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2017

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Understanding Perceptions Of Barriers To International, Interdisciplinary Scientific Teamwork And The Expansion Of Mexican Oil Palm Plantations, Erin Pischke Jan 2017

Understanding Perceptions Of Barriers To International, Interdisciplinary Scientific Teamwork And The Expansion Of Mexican Oil Palm Plantations, Erin Pischke

Dissertations, Master's Theses and Master's Reports

Understanding the multiple drivers of environmental change is essential for devising strategies for overcoming impacts and planning for the future. Anthropogenic causes and physical impacts of such environmental changes are not fixed in space; thus, it is necessary to conduct international research to solve such problems by integrating multiple disciplinary approaches. My dissertation research examines the public perceptions of socioecological impacts of oil palm production and uncovers barriers that international, interdisciplinary teams face when studying such impacts. In one chapter, I present research that identifies challenges that interdisciplinary researchers are confronted with when working in an international setting. Findings show …


An Algorithm For Reconstructing Three-Dimensional Images From Overlapping Two-Dimensional Intensity Measurements With Relaxed Camera Positioning Requirements, With Application To Additive Manufacturing, Siranee Nuchitprasitchai Jan 2017

An Algorithm For Reconstructing Three-Dimensional Images From Overlapping Two-Dimensional Intensity Measurements With Relaxed Camera Positioning Requirements, With Application To Additive Manufacturing, Siranee Nuchitprasitchai

Dissertations, Master's Theses and Master's Reports

Cameras are everywhere for security purposes and there are often many cameras installed close to each other to cover areas of interest, such as airport passenger terminals. These systems are often designed to have overlapping fields of view to provide different aspects of the scene to review when, for example, law enforcement issues arise. However, these cameras are rarely, if ever positioned in a way that would be conducive to conventional stereo image processing. To address this, issue an algorithm was developed to rectify images measured under such conditions, and then perform stereo image reconstruction. The initial experiments described here …


Multi-Modal And Short-Range Transmission Loss In Ice-Covered, Near-Shore Arctic Waters, Miles B. Penhale Jan 2017

Multi-Modal And Short-Range Transmission Loss In Ice-Covered, Near-Shore Arctic Waters, Miles B. Penhale

Dissertations, Master's Theses and Master's Reports

In the past century, extensive research has been done regarding the sound propagation in arctic ice sheets. The majority of this research has focused on low frequency propagation over long distances. One of the most commonly used excitation methods for air-ice-water layers has been explosives. However, environmental regulation has become more stringent, disallowing the use of almost all explosive excitation types. Due to changing climate conditions in these environments, new experimentation is warranted to determine sound propagation characteristics in, through, and under thin ice sheets, in shallow water, over short distances. In April, 2016 several experiments were conducted approximately 2 …


Developing A Gis Tool For Infinite Slope Stability Analysis (Gis-Tissa), Jonathon Sanders Jan 2017

Developing A Gis Tool For Infinite Slope Stability Analysis (Gis-Tissa), Jonathon Sanders

Dissertations, Master's Theses and Master's Reports

The Probabilistic Infinite Slope Analysis model (PISA-m) is a widely used computer program that uses infinite slope equations to calculate the spatially varying Factor of Safety of slopes. ESRI’s ArcGIS software and accompanying geoprocessing tools have become a mainstay in spatial data processing, and received full support for Python with the release of version 10. With many of the geoprocessing tools now available as a Python function, the software can be used for physics-based spatial landslide hazard analysis. A model that mimics PISA-m and its processing of normally distributed soil properties was created using the Python utility as a tool …


The Emission And Particulate Matter Oxidation Performance Of A Scr Catalyst On A Diesel Particulate Filter With A Downstream Scr, Sagar Sharma Jan 2017

The Emission And Particulate Matter Oxidation Performance Of A Scr Catalyst On A Diesel Particulate Filter With A Downstream Scr, Sagar Sharma

Dissertations, Master's Theses and Master's Reports

Selective catalytic reduction (SCR) systems along with a NH₃ slip control catalyst (ASC) offers NOₓ conversion efficiency >90 % with NH₃ slip < 20 ppm. However, future heavy duty diesel (HDD) engines are designed for higher engine-out NOₓ to improve fuel consumption. Consequently, there is a strong desire to further improve the NOₓ reduction performance of SCR systems, to meet the 2015 California Optional Low NOₓ Standard. SCR catalysts on a diesel particulate filter provide an effective solution to reduce NOₓ and PM using a single aftertreatment device. It also provides an opportunity to increase the SCR volume to achieve NOₓ conversion efficiency >95 %. A downstream SCR catalyst substrate can be used to get additional NOx conversion by using the SCRF® outlet NH₃ to increase the cumulative NOₓ conversion of the system.

