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2021

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Reflections On Building And Then Teaching In A Hyflex Classroom At Allard Hall, Douglas C. Harris, Samuel Beswick Jan 2021

Reflections On Building And Then Teaching In A Hyflex Classroom At Allard Hall, Douglas C. Harris, Samuel Beswick

All Faculty Publications

How to teach in a pandemic? This is the question we were forced to answer over the course of a weekend in March when UBC’s physical campus closed and in-person teaching was no longer possible. The pivot to the world of online teaching was abrupt and reactive; there simply wasn’t time to do anything other than keep courses going as best we could, with technology and techniques we were learning as we taught.


Recruiting And Retaining School Psychologists: The Role Of District Level Administrative Supervisors, Ellie L. Young, Rachel Butler, Timothy B. Smith, Sterling Hilton, Alivia Smith Jan 2021

Recruiting And Retaining School Psychologists: The Role Of District Level Administrative Supervisors, Ellie L. Young, Rachel Butler, Timothy B. Smith, Sterling Hilton, Alivia Smith

Faculty Publications

A shortage of school psychologists has been evident since the profession was initially recognized as a distinct field, and there is insufficient research on what current administrative supervisors are doing to address this problem. This qualitative study examined the perceptions of district level administrative supervisors regarding recruitment and retention of school psychologists. Participants reported the following: (a) school psychology graduate programs not producing enough school psychologists, (b) challenges of finding school psychologists to hire, (c) competing with neighboring school districts, and (d) trying to recruit and retain in a worker’s market that favors the school psychologist. These administrative supervisors also …


Non-Consensual Condom Removal In Canadian Law Before And After R. V. Hutchinson, Isabel Grant, Lise Gotell Jan 2021

Non-Consensual Condom Removal In Canadian Law Before And After R. V. Hutchinson, Isabel Grant, Lise Gotell

All Faculty Publications

This paper examines the phenomenon of nonconsensual condom removal (NCCR) and its relationship to sexual assault in Canada. Using empirical studies and the insights of feminist theory, we explore the nature of the harms caused by NCCR and contend that this pervasive practice constitutes sexual assault. We then critique the decision of R v Hutchinson, which held that condom sabotage does not negate subjective consent, ignoring the dignitary harms of NCCR. While lower court decisions before Hutchinson recognized that consent to sex with a condom does not include consent to sex without, courts after Hutchinson have struggled to distinguish the …


Freedom Of Thought At The Ethical Frontier Of Law & Science, Marcus Moore Jan 2021

Freedom Of Thought At The Ethical Frontier Of Law & Science, Marcus Moore

All Faculty Publications

Some of the most compelling contemporary ethical questions surround 21st Century neuroscientific technologies. Among these, neurocognitive intervention technologies allow an unprecedented ability to alter thought. Concerns exist about their impact on individual freedom, behavior and personhood. They could also distort society, eroding core values of dignity, equality, and diversity. Potent laws are needed to anchor regulation in this rising field. The article explores how the long-neglected human right of Freedom of Thought might protect the integrity of the mind at the legal system’s highest level. Sample cases illustrate how it could be given effect ethically and legally to set boundaries …


Em Estimation For Zero- And K-Inflated Poisson Regression Model, Monika Arora, N. Rao Chaganty Jan 2021

Em Estimation For Zero- And K-Inflated Poisson Regression Model, Monika Arora, N. Rao Chaganty

Mathematics & Statistics Faculty Publications

Count data with excessive zeros are ubiquitous in healthcare, medical, and scientific studies. There are numerous articles that show how to fit Poisson and other models which account for the excessive zeros. However, in many situations, besides zero, the frequency of another count k tends to be higher in the data. The zero- and k-inflated Poisson distribution model (ZkIP) is appropriate in such situations The ZkIP distribution essentially is a mixture distribution of Poisson and degenerate distributions at points zero and k. In this article, we study the fundamental properties of this mixture distribution. Using stochastic representation, we …


Repeated Word Production Is Inconsistent In Both Aphasia And Apraxia Of Speech, Tyson G. Harmon, Katarina L. Haley, Kevin T. Cunningham, Adam Jacks, Jessica D. Richardson, Peter E. Turkeltaub Jan 2021

Repeated Word Production Is Inconsistent In Both Aphasia And Apraxia Of Speech, Tyson G. Harmon, Katarina L. Haley, Kevin T. Cunningham, Adam Jacks, Jessica D. Richardson, Peter E. Turkeltaub

Faculty Publications

Purpose: There is persistent uncertainty about whether sound error consistency is a valid criterion for differentiating between apraxia of speech (AOS) and aphasia with phonemic paraphasia. The purpose of this study was to determine whether speakers with a profile of aphasia and AOS differ in error consistency from speakers with aphasia who do not have AOS. By accounting for differences in overall severity and using a sample size well over three times that of the largest study on the topic to date, our ambition was to resolve the existing controversy.

