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2024

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A New-Type Deep Learning Model Based On Shapley Regulation For Containerized Freight Index Prediction, Yen-Chang Shih, Ming-Shue Lin, Taih-Cherng Lirn, Jih-Gau Juang Jan 2024

A New-Type Deep Learning Model Based On Shapley Regulation For Containerized Freight Index Prediction, Yen-Chang Shih, Ming-Shue Lin, Taih-Cherng Lirn, Jih-Gau Juang

Journal of Marine Science and Technology–Taiwan

In this study, we have crafted an innovative methodology that represents a groundbreaking synthesis of deep learning techniques with cooperative game theory. In this study, we use the accuracy of data prediction by different LSTM models as a measurement index and assign different LSTM models corresponding weights through the Shapley value calculation method to construct a more accurate predictive analysis model. We use this improved Shapley regulation model to calibrate a long short-term memory (LSTM) neural network by using historical freight data to predict the China Container Freight Index (CCFI), the leading export container freight index commonly used in China. …


Applicability Of Reducing Valve Timing Overlap For Diesel Engines Under High Exhaust Back Pressure, Chien-Cheng Chen, Yuan-Liang Jeng, Shun-Chang Yen Jan 2024

Applicability Of Reducing Valve Timing Overlap For Diesel Engines Under High Exhaust Back Pressure, Chien-Cheng Chen, Yuan-Liang Jeng, Shun-Chang Yen

Journal of Marine Science and Technology–Taiwan

The exhaust back pressure of diesel engines becomes increasing higher nowadays. As an example, the De-NOx system and DE-SOx system necessitated by the increasingly stringent emission standards, would result in increased exhaust back pressure for those diesel engines adopting such systems. Some ships adopt underwater exhaust system to save space on the working deck and to reduce noise and air pollution, while the hydrostatic pressure under water level has made the exhaust back pressure of diesel engines getting much higher. Under high exhaust back pressure, to keep discharging exhaust unhindered and operating smoothly for diesel engine, it often results in …


Elimination Of Noise In A Ship Cabin Using Multi-Layered Acoustic Boards: An Apso And Sa Approach, Min-Chie Chiu, Ho-Chih Cheng Jan 2024

Elimination Of Noise In A Ship Cabin Using Multi-Layered Acoustic Boards: An Apso And Sa Approach, Min-Chie Chiu, Ho-Chih Cheng

Journal of Marine Science and Technology–Taiwan

A high level of noise, combined with pure tones, is often encountered in ship's cabins, leading to severe psychological and physiological issues for the crew. To address this problem, an indoor noise abatement solution becomes necessary that utilizes efficient acoustic boards integrated with resonators, positioned along the inner walls of the cabin. However, the thickness of the acoustic boards must be strictly limited due to maintenance and operational considerations. This limitation results in insufficient sound absorption capabilities and a restricted range of tuned frequencies, as the resonating frequency of a standard Helmholtz resonator is closely tied to its cavity. A …


Numerical Study On The Aerodynamic Performance Of Four Flettner Rotors By Varying Distance And Spin Ratio, Janghoon Seo, Dong-Woo Park Jan 2024

Numerical Study On The Aerodynamic Performance Of Four Flettner Rotors By Varying Distance And Spin Ratio, Janghoon Seo, Dong-Woo Park

Journal of Marine Science and Technology–Taiwan

The Flettner rotor is a wind-assisted propulsion system applied in eco-friendly ship to reduce greenhouse gas emissions. As the requirements of international regulations on greenhouse gas emissions become increasingly strict, multiple Flettner rotors are being applied, necessitating the evaluation of their performance with varying design parameters. The present study focuses on the aerodynamic performances of four Flettner rotors with variable design parameters of distance and spin ratio. Distances and spin ratios, including relative spin ratios, are considered. The drag and lift coefficients and lift-to-drag ratio of Flettner rotors are determined using Computational Fluid Dynamics (CFD), and the associated flow fields …


Contemporary Challenges And Regulatory Improvements Regarding “Temporary Passengers” On Ro-Ro Ships: A Case Study From South Korea, Junghwan Choi, Sangseop Lim Jan 2024

