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Cross-Kingdom Interactions Shape Soil Biogeochemistry In Natural And Agricultural Ecosystems, Jennifer Lynne Kane

Graduate Theses, Dissertations, and Problem Reports (ETD)

Microorganisms influence life on earth in innumerable ways, including in medical, industrial, environmental, and agricultural contexts. Given the increasingly apparent consequences of climate warming, interest in how to better predict and manage Earth’s carbon sinks has never been greater. Soil, the largest terrestrial carbon sink, harbors an incredibly taxonomically and functionally diverse microbial community. These soil-dwelling microbes govern the fate of soil carbon and nutrients by cycling organic matter as they live, grow, and die. It has only been relatively recently that technological advancement has allowed for in-depth surveys of the vast diversity of soil microbes. High throughput analytical capabilities …

Information As Power: Democratizing Environmental Data, Annie Brett

Utah Law Review

Environmental data systems have largely escaped scrutiny in the past decades. But these systems are the foundations for evaluating environmental priorities, making management decisions, and deciding which perspectives to value. Information is the foundation of effective regulation. The decisions regulators make about gathering, assimilating, and sharing information are, in many cases, determinative of the outcomes they reach. This is certainly true in the case of the environment.

This paper looks at how current environmental regulation has created data systems that undermine scientific legitimacy and systematically prevent stakeholder participation in environmental decision-making. These data systems concentrate power within federal and state …

Constitutional Authority, Common Resources, And The Climate, Anthony Moffa

Utah Law Review

History, text, and precedent reveal an understudied and underutilized source of constitutional authority for environmental protection—the Property Clause of Article IV, Section 3. The Clause vests Congress with the “Power to dispose of and make all needful Rules and Regulations respecting the Territory or other Property belonging to the United States.” This work re-examines these words, the context in which they were written, and the limited judicial decisions interpreting them with an eye towards increased congressional reliance on the Property Clause in the face of daunting threats to our natural environment. Much prior scholarly explanation of the Property Clause focused …

The Late Onset Of Emotional Distress In People With Progressive Multiple Sclerosis During The Covid-19 Pandemic: Longitudinal Findings From The Cogex Study, Anthony Feinstein, Maria Pia Amato, Giampaolo Brichetto, Jeremy Chataway, Nancy D. Chiaravalloti, Gary Cutter, Ulrik Dalgas, John Deluca, Rachel Farrell, Peter Feys, Massimo Filippi, Jennifer Freeman, Matilde Inglese, Cecilia Meza, Robert W. Motl, Maria Assunta Rocca, Brian M. Sandroff, Amber Salter

School of Health Professions

Objective: An earlier follow-up study from the CogEx rehabilitation trial showed little change in symptoms of depression, anxiety and psychological distress during the first COVID-19 lockdown compared to pre-pandemic measurements. Here we provide a second follow-up set of behavioral data on the CogEx sample. Methods: This was an ancillary, longitudinal follow-up study in CogEx, a randomized controlled trial of exercise and cognitive rehabilitation in people with progressive MS involving 11 centres in North America and Europe. Only individuals impaired on the Symbol Digit Modalities Test (SDMT) were included. Participants repeated the COVID Impact survey administered approximately a year later and …

Synergistic Effects Of A Domestic (Thiacloprid Based) Neonicotinoid Pesticide And Nitrogen, Phosphorus And Potassium Fertiliser On Common Earthworms (Lumbricus Terrestris)., Tristan Holmes

School of Biological and Marine Sciences Theses

Neonicotinoids are designed to target insect pests, but their extensive use and long persistence in soils mean that non-target soil organisms such as earthworms are likely to be chronically exposed to them. The common use of neonicotinoids in agricultural systems makes them highly likely to come into contact with other agro-chemicals that may give rise to synergistic effects. Chronic exposure of common earthworm (Lumbricus terrestris) to neonicotinoids in single or combined use with inorganic NPK fertiliser may pose problems that are not accounted for in most biological risk assessments under laboratory conditions. To assess the impacts of such chronic exposure …

Snake Community Ecology And Conservation In Cusuco National Park, Honduras, George Lonsdale

School of Biological and Marine Sciences Theses

The Mesoamerican biodiversity hotspot is threatened with agriculture related deforestation and global climate change, both of which drive widespread changes in forest composition. As the forests change, so too does the community of animals they can support; of which many reptiles have evolved micro-niches specific to these forests. Studying how these anthropogenic pressures affect the assemblages of animals that can persist there, could be vital in understanding how biodiversity will be affected on a global scale. Cusuco National Park (CNP), Honduras, is one of the most important protected sites worldwide for herpetofauna biodiversity, due to having such a high diversity …

