Digital Commons Network^™

Improving Base Metal Electrowinning, Charles Ebenezer Abbey

Doctoral Dissertations

"In zinc electrowinning, Mn oxidizes to form MnO₂ on Pb-Ag anodes, cell walls and pipes. MnO₂ reduces anode corrosion but also leads to short circuits and maintenance issues. MnO₂ is thought to interact with chloride ions and produce oxidized chlorine species. The interactions between Mn and Cl are not well understood. Bench scale experiments were conducted to investigate the effects of the manganese to chloride ratio on anode corrosion rate and electrolyte chemistry using rolled Pb-Ag anodes. Increasing the average Mn/Cl^- ratio from ~7:1 to ~11:1 reduced the anode corrosion rate. Anode scales produced with Mn/Cl …

Hardware Architectures For Compact Microwave And Millimeter Wave Cameras, Matthew Jared Horst

Doctoral Dissertations

"Millimeter wave SAR imaging has shown promise as an inspection tool for human skin for characterizing burns and skin cancers. However, the current state-of-the-art in microwave camera technology is not yet suited for developing a millimeter wave camera for human skin inspection. Consequently, the objective of this dissertation has been to build the necessary foundation of research to achieve such a millimeter wave camera. First, frequency uncertainty in signals generated by a practical microwave source, which is prone to drift in output frequency, was studied to determine its effect on SAR-generated images. A direct relationship was found between the level …

The Tabu Ant Colony Optimizer And Its Application In An Energy Market, David Donald Haynes

Doctoral Dissertations

"A new ant colony optimizer, the 'tabu ant colony optimizer' (TabuACO) is introduced, tested, and applied to a contemporary problem. The TabuACO uses both attractive and repulsive pheromones to speed convergence to a solution. The dual pheromone TabuACO is benchmarked against several other solvers using the traveling salesman problem (TSP), the quadratic assignment problem (QAP), and the Steiner tree problem. In tree-shaped puzzles, the dual pheromone TabuACO was able to demonstrate a significant improvement in performance over a conventional ACO. As the amount of connectedness in the network increased, the dual pheromone TabuACO offered less improvement in performance over the …

Reliability Analysis For Systems With Outsourced Components, Zhengwei Hu

Doctoral Dissertations

"The current business model for many industrial firms is to function as system integrators, depending on numerous outsourced components from outside component suppliers. This practice has resulted in tremendous cost savings; it makes system reliability analysis, however, more challenging due to the limited component information available to system designers. The component information is often proprietary to component suppliers. Motivated by the need of system reliability prediction with outsourced components, this work aims to explore feasible ways to accurately predict the system reliability during the system design stage. Four methods are proposed. The first method reconstructs component reliability functions using limited …

Plugging Performance Of Preformed Particle Gels In Fractures And Its Influencing Factors, Ze Wang

Doctoral Dissertations

"Preformed particle gels (PPG) has been successfully applied to combat the water channeling caused by fractures or fracture-like channels. Understanding the placement and plugging of PPG in fractures is crucial for gel treatment design. The objective of the dissertation is to explore the plugging performance of three PPG products in two types of fracture models, the partially and fully open fractures. The following studies has been conducted and conclusions have been drawn based on the results and analysis. First, the placement and plugging performance of conventional PPG was investigated using core flooding experiments conducted partially open fractures. The plugging efficiency …

Military Applications Of Geological Engineering, Stephen H. Tupper

Doctoral Dissertations

"This work examines the premise that military engineering and geological engineering are intellectually paired and overlapped in practice to a significant extent. Geological engineering is an established, albeit young, academic discipline that enjoys wide industry and civil demand and is supported by many professional organizations. In contrast, military engineering is an ancient, empirically derived training or "OJT" program with practice-based trade-associations that has narrow government-only utility. The premise is formed by decades-long observation of U. S. Army military engineer officers completing a Master of Science degree in geological engineering as a complement to their practice-based training in military engineering at …

Provenance And Depositional Environments Of The Upper Permian-Lowermost Triassic Fluvial And Lacustrine Sandstones, Wutonggou Low-Order Cycle, Bogda Mountains, Nw China, Dongyu Zheng

