Digital Commons Network^™

Structurally And Electronically Diverse Polyanion-Based Cathode Materials For Alkali-Ion Batteries, Prashanth Sandineni

Doctoral Dissertations

”Through this investigation polyanion-based cathode materials including sulfates, phosphates, and phosphites of transition metal have been synthesized for lithium and sodium-ion batteries and their electrochemical performances were evaluated. The emphasis was on soft chemical routes to discover metastable phases which are often missed in high temperature synthesis. Iron-based compounds were the main focus of this investigation, however, concurrently a few vanadium-analogues of iron compounds were investigated to evaluate the effect of multi-electron process on achievable voltage and capacity.

This investigation resulted in the discovery of several compounds with unique crystal structures, namely AFe₃(SO₄)₂(OH)_{6 …}

System Efficient Esd Design Concept For Soft Failures, Giorgi Maghlakelidze

Doctoral Dissertations

"This research covers the topic of developing a systematic methodology of studying electrostatic discharge (ESD)-induced soft failures. ESD-induced soft failures (SF) are non-destructive disruptions of the functionality of an electronic system. The soft failure robustness of a USB3 Gen 1 interface is investigated, modeled, and improved. The injection is performed directly using transmission line pulser (TLP) with varying: pulse width, amplitude, polarity. Characterization provides data for failure thresholds and a SPICE circuit model that describes the transient voltage and current at the victim. Using the injected current, the likelihood of a SF is predicted. ESD protection by transient voltage suppressor …

Behavior Of Negative Stiffness Metamaterial Systems In Structural Engineering Applications, Yasser Darwish

Doctoral Dissertations

“Metamaterial systems with negative stiffness behavior became a point of interest in many energy dissipation applications due to their ability to dissipate high levels of energy. Negative stiffness metamaterial elements can dissipate energy through non-linear elastic behavior when transferred from one stable mode of buckling to another. Hence, the ability of such elements to be reusable for multiple loading cycles exists. Such unique properties made the metamaterial systems a perfect candidate for structural applications such as impact protection of bridges against collision. This research provides innovative metamaterial shell structure that can exhibit negative stiffness behavior by deforming from one shape …

Enhanced Electrochemical Performance Of Li-Ion Battery Cathodes By Atomic Layer Deposition, Yan Gao

Doctoral Dissertations

”Li-ion battery now plays an irreplaceable role in supplying green and convenient energy. In this work, atomic layer deposition (ALD) was used to modify Li-ion battery cathode particles for performance enhancement.

An ultrathin and conductive CeO₂ ALD film was deposited on Li-rich layered cathode particles, of which the specific capacity and cyclic stability were significantly improved. On the same cathode particles, FeO_x ALD and post-annealing resulted in a stable and conductive surface spinel phase to improve the performance.

Synergetic TiN coating and Ti doping were performed on a LiFePO₄ (LFP) cathode and extended its cycle life. The …

Minimizing The Negative Effect Of Pumping On Scc Freeze-Thaw Durability, Daniel Galvez-Moreno

Doctoral Dissertations

“The durability of concrete must be ensured to reduce the carbon footprint of the production of portland cement. If concrete is properly designed to preserve its integrity under adverse exposure conditions, the service life of the material can be extended with minimum maintenance. Nevertheless, bad handling, placing, finishing or curing practices can abate the durability potential and service life of even the best mix design. Pumping concrete is a very efficient placing technique that offers significant cost reduction and versatility at the jobsite, but it also has the potential of altering the air void system parameters, which are key to …

Optimal Adaptive Control Of Time-Delay Dynamical Systems With Known And Uncertain Dynamics, Rohollah Moghadam

Doctoral Dissertations

"Delays are found in many industrial pneumatic and hydraulic systems, and as a result, the performance of the overall closed-loop system deteriorates unless they are explicitly accounted. It is also possible that the dynamics of such systems are uncertain. On the other hand, optimal control of time-delay systems in the presence of known and uncertain dynamics by using state and output feedback is of paramount importance. Therefore, in this research, a suite of novel optimal adaptive control (OAC) techniques are undertaken for linear and nonlinear continuous time-delay systems in the presence of uncertain system dynamics using state and/or output feedback. …