Contemporary Challenges And Regulatory Improvements Regarding “Temporary Passengers” On Ro-Ro Ships: A Case Study From South Korea, Junghwan Choi, Sangseop Lim

Journal of Marine Science and Technology–Taiwan

The coastal shipping industry plays a crucial role in Korea’s industrial development by transporting essential goods for citizens and bulk shipments that are the backbone of national key industries from 28 trade ports and 22 coastal ports nationwide to inhabited islands. Since the revision of the Ship Safety Act in 2007, cargo truck drivers have been boarding the Ro-Ro (Roll-on, Roll-off) cargo ships along with the cargo as temporary passengers. However, persistent concerns have been raised about the human and cargo safety aspects of this practice in coastal shipping. This study aims to examine these issues and propose improvements to …


Underwater Image Enhancement Algorithm For Dual Color Spaces, Xingsheng Shen, Yalin Song, Shichang Li, Xiaoshu Hu Jan 2024

Underwater Image Enhancement Algorithm For Dual Color Spaces, Xingsheng Shen, Yalin Song, Shichang Li, Xiaoshu Hu

Journal of Marine Science and Technology–Taiwan

Targeting issues related to low contrast, blurring, and loss of detail prevalent in underwater image enhancement algorithms, we propose a dual-color space multiscale residual network (DMR-SCNet) based on SCNet. First, we introduce the HSV color space feature extraction module, which aims to optimize the color representation and saturation of underwater images. Subsequently, we propose the RGB color space denoising module, which focuses on repairing the content and structure of underwater images to enhance their clarity and visual quality. Finally, by designing the residual attention (RAB) module, we aim to further refine the detailed representation and feature extraction of underwater images. …


A Novel Identity Authentication Mechanism For Unmanned Maritime Vessels Communication Based On Mitre Att&Ck Framework, Junxian He, Shih-Hao Chang Jan 2024

A Novel Identity Authentication Mechanism For Unmanned Maritime Vessels Communication Based On Mitre Att&Ck Framework, Junxian He, Shih-Hao Chang

Journal of Marine Science and Technology–Taiwan

With the development of the smart shipping industry, unmanned vessel technology is rapidly evolving, accompanied by a demand for robust Internet of Things (IoT) communication security practices. Key communication technologies for the operation of unmanned vessels include external vessel communication. One crucial aspect is the verification of the identities of the parties involved in these communication systems, as this ensures secure and trusted interactions between unmanned vessels and port management authorities. Identity authentication plays a vital role in ensuring the secure communication of unmanned vessels.This paper aims to analyze potential risks related to identity authentication technology in unmanned vessel communication …


Corrigendum To “Applicability Of Reducing Valve Timing Overlap For Diesel Engines Under High Exhaust Back Pressure” Jan 2024

Corrigendum To “Applicability Of Reducing Valve Timing Overlap For Diesel Engines Under High Exhaust Back Pressure”

Journal of Marine Science and Technology–Taiwan

No abstract provided.


Distribution And Population Structure Of Corallivorous Drupella Snails In The Coral Reefs Of Kenting In Taiwan, Chih-Jui Tan, Dun-Ru Kang, Li-Lian Liu Jan 2024

Distribution And Population Structure Of Corallivorous Drupella Snails In The Coral Reefs Of Kenting In Taiwan, Chih-Jui Tan, Dun-Ru Kang, Li-Lian Liu

Journal of Marine Science and Technology–Taiwan

The corallivorous Drupella snails are common predators of living hard corals in the Indo-Pacific Ocean, and they can significantly threaten coral reef ecosystems when outbreaks occur. In Taiwan, a Drupella outbreak, which resulted in the dramatic decline of Acropora and Montipora corals, was reported in Penghu in 2002 – 2009. However, the Drupella species involved was not identified, and no further research has been conducted. To obtain current knowledge on the predation pressure of corallivorous snails on hard corals, we investigated benthic communities and the distribution and population structure of Drupella snails in the coral reefs of Kenting, Taiwan. The …