In this study, NOₓ reduction, NH₃ slip and PM oxidation performance of a Cu-zeolite SCRF® with a downstream Cu-zeolite SCR were investigated based on engine experimental data at steady state conditions. The experimental data were collected at varying SCRF® inlet temperatures, space velocities, inlet …


Wetland Policy Design In The Upper Great Lakes States: Cases Of Policy Success And Failure, Miranda N. Smith Jan 2017

Wetland Policy Design In The Upper Great Lakes States: Cases Of Policy Success And Failure, Miranda N. Smith

Dissertations, Master's Theses and Master's Reports

The national goal of “no net loss” of wetlands in the United States has significantly lowered the rate of wetland loss, but wetlands are still being impacted in some areas. Many states have their own policies in place to protect wetlands aside from the main federal policy, Section 404 of the Clean Water Act, and those policies are implemented in different ways by different levels of government. This research focuses on wetland policy in the Upper Great Lakes states comparing Michigan, Minnesota, and Wisconsin. Wetland policy and implementation practices vary from state to state, with wetland approval being more devolved …


Blossomsttm Hub – An Online Tool For Designing Sttm Vectors And Visualizing Phenotypic Changes Of Sttm Transgenic Lines, Avinash Subramanian Jan 2017

Blossomsttm Hub – An Online Tool For Designing Sttm Vectors And Visualizing Phenotypic Changes Of Sttm Transgenic Lines, Avinash Subramanian

Dissertations, Master's Theses and Master's Reports

Small RNAs including microRNAs (miRNAs) and short interfering RNAs (siRNAs) are widely present in plants. They are transcribed from non-coding small RNA genes and then play as regulators to modulate the levels of messenger RNAs (mRNAs) of protein-coding genes via sequence pairings. This is because a paired complementary double sequence helix structure can trigger mRNA degradation or interfere with mRNA translation. Short Tandem Target Mimic (STTM) is a recently developed technology that can be used to produce a complementary sequence to a miRNA and destroy it or reduce the expression level of this miRNA via the formation of paired double-strand …


Rock Magnetic Investigation Of The Michigan Basin Soils And Sediments Overlying The Oil-Bearing Silurian Pinnacle Reefs, Jake Tresnak Jan 2017

Rock Magnetic Investigation Of The Michigan Basin Soils And Sediments Overlying The Oil-Bearing Silurian Pinnacle Reefs, Jake Tresnak

Dissertations, Master's Theses and Master's Reports

A relationship between the hydrocarbon migration and magnetic properties of near-surface sediments was investigated from several hundreds of samples collected over the hydrocarbon-bearing Silurian pinnacle reef belt of the Michigan Basin. The collected samples were investigated using several rock magnetic methods and optical microscopy. The investigation has not revealed a straightforward relationship between the magnetic susceptibility and hydrocarbon reservoirs within the reef belt; both anomalously high and low susceptibility values were observed. The elevated values are associated with newly formed magnetite in the form of spheroidal grains produced by hydrocarbon-related diagenesis while the extremely low susceptibilities may reflect dissolution of …


Position Control Of An Unmanned Aerial Vehicle From A Mobile Ground Vehicle, Astha Tiwari Jan 2017

Position Control Of An Unmanned Aerial Vehicle From A Mobile Ground Vehicle, Astha Tiwari

Dissertations, Master's Theses and Master's Reports

Quadcopters have been developed with controls providing good maneuverability, simple mechanics, and the ability to hover, take-off and land vertically with precision. Due to their small size, they can get close to targets of interest and furthermore stay undetected at lower heights. The main drawbacks of a quadcopter are its high-power consumption and payload restriction, due to which, the number of onboard sensors is constrained. To overcome this limitation, vision-based localization techniques and remote control for the quadcopter are essential areas of current research. The core objective of this research is to develop a closed loop feedback system between an …