Method: We analyzed speech samples from 171 speakers …


A Deblurring/Denoising Corrected Scintigraphic Planar Image Reconstruction Model For Targeted Alpha Theory, Charles Ross Schmidtlein, Matthew Maroun, Andrzej Krol, Howard Gifford, Lisa Bodei, Joseph O'Donoghue, Ida Häggström, Yuesheng Xu, Si Li Jan 2021

A Deblurring/Denoising Corrected Scintigraphic Planar Image Reconstruction Model For Targeted Alpha Theory, Charles Ross Schmidtlein, Matthew Maroun, Andrzej Krol, Howard Gifford, Lisa Bodei, Joseph O'Donoghue, Ida Häggström, Yuesheng Xu, Si Li

Mathematics & Statistics Faculty Publications

Scintigraphy is a common nuclear medicine method to image molecular target’s bio-distribution and pharmacokinetics through the use of radiotracers and gamma cameras. The patient’s images are obtained by using a pair of opposing large flat gamma ray detectors equipped with parallel-hole lead or tungsten collimators that preferentially detect gamma-rays that are emitted perpendicular to the plane of the detector. The resulting images form an anterior/posterior (A/P) planar image pairs. The obtained images are contaminated by noise and contain artifacts caused by gamma-ray attenuation, collimator penetration, scatter and other detrimental factors. Post-filtering of the images can reduce the noise, but at …


A Foundation For Collaboration: An Analysis Of Robert Schumann’S Dichterliebe, Op. 48, Kailang Zhan Jan 2021

A Foundation For Collaboration: An Analysis Of Robert Schumann’S Dichterliebe, Op. 48, Kailang Zhan

Graduate Theses, Dissertations, and Problem Reports (ETD)

This paper provides an analysis of Robert Schumann’s Dichterliebe offering historical information and insights into each of the sixteen songs. The analysis includes the English translation of the texts and discussion of the form of each song as well as highlights of the special moments of harmonic, rhythmic, and melodic structure in relation to Schumann’s setting of each poem. The analysis provides a foundation for collaborative skills for the singer and pianist for the study and performance of Dichterliebe. In addition, the paper includes brief biographies of Robert Schumann and Heinrich Heine and background information on the poetry and …


Dynamic Optimization Algorithms For Baseload Power Plant Cycling Under Variable Renewable Energy, Rebecca Hyen Hae Kim Jan 2021

Dynamic Optimization Algorithms For Baseload Power Plant Cycling Under Variable Renewable Energy, Rebecca Hyen Hae Kim

Graduate Theses, Dissertations, and Problem Reports (ETD)

The growing deployment of variable renewable energy (VRE) sources, such as wind and solar, is mainly due to the decline in the cost of renewable technologies and the increase of societal and cultural pressures. Solar and wind power generation are also known to have zero marginal costs and fuel emissions during dispatch. Thereby, the VRE from these sources should be prioritized when available. However, the rapid deployment of VRE has heightened concerns regarding the challenges in the integration between fossil-fueled and renewable energy systems. The high variability introduced by the VRE as well as the limited alignment between demand and …


Discriminative Stimulus Effects Of Cannabidiol Oil In Rats, Rebecca L. Chalme Jan 2021

Discriminative Stimulus Effects Of Cannabidiol Oil In Rats, Rebecca L. Chalme

Graduate Theses, Dissertations, and Problem Reports (ETD)

Cannabidiol (CBD) is one of the major centrally active phytocannabinoid components of cannabis, and has been approved by the FDA only for the treatment of two rare seizure disorders. However, CBD has been touted as a potential treatment for anxiety in place of more traditional treatments like benzodiazepines. Although there is some evidence of anxiolytic effects of CBD, its suitability as a substitute for benzodiazepines is unknown. This experiment was designed to assess to what extent CBD shares interoceptive discriminative-stimulus properties with the anxiolytic chlordiazepoxide (CDP), a benzodiazepine. In the present experiment, a range of doses (0-333.3 mg/kg) of over-the-counter …