Evaluating The Connectivity Reliability Of The Seaborne Transportation Network Using Uncertainty Theory, Tianshou Liu, Haiyang Bian, Lin Feng, Chenyang Fan, Chaojun Ding, Grifoll Manel, Hongxiang Feng Jan 2024

Evaluating The Connectivity Reliability Of The Seaborne Transportation Network Using Uncertainty Theory, Tianshou Liu, Haiyang Bian, Lin Feng, Chenyang Fan, Chaojun Ding, Grifoll Manel, Hongxiang Feng

Journal of Marine Science and Technology–Taiwan

The shipping network serves as the backbone of international trade. However, due to unstable geopolitical conditions, unexpected events have occurred frequently in recent years that have impacted the global shipping supply chain, and this has placed enormous pressure and had adverse effects on seaborne transportation. To measure the reliability of the global shipping network under unexpected events, we abstract the global shipping network into a small world network using uncertainty theory. A method is proposed for selecting (i) the optimal reliable path and (ii) the optimal reliable path with a maximum measurement under different confidence intervals. Our approach is then …


Mechanical Property Analysis And Three-Dimensional Reverse Reconstruction Based On Corrosion Pit Characteristics Of Strong Corrosion Steel Plate, Qiujun Ning, Xiaosong Lu, Jiawei Lu Jan 2024

Mechanical Property Analysis And Three-Dimensional Reverse Reconstruction Based On Corrosion Pit Characteristics Of Strong Corrosion Steel Plate, Qiujun Ning, Xiaosong Lu, Jiawei Lu

Journal of Marine Science and Technology–Taiwan

To investigate the strong corrosion effect of 36% industrial hydrochloric acid on Q370 steel for bridges at room temperature. The surface morphology variations of the Q370 steel for bridges with corrosion time were measured and analyzed using a three-dimensional non-contact scanning profilometer. Subsequently, the standard monotonic tensile test was carried out to obtain the load-displacement curve and analyze the mechanical properties of the heavily corroded steel. Moreover, the constitutive model parameters of the heavily corroded steel were optimized. Furthermore, the heavily corroded steel model base on the actual corroded surface morphology was established, employing three-dimensional reverse reconstruction technology and finite …


Sea Ice Identification And Risk Assessment For Navigation In Ice Regions Based On Shipboard Camera Images, Tsung-Hsuan Hsieh, Xuan Lu, Shengzheng Wang, Wei Liu, Jianan Luo Jan 2024

Sea Ice Identification And Risk Assessment For Navigation In Ice Regions Based On Shipboard Camera Images, Tsung-Hsuan Hsieh, Xuan Lu, Shengzheng Wang, Wei Liu, Jianan Luo

Journal of Marine Science and Technology–Taiwan

In order to guarantee the safe navigation of vessels in icy regions and effectively capture sea ice risk information surrounding ships, this study introduces a sea ice identification and risk assessment process utilizing shipboard camera images. Firstly, based on the distribution characteristics of sea area, a hierarchical region segmentation algorithm is proposed to precisely remove interference factors and extract the region of interest. Then, a multivariate K-means clustering algorithm is proposed to classify sea ice classes based on various characteristics, including spatial similarity, sea ice area, sea ice thickness, gray scale, and other multivariate information. Finally, a method for small …


Optimization On Container Drayage Scheduling In Stochastic Time-Dependent Network, Qi Xu, Jie Huang, Xingyue Chen, Rui Cheng, Xiangyu Yin, Zhongzhen Yang Jan 2024

Optimization On Container Drayage Scheduling In Stochastic Time-Dependent Network, Qi Xu, Jie Huang, Xingyue Chen, Rui Cheng, Xiangyu Yin, Zhongzhen Yang

Journal of Marine Science and Technology–Taiwan

To ensure a reliable operation of container drayage transport system, this paper investigates the drayage scheduling problem in a stochastic time-dependent network. Based on the theory of the robust optimization, a mathematical model considering the attributes of “synchronized operation of multi machines” is built with the aim of minimization of the schedule delay in the whole system. A Simulated Annealing algorithm with Embedded Heuristics (SAEH) is designed for model solution. Comparisons between the results from the robust optimization and traditional expected value approach, and the results from the SAEH and CPLEX are conducted. Based on that, the effectiveness of our …