A Socio-Economic And Ecological Approach To Informing Sustainable Marine Management In Jersey, Channel Islands, Samantha Robyn Blampied

School of Biological and Marine Sciences Theses

Marine ecosystems support human life in multi-faceted ways and are depended on for food and income by many coastal communities. However, marine habitats are being altered by anthropogenic pressures, influencing the diversity and distribution of species, including species that are relied upon by commercial fisheries. Destructive fishing practices such as dredging and trawling can have adverse impacts on the seabed and associated species through the degradation and fragmentation of benthic habitats. Spatial management of marine areas is required to mitigate impacts, with Marine Protected Areas (MPAs) being advocated as tools that can not only protect and restore biodiversity but also …

A Phenotypic And Genomic Investigation Of The Identity And Variation In The European Dark Bee (Apis Mellifera Mellifera), Victoria G Buswell

School of Biological and Marine Sciences Theses

Apis mellifera (the Western honey bee) is a predominantly human managed pollinator consisting of different evolutionary lineages each containing a number of subspecies. Apis mellifera is threatened by various factors for example, parasites, viruses and pesticide use. The native subspecies of the British Isles Apis mellifera mellifera is additionally threatened by introgression resulting from the importation of foreign subspecies perceived to have more desirable characteristics. This thesis investigates the integrity of Apis mellifera mellifera in the UK and how that can be assessed. Initially, introgression levels over time in a conservation program were assessed. This revealed temporal decreases in introgression, …

Can You See Me, Or Can You Smell Me? An Investigation Into Information Transfer In Betta Splendens, Alex Daniel Lynch

School of Biological and Marine Sciences Theses

Visual communication in Betta splendens has been studied in great detail. Chemical information transfer in this species has been studied less, and the interaction between chemical and visual information transfer less still. Betta may have a need for chemical information transfer; a need which is often neglected when housing this species in isolation from conspecifics. There is evidence that many fish species communicate using visual signals and spy on one another using chemical cues. Which type of information transfer is important and how they interact in which social context is less clear. Eavesdropping and mate choice has been studied extensively …

Investigating The Microbiota Associated With Maerl Beds Located In The Fal Estuary, Cornwall, Anthony Scales

School of Biological and Marine Sciences Theses

The microbiota of maerl has the potential to contain diverse communities of bacteria which are thought to aid in maintaining maerl health and potentially be a driving factor in the settlement and development of ecological and economical important bi-valve species. However, little is currently known regarding the composition and structure of these communities, leading to uncertainty of their importance and their direct association to maerl beds. Using 16s amplicon sequencing analysis, the bacterial community composition associated with live and dead maerl (Phymatolithon calcareum) has been examined and compared to the communities associated with those of the surrounding environment - adjacent …

A Step Towards Automating Real-Time Collection Of Ecological Data On Observational Platforms : A Pilot Study On Deep-Sea Benthic Species Syringammina Fragilissima, Erin Browne

School of Biological and Marine Sciences Theses

Despite current efforts to study deep-sea life, there is a dependency on technological advancements to asses it at a scale and pace required to inform effective management and conservation. Data collection platforms, such as Remotely Operated Vehicles (ROVs) are routinely applied to studying the deep sea due to their ability to collect large image-based datasets. Thus, data collection in the deep sea is becoming less of a problem in comparison to data interpretation, where terabytes of video data is collected during expeditions and manual interpretation of this is currently the standard procedure. Deep learning (DL), a sub-field of artificial intelligence …

Ecological Studies Of The South Atlantic Deep Sea To Inform Sustainable Management, Amelia Bridges

School of Biological and Marine Sciences Theses

Although deep-sea science continues to progress, the southern hemisphere represents a vast and yet understudied area, and the South Atlantic is no exception to this. However, as with other ocean basins, blue growth and the potential for expansion of new and emerging industries mean that information is required to characterise the ecology of the basin to inform sustainable management. Furthermore, novel tools will be required to assist in translating ecological knowledge into usable products that can facilitate marine spatial planning. The aims of this thesis were to contribute to our understanding of the benthic ecology of seamount and oceanic island …

An Interdisciplinary Assessment Of The Mud Crab Scylla Serrata As A Sustainable Livelihood Resource In Southwest India, Elina Apine

School of Biological and Marine Sciences Theses

Fishing and aquaculture are important income-generating activities for coastal communities in India. However, the challenges of climate change and overexploitation have prompted the exploration of new, alternative, sustainable, target species that previously have received little attention. This thesis considers the potential of the mud crab Scylla serrata as a sustainable livelihood resource for local communities in southwest India where currently crab fishing and, particularly, farming is less common compared to southeast India. As fisheries and aquaculture are inherently complex social-ecological systems affected both by biological and socio-economic factors, this thesis has taken an interdisciplinary approach to identify the main barriers …

