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The Impact Of Culture, Leadership, And Power, On Staff Motivation In The Context Of International Organizations, Erdem Erciyes

Plymouth Business School Theses

This thesis investigates the impact of culture, leadership, and power, on staff motivation in selected international organizations (IOs), and develops a theoretical framework to assist with the practice of workforce motivation. The main research question is: “How can supervisors motivate their staff in the context of IOs?” Utilizing critical theory as a paradigm of inquiry, the study’s philosophical perspective leans heavily on “phenomenology”. Conducting this research led to the realization that there are a few studies in the existing literature on this subject matter. After investigating grand theories, the meso theories which form the theoretical background of the research were …

2017 Nyar (Savannah) Program, National-Youth-Risk (Savannah) Conference

National Youth Advocacy & Resilience Conference

N/A

The Impact Of The Boston Marathon Bombing On Public Willingness To Cooperate With Police, Gary Lafree, Amy Adamczyk

Publications and Research

While a key to law enforcement success is the willingness of the public to cooperate with police, we have limited understanding of how terrorist attacks affect this public readiness. Prior research suggests that terrorist attacks might increase citizen cooperation with police through both prevention efforts and rally effects. We test these assertions with three nationally representative surveys on respondents’ willingness to help police combat terrorism: one before the Boston Marathon bombings and two after. As predicted, public willingness to report suspicious behavior to police increases significantly following the bombings and there is evidence that these increases generalize to ordinary crime. …

Income Taxation And Asset Valuation (Ii) The Value Of Preferential Taxation, Theodore S. Sims

Faculty Scholarship

The predecessor to this Article explored the properties of an income tax that uses economic depreciation in measuring capital income. This Article investigates some fundamental properties of an income tax that does not. The predecessor illuminated the equivalence between economic depreciation and accrual taxation, and highlighted the insight, due to Paul Samuelson, that either produces asset values that are independent of their holders' marginal rates, even in a system with graduated rates (and even if those rates vary over time). The current Article explores in qualitative terms the value of "preferential" departures from valuation-neutral taxation.

Nano-Magnetic Resonance Imaging (Nano-Mri) Gives Personalized Medicine A New Perspective, Lorenzo Rosa, Jonathan Blackledge, Albert Boretti

Articles

This paper reviews some of the major and most recent advances in nanoscale-magnetic resonance imaging (nano-MRI) for personalized medicine (PM). Nano-MRI may drastically expand the capabilities of the traditional magnetic resonance images (MRI), down to the nanometer scale and possibly, in the near future, at the atomic scale. Nano-MRI is potentially able to observe structures which cannot be seen using today’s molecular imaging, with sensitivities of many billions of times better than MRI as currently used in hospitals, for example. The paper briefly reports on the foremost research themes in nano-MRI.

Information Hiding With Data Diffusion Using Convolutional Encoding For Super-Encryption, Jonathan Blackledge, Paul Tobin, J. Myeza, C.M. Adolfo

Articles

The unification of data encryption with information hiding methods continues to receive significant attention because of the importance of protecting encrypted information by making it covert. This is because one of the principal limitations in any cryptographic system is that encrypted data flags the potential importance of the data (i.e. the plaintext information that has been encrypted) possibly leading to the launch of an attack which may or may not be successful. Information hiding overcomes this limitation by making the data (which may be the plaintext or the encrypted plaintext) imperceptible, the security of the hidden information being compromised if …

Characterization Of The Sub-Micrometer Hierarchy Levels In The Twist-Bend Nematic Phase With Nanometric Helices Via Photopolymerization: Explanation For The Sign Reversal In The Polar Response, Vitaly Panov, Sithara Sreenilayam, Yuri Panarin, Jagdish Vij, Chris Welch, Georg Mehl

Articles

Photopolymerization of a reactive mesogen mixed with a mesogenic dimer, shown to exhibit the twist-bend nematic phase (NTB), reveals the complex structure of the self-deformation patterns observed in planar cells. The polymerized reactive mesogen retains the structure formed by liquid crystalline molecules in the twist bend phase, thus enabling its observation by scanning electron microscopy (SEM). Hierarchical ordering scales ranging from tens of nanometers to micrometers are imaged in detail. Submicron features, anticipated from earlier X-ray experiments, are visualized directly. In the self-deformation stripes formed in the NTB phase, the average director field is found tilted in …

An Analysis Of Harmonic Heating In Smart Buildings And Distribution Network Implications With Increasing Non-Linear (Domestic) Load And Embedded Generation, Chittesh Veni Chandran, Keith Sunderland, Malabika Basu

Articles

Harmonic distortion is generally not taken into account within domestic installations and the associated wiring systems, as its potential is considered sufficiently small to be neglected. Standards to limit harmonic manifestations in the low voltage (LV) network are available, but these can be breached as a consequence of advancements in power electronics in some modern household devices contributing higher levels of harmonic distortion than permitted. While these devices individually might not be considered serious in terms of system level harmonic distortion manifestations, electrical equipment failures and insulation failures - increasingly being derived from harmonic cable heating - suggest a different …