Offshore Vertical Axis Wind-Photovoltaic Power Plants: Development And Case Study, Victor V. Cheboxarov, Pavel N. Kuznetsov, Shun-Han Yang, Shiu-Wu Chau Jan 2024

Offshore Vertical Axis Wind-Photovoltaic Power Plants: Development And Case Study, Victor V. Cheboxarov, Pavel N. Kuznetsov, Shun-Han Yang, Shiu-Wu Chau

Journal of Marine Science and Technology–Taiwan

This paper examines the potential for the development and implementation of hybrid wind-solar power plants utilizing large-scale offshore vertical-axis wind turbines. The proposed solution aims to increase energy production and reliability through the integration of photovoltaic modules directly into the wind turbine structure. Schematics of photovoltaic modules on the upper annular surface of the respective wind turbine are considered. The operation of the hybrid power plant is described. Equations to estimate the power characteristics of the plant are given. The case study analyzes the potential energy production of a hybrid marine power plant with a diameter of 200 m at …


Harvest By Autoflocculation, Biomass, And Carotenoid Production In Sequential Batch Culture Of Haematococcus Pluvialis Under High Ionic Strength And Macroelements Content, J. Galán-González, I. Quintero-Zapata, M Elías-Santos, L.J. Galán-Wong, U.J. López-Chuken, C Guajardo-Barbosa, J.C Beltrán-Rocha Jan 2024

Harvest By Autoflocculation, Biomass, And Carotenoid Production In Sequential Batch Culture Of Haematococcus Pluvialis Under High Ionic Strength And Macroelements Content, J. Galán-González, I. Quintero-Zapata, M Elías-Santos, L.J. Galán-Wong, U.J. López-Chuken, C Guajardo-Barbosa, J.C Beltrán-Rocha

Journal of Marine Science and Technology–Taiwan

Haematococcus pluvialis is a microalga with significant potential due to its capacity to produce carotenoids with antioxidant and nutraceutical benefits. However, the cost of harvesting this microalga, constituting over 30% of total expenses in large-scale production, is a major concern. Efficient flocculation, aiding in cell separation from the culture medium, is crucial to address this issue. The study contrasted Bold’s Basal Medium (BBM) with Lopez-Chuken & Young nutrient solution (LC-Y). The heightened salt content in LC-Y plays a crucial role in fostering saline stress, which is essential for evaluating H. pluvialis flocculation, biomass yield, and carotenoid production. To assess stability …


Research Progress On Ship Trajectory Prediction In Marine Transportation, Xiangen Bai, Kai Ye, Xiaofeng Xu Jan 2024

Research Progress On Ship Trajectory Prediction In Marine Transportation, Xiangen Bai, Kai Ye, Xiaofeng Xu

Journal of Marine Science and Technology–Taiwan

The prediction of ship navigation trajectories is crucial for ensuring maritime navigation safety and forecasting risk. In recent years, extensive research has been conducted on the prediction of ship navigation trajectories at home and abroad, and some results have been achieved. At present, most research on ship navigation trajectory prediction relies heavily on automatic identification system (AIS) data and the historical trajectories of ships. This study first reviews the research background and current situation of ship navigation trajectory prediction. Second, it provides an overview of ship navigation trajectory prediction, with an emphasis on sorting out and elaborating on artificial intelligence …


Numerical Investigations On Particle Collection And Discharge Of Rounded Rectangle Aquaculture Tank In Dual-Diagonal-Inlet Layout, Xiaozhong Ren, Shupeng Du, Hangfei Liu, Xianying Shi, Meng Li, Xian Wang, Suping Liu Jan 2024

Numerical Investigations On Particle Collection And Discharge Of Rounded Rectangle Aquaculture Tank In Dual-Diagonal-Inlet Layout, Xiaozhong Ren, Shupeng Du, Hangfei Liu, Xianying Shi, Meng Li, Xian Wang, Suping Liu