The Potential Impact Of Macroalgal Generated Hydrogen Peroxide Levels On Co-Occurring Organism In Rock Pools, Agapery Yoane Pattinasarany

School of Biological and Marine Sciences Theses

Abstract Macroalgae have been identified as a potential source of ROS (e.g., hydrogen peroxide) in some rock pools and enclosed habitats; the accumulation of ROS may be harmful to other organisms. Although some studies have found vulnerability to these ROS, there has been little research on the potential impact of photosynthesis-induced oxidative stress on organisms living in rock pools. The aims of this study were to investigate the levels of hydrogen peroxide produced by macroalgae and to assess the effect of similar levels of H2O2 on a rock-pool resident, the snakelocks anemone. The objective of the first experimental chapter was …

Intraspecific Variability In Thermal Tolerance Across Environmental Temperature Gradients In The Intertidal Periwinkle Littorina Saxatilis, Christopher Patrick Dwane

School of Biological and Marine Sciences Theses

Comparisons of thermal tolerance limits of organisms living across environmental temperature gradients represent a valuable means by which to study physiological adaptation. Intertidal organisms are subject to variation in levels of thermal stress both across latitude and shore height. However, our current understanding of how this variation relates to thermal adaptation is largely based on comparisons between species, and we lack a clear picture of the degree to which different populations from the same species display local adaptation along these temperature gradients. In this thesis, I investigate the extent and nature of intraspecific local adaptation of thermal tolerance across shore …

Bias Impedes Progress In Physical Biology, Consciousness Studies And Quantum Gravity, Maurice Goodman

Articles

If scientists hope to make progress in consciousness studies they needs to accept that biased judgments have a major influence on the sciences, how we divide them up, how they are funded and this, in turn, has a profound impact on progress. The imbalance in funding, resulting from bias, in favour of the life and health sciences needs to be addressed as does why perversely little of this funding is devoted to a physics explanation of self-organisation and life on the mesoscopic scale? While life (the cell) is an outstanding example of self-organisation on the mesoscopic scale we need to …

Quantitative Raman Analysis Of Carotenoid Protein Complexes In Aqueous Solution, Joy Udensi, Ekaterina Loskutova, James Loughman, Hugh Byrne

Datasets

Carotenoids are naturally abundant fat-soluble pigmented compounds, with dietary, antioxidant and vision protection advantages. The dietary carotenoids, Beta Carotene, Lutein and Zeaxanthin, complexed with in bovine serum albumin (BSA) in aqueous solution, were explored using Raman spectroscopy to differentiate and quantify their spectral signatures. UV visible absorption spectroscopy was employed to confirm the linearity of responses over the concentration range employed (0.05-1mg/ml) and, of the 4 source wavelengths, 785nm, 660nm, 532nm, 473nm, 532nm was chosen to provide the optimal response. After preprocessing to remove water and BSA contributions, and correct for self-absorption, a partial least squares model with R^{2 …}

Synthesis Of Modified Nanocomposite Material And Its Use On Removal Of Cesium Fromaqueous Media, Bi̇lal Çeti̇n, Mustafa Özcan, Bektaş Karakelle

Turkish Journal of Chemistry

A nanocomposite containing Fe3O4, chitosan (Ch), and hexacyanoferrate (HCF) was synthesized in the form of powder. The physicochemical properties of this nanocomposite are determined using different techniques including Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM). The existence of Cs (Cs) ions onto the surface of the nanocomposite was verified by dispersive X-ray spectroscopy (EDX). FTIR spectra confirmed that the nanocomposite was well coordinated. The batch technique was applied to evaluate the influences of initial pH value, temperature, contact time, shaking rate, initial Cs concentration, and competing cations on the efficiency of Cs …

Virtual Screening, Drug-Likeness Analysis, And Molecular Docking Study Of Potentialsevere Acute Respiratory Syndrome Coronavirus 2 Main Protease Inhibitors, Nikola Nedeljkovic, Milos Nikolic, Ana Stankovic, Nevena Jeremic, Dusan Tomovic, Andriana Bukonjic, Gordana Radic, Marina Mijajlovic