Improving Characterization Of Small Molecules Using Enhanced Molecular Reaction And Ionization Techniques, Sandra N. Majuta Jan 2021

Improving Characterization Of Small Molecules Using Enhanced Molecular Reaction And Ionization Techniques, Sandra N. Majuta

Graduate Theses, Dissertations, and Problem Reports (ETD)

Metabolomics is an emerging “omics” field, which is comprised of the study of small molecule metabolites in biological systems. It can be argued that the abundances of metabolites within biological samples, such as tissue and plasma, are indicative of various physiological states. Thus, metabolomics analysis has the potential in the clinical scientific field to be an effective tool for early disease diagnosis as well as for proposing and monitoring new treatments for diseases. However, full characterization of the metabolome complement is often hampered by the wide diversity of metabolites, which also exhibit an extremely large concentration range in biological samples. …


Perceptions Of Integrated Mental And Behavioral Health In Pediatric Specialty Care Settings: A Mixed-Methods Study, Desireé Nicole Williford Jan 2021

Perceptions Of Integrated Mental And Behavioral Health In Pediatric Specialty Care Settings: A Mixed-Methods Study, Desireé Nicole Williford

Graduate Theses, Dissertations, and Problem Reports (ETD)

Pediatric patients are at an increased risk of experiencing mental and behavioral health concerns, which have direct associations with HRQOL, physiological health, and likelihood that youth will engage in health promoting behavior. Researchers and practitioners have increased their awareness of these concerns and identified strategies for improving the mental and behavioral health of these youth, specifically via implementing organizational efforts (i.e., task forces) and guidelines around integrating psychosocial screening and other services into routine practice. Despite this, there are several identified barriers to families receiving mental/behavioral health care in these settings. These barriers exist at all levels, including at the …


An Analysis Of Coordinated Responding, Brian Katz Jan 2021

An Analysis Of Coordinated Responding, Brian Katz

Graduate Theses, Dissertations, and Problem Reports (ETD)

Experimental analyses of coordinated responding (i.e., cooperation) have been derived from a procedure described by Skinner (1962) in which reinforcers were delivered to a pair of subjects (a dyad) if both responded within a short interval, thus satisfying a mutual-reinforcement contingency. Although it has been suggested that this contingency enhances rates of temporally coordinated responding, limitations of past experiments have raised questions concerning this conclusion. The present experiments assessed three of those limitations by holding the schedule of reinforcement (Experiment 1: fixed-ratio 1; Experiment 2; variable-interval 20 s) constant (1) across phases and (2) between dyad members, and (3) varying …


The Road Less Traveled: Economic Analysis Of Roads And Highways, Margaret C. Bock Jan 2021

The Road Less Traveled: Economic Analysis Of Roads And Highways, Margaret C. Bock

Graduate Theses, Dissertations, and Problem Reports (ETD)

Roads are an integral component of civilization, connecting people, markets, and ideas. In different settings and geographies, roads can take on many different purposes. In rural, more isolated areas, roads can serve as a cost-saving benefit and can be used as tools to increase accessibility. In urban, more congested areas, roads can be seen as an externality-producing hindrance. Naturally, given this view, the overall analysis of roads should reflect these different settings. To date, however, the study of roads in the economics literature has surprisingly large pitfalls, notably in terms of topics of study and methodologies used.

Spending on roads …


An In Vitro Comparison Of Shear Bond Strength Between Two Orthodontic Light-Curable Adhesive Pastes, Stephanie Becker Jan 2021

An In Vitro Comparison Of Shear Bond Strength Between Two Orthodontic Light-Curable Adhesive Pastes, Stephanie Becker

Graduate Theses, Dissertations, and Problem Reports (ETD)

Background and Objectives: A relatively new light-cure orthodontic adhesive BracePaste® can fluoresce under UV light to assist in cleaning up excess flash after bonding. Complete removal of excess resins around the bonded brackets may minimize excessive loss of enamel upon debonding. The objective of this study was to determine the shear bond strength of BracePaste compared to that of the conventional “Transbond XT” adhesive. Additionally, enamel and bracket interfaces were examined to determine the location of bond failure and the tooth surfaces were visually examined to assess severity of enamel marks and the presence of remaining adhesives on the …