The Visual And Performing Arts In The Technical Communication Classroom: Reinforcing The University's Internal Community Literacy Via Service-Learning, Richard L. Ward Jan 2017

The Visual And Performing Arts In The Technical Communication Classroom: Reinforcing The University's Internal Community Literacy Via Service-Learning, Richard L. Ward

Dissertations, Master's Theses and Master's Reports

This report details a class taught that was an exploration into the value of STEAM or science, technology, engineering, arts, and mathematics within the confines of Technical Communication as it applies to the business and industry of theatre. It was an experiment in service learning as it could be tied into the Arts via differing technai, as described by John Wild in “Plato’s Theory of Texnh a Phenomenological Interpretation,” demonstrating a necessity for Arts as they pertain to STEM-centric universities. This report discusses a section of Technical and Professional Communication taught at Michigan technological University that consisted of twenty-five students …


Surface Enabled Lab-On-A-Chip (Loc) Device For Protein Detection And Separation, Zhichao Wang Jan 2017

Surface Enabled Lab-On-A-Chip (Loc) Device For Protein Detection And Separation, Zhichao Wang

Dissertations, Master's Theses and Master's Reports

Sensitive and selective chemical/biological detection/analysis for proteins is essential for applications such as disease diagnosis, species phenotype identification, product quality control, and sample examination. Lab-on-a-chip (LOC) device provides advantages of fast analysis, reduced amount of sample requirements, and low cost, to magnificently facilitate protein detection research. Isoelectric focusing (IEF) is a strong and reliable electrophoretic technique capable of discerning proteins from complex mixtures based on the isoelectric point (pI) differences. It has experienced plenty of fruitful developments during previous decades which has given it the capability of performing with highly robust and reproducible analysis. This progress has made IEF devices …


Techno-Economic And Life Cycle Assessments Of Biofuel Production From Woody Biomass Through Torrefaction-Fast Pyrolysis And Catalytic Upgrading, Olumide Winjobi Jan 2017

Techno-Economic And Life Cycle Assessments Of Biofuel Production From Woody Biomass Through Torrefaction-Fast Pyrolysis And Catalytic Upgrading, Olumide Winjobi

Dissertations, Master's Theses and Master's Reports

Biofuel production through fast pyrolysis of biomass is a promising conversion route in the production of biofuels compatible with existing technology. The bio-oil produced from fast pyrolysis is a versatile feedstock that can be used as a heating oil or upgraded to a transportation hydrocarbon biofuel. Comparative study of a one-step, fast pyrolysis only pathway and a two-step torrefaction-fast pyrolysis pathway was carried out to evaluate the effect of torrefcation on (i) the minimum selling price of biofuel and (ii) the potential life cycle GHG emissions of the biofuel production pathway.

To produce bio-oil which can serve as a substitute …


Laboratory, Computational And Theoretical Investigations Of Ice Nucleation And Its Implications For Mixed Phase Clouds, Fan Yang Jan 2017

Laboratory, Computational And Theoretical Investigations Of Ice Nucleation And Its Implications For Mixed Phase Clouds, Fan Yang

Dissertations, Master's Theses and Master's Reports

Ice particles in atmospheric clouds play an important role in determining cloud lifetime, precipitation and radiation. It is therefore important to understand the whole life cycle of ice particles in the atmosphere, e.g., where they come from (nucleation), how they evolve (growth), and where they go (precipitation). Ice nucleation is the crucial step for ice formation, and in this study, we will mainly focus on ice nucleation in the lab and its effect on mixed-phase stratiform clouds.

In the first half of this study, we investigate the relevance of moving contact lines (i.e., the region where three or more phases …


On The Logic, Method And Scientific Diversity Of Technical Systems: An Inquiry Into The Diagnostic Measurement Of Human Skin, Joel Beatty Jan 2017

On The Logic, Method And Scientific Diversity Of Technical Systems: An Inquiry Into The Diagnostic Measurement Of Human Skin, Joel Beatty

Dissertations, Master's Theses and Master's Reports

This dissertation explores some of the scientific, technical and cultural history of human skin measurement and diagnostics. Through a significant collection of primary texts and case studies, I track the changing technologies and methods used to measure skin, as well as the scientific and sociotechnical applications. I then map these histories onto some of the diverse understandings of the human body, physics, biology, natural philosophy and language that underpinned the scientific enterprise of skin measurement. The main argument of my thesis demonstrates how these diverse histories of science historically and theoretically inform the succeeding methods and applications for skin measurement …