Turkish Journal of Chemistry

Due to the length of time required to develop specific antiviral agents, the World Health Organization adopted the strategy of repurposing existing medications to treat Coronavirus disease 2019 infection. Severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) main protease is possible biological target for potential antiviral drugs. We selected various compounds from PubChem database based on the structure of main protease inhibitors in Protein Data Bank database. Ten compounds showed nontumorigenic and nonmutagenic potential and met Egan's and Lipinski's rules. Molecular docking analysis was performed using AutoDock Vina software. Based on number and type of key binding interactions, as well as …

Recycled Human Hair-Derived Activated Carbon For Energy-Related Applications, Oğuzhan Kotan, Hati̇ce Bayrakçeken

Turkish Journal of Chemistry

Activated carbon, having high surface area and porosity, is a carbonaceous material that comes from organic main sources. In this work, activated carbon materials were produced from human hair that belongs to people who can be classified into two age groups (0-18 or 18-40 years). Activated carbons were characterized by nitrogen adsorption/desorption isotherms (BET), X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Raman spectroscopy, scanning electron microscopy (SEM), and elemental analysis techniques. Capacitances of the synthesized materials were determined by using cyclic voltammetry (CV). Characterization results showed that the structural properties of activated carbon materials and capacitance values are changed …

Investigation Of Biological Activities Of Plant Extract And Green Synthesis Silvernanoparticles Obtained From Gilaburu (Viburnum Opulus L.) Fruits, Bi̇rgütay Şahi̇n, Ali̇ Savaş Bülbül, İbrahi̇m Seyfetti̇n Çeli̇k, Nesri̇n Korkmaz, Ahmet Karadağ

Turkish Journal of Chemistry

In this study, biological activities of silver nanoparticles (AgNP) synthesized by green synthesis method using the fruit extract of Gilaburu (Viburnum opulus L.) plant were investigated. The characterization of the synthesized AgNPs was performed by ultraviolet visible region spectroscopy (UV-Vis), Fourier transform - infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray diffraction (XRD) techniques. The crystal size was found to be 52.32 nm when the XRD data were calculated with the Debye- Scherrer's equation. The antimicrobial activities of extract and AgNPs were investigated by microdilution and disk diffusion methods. Antibiofilm activities were examined by the crystal violet technique. The …

Phytochemical Composition And Pharmacological Activities Of Teucrium Polium L. Collected From Eastern Turkey, Gi̇zem Gülsoy Toplan, Fati̇h Göger, Turgut Taşkin, Gülay Ecevi̇t Genç, Ayşe Ci̇vaş, Gökalp İşcan, Mi̇ne Kürkçüoğlu, Afi̇fe Mat, Kemal Hüsnü Can Başer

Turkish Journal of Chemistry

Teucrium species that belong to the family Lamiaceae have been traditionally used for their medicinal properties. T. polium is one the most widespread members of the genus for its use in the treatment of several diseases. In this study, the essential oil and phenolic composition of the aerial parts from T. polium were assessed by GC-FID, GC/MS, and LC-MS/MS as well as for its total phenolic content. Several extracts such as n-hexane, chloroform, methanol, and infusion were prepared and their antimicrobial, antioxidant, and also acetylcholinesterase activities were studied. According to GC/MS results, β -caryophyllene (8.8%), t-cadinol (6.2%), (E)-nerolidol (5%), α …

Selective Catalytic Hydrogenation Of Cellulose Into Sorbitol With Ru-Based Catalysts, Ceren Orak, Aycan Sapmaz, Asli Yüksel Özşen

Turkish Journal of Chemistry

Sorbitol is one of the platform chemicals and can be produced from various renewable and sustainable sources via different processes. Hydrothermal liquefaction is an effective and promising approach to produce sorbitol, since the subcritical reaction media and appropriate catalysts provide a selective production of platform chemicals. In this study, sorbitol was produced from different renewable sources (cellulose and glucose) in the presence of Ru-based catalysts (Ru/SiO2, Ru/AC, Ru/SBA-15, and Ru/SBA-15-SO3) under subcritical conditions. The highest cellulose conversion was achieved as 90% in the presence of Ru/SBA-15-SO3 for 1 h of reaction duration. The highest sorbitol yield (%) by hydrothermal liquefaction …

Fluorometric Determination Of Ornidazole By Using Bsa Coated Copper Nanoclusters As A Novel Turn Off Sensor, Mehmetcan Bi̇lkay, Hayri̇ye Eda Şatana Kara

Turkish Journal of Chemistry

A fluorescent probe based on bovine serum albumin stabilized copper nanoclusters (BSA-CuNCs) was developed for the selective and sensitive determination of ornidazole (ORN). The nanoclusters were synthesized via a one-pot hydrothermal process in basic media. The synthesized and characterized BSA-CuNCs have less than 3 nm particle size and exhibited blue emission at 405 nm when excited at 325 nm. Synthesized and characterized nanoclusters were successfully applied as a turn-off fluorescent probe for the determination of ORN in pharmaceutical dosage forms. The quenching mechanism created an was inner filter effect (IFE). The method was linear in the concentration range of 0.52-13.56 …