Doctoral Dissertations

"This work integrates petrographic and fieldwork studies and documents the spatial and temporal distributions of compositions and textures of the upper Permian-lowermost Triassic fluvial-lacustrine sandstones, Wutonggou low-order cycle (WTG LC), Bogda Mountains, NW China. In the first part, three petrofacies are identified on the basis of the relative abundances of quartz, feldspar, and lithics and conglomerate compositions and paleocurrent directions are documented. These data indicate that rocks of the eastern North Tianshan Suture (ENTS) and rift shoulders were the provenance lithology. Moreover, the upsection changes of petrofacies and conglomerate compositions suggest that the lithology of ENTS changed. During approximately Wuchiapingian, …

Non-Invasive Microwave And Millimeter Wave Reflectometry And Imaging For Human Skin Diagnosis And Materials Characterization, Yuan Gao

Doctoral Dissertations

"Microwave and millimeter wave reflectometry and synthetic aperture radar (SAR) imaging techniques have been successfully applied in many applications, such as nondestructive testing and evaluation (NDT&E), security inspection and medical diagnosis. In this dissertation, the feasibility of using microwave and millimeter reflectometry and SAR imaging for burn diagnosis is investigated through both simulations and measurements, with promising results. To correctly model the interaction between electromagnetic waves and skin, the proper knowledge of the complex permittivity of healthy skin is critically important. To this end, the common used measurement methods for in vivo skin complex permittivity are reviewed and analyzed in …

Nanomorphology Dependent Optical And Mechanical Properties Of Aerogels, Chandana Mandal

Doctoral Dissertations

"Aerogels are very low density, light weight open pore materials. A hypothesis that is under intense current investigation by the scientific community states that the mechanical properties of nanostructured polymers depend on their nanomorphology. Aerogels are nanostructured ultra-lightweight nanoporous materials with skeletal frameworks that can display a wide range of nanomorphologies. Thereby aerogels comprise a suitable platform for testing not only that hypothesis but also a wide range of other properties such as light scattering for applications, for example, in thermally insulating windows.

To study the mechanical properties of nanostructured matter as a function of nanomorphology, various shape-memory polyurethane aerogels …

Passive Harmonic Generation At Spring Contacts, Sen Yang

Doctoral Dissertations

"In the first paper, the RF passive harmonic generation phenomenon on the spring contact is studied. A spring contact harmonic generation measurement system is developed. The factors that may have an impact on the spring contact harmonic generation, such as contact material, contact force, and contact resistance are characterized by the measurement system. The gold-to-gold contact is found to be much superior to the stainless-steel contacts. It is also found that the passive nonlinearity at the spring contact is the semiconductor-like junction formed by the surface oxide film.

In the second paper, we show that the maximum E-field coupling occurs …

A Systems And Cost Analysis Of Human Rated Mars Entry, Descent, And Landing Vehicles, Paul Daniel Friz

Doctoral Dissertations

"Cost is one of the biggest obstacles to sending humans to Mars. However, spacecraft costs are typically not taken into consideration until after the preliminary vehicle and mission concepts have been designed. Once costs have been estimated, managers and project teams often lack confidence that the final cost of the mission will match the preliminary estimates. The present work provides a robust methodology for using cost as a valid metric early in the design phase of future human Mars Entry, Descent, and Landing (EDL) vehicles. This is done in three parts. First, state of the art parametric costing methods are …

Origin Of Periclines In The Ozark Plateau, Missouri: A Field And Numerical Modeling, Chao Liu

Doctoral Dissertations

"A series upright sub-horizontal folds in sandstones of the early Ordovician Roubidoux Formation are exposed in road cuts along US Highway 63 in the northern part of the Salem Plateau of central Missouri for over a distance of approximately 10 km. These folds are in marked contrast to the more typical horizontal to sub-horizontal Ordovician strata of the Ozark Plateau. The origin of those folds remains enigmatic. The inspection of the characteristics of these folds using stereographic analysis revealed a non-cylindrical geometrical pattern than a near cylindrical fold. Structural data of 54 folds indicate an alternating basin and dome pattern. …

Applications Of Machine Learning In Nuclear Imaging And Radiation Detection, Shaikat Mahmood Galib

Doctoral Dissertations

"The main focus of this work is to use machine learning and data mining techniques to address some challenging problems that arise from nuclear data. Specifically, two problem areas are discussed: nuclear imaging and radiation detection. The techniques to approach these problems are primarily based on a variant of Artificial Neural Network (ANN) called Convolutional Neural Network (CNN), which is one of the most popular forms of 'deep learning' technique.