Performance Comparison Of Binarized Neural Network With Convolutional Neural Network, Lopamudra Baruah Jan 2017

Performance Comparison Of Binarized Neural Network With Convolutional Neural Network, Lopamudra Baruah

Dissertations, Master's Theses and Master's Reports

Deep learning is a trending topic widely studied by researchers due to increase in the abundance of data and getting meaningful results with them. Convolutional Neural Networks (CNN) is one of the most popular architectures used in deep learning. Binarized Neural Network (BNN) is also a neural network which consists of binary weights and activations. Neural Networks has large number of parameters and overfitting is a common problem to these networks. To overcome the overfitting problem, dropout is a solution. Randomly dropping some neurons along with its connections helps to prevent co-adaptations which finally help in reducing overfitting. Many researchers …


An Investigation Of Historic Landscape Occupation, Transformation, And Interpretation At Windigo, Isle Royale National Park, Marley Chynoweth Jan 2017

An Investigation Of Historic Landscape Occupation, Transformation, And Interpretation At Windigo, Isle Royale National Park, Marley Chynoweth

Dissertations, Master's Theses and Master's Reports

Windigo Ranger Station, Isle Royale National Park, is an historic landscape that provides a gateway to wilderness at one of America’s least visited national parks. Aspects of isolation have helped preserve Isle Royale’s extensive natural and cultural resources, making it an enticing setting for researchers and outdoor enthusiasts. This thesis combines information gathered from archaeological fieldwork and archival research to construct a narrative of landscape transformation at Windigo, Isle Royale National Park. From historic industrial townsite to contemporary NPS visitor port, this narrative highlights three prominent eras of landscape occupation headlined by the Wendigo Copper Company, Washington Club, and a …


Catalytic Hydrotreatment For The Development Of Renewable Transportation Fuels, Lilu Funkenbusch Jan 2017

Catalytic Hydrotreatment For The Development Of Renewable Transportation Fuels, Lilu Funkenbusch

Dissertations, Master's Theses and Master's Reports

Biologically-derived feedstocks are a highly desirable source of renewable transportation fuel. They can be grown renewably and can produce fuels similar in composition to conventional fossil fuels. They are also versatile and wide-ranging. Plant oils can produce renewable diesel and wood-based pyrolysis oils can be made into renewable gasoline. Catalytic hydrotreatment can be used to reduce the oxygen content of the oils and increase their viability as a “drop-in” transportation fuel, since they can then easily be blended with existing petroleum-based fuels. However, product distribution depends strongly on feedstock composition and processing parameters, especially temperature and type of catalyst. Current …


Guaranteed Rendezvous For Cognitive Radio Networks Based On Cycle Length, Li Gou Jan 2017

Guaranteed Rendezvous For Cognitive Radio Networks Based On Cycle Length, Li Gou

Dissertations, Master's Theses and Master's Reports

Rendezvous is a fundamental process establishing a communication link on common channel between a pair of nodes in the cognitive radio networks. How to reach rendezvous efficiently and effectively is still an open problem. In this work, we propose a guaranteed cycle lengths based rendezvous (CLR) algorithm for cognitive radio networks. When the cycle lengths of the two nodes are coprime, the rendezvous is guaranteed within one rendezvous period considering the time skew between the two nodes. When Ti and Tj are not coprime, i.e., Ti=Tj, the deadlock checking and node IDs are combined …


Massively Parallel Algorithms For Point Cloud Based Object Recognition On Heterogeneous Architecture, Linjia Hu Jan 2017

Massively Parallel Algorithms For Point Cloud Based Object Recognition On Heterogeneous Architecture, Linjia Hu

Dissertations, Master's Theses and Master's Reports

With the advent of new commodity depth sensors, point cloud data processing plays an increasingly important role in object recognition and perception. However, the computational cost of point cloud data processing is extremely high due to the large data size, high dimensionality, and algorithmic complexity. To address the computational challenges of real-time processing, this work investigates the possibilities of using modern heterogeneous computing platforms and its supporting ecosystem such as massively parallel architecture (MPA), computing cluster, compute unified device architecture (CUDA), and multithreaded programming to accelerate the point cloud based object recognition. The aforementioned computing platforms would not yield high …