Complexities Observed During The Development Of A Rheological Testing Procedure For Small Cement Paste Samples, Aida Margarita Ley-Hernandez

Doctoral Dissertations

“Rheology has been widely used to describe the flow properties of fresh cement-based suspensions. The use of a rheometer to characterize these properties is not a straightforward task due to the dependency to different preparation conditions, mixing processes, testing procedures and measuring instruments employed. In addition, shear and time dependency of the material which undergoes chemical and physical particle bonding, caused by hydration of cement and flocculation. Nevertheless, the characterization and understanding of the rheological behavior of cement-based materials have become essential with the recent introduction of novel applications like digital construction in the field of civil engineering, among others. …

Analysis And Modeling Of Power Supply Induced Jitter For High Speed Driver And Low Dropout Voltage Regulator, Yin Sun

Doctoral Dissertations

”With the scaling of power supply voltage levels and improving trans-conductance of drivers, the sensitivity of drivers to power supply induced delays has increased. The power supply induced jitter (PSIJ) has become one of the major concerns for high-speed system. In this work, the PSIJ analysis and modeling method are proposed for high speed drivers and the system with on-die low dropout (LDO) voltage regulator. In addition, a jitter-aware target impedance concept is proposed for power distribution network (PDN) design to correlate the PSIJ with PDN parasitic.

The proposed PSIJ analysis model is based on the driver power supply rejection …

Structured Catalysts Designed And Manufactured By 3d-Printing Technique For Functional Integration Of Catalytic Systems, Fatima Magzoub

Doctoral Dissertations

"Microporous zeolites are widely used as heterogeneous catalysts in a wide variety of chemical and petrochemical industries to produce value-added chemicals and fuels, owing to their large surface area, acid-base properties, high thermal stability, and excellent shape-selectivity.

The overall goal of this research was to shape engineer composite zeolites and fine-tune their physiochemical properties to improve the catalytic production of dimethyl ether (DME) and light olefins that are typically used as substitution to diesel fuel and polymer precursors, respectively. Specifically, HZSM-5 and silicalite-1 zeolites were formulated into monolithic contactors using 3D printing technique, followed by subsequent SAPO-34 crystals growth through …

Investigation Of Urea Decomposition And Deposit Formation In Diesel Exhaust After-Treatment System, Anand Alembath

Doctoral Dissertations

“Urea-selective catalytic reduction (SCR) system has proved to be an effective solution to reduce NO_x emissions in commercial vehicle (CV) diesel engines. A significant challenge in urea injection is to comprehend its decomposition chemistry that leads to formation of undesired deposits in the exhaust system unit. Due to complex interaction of multi-phase fluid flow and transport processes, significant uncertainty is associated with the identification of interacting factors that control the deposit initiation and its growth. To meet the future ultra-low NO_x emissions and to deliver ammonia without deposit formation, there is an imminent need to develop the urea-SCR …

Improvising Intellectual Property In Saigon, David A. Bergan

Vanderbilt Journal of Entertainment & Technology Law

How does intellectual property become part of the structure of social practice? The traditional answers are enforcement, education, and incentivized self-interest. This Article challenges that understanding by examining the social field of young engineers in Vietnam. In Ho Chi Minh City, Vietnam, intellectual production is not only about producing the legal commodity we call intellectual property. For many young engineers working with multinational companies, it is not about producing a product at all. It is about improving their position in society. Relying on over a year of qualitative, ethnographic fieldwork from 2012 to 2014, this Article develops a critique of …

Gmo Corn, Mexico, And Coloniality, Ernesto Hernandez-Lopez

Vanderbilt Journal of Entertainment & Technology Law

Genetically modified ("GMO") corn germinates legal controversies in Mexico. Since 2013, Mexican courts have temporarily suspended GMO corn because it threatens biodiversity. In the Colectividad del Maiz lawsuit, courts have prohibited Mexico from issuing commercial GMO permits while the litigation continues. Companies like Monsanto need these permits to sell GMO seeds. Corn is the most essential food item for millions of Mexicans and is central to Mexican culture. Mexicans wait for Colectividad del Maiz's resolution, siding with biodiversity or GMOs. This Article describes scientific GMO controversies and analyzes biosecurity, class-action, and international environmental law. It argues that this corn fight …