The Development And Distinction Of Emerging School Professionals: Boundary Work Of Guidance Counselors And School Psychologists, Madison E. Wilson Jan 2021

The Development And Distinction Of Emerging School Professionals: Boundary Work Of Guidance Counselors And School Psychologists, Madison E. Wilson

Graduate Theses, Dissertations, and Problem Reports (ETD)

As a compulsory part of our society, schools are a prominent institution in the United States and abroad. In a system with multiple domains of specialized professionals, it is important to define their roles, determine where there is overlap, and assess if both professions are functioning to best assist students. This study examines the boundary work and professionalization of two emerging mental health professions within the school system: guidance counselors and school psychologists. Thematic analysis of the boundary work in the editorials of each professions’ flagship journal show that much of the boundary work between the journals is similar and …


An In-Depth Exploration Of Hospital-Based Physical And Occupational Therapists’ Needs, Perceptions And Participation In A Safe Patient Handling And Mobility Program, Kimeran W. Evans Jan 2021

An In-Depth Exploration Of Hospital-Based Physical And Occupational Therapists’ Needs, Perceptions And Participation In A Safe Patient Handling And Mobility Program, Kimeran W. Evans

Graduate Theses, Dissertations, and Problem Reports (ETD)

Introduction - Patient mobility performed in the hospital setting places healthcare workers at high risk for WMSDs. The healthcare industry has responded through the creation of SPHM programs that are successful in reducing work-related injuries broadly. However, less is known about the distinct experiences of rehabilitation professionals. Therefore, an in depth exploration of the perceptions, participation, and needs pertaining to lift equipment usage among rehabilitation professionals was performed.

Methods – A qualitative case study approach explored this bounded system. Six focus groups were conducted with 25 members of the rehabilitation team and three interviews were conducted with key administrative personnel. …


Property Rights, Consequences Of Electrical Blackouts, And Measures Of Institutional Quality, Kerianne Nicole Lawson Jan 2021

Property Rights, Consequences Of Electrical Blackouts, And Measures Of Institutional Quality, Kerianne Nicole Lawson

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation is comprised of three essays. Chapter 1 is about a house titling program, called Khaya Lam, in South Africa. Despite it being legal in South Africa to acquire a title deed to a government-issued home, roughly 20 million South Africans do not hold title to their property. Millions of homes are eligible to have ownership transferred from the government to the individuals living in them, but legal costs and lack of awareness keep these renters from going through the steps to secure title deeds. Though they may occupy the property for years, without a title deed South Africans …


An Examination Of The Start Now Dialectical Behavior Therapy-Based Intervention Plus A Behavioral Level System On Male Inmate Misbehavior, Aggressive Behavior, And Mental Health, Victoria Disciullo Jan 2021

An Examination Of The Start Now Dialectical Behavior Therapy-Based Intervention Plus A Behavioral Level System On Male Inmate Misbehavior, Aggressive Behavior, And Mental Health, Victoria Disciullo

Graduate Theses, Dissertations, and Problem Reports (ETD)

The purpose of this study was to evaluate the impact of the START NOW program + behavioral level system (BLS) in a self-contained therapeutic community (SCTC) on inmate misbehavior at a correctional facility in a southern state. The SCTC includes the START NOW manualized mental health treatment, recreation groups, process groups as needed, and additional positive reinforcement to target inmate prosocial behavior (i.e., level system to obtain privileges). Inmate data was evaluated at 3-months pre-START NOW intervention and 3-months post-START NOW intervention to determine if there were differences in the number of referrals to mental health services for misbehavior, write-ups …


Gendered Use Of Language In Facebook Status Updates Among Jordanian And American Youths: A Sociopragmatic Study, Ashraf Wenas Al Sad Jan 2021

Gendered Use Of Language In Facebook Status Updates Among Jordanian And American Youths: A Sociopragmatic Study, Ashraf Wenas Al Sad

Graduate Theses, Dissertations, and Problem Reports (ETD)

The study examines the types of speech acts of Facebook status updates that are posted by Jordanian and American youth. The participants were from Yarmouk University which is located in northern Jordan and from West Virginia University which is located in the US. The data was elicited from 50 American males, 50 American females, 50 Jordanian males, and 50 Jordanian females. Searle’s taxonomy was used to do the content analysis of the data. Searle’s taxonomy and additional speech acts were found: directive, expressive, assertive, God’s invocation, humor, and quotation. The findings of the study indicate that the religious and cultural …