Effect Of Spark Advance And Fuel On Knocking Tendency Of Spark Ignited Engine, Abhay S. Joshi Jan 2017

Effect Of Spark Advance And Fuel On Knocking Tendency Of Spark Ignited Engine, Abhay S. Joshi

Dissertations, Master's Theses and Master's Reports

Knock, in spark ignition engine is the combustion caused by the autoignition of the fuel-air mixture. It is the phenomenon that limits engine performance and thermal efficiency. Knock also has an adverse effect on emissions and fuel economy. Engine designers target engines with maximum power and torque output without compromising on fuel economy. Engine downsizing is the method generally adopted. The main goal of engine downsizing is to achieve better fuel economy while increasing the power and torque output of the engine. Better fuel economy is achieved by reducing the displaced volume which in turn means a much higher brake …


Simulation Of Diesel Particulate Filter Regeneration Using Lattice Boltzmann Method, Kshitiz Kumar Jain Jan 2017

Simulation Of Diesel Particulate Filter Regeneration Using Lattice Boltzmann Method, Kshitiz Kumar Jain

Dissertations, Master's Theses and Master's Reports

Lattice Boltzmann Method is a novel approach, which has shown promise in solving a wide variety of fluid flow problems including single and multi-phase flows in complex geometries. Volume elements of the fluid domain are considered to be composed of particles and these particles fall under a velocity distribution function at each grid point. Particles collide with each other under the influence of external forces and the rules of collision are defined so as to be compatible with the Navier-Stokes Equation. In the current work, LBM has been applied to Diesel Particulate filters which is a device used for reducing …


Bruise Detection In Apples Using 3d Infrared Imaging And Machine Learning Technologies, Zilong Hu Jan 2017

Bruise Detection In Apples Using 3d Infrared Imaging And Machine Learning Technologies, Zilong Hu

Dissertations, Master's Theses and Master's Reports

Bruise detection plays an important role in fruit grading. A bruise detection system capable of finding and removing damaged products on the production lines will distinctly improve the quality of fruits for sale, and consequently improve the fruit economy. This dissertation presents a novel automatic detection system based on surface information obtained from 3D near-infrared imaging technique for bruised apple identification. The proposed 3D bruise detection system is expected to provide better performance in bruise detection than the existing 2D systems.

We first propose a mesh denoising filter to reduce noise effect while preserving the geometric features of the meshes. …


Forensic Analysis Of Shallow Precipitation Triggered Lahars In 2016 On Concepción And Maderas Volcanoes, Ometepe Island, Nicaragua, Lindsay Ellingson Jan 2017

Forensic Analysis Of Shallow Precipitation Triggered Lahars In 2016 On Concepción And Maderas Volcanoes, Ometepe Island, Nicaragua, Lindsay Ellingson

Dissertations, Master's Theses and Master's Reports

Residents of volcanic landscapes are vulnerable to eruptions and earthquakes where volcanism is active and landslides, lahars, and flooding regardless of activity. Ometepe Island is formed from a pair of volcanoes, one active and the other less so, located in Lake Nicaragua. Steep slopes and tropical storms yield frequent surface movement that present potential for large landslide and lahar/mud/debris-flow catastrophes. Climate and land-use changes exacerbate the hazard potential, but land-use changes continue unregulated and the area lacks a sufficient system of weather monitoring to understand variability across the two volcanic edifices over time. Over the 2016 year, weather stations located …


Predicitng Failure Of Culverts And Associated Impacts In Low Order Streams Of Northern Michigan, Charles King Jan 2017

Predicitng Failure Of Culverts And Associated Impacts In Low Order Streams Of Northern Michigan, Charles King

Dissertations, Master's Theses and Master's Reports

The Great Lakes Region of North America has experienced more frequent extreme precipitation events recently, resulting in a large number of stream crossing failures. To evaluate failure risk and potential impacts of crossings in northern Michigan, we identified and conducted coarse assessments of all the stream crossings and dams in the North Branch Paint River Watershed. A subset of 11 culverts were selected from 49 identified sites for hydraulic analysis to estimate crossing failure discharge conditions. Stream crossing dimensions and upstream attributes were used to create metrics that predict failure risk without the need for complex hydraulic modeling, and these …