Journal of Marine Science and Technology–Taiwan

To improve the space utilization rate of aquaculture tanks in aquaculture facilities and investigate the effect of the length-width ratio parameter (abbr. L/W, with L being the length of the tank and W being its width) on the particle collection and discharge characteristics of the rounded rectangle aquaculture tank with diagonal double inlet pipes. The study simulates the particle discharge procedure of the tank using a solidliquid two-phase numerical model (discrete phase model and RNG k-ε turbulence model adopted). The validity of the numerical model was confirmed through physical experiments. The simulation results for two jet condition indicate that when …


On The History And Semantics Of Burble In Aerodynamic Theory, Benjamin C. Moulton, Cory D. Goates, Troy A. Abraham Jan 2024

On The History And Semantics Of Burble In Aerodynamic Theory, Benjamin C. Moulton, Cory D. Goates, Troy A. Abraham

Mechanical and Aerospace Engineering Student Publications and Presentations

The term burble has been in use in aerodynamic theory for over a century. While burble may be unfamiliar to most contemporary aerodynamicists, the word has a rich history based in aerodynamic theory and experimentation. The present paper outlines the fluidity of burble's meaning over time. From analyzing subsonic flow over an airfoil, to the implementation of stochastic turbulence in aircraft carrier landing simulations, the term burble has had a significant impact on the study of aerodynamics. The term burble has fallen out of use in aerodynamic engineering circles. Why did this happen? And what can be learned from the …


Movement For Quality Government V. Knesset, Esther Hayut, Yael Willner, Alex Stein, Gila Canfy-Steinitz, Yechiel Meir Kasher, Noam Sohlberg, David Mintz, Yosef Elron, Isaac Amit, Ruth Ronnen, Uzi Vogelman, Khaled Kabub, Anat Baron, Ofer Grosskopf, Daphne Barak-Erez Jan 2024

Movement For Quality Government V. Knesset, Esther Hayut, Yael Willner, Alex Stein, Gila Canfy-Steinitz, Yechiel Meir Kasher, Noam Sohlberg, David Mintz, Yosef Elron, Isaac Amit, Ruth Ronnen, Uzi Vogelman, Khaled Kabub, Anat Baron, Ofer Grosskopf, Daphne Barak-Erez

Translated Opinions

Movement for Quality Government v. Knesset concerned challenges to Amendment No. 3 to Basic Law: The Judiciary (the “reasonableness amendment”). In view of the controversy surrounding the amendment and the fundamental constitutional question it raised in regard to the Supreme Court’s jurisdiction to review Basic Laws, the Court took the unprecedented step of sitting en banc. A translation of the official abstract issued by the Court appears here.

On January 1, 2024, a majority of the Court (12 of 15 justices) held that the Court held the authority to conduct judicial review of Basic Laws and to intervene in …


Movement For Quality Government In Israel V. The Knesset, Esther Hayut, Yael Willner, Alex Stein, Gila Canfy-Steinitz, Yechiel Meir Kasher, Noam Sohlberg, David Mintz, Yosef Elron, Isaac Amit, Ruth Ronnen, Uzi Vogelman, Khaled Kabub, Anat Baron, Ofer Grosskopf, Daphne Barak-Erez Jan 2024

Movement For Quality Government In Israel V. The Knesset, Esther Hayut, Yael Willner, Alex Stein, Gila Canfy-Steinitz, Yechiel Meir Kasher, Noam Sohlberg, David Mintz, Yosef Elron, Isaac Amit, Ruth Ronnen, Uzi Vogelman, Khaled Kabub, Anat Baron, Ofer Grosskopf, Daphne Barak-Erez

Translated Opinions

Movement for Quality Government v. Knesset concerns challenges to Amendment No. 3 to Basic Law: The Judiciary (the “reasonableness amendment”). In view of the controversy surrounding the amendment and the fundamental constitutional question it raised in regard to the Supreme Court’s jurisdiction to review Basic Laws, the Court took the unprecedented step of sitting en banc. We translate here Chief Justice Hayut's majority opinion.