The Effects Of Myriad And Mayo On Molecular-Test Development In The United States And Europe: Interviews From The Frontline, Johnathon Liddicoat, Kathleen Liddell, Mateo Aboy

Vanderbilt Journal of Entertainment & Technology Law

US Supreme Court decisions in Mayo Collaborative Services v. Prometheus Laboratories and Association for Molecular Pathology v. Myriad Genetics Inc. caused US and European law on what is patentable subject matter to diverge significantly. Both cases related to molecular tests and changed decades of patent practice. Whether the decisions adversely affect the development of molecular tests in the United States and Europe has been a matter of much speculation but limited empirical investigation. This interview-based study has three main findings. First, Myriad and Mayo have negatively affected the development of some molecular tests. Notably, half of the US university technology-transfer …

People V. Robots: A Roadmap For Enforcing California's New Online Bot Disclosure Act, Barry Stricke

Vanderbilt Journal of Entertainment & Technology Law

Bots are software applications that complete tasks automatically. A bot's communication is disembodied, so humans can mistake it for a real person, and their misbelief can be exploited by the bot owner to deploy malware or phish personal data. Bots also pose as consumers posting online product reviews or spread (often fake) news, and a bot owner can coordinate multiple social-network accounts to trick a network's "trending" algorithms, boosting the visibility of specific content, sowing and exacerbating controversy, or fabricating an impression of mass individual consensus. California's 2019 Bolstering Online Transparency Act (the "CA Bot Act') imposes conspicuous disclosure requirements …

Continuous Viral Vaccine Manufacturing And Viral Detection Strategies, Dylan G. Turpeinen

Dissertations, Master's Theses and Master's Reports

Viruses are responsible for many human diseases that lead to suffering and death. Acquired immunodeficiency syndrome (AIDS), influenza, and coronavirus disease 2019 (COVID-19) have claimed the lives of millions of people. Two methods have been created to reduce the suffering caused by these diseases. The first is the manufacturing of vaccines that prevent disease and the second is the development of virus detection tests that lead to treatment. The work summarized in this dissertation discusses the development of a continuous virus purification process using an aqueous two-phase system for use in vaccine manufacturing. Additionally, two novel virus detection methods were …

Archaeological Investigations At The Quincy Mining Company Office (Tract 102-04) The Quincy National Guard Encampment (Tract 102-03). Keweenaw National Historical Park, Houghton County, Michigan., Gideon Hoekstra

Dissertations, Master's Theses and Master's Reports

This report presents the results of preliminary archaeological research at the Quincy Unit as part of the Cooperative Agreement P18AC00178 between the United States Department of Interior/National Park Service and Michigan Technological University titled An Inventory of Historic Archaeological Resources at Keweenaw National Historical Park (KEWE) and Isle Royale National Park (ISRO). Archaeological investigation concentrated on the lot housing the Quincy Mine Office and the location of the Quincy Michigan National Guard encampment located across US-41 from the No.2 Rockhouse, used during the Copper Country Miners’ Strike of 1913-14. This is a multi-year project, primarily looking at the Quincy Mining …

Role Of Flocculation And Dispersion In Pelletization Of Iron Ore, Victor J. Claremboux

Dissertations, Master's Theses and Master's Reports

Traditional modeling of iron ore pellet strength utilizes micromechanical models such as Rumpf’s equation, which correlate attractive forces and pellet properties into an average expected pellet strength. These models combine with repulsive forces within pellets to predict that pellet strength decreases with the introduction of these forces. However, naïvely applying Rumpf’s equation readily leads to incorrect predictions about the resulting behavior. Pellets created with strong repulsive forces arising from dispersion conditions are observed to be significantly stronger overall than pellets formed in the absence of dispersants. A new model is required to understand and predict the effects of these additives …

Virus-Like Particle Vaccine Manufacturing From Yeast, Ananya Ananya

Dissertations, Master's Theses and Master's Reports

Influenza virus has an intrinsic nature to undergo mutations. Hence, there have been struggles to combat this disease since the time when the worst influenza pandemic first hit in 1918. Vaccines have proved to be effective in controlling the spread of the influenza A virus by providing herd immunity. However, the contemporary design of influenza A virus based on egg and cell-culture is not efficient in tackling influenza A virus transformation. Virus-like particles (VLPs) have established themselves as a potental platform for future vaccine candidates. VLPs have all the credentials to supplant contemporary vaccine designs without compromising on immunogenicity. For …