Lakebed Characterization Using Side-Scan Data For Investigating The Latest Lake Superior Coastal Environment Conditions, Hasan Salih Kulunk Jan 2017

Lakebed Characterization Using Side-Scan Data For Investigating The Latest Lake Superior Coastal Environment Conditions, Hasan Salih Kulunk

Dissertations, Master's Theses and Master's Reports

This thesis provides a review of the development of hydrographic survey equipment and supporting geospatial equipment and technology such as GPS. Using SonarWiz, a sonar image processing software package, lakebed classification methodologies were evaluated for mapping Buffalo Reef in Lake Superior located near Gay, Michigan. The goal was to develop an approach to mapping the reef bed and delineating various components of the lake bottom, including stamp sands, which are migrating from the abandoned Gay copper processing stamp mill to the reef. This contamination of the reef is having an adverse effect on habitats important to local flora and fauna. …


How A Diverse Research Ecosystem Has Generated New Rehabilitation Technologies: Review Of Nidilrr’S Rehabilitation Engineering Research Centers, David J. Reinkensmeyer, Sarah Blackstone, Cathy Bodine, John Brabyn, David Brienza, Kevin Caves, Frank Deruyter, Edmund Durfee, Stefania Fatone, Geoff Fernie, Steven Gard, Patricia Karg, Todd A. Kuiken, Gerald F. Harris, Mike Jones, Yue Li, Jordana Maisel, Michael Mccue, Michelle A. Meade, Helena Mitchell, Tracy L. Mitzner, James L. Patton, Philip S. Requejo, James H. Rimmer, Wendy A. Rogers, W. Zev Rymer, Jon A. Sanford, Lawrence Schneider, Levin Sliker, Stephen Sprigle, Aaron Steinfeld, Edward Steinfeld, Gregg Vanderheiden, Carolee Winstein, Li-Qun Zhang, Thomas Corfman Jan 2017

How A Diverse Research Ecosystem Has Generated New Rehabilitation Technologies: Review Of Nidilrr’S Rehabilitation Engineering Research Centers, David J. Reinkensmeyer, Sarah Blackstone, Cathy Bodine, John Brabyn, David Brienza, Kevin Caves, Frank Deruyter, Edmund Durfee, Stefania Fatone, Geoff Fernie, Steven Gard, Patricia Karg, Todd A. Kuiken, Gerald F. Harris, Mike Jones, Yue Li, Jordana Maisel, Michael Mccue, Michelle A. Meade, Helena Mitchell, Tracy L. Mitzner, James L. Patton, Philip S. Requejo, James H. Rimmer, Wendy A. Rogers, W. Zev Rymer, Jon A. Sanford, Lawrence Schneider, Levin Sliker, Stephen Sprigle, Aaron Steinfeld, Edward Steinfeld, Gregg Vanderheiden, Carolee Winstein, Li-Qun Zhang, Thomas Corfman

Biomedical Engineering Faculty Research and Publications

Over 50 million United States citizens (1 in 6 people in the US) have a developmental, acquired, or degenerative disability. The average US citizen can expect to live 20% of his or her life with a disability. Rehabilitation technologies play a major role in improving the quality of life for people with a disability, yet widespread and highly challenging needs remain. Within the US, a major effort aimed at the creation and evaluation of rehabilitation technology has been the Rehabilitation Engineering Research Centers (RERCs) sponsored by the National Institute on Disability, Independent Living, and Rehabilitation Research. As envisioned at their …


Synthesis And Characterization Of Cross-Linked Polyimide Film Using Tolylene Diisocyanate, Sirichai Reeyakad Jan 2017

Synthesis And Characterization Of Cross-Linked Polyimide Film Using Tolylene Diisocyanate, Sirichai Reeyakad

Chulalongkorn University Theses and Dissertations (Chula ETD)

Cross-linked polyimide films were synthesized by the reaction between diisocyanate groups and hydroxyl functional groups in polyimide structure, which was confirmed by IR. During the thermal treatment of the cross-linked polyimide, the thermal labile component (CO₂) in the urethane segments was decomposed which might generate pores in the film. The presence of the pores was confirmed from the dielectric constant of the film. The dielectric constant of the films decreased with the increase of TDI loading. By comparing the properties of the films, the PI50-C1.0 exhibited optimum mechanical and good dielectric properties. The cross-linked structure was also confirmed by DMA. …