On January 1, 2024, a majority of the Court (12 of 15 justices) held that the Court held the authority to conduct judicial review of Basic Laws and to intervene in exceptional, extreme cases in …


An Accidental Sociologist Learns The Power Of Listening, Jessie Daniels Jan 2024

An Accidental Sociologist Learns The Power Of Listening, Jessie Daniels

Publications and Research

A personal essay by a white sociologist describes her experience with becoming a sociologist and unlearning racism through a qualitative research project in which she had to transcribe interviews with middle-class Black Americans.


Examining The Impact Of Registered Nurse Engagement In Medical Assistant Clinical Competency Development And Team Effectiveness In Ambulatory Care, Colleen Burckin Jan 2024

Examining The Impact Of Registered Nurse Engagement In Medical Assistant Clinical Competency Development And Team Effectiveness In Ambulatory Care, Colleen Burckin

Doctoral Projects

Background

As ambulatory care grows in complexity, there is a growing need to ensure that staff possess a high level of competence and team effectiveness to provide safe, efficient, and cost-effective care. Leveraging the expertise and leadership skills of Registered Nurses (RN) to support the team of unlicensed, Medical Assistants (MA) will be incentivized. With limited knowledge of MA preparation to meet the rapidly changing demands, managers will struggle to build effective teams and look to the impact of RN- supported MA onboarding to bridge skill gaps.

Purpose

To examine this issue, a quasi-experimental, quality improvement study was done to …


2024 Conference Program, Georgia Southern University Jan 2024

2024 Conference Program, Georgia Southern University

SoTL Commons Conference

Conference program for 2024


Protecting The Innocent: How To Prevent The Consequences Of Misidentification And Doxing By Volunteers Helping With Open Source Investigations, Leigh M. Dannhauser Jan 2024

Protecting The Innocent: How To Prevent The Consequences Of Misidentification And Doxing By Volunteers Helping With Open Source Investigations, Leigh M. Dannhauser

Catholic University Journal of Law and Technology

Individuals performing open source investigations can misidentify alleged perpetrators and dox innocent parties online, which can subsequently lead to threats and harassment against innocent parties and their loved ones. For example, threats were made against Sunil Tripathi’s family after he was wrongly identified as one of the Boston Marathon bombers and doxed on Reddit and Twitter. In 2020, the Berkeley Protocol on Digital Open Source Investigations was published as a guide, and it includes a set of principles to govern open source investigations. However, the Berkeley Protocol is limited to open source investigations performed by those working for organizations. It …


Common Data Set, 2023-2024, Planning, Research, And Policy Analysis Jan 2024

Common Data Set, 2023-2024, Planning, Research, And Policy Analysis

Common Data Set (2001-present)

Common Data Set 2023-2024 for Illinois State University


Volume 69 Masthead Jan 2024

Volume 69 Masthead

Villanova Law Review (1956 - )

No abstract provided.


Biodegradable Polyhydroxybutyrate Microfiber Membranes Decorated With Photoactive Ag-Tio2 Nanoparticles For Enhanced Antibacterial And Anti-Biofouling Activities, Safa Ladhari, Nhu-Nang Vu, Cédrik Boisvert, Marcos Antonio Polinarski, Camille Venne, Alireza Saidi, Simon Barnabé, Phuong Nguyen-Tri Jan 2024

Biodegradable Polyhydroxybutyrate Microfiber Membranes Decorated With Photoactive Ag-Tio2 Nanoparticles For Enhanced Antibacterial And Anti-Biofouling Activities, Safa Ladhari, Nhu-Nang Vu, Cédrik Boisvert, Marcos Antonio Polinarski, Camille Venne, Alireza Saidi, Simon Barnabé, Phuong Nguyen-Tri

Études primaires

Developing advanced materials with antibacterial and antifouling activities offers an adequate protection solution against surface bacterial contamination—a common cause of infection threatening human health. The current work reports the preparation of polyhydroxybutyrate (PHB) microfiber membranes decorated with photoactive Ag-TiO2 nanoparticles using electrospinning coupled with dip-coating methods. The decoration of Ag-TiO2 nanoparticles strongly enhances the antibacterial properties of prepared membranes, particularly under light illumination, thanks to their photocatalytic activity. The best-performing sample exhibits potent antibacterial efficiency exceeding 99% against Escherichia coli and Staphylococcus epidermidis after 3 and 1 h of exposure to low-power commercial LED light, respectively. The prepared samples also …