Vehicle Dynamics Modeling For Autonomous Drifting And Clothoid Based Waypoint Interpolation, Shubham Vatsa

Dissertations, Master's Theses and Master's Reports

The advent of autonomous vehicles necessitates a redefinition of road safety regulations, considering a controller can possess better driving skills than an average person. The work presented here partly focuses on a vehicle dynamics model development to help imitate and control vehicle drifting maneuvers. As we see, a professional driver drifting through the traffic while keeping the car safe, it can be utilized to avoid accidents at high speeds, if required. Although drifting can produce higher yaw rates than the regular driving regime, these control capabilities have not yet been exploited in the current automotive control systems. Therefore, this report …

Linking Energy Efficiency And Public Health: A Case Study Of Illinois, Azat Turegeldin

Dissertations, Master's Theses and Master's Reports

A growing body of research has established the connection between emissions from fossil fuels and severe impacts on human health, such as asthma attacks in children and adults and chronic cardiovascular problems. This work evaluates in monetary terms the implementation of two energy-saving scenarios. Illinois, as a state with high coal electricity generating content, has been chosen as a case study to quantify the impacts brought up by air pollution on public health. The potential benefits of improved air quality and health are the considered results of implemented energy efficiency technologies. This report is a culmination of a summer internship …

Thermodynamic Investigations Of Pure And Blended Cement Mixtures, Jonathan Lapeyre

Doctoral Dissertations

” This research is made up of several studies. The first study focused on understanding the reaction kinetics of Ca₃SiO₅ and metakaolin (MK) mixtures compared to Ca₃SiO₅ and silica fume (SF) mixtures. It was shown that MK was a more effective additive than SF at small replacement levels (i.e. ≥ 10% by mass) while higher replacement levels of MK became a detriment due to excess (Al(OH)₄¯) ions preventing the nucleation and growth of C-S-H. In a follow-up study where the MK particle size distribution (PSD) was modified, similar effects were observed but …

An Investigation Of The Impact Of A Stem Program On Students’ Knowledge On Interest In Stem, Danielle Dean

Dissertations, Master's Theses and Master's Reports

The objective of the study was to investigate middle school students’ attitudes towards Science, Technology, Engineering, and Math (STEM), as well as their knowledge about engineering practices. A quantitative design was employed with a total of 51 participants randomly assigned to two conditions. 24 students took a STEM elective course and the other 27 an equivalent course with a career focus on forensics as a career.

Over nine weeks participants took a pre and post survey on attitudes and completed a project that was assessed using a common rubric. The results on gains in student attitude were mixed. On the …

Study Of Silica Nanoparticle Composite On Silica-Hydrogen Peroxide Complexations And Their Effects In Catechol Based Adhesives, Rattapol Pinnaratip

Dissertations, Master's Theses and Master's Reports

Mussel adhesive proteins contain catechol moiety, which allows the protein to crosslinked, solidify, and adhere to surrounding surfaces even under wet conditions. Incorporating the catechol moiety into polymeric adhesive resulted in bioadhesive, which still functions under wet conditions. However, the adhesive must be oxidized in order to crosslink and adhere to surfaces. The oxidation process of catechol adhesive was proven to produce singlet oxygen, superoxide, and hydrogen peroxide (H₂O₂). These reactive oxygen species, with lack of control, can wreak havoc to the biological system causing poor healing and undesired biological response.

Here, we studied the silica …

Measurement Of Current Distribution In The Land Channel Direction Of A Proton Exchange Membrane Fuel Cell, Chinmay Kulkarni

Dissertations, Master's Theses and Master's Reports

A fully functional proton exchange membrane fuel cell with single land channel geometry on the cathode and segmented anode current collector with 9 mm² active area with a 350μm spatial resolution was utilized to measure the local current distribution in the land channel direction. A distinguished printed circuit board approach was used for the data acquisition to adapt to any flow field design.