พอลิแล็กทิกแอซิด/พอลิไวนิลแอลกอฮอล์/แกรฟีนนาโนคอมพอสิต, จาฬุพักต์ รัตนคช Jan 2017

พอลิแล็กทิกแอซิด/พอลิไวนิลแอลกอฮอล์/แกรฟีนนาโนคอมพอสิต, จาฬุพักต์ รัตนคช

Chulalongkorn University Theses and Dissertations (Chula ETD)

งานวิจัยนี้มีวัตถุประสงค์เพื่อพัฒนาวิธีการเตรียมพอลิแล็กทิกแอซิด/พอลิไวนิลแอลกอฮอล์/แกรฟีนนาโนคอมพอสิต รวมถึงศึกษาอิทธิพลของการเติมอนุภาคแกรฟีนต่อสัณฐานวิทยา สมบัติเชิงกล สมบัติทางความร้อน และสมบัติการนำไฟฟ้าของวัสดุนาโนคอมพอสิตที่เตรียมได้ โดยเริ่มด้วยการสังเคราะห์แกรฟีนจากแกรไฟต์ด้วยวิธีของฮัมเมอร์ และใช้กรดแอลแอสคอร์บิกเป็นตัวรีดิวซ์ พิสูจน์เอกลักษณ์ของอนุภาคแกรฟีนที่เตรียมได้ด้วยเทคนิคอินฟราเรดสเปกโทรสโกปีและเทคนิคเอกซเรย์ดิฟแฟรกชัน จากนั้นเตรียมของผสมระหว่างพอลิไวนิลแอลกอฮอล์กับแกรฟีนที่ปริมาณต่าง ๆ ด้วยวิธีแช่เยือกแข็ง แล้วนำไปผสมกับพอลิแล็กทิกแอซิดด้วยเครื่องอัดรีดสกรูคู่และขึ้นรูปเป็นชิ้นงานด้วยกระบวนการอัดแบบ ศึกษาสัณฐานวิทยาเพื่อวิเคราะห์อันตรกิริยาของผสมระหว่างพอลิไวนิลแอลกอฮอล์กับแกรฟีนด้วยกล้องจุลทรรศน์แบบคอนโฟคอล และวิเคราะห์ภาคตัดขวางของชิ้นงานคอมพอสิตด้วยกล้องจุลทรรศน์อิเล็กตรอนแบบส่องกราด ผลการทดสอบสมบัติเชิงกล สมบัติทางความร้อน และสมบัติการนำไฟฟ้าของวัสดุนาโนคอมพอสิตที่เตรียมได้ พบว่าปริมาณผลึกลดลงเมื่อปริมาณแกรฟีนเพิ่มขึ้น แต่ไม่ส่งผลต่ออุณหภูมิกลาสทรานสิชัน อุณหภูมิหลอมเหลวผลึก และอุณหภูมิการเกิดผลึก อีกทั้งการเติมแกรฟีนที่มีการใช้พอลิไวนิลแอลกอฮอล์เป็นตัวพาลงในพอลิเมอร์เมทริกซ์ ทำให้ความทนแรงดึง และความยืดสูงสุด ณ จุดขาด มีแนวโน้มลดลงด้วย อย่างไรก็ดีการเติมแกรฟีนในปริมาณน้อย ๆ สามารถช่วยเพิ่มความทนแรงดึงได้เมื่อเปรียบเทียบกับงานวิจัยก่อนหน้าที่ไม่มีการเติมตัวพาหรือตัวช่วยเพิ่มการกระจายตัว นอกจากนี้พบว่าปริมาณแกรฟีนที่เพิ่มขึ้น ทำให้ค่าการนำไฟฟ้าของคอมพอสิตเมื่อเทียบกับพอลิแล็กทิกแอซิดบริสุทธิ์เพิ่มขึ้น คอมพอสิตที่พัฒนาขึ้นสามารถนำไปประยุกต์ในงานที่ต้องการสมบัติการต้านทานไฟฟ้าสถิตย์ได้


ผลของการเติมเถ้าแกลบต่อการเกิดชั้นฟิล์มในกระบวนการอะลูมิไนซิงแบบผงบนนิกเกิลบริสุทธิ์, บุญฤทธิ์ เฮงประยูร Jan 2017