Host-Defense Piscidin Peptides As Antibiotic Adjuvants Against Clostridioides Difficile, Adenrele Oludiran, Areej Malik, Andriana C. Zourou, Yonghan Wu, Steven P. Gross, Albert Siryapon, Asia Poudel, Kwincy Alleyne, Savion Adams, David S. Courson, Myriam L. Cotten, Erin B. Purcell Jan 2024

Host-Defense Piscidin Peptides As Antibiotic Adjuvants Against Clostridioides Difficile, Adenrele Oludiran, Areej Malik, Andriana C. Zourou, Yonghan Wu, Steven P. Gross, Albert Siryapon, Asia Poudel, Kwincy Alleyne, Savion Adams, David S. Courson, Myriam L. Cotten, Erin B. Purcell

Chemistry & Biochemistry Faculty Publications

The spore-forming intestinal pathogen Clostridioides difficile causes multidrug resistant infection with a high rate of recurrence after treatment. Piscidins 1 (p1) and 3 (p3), cationic host defense peptides with micromolar cytotoxicity against C. difficile, sensitize C. difficile to clinically relevant antibiotics tested at sublethal concentrations. Both peptides bind to Cu2+ using an amino terminal copper and nickel binding motif. Here, we investigate the two peptides in the apo and holo states as antibiotic adjuvants against an epidemic strain of C. difficile. We find that the presence of the peptides leads to lower doses of …


Photoluminescence Switching In Quantum Dots Connected With Fluorinated And Hydrogenated Photochromic Molecules, Ephraiem S. Sarabamoun, Jonathan M. Bietsch, Pramod Aryal, Amelia G. Reid, Maurice Curran, Grayson Johnson, Esther H. R. Tsai, Charles W. Machan, Guijun Wang, Joshua J. Choi Jan 2024

Photoluminescence Switching In Quantum Dots Connected With Fluorinated And Hydrogenated Photochromic Molecules, Ephraiem S. Sarabamoun, Jonathan M. Bietsch, Pramod Aryal, Amelia G. Reid, Maurice Curran, Grayson Johnson, Esther H. R. Tsai, Charles W. Machan, Guijun Wang, Joshua J. Choi

Chemistry & Biochemistry Faculty Publications

We investigate switching of photoluminescence (PL) from PbS quantum dots (QDs) crosslinked with two different types of photochromic diarylethene molecules, 4,4'-(1-cyclopentene-1,2-diyl)bis[5-methyl-2-thiophenecarboxylic acid] (1H) and 4,4'-(1-perfluorocyclopentene-1,2-diyl)bis[5-methyl-2-thiophenecarboxylic acid] (2F). Our results show that the QDs crosslinked with the hydrogenated molecule (1H) exhibit a greater amount of switching in photoluminescence intensity compared to QDs crosslinked with the fluorinated molecule (2F). With a combination of differential pulse voltammetry and density functional theory, we attribute the different amount of PL switching to the different energy levels between 1H and 2F molecules which result in different potential barrier …


The A²Π–X²Σ⁺ Band System Of Yo, Peter F. Bernath, Manish Bhusal, Adam Pastorek Jan 2024

The A²Π–X²Σ⁺ Band System Of Yo, Peter F. Bernath, Manish Bhusal, Adam Pastorek

Chemistry & Biochemistry Faculty Publications

YO bands are conspicuous in the spectra of S stars. The laboratory spectrum of the A2Π–X2Σ+ electronic transition has been recorded with a Fourier transform spectrometer using a composite-wall hollow cathode lamp source. The A2Π–X2Σ+ transition with v ' ≤ 4 and v'' ≤ 4 has been rotationally analyzed using the modern spectral fitting program PGOPHER. Vibronic band strengths were calculated using an ab initio transition dipole moment function. A line list for the A2Π–X2Σ+ transition is provided and can be utilized in the modeling …