The first problem is about interpreting and analyzing 3D medical radiation images automatically. A method is developed to identify and quantify deformable image registration (DIR) errors from lung CT scans …

Development And Characterization Of Nanostructured Steels And High Entropy Alloys For Nuclear Applications, Andrew Kalevi Hoffman

Doctoral Dissertations

"Nuclear reactor materials are subjected to a harsh environment including high temperatures and radiation fluences. In order to extend the lifetime of current light water reactors (LWRs) and realize the development of advanced Gen IV nuclear reactors new materials must be developed which can withstand such an environment. This thesis involves two approaches to solving this materials problem: advanced manufacturing of current commercial alloys using severe plastic deformation (SPD) and the development of new advanced high entropy alloys (HEAs).

Because SPD is effective at achieving grain refinement, this technique was used to obtain material having a high volume fraction of …

Characterization Of A Green Electric Solid Propellant For Electric Propulsion, Matthew Scott Glascock

Doctoral Dissertations

"Electric solid propellants are advanced solid chemical rocket propellants that can be controlled (ignited, throttled and extinguished) through the application and removal of an electric current. These propellants are also being considered for use in ablative pulsed plasma thruster and multimode systems. In this work, the behavior and performance of a novel green electric solid propellant operating in an electrothermal ablation-fed pulsed plasma thruster was investigated. Using an inverted pendulum micro-Newton thrust stand, the impulse bit and specific impulse of the device using the electric solid propellant were measured for short-duration and long-duration runs to end-of-life, at energy levels of …

Modeling Strategies For Estimating And Suppressing Electromagnetic Interference And Improving Power Integrity, Tamar Makharashvili

Doctoral Dissertations

"Decoupling capacitors are used to suppress high-frequency noise in power distribution networks. The inductance associated with a mounted decoupling capacitor can vary by 26% depending on characteristics of the printed circuit board. Here, simple and accurate inductance models of 2- and 8-terminal capacitors including connections to the power and return plane are developed. Circuit models of the capacitors and layout are created using the partial equivalent element circuit method which provide options for circuit-level simulations as well as analytic estimation of inductance. The circuit solution matches results from the full-wave simulation model within 9% for the 8-terminal capacitor and within …

Fault Imaging Enhancement In Taranaki Basin, New Zealand And Rock Physics And Inversion Based Reservoir Characterization In The Central Gulf Coast Region Of Texas, Tianze Zhang

Doctoral Dissertations

"Fault imaging technique and reservoir characterization based on rock physics analysis and pre-stack inversion has been widely used hydrocarbon exploration. For the fault imaging technique, the ant tracking has been widely used in fault interpretation. However, the reliability of the results is highly dependent on appropriately choosing a signal processing method and volume attributes. In our study area, which lies in the southern Taranaki Basin, we applied Graphic Equalizer as the processing tool and the Chaos attribute before running the ant tracking algorithm. Results show that the procedure provides a better result and can map both the major and minor …

Designing Novel Multinary Transition Metal Selenides As High-Efficiency Oxygen Evolution Reaction Electrocatalysts And Investigating Surface Properties, Xi Cao

Doctoral Dissertations

”Water splitting has been widely considered to be an efficient way to generate sustainable and renewable energy resources in fuel cells, metal-air batteries and other energy conversion devices. Exploring efficient electrocatalysts to expedite the anodic oxygen evolution reaction (OER) is a crucial task that needs to be addressed to boost the practical application of water splitting. This research focuses on the identification of OER electrocatalysts by systematically designing non-stochiometric mixed transition metal-based selenide OER electrocatalysts through combinatorial electrodeposition and investigation of selenide-based naturally occurring minerals as effective OER electrocatalyst. Paper I describes the study of Ni-Fe-Co selenides as OER catalysts …