ผลของการเติมเถ้าแกลบต่อการเกิดชั้นฟิล์มในกระบวนการอะลูมิไนซิงแบบผงบนนิกเกิลบริสุทธิ์, บุญฤทธิ์ เฮงประยูร

Chulalongkorn University Theses and Dissertations (Chula ETD)

การปรับปรุงกระบวนการอะลูมิไนซิงแบบผงทำได้โดยการเจือธาตุซิลิกอนเพื่อเพิ่มความเสถียรของชั้นออกไซด์ที่เกิดขึ้นในการใช้งานที่อุณหภูมิสูง ซึ่งเถ้าแกลบมีส่วนประกอบของซิลิกาอยู่มากกว่า 90 เปอร์เซ็นต์โดยน้ำหนัก ในงานวิจัยนี้จะหาความเป็นไปได้ในการใช้เถ้าแกลบแทนซิลิกาจากอุตสาหกรรม (ควอทซ์) เพื่อเจือซิลิกอนลงในกระบวนการอะลูมิไนซิงแบบผง โดยวิเคราะห์ถึงความแตกต่างของโครงสร้างผลึก สารเจือในเถ้าแกลบ ขนาดอนุภาค ลักษณะพิ้นผิวและพื้นที่ผิวจำเพาะระหว่างผงควอทซ์และผงเถ้าแกลบที่จะส่งผลต่อโครงสร้างจุลภาค โครงสร้างของสารประกอบของชั้นแพร่และปริมาณซิลิกอนที่พบในชั้นแพร่ในผิวชิ้นงานที่ใช้สารตั้งต้นเป็นควอทซ์และเถ้าแกลบ ซึ่งปริมาณสารเจือที่เติมคือ 9, 13.5, 18 เปอร์เซ็นต์โดยน้ำหนัก เผาที่อุณหภูมิ 800 และ 1000๐C เป็นเวลา 4 ชั่วโมง และทดสอบความต้านทานการเกิดออกซิเดชันที่อุณหภูมิ 1000๐C เป็นเวลา 100 ชั่วโมง ชิ้นงานที่นำมาทดสอบคือ นิกเกิลบริสุทธิ์, ชิ้นงานที่ทำอะลูมิไนซิงที่ 900๐C เป็นเวลา 4 ชั่วโมง, ชิ้นงานที่เติมควอทซ์ 13.5 เปอร์เซ็นต์โดยน้ำหนัก ทำอะลูมิไนซิงที่ 1000๐C เป็นเวลา 4 ชั่วโมงและชิ้นงานที่เติมเถ้าแกลบ 13.5 เปอร์เซ็นต์โดยน้ำหนัก ทำอะลูมิไนซิงที่ 1000๐C เป็นเวลา 4 ชั่วโมง นำชิ้นงานมาวิเคราะห์ลักษณะพื้นผิวและโครงสร้างของสารประกอบออกไซด์ที่เกิดขึ้นที่ผิว พบว่าชิ้นงานที่เติมเถ้าแกลบจะมีปริมาณซิลิกอนที่พบในชั้นแพร่มากกว่าและมีความสามารถในการต้านทานการเกิดออกซิเดชันที่อุณหภูมิสูงดีกว่าชิ้นงานที่เติมควอทซ์


Long-Period Fiber Grating Corrosion Sensors For Life-Cycle Monitoring And Assessment Of Reinforced Concrete Structures, Yizheng Chen Jan 2017

Long-Period Fiber Grating Corrosion Sensors For Life-Cycle Monitoring And Assessment Of Reinforced Concrete Structures, Yizheng Chen

Doctoral Dissertations

"This study aims to: (1) explore, develop, calibrate and validate Fe-C coated, long period fiber grating (LPFG) sensors for short-term mass loss measurement of the Fe-C coating; (2) develop, calibrate, and validate steel tube-encapsulated, fiber optic probes and LPFG sensors for long-term mass loss detection of the steel tube; (3) correlate the corrosion process of packaging metal materials with that of steel bars in direct contact with the packaged probe or sensor except for a thin insulation tape; and (4) apply both types of corrosion sensors into reinforced concrete (RC) structures for reinforcing bar corrosion monitoring and structural condition assessment. …