Investigation Of Novel Mitoneet Ligand Nl-1 As A Therapeutic For Cerebral Ischemia And Reperfusion Injury, Pushkar Saralkar Jan 2021

Investigation Of Novel Mitoneet Ligand Nl-1 As A Therapeutic For Cerebral Ischemia And Reperfusion Injury, Pushkar Saralkar

Graduate Theses, Dissertations, and Problem Reports (ETD)

Cerebral ischemia reperfusion injury, a common type of stroke, is a neurodegenerative disorder which is the leading cause of permanent disability in the United States. The underlying pathophysiology of ischemic stroke involves an occlusion in the vasculature supplying oxygen and glucose to the brain tissue, leading to infarction and eventual necrosis in the brain. MitoNEET is an outer mitochondrial protein that plays a role in the cellular bioenergetics and its redox physiology. Although its endogenous ligands are under investigation, mitoNEET binds molecules with a thiazolidinedione moiety, such as NL-1. This dissertation investigates NL-1 as a potential cytoprotective agent, and its …


Dynamic Modelling And Control Of Grid-Level Energy Storage Systems, Sai Pushpitha Vudata Jan 2021

Dynamic Modelling And Control Of Grid-Level Energy Storage Systems, Sai Pushpitha Vudata

Graduate Theses, Dissertations, and Problem Reports (ETD)

The focus of this work is on two energy storage technologies, namely pumped storage hydroelectricity (PHS) and secondary batteries. Under secondary battery technologies, two potential technologies for grid-scale storage, namely high-temperature sodium-sulfur (NaS) battery and vanadium redox flow battery (VRFB), are investigated. PHS is a largescale (>100 MW) technology that stores and generates energy by transporting water between two reservoirs at different elevations. The goal is to develop a detailed dynamic model of PHS and then design the controllers to follow the desired load trajectory accurately with high efficiency. The NaS battery and VRFB are advanced secondary batteries which …


Analysis Of Cell Signaling Perturbations In Response To Chronic Localized Infections, Amber Nicole Prince Jan 2021

Analysis Of Cell Signaling Perturbations In Response To Chronic Localized Infections, Amber Nicole Prince

Graduate Theses, Dissertations, and Problem Reports (ETD)

The tissue-level response to pathogens involves an intricate series of signal transduction events, influenced by immune and healing mediators that alert the host to danger and eliminate the infection. Disruptions to normal signaling events can compromise the host’s ability to respond and lead to the development of chronic infections that cannot be resolved without clinical intervention. Prolonged inflammation due to chronic infection can damage tissues and compromise healing processes, thus, the interactions of immune and healing mediators in signaling cascades are intimately linked to tissue health outcomes. Studying signaling networks relevant to these responses provided a more thorough understanding of …


Kindergarten Entry Assessment Practices In Pennsylvania, Anne Katona Linn Ed.D. Jan 2021

Kindergarten Entry Assessment Practices In Pennsylvania, Anne Katona Linn Ed.D.

Graduate Theses, Dissertations, and Problem Reports (ETD)

In the Commonwealth of Pennsylvania, there is significant variation in kindergarten programs and the entry assessment systems used in school districts. There are no reliable data on the kindergarten entry assessment (KEA) systems used in public kindergarten programs across the Commonwealth. It is well-established that comprehensive KEAs should be part of a broader preschool through third grade (P-3) continuum of early childhood education to assess whole-child skills, include families and community partners, be culturally and linguistically responsive, and developmentally appropriate. This study aimed to understand the KEA practices of kindergarten teachers in Pennsylvania. An online survey was distributed to kindergarten …


Exposure Therapy: Stimulus Intensity As A Factor In Treatment Preference, Matthew C. Arias Jan 2021

Exposure Therapy: Stimulus Intensity As A Factor In Treatment Preference, Matthew C. Arias

Graduate Theses, Dissertations, and Problem Reports (ETD)

Currently, a host of treatments are available for treating anxiety disorders, including specific phobia. Treatment of specific phobia includes pharmacological, psychosocial, and combined approaches. Exposure therapy, however, is considered the leading psychological treatment for specific phobia, and has shown to be effective. Exposure therapy challenges held beliefs about feared stimuli/situations and attempts to integrate new learning about the feared object/situation. Despite exposure being effective to treat specific phobia, it is associated with low adherence and high dropout rates. There is a need to examine, therefore, ways to improve patient adherence for exposure. A way to examine this issue is to …