Performance of this segmented cell was examined at dry, wet and moderate humidity settings to study the water transport phenomenon in the PEMFC. In the dry condition at 60 ͦ C with 0% relative humidity, the …

Assessing The Accuracy Of A Uav Snow Depth Survey: Utqiagvik (Barrow), Alaska Calm Grid, Ian Nichols

Dissertations, Master's Theses and Master's Reports

Active layer depth and snow depth are annually collected across the Circumpolar Active Layer Monitoring (CALM) Network to observe the response of the active layer and near-surface permafrost to climate change over decadal-time scales. Snow depth is typically measured using a graduated steel probe at each grid node but, in this paper, we explore the viability of using Unmanned Aerial Vehicle (UAV) (drone) technology to collect snow depth measurements at the 1 km² Utqiagvik (Barrow), Alaska CALM grid. This is achieved by comparing estimated UAV snow depths to measured snow depths collected using a MagnaProbe (MP) at each of …

Matlabta: A Style Critiquer For Novice Engineering Students, Marissa L. Walther

Dissertations, Master's Theses and Master's Reports

Novice programmers, considered to be those who have yet to understand the fundamentals of programming, exist in both engineering and computing fields. Within computing, various resources exist to help novice programmers understand fundamentals and style guidelines such as WebTA, a code critique program that gives Java students feedback about their error and style issues. There is, however, a gap in automated code critique for MATLAB, a programming language that is popular in the engineering community. When it comes to MATLAB, there are not many programs that help novices understand their errors, and even fewer that help them understand style guidelines. …

Mechanisms Of Pathogen Inactivation In Wastewater And Pharmaceutical Applications, Christa L. Meingast

Dissertations, Master's Theses and Master's Reports

Infectious diseases are a significant threat to public health. Though society enacts practices to prevent the spread of these dangerous diseases, challenges remain. Therefore, continual advancements in treatment and prevention are required. Wastewater treatment and viral clearance in pharmaceutical applications are two key health measures that prevent the spread of infections.

A low-cost, low-technology biosolids treatment process was developed to improve wastewater treatment by collecting key information on storage temperature, ammonia, volatile solids, moisture content, pH, and pathogen inactivation in biosolids over long-term storage at two wastewater treatment plants located in northern climates of the United States. Inactivation of pathogens …

Joint Simulation Of Continuous And Categorical Variables For Mineral Resource Modeling And Recoverable Reserves Calculation, Sentle Augustinus Hlajoane

Dissertations, Master's Theses and Master's Reports

Spatial variability and uncertainty of continuous variables (grade) and categorical variables (rock-types) in mineral evaluation significantly impact the economics of mining projects. The conventional approach of simulating grades using deterministic rock- types is problematic since spatial variability, and uncertainty of grades at rock-type contacts are not well captured in deposits where the grade changes gradually between rock-types. Therefore, jointly simulating these variables can improve confidence (reduce uncertainty) in a resource model. Also, resource classification and recoverable reserve calculation can significantly improve the understanding of the deposit and its economic viability. This research utilized the Plural-Gaussian geostatistical simulation to jointly simulate …

Development Of A Software-Defined Underwater Acoustic Communication System, Zijian Zhu

Dissertations, Master's Theses and Master's Reports

This report started with a brief history and recent development of underwater acoustic communication systems as well as software-defined radio technologies. Then, some challenges from underwater acoustic channels and available underwater acoustic communication modems are discussed. After finished introducing the basics of SDR and GNU Radio, a detailed description of implementing a software-defined acoustic communication system in GNU Radio are presented, along with some key concepts of the system.

Then, some hardware specifications are presented, following by detailed documentation on a software-defined acoustic communication system experiment with a host computer, a USRP, an acoustic hydrophone, and a hydrophone. At the …

Demand-Driven Execution Using Future Gated Single Assignment Form, Omkar Javeri

Dissertations, Master's Theses and Master's Reports

This dissertation discusses a novel, previously unexplored execution model called Demand-Driven Execution (DDE), which executes programs starting from the outputs of the program, progressing towards the inputs of the program. This approach is significantly different from prior demand-driven reduction machines as it can execute a program written in an imperative language using the demand-driven paradigm while extracting both instruction and data level parallelism. The execution model relies on an executable Single Assignment Form which serves both as the internal representation of the compiler as well as the Instruction Set Architecture (ISA) of the machine. This work develops the instruction set …