Numerical Modeling Study Of A Neutron Depth Profiling (Ndp) System For The Missouri S&T Reactor, Mubarak Mohammed Albarqi

Doctoral Dissertations

”For decades, Neutron Depth Profiling has been used for the non-destructive analysis and quantification of boron in electronic materials and lithium in lithium ion batteries. NDP is one of the few non-destructive analytical techniques capable of measuring the depth profiles of light elements to depths of several microns with nanometer spatial resolution. The technique, however, is applicable only to a handful of light elements with large neutron absorption cross sections. This work discusses the possibility of coupling Particle Induced X-ray Emission spectroscopy with Neutron Depth Profiling to yield additional information about the depth profiles of other elements within a material. …

Volumetric Error Compensation For Industrial Robots And Machine Tools, Le Ma

Doctoral Dissertations

“A more efficient and increasingly popular volumetric error compensation method for machine tools is to compute compensation tables in axis space with tool tip volumetric measurements. However, machine tools have high-order geometric errors and some workspace is not reachable by measurement devices, the compensation method suffers a curve-fitting challenge, overfitting measurements in measured space and losing accuracy around and out of the measured space. Paper I presents a novel method that aims to uniformly interpolate and extrapolate the compensation tables throughout the entire workspace. By using a uniform constraint to bound the tool tip error slopes, an optimal model with …

Annual Report: Fy 2019 Quality Of Kerosene And Motor Fuel In Tennessee, Tennessee. Department Of Agriculture

Annual Reports on Kerosene & Motor Fuel Quality

This annual report provides data on the effectiveness of the 1989 Kerosene and Motor Fuels Quality Inspection Act, consumer complaints, inspection data, and a summary of enforcement.

Molecular Dynamics Study Of Creep Deformation In Nickel-Based Superalloy, Sabila Kader Pinky

Graduate Theses/Dissertations

The present study employs molecular dynamics simulations of Ni-based superalloy to investigate the creep behavior under uniaxial compression test. Dislocation dynamics is analyzed for the nickel-based single crystal superalloy with the presence of void and with varying the distribution of gamma-prime phase The results show that multiple-void systems are more prone to yield than single-void systems and single-void systems are more prone to yield than the system without void. From the simulations, it has been determined that the creep mechanism in Ni/Ni3Al is subject to change on the applied stress depending on the distribution of gamma-prime phases change. Dislocation behavior …

Commercial Clicks: Advertising Algorithms As Commercial Speech, Kerri A. Thompson

Vanderbilt Journal of Entertainment & Technology Law

Congressional hearings have finally called for the "right regulation" of social media platforms. The First Amendment, however, has shielded internet companies from regulation since the birth of social media. Even if Congress enacts legislation now, internet companies will be able to defend against the "wrong regulation" by claiming the regulation unconstitutionally limits their freedom of speech. This Article uses Facebook's advertising algorithms as a case study of how Congress can properly regulate Facebook by analyzing the advertising algorithms as commercial speech, which receives less protection under First Amendment jurisprudence. In doing so, Congress can protect the strong public interest in …

Sharing The Costs Of Artificial Intelligence: Universal No-Fault Social Insurance For Personal Injuries, Jin Yoshikawa

Vanderbilt Journal of Entertainment & Technology Law

The twenty-first century is the artificial intelligence (AI) century. In the past few years, AI has become a familiar fixture of everyday life thanks to services like YouTube, Spotify, Netflix, and Alexa. Stocktraders, doctors, insurance brokers, real estate agents, recruiters, artists,and even lawyers now rely on predictive tools powered by AI to perform their highly skilled--even creative--tasks. In the following decades, AI will continue to transform more fields and deliver astonishing advancements in convenience, comfort, safety, and security. At the same time, however, AI will bring about new challenges. AI will offend, disrupt, crash, breach, incite, injure, and even kill …

The Right Of Attribution In Literary Works In Three Acts, By W. Shakespeare, Daniel J. Gervais