Correctional Officer Opinions About Offenders With Mental Illness: The Relationships Among Opinions, Burnout, Emotional Intelligence, And Mental Health Training, Courtney Hull Jan 2021

Correctional Officer Opinions About Offenders With Mental Illness: The Relationships Among Opinions, Burnout, Emotional Intelligence, And Mental Health Training, Courtney Hull

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rates of mental illness among incarcerated individuals in the United States are high and have been well documented. Correctional officers are on the front line of identifying symptoms and alerting mental health professionals to problems as they arise. Correctional officers often lack an understating of mental illness, feel ill-equipped to manage mental health crises, and experience high levels of job-related stress. The objective of this study was to better understand the relationship between correctional officers’ emotional intelligence and opinions about mental illness, and to identify if burnout moderated the relationship between the variables. Additionally, the study sought to understand the …


Population Genetics Of A Reintroduced Fisher (Pekania Pennanti) Population In West Virginia, Caroline E. Harms Jan 2021

Population Genetics Of A Reintroduced Fisher (Pekania Pennanti) Population In West Virginia, Caroline E. Harms

Graduate Theses, Dissertations, and Problem Reports (ETD)

Fishers (Pekania pennanti) were reintroduced in West Virginia in 1969 with no population wide genetic analysis ever having been conducted. Genetic analysis of reintroduced populations is vital to assess genetic diversity as an indicative of population viability. My objective was to collect fisher samples throughout West Virginia, nearby states where fisher may be migrating (PA and NY), and the New Hampshire source population to provide a full genetic interpretation of the reintroduced West Virginia population. Genetic analysis was used to measure genetic diversity, admixture or delineation of subpopulations, and effective population size. Sample location and genetic data were …


Biomechanically Inspired Assistive Technology To Restore Movement Of The Upper Limbs After Stroke, Ariel Thomas Jan 2021

Biomechanically Inspired Assistive Technology To Restore Movement Of The Upper Limbs After Stroke, Ariel Thomas

Graduate Theses, Dissertations, and Problem Reports (ETD)

A stroke often damages the neural structures responsible for movement. Stroke is a heterogeneous disease, affecting each survivor differently. There are common motor features of a stroke, but even these features vary across time as an individual proceeds through different stages of recovery. The different ways in which stroke motor impairment can present itself are often overlooked, but these differences are fundamental to the understanding of the disease and its recovery. When motor assessments are capable of acquiring information necessary to parse out a detailed profile of each stroke case, this will lead to an improved neuromechanical understanding of the …


Accuracy Of Implant Placement Utilizing Stereolithographic Guides Printed With And Without Cross-Arch Stabilization Struts, Caitlin Libby Dds Jan 2021

Accuracy Of Implant Placement Utilizing Stereolithographic Guides Printed With And Without Cross-Arch Stabilization Struts, Caitlin Libby Dds

Graduate Theses, Dissertations, and Problem Reports (ETD)

Objectives: The purpose of this study was to assess the accuracy of implant placement using stereolithographic guides printed with and without stabilization struts by comparing the post-operative position to the planned implant position.

Methods: A pre-operative cone-beam computed tomography (CBCT) of a drillable maxillary model was obtained and data was uploaded into coDiagnostiX for preoperative planning. The implant position was planned in an edentulous space of #5 using a 3.3x10mm Bone Level Tapered (BLT) implant (Straumann). Ten surgical guides were designed utilizing a stabilization strut (Group A), while ten guides were designed without the stabilization strut (Group B). Twenty guides …


Gas Phase Reactions Of Cyclopentadiene With Ch And Oh Radicals, Kacee Lynn Caster Jan 2021

Gas Phase Reactions Of Cyclopentadiene With Ch And Oh Radicals, Kacee Lynn Caster

Graduate Theses, Dissertations, and Problem Reports (ETD)

The formation of polycyclic aromatic hydrocarbons (PAHs) and carbon-based nanoparticles in combustion environments is driven by the pyrolysis and oxidation of abundant fuel molecules. The subsequent growth of these pyrolytic byproducts is then propagated by reactions with small free radical species like OH, CH, O atoms, and C2H. Cyclopentadiene (C5H6) is a significant five-member combustion intermediate that has been detected in many high temperature reactions, such as in the pyrolysis of jet fuels like JP-10. Experimental and theoretical investigations in the reactions of cyclopentadiene with these small free radical species are necessary towards understanding …