Hill, Sc, White Family, Rock Hill History

Manuscript Collection

The Historic Rock Hill Collection consists of materials relating to the history of Rock Hill, South Carolina and its notable historic buildings, businesses, and people. The collection also documents the pioneering White Family of Rock Hill as well as the history of Historic Rock Hill, a nonprofit historical preservation organization headquartered at the historic White Home in Rock Hill, SC. Founded in the 1980s as the Midtown Preservation Association, the group continues to work to preserve and promote the many historic sites and stories of Rock Hill through preservation projects and educational programming. HRH records (by-laws, newsletters, agendas, etc.), …