Biological Potential Of Copper Complexes: A Review, Jamshaid Ashraf, Muhammad Asad Riaz

Turkish Journal of Chemistry

This review comprises the inorganic compounds particularly metal coordinated complexes, as drugs play a relevant role in medicinal chemistry. It has been observed that copper complexes are potentially attractive as medicinal importance. In this review, the most remarkable achievements of copper complexes undertaken over the past few decades as antimicrobial, antioxidant, enzyme inhibition activity, and anti-cancer agents are discussed. This work was motivated by the observation that no comprehensive surveys of the diversity of biological activities of copper complexes were available in the literature.

Removal Of Cd2+ Metal Ions From Aqueous Solutions By Na-Alginate-Containingcomposite Biosorbent, Ramazan Donat

Turkish Journal of Chemistry

This research is related to the effect of alginate-containing composite biosorbent on the sorption capacity of heavy metal Cd2+ ions. The study aims to determine the character and optimization of the sorption of Na-alginate-containing composite biosorbent on the sorption of heavy metal Cd2+ metal ions in an aqueous solution. Optimum conditions of parameters such as biosorbent amount, pH value effect, concentration effect, contact time, and temperature that affect the sorption of Cd2+ ions were determined. Langmuir, Freundlich, D-R isotherms were applied to the obtained data, and it was noted that the sorption Cd2+ ions are better explained with Freundlich and …

Design, Synthesis, And In Vitro Antitumor Activity Of 6-Aryloxyl Substituted Quinazolinederivatives, Meixia Fan, Lei Yao

Turkish Journal of Chemistry

Quinazoline derivatives are a class of important antitumor drugs known as small molecule inhibitors that include epidermal growth factor receptor (EGFR) inhibitors. Based on the structure of poziotinib, a series of 6-aryloxyl substituted quinazoline derivatives were designed and synthesized. The in vitro antitumor activities of the compounds were evaluated by the 3-(4,5-dimethyl-thiazol-2- yl)2,5-diphenyltetrazolium bromide (MTT) method using the human gastric cancer N87 (HER2), nonsmall-cell lung cancer H1975 (EGFRT790M/L858R), and A549 (EGFRWT) cell lines. The most promising compound 4m exhibited potent antitumoral activities with IC50 values of 6.3 nM and 7.5 nM for N87 and H1975 cell lines, respectively. Meanwhile, it …

Boric Acid And Schiff Base-Based Fluorescent Sensor For Detection Of L-Tryptophan In Milk And Bsa Samples, Ümran Duru Kamaci, Musa Kamaci

Turkish Journal of Chemistry

In the present paper, the fluorescence sensor based on Schiff base and boric acid was developed for easy and rapid detection of L-tryptophan in different samples such as milk and bovine serum albumin. The photoluminescence intensity was measured by using fluorescent measurements and the results indicated that the developed fluorescent sensor was exhibited selective, sensitive, reliable determination against L-tryptophan, and a series of various analytes such as cations, amino acids, and organic compounds were used to investigate the selectivity of the fluorescent chemosensor. The limit of detection and linear range of the chemosensor were calculated as 0.82 μM, and 0.1?500 …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

The 4-(Dimethylaminoalkyl)Piperazine Inhibitors Of Α-Glucosidase: Allosteric Enzyme Inhibition And Identification Of Interacting Chemical Groups, Usman Ghani, Sajda Ashraf, Zaheer Ul Haq, Zafer Asim Kaplancikli, Fati̇h Demi̇rci̇, Yusuf Özkay, Sibtain Afzal

Turkish Journal of Chemistry

In continuation of our interest in identifying new α-glucosidase inhibitors with potential to become antidiabetic drugs, this work focuses on the study of 4-(dimethylaminoalkyl)piperazine-1-carbodithioate derivatives as α-glucosidase inhibitors. The eight heterocyclic piperazine-dithiocarbamate complexes studied in this work contain a variety of substitutions on their benzene ring exhibiting potent, noncompetitive inhibition of α-glucosidase. Dithiocarbamate and piperazine moieties are important pharmacophores with promising therapeutic prospects featuring facilitated drug delivery due to their lipophilic nature in addition to their α-glucosidase inhibitory activity. Enzyme kinetics, molecular dynamics simulations, and docking studies revealed that the target compounds bind to a new allosteric site that is …