Vanderbilt Journal of Entertainment & Technology Law

This Article charts the three phases in the evolution of the norm of attribution in literary works: the norm in England before and during Shakespeare's time, the emergence of authorship-based norms in the Romantic period (allowing moral rights to be enshrined in international copyright treaties) and their demise at the hands of postmodernism and New Criticism, and the current norms that aim to protect the integrity of educational processes and to inform readers and other users of books, plays, or other creative works about their "source." It tracks a debate during Shakespeare's lifetime on the difference between nonattribution and false …

Computational Simulations Of Compressible Transitional Flows In A Turbine Vane Cascade, Alan James Perrault

Mechanical Engineering and Applied Mechanics

In order to improve the efficiency and reduce the emissions of aircraft engines, new combustor designs have been developed to reduce outlet temperatures and increase mixing. At high altitudes, the low pressure and low Reynolds number flow would normally produce a laminar boundary layer on the turbine vanes. The increased turbulence generated by these newer combustors can cause transitional flow on the vane surfaces, which leads to increased heat transfer. Accurate computational simulations can reduce development costs by allowing rapid iteration of designs. Aerodynamic and heat transfer characteristics of the first stage stator vane from a high-altitude UAV has been …

Numerical Analysis Of A Pv/Microchannel Integrated Co2 Direct-Expansion Heat Pump Water Heater, Mohammad Rajib Uddin Rony

Mechanical Engineering and Applied Mechanics

A steady-state numerical model of a PV/microchannel integrated direct-expansion CO2 heat pump (PV-DXHP) water heater is developed, validated, and analyzed in the present study. To accomplish the objectives, a numerical model of a microchannel evaporator integrated into a CO2 PV DXHP is developed and validated. The effects of evaporator operating parameters on the heat absorption and pressure drop are analyzed. Utilizing the evaporator model, the PV-DXHP model is developed, and the baseline values of the heat pump operating parameters are determined from the evaporator parametric study. The PV-DXHP demonstrates high water heating capability, while maintaining a reasonably high COP. The …

Microstructural Characteristics And Mechanical Behavior Of Anticorrosive Al-Zn Thermal Spray Coatings Deposited By Wire Arc Spraying And Cold Spraying Techniques, Amir Darabi Noferesti

Mechanical Engineering and Applied Mechanics

Mechanical properties of thermal spray deposited coatings are highly influenced by their microstructural characteristics. The objective of this investigation is to evaluate the mechanical properties of thermally sprayed coatings consisted of aluminum and zinc based on the coating microstructure, using an image based computational scheme. Microstructural images of coating samples were subjected to image-based finite element analysis and the results were validated by experimental tests and analytical models. Comparison of the experimental data with FEA was used to explain the microstructural basis of the mechanical characteristics of Al-Zn coatings and the differences between two methods of thermal spray techniques. It …

The Fayoum, The Seila Pyramid, Fag El-Gamous And Its Nearby Cities: A Background, Kerry Muhlestein, Cannon Fairbairn, Ronald Harris

Faculty Publications

Because the excavations discussed in this volume take place in the Fayoum, and cover a time period that spans from the Old Kingdom through the Byzantine era, many readers will find it helpful to understand the history, geography, and geology of the Fayoum. Here we provide a brief outline of those subjects. This is not intended to present new information or be a definitive discussion. Rather, it is aimed at contextualizing the rest of the material presented in this volume, and thus making all of its information more accessible. The Fag el-Gamous cemetery and the Seila Pyramid are located on …

Excavations At The Seila Pyramid And Ritual Ramifications, Kerry Muhlestein

Faculty Publications

In modern times it was not apparent that the structure many travelers had seen atop the remote escarpment in Gebel El-Rus was actually a pyramid. Before its excavation it was locally known as el-Qalah, meaning “the fortress,” though it has since come to be called Harem Seila, or the Seila Pyramid. Even before excavation it could be easily seen as far away as Hawara when the air was clear. Though it stood six miles straight west of the Meidum Pyramid, there was nothing about the visible square covered in aeolian sand that would make explorers or archaeologists think it was …