Magnetic Field Sensing Using Whispering Gallery Modes In A Cylindrical Microresonator Infilitrated With Ferronematic Liquid Crystal, Aseel Mahmood, Vishnu Kavungal, Sudad S. Ahmed, Peter Kopcansky, Vlasta Zavisova, Gerald Farrell, Yuliya Semenova

Articles

An all-fiber magnetic field sensor based on whispering-gallery modes (WGM) in a fiber micro-resonator infiltrated with ferronematic liquid crystal is proposed and experimentally demonstrated. The cylindrical microresonator is formed by a 1 cm-long section of a photonic crystal fiber infiltrated with ferronematic materials. Both ferronematics suspensions are prepared based on the nematic liquid crystal 1-(trans-4-Hexylcyclohexyl)-4-isothiocyanatobenzene (6CHBT) doped with rod-like magnetic particles in the first case and with spherical magnetic particles in the second case. WGMs are excited in the fiber microresonator by evanescent light coupling using a tapered fiber with a micron-size diameter. The Q-factor of the microresonator determined from …

The Role Of The Dendritic Growth Models Dimensionality In Predicting The Columnar To Equiaxed Transition (Cet), M. Seredynski, Marek Rebow, J. Banaszek

Articles

The dendrite tip kinetics model accuracy relies on the reliability of the stability constant used, which is usually experimentally determined for 3D situations and applied to 2D models. The paper reports authors` attempts to cure the situation by deriving 2D dendritic tip scaling parameter for aluminium-based alloy: Al-4wt%Cu. The obtained parameter is then incorporated into the KGT dendritic growth model in order to compare it with the original 3D KGT counterpart and to derive two-dimensional and three-dimensional versions of the modified Hunt’s analytical model for the columnar-to-equiaxed transition (CET). The conclusions drawn from the above analysis are further confirmed through …

Adaptive Linear Prediction For Optimal Control Of Wind Turbines, Mahinsasa Narayana, Keith Sunderland, Ghanim Putrus, Michael Conlon

Articles

In order to obtain maximum power output of a Wind Energy Conversion System (WECS), the rotor speed needs to be optimised for a particular wind speed. However, due to inherent inertia, the rotor of a WECS cannot react instantaneously according to wind speed variations. As a consequence, the performance of the system and consequently the wind energy conversion capability of the rotor are negatively affected. This study considers the use of a time series Adaptive Linear Prediction (ALP) technique as a means to improve the performance and conversion efficiency of wind turbines. The ALP technique is introduced as a real …

Compact Humidity Sensor Based On A Multi-Layer Agarose Hydrogel Coated Silica Microsphere Resonator, Arun Mallik, Yuliya Semenova, Vishnu Kavungal, Dejun Liu

Conference Papers

In this paper we report on a novel approach to implementing a compact humidity sensor that utilizes whispering gallery mode (WGM) phenomena in a silica microsphere coated with Agarose hydrogel. The spectral positions of the WGM resonances for such a sensor depend strongly on the refractive index and thickness of the coating. The WGM’s spectral shift occurs due to adsorption/desorption of the water vapor in response to changes in ambient humidity and also due to the corresponding changes of the coating thickness. We experimentally investigated the WGMs spectral shift for a 100 μm diameter silica microsphere coated with Agarose hydrogel …

Size And Shape Control In Metal Nanoparticles And Nanocomposites, Tomendro Subedi

Theses and Dissertations (Comprehensive)

This thesis describes major findings on the shape transformation of the precursor silver decahedral nanoparticles (AgDeNPs) with pentagonal symmetry and twin defects into silver pentagonal prism nanoparticles (AgPPNPs) using Br¯ as a shape selective reagent. Silica-encapsulation of the gold-plated AgDeNPs was also carried out forming ordered arrays of silica encapsulated gold-plated AgDeNPs (SiO₂@Au@AgDeNPs) of different sizes. At first, synthetic procedures for AgDeNPs (pentagonal bipyramids), silver pentagonal rod nanoparticles (AgPRNPs) and gold-plating of AgDeNPs (Au@AgDeNPs) were optimized. Gold plating enhances the chemical stability of AgDeNPs and preserves the superior plasmonic properties of silver. This thesis deals with the transformation …

Accountability, Conservation And Community: Measuring The Local Economic Impacts Of Protected Areas, Catharine A.M. Brazeau

Theses and Dissertations (Comprehensive)

As a signatory to the Convention on Biological Diversity, Canada has committed to help protect biodiversity through an increase in effectively and equitably managed systems of protected areas (PAs) by 2020. If Canada fulfills this commitment, the country will see the largest expansion of PA networks in its history. Although employing ‘equitable and effective management’ suggests PAs have a responsibility to consider their effects on local stakeholders, on the whole, Canada’s PA agencies do not publicly and systematically report on their jurisdictions’ local economic impacts. To address this gap, this thesis aims investigate mechanisms for PA agencies to identify and …

Disease Models With Immigration, Reem Almarashi

Theses and Dissertations (Comprehensive)

In this thesis we focus first on studying the susceptible, exposed, and infected ($SEI$) disease model without immigration. We determine the basic reproduction number $\mathcal{R}_0$, which can be interpreted as the expected number of new cases that can be produced by a single infection in a completely susceptible population. Further, by using the Jacobian matrix, we determine the local stability of the disease model. Then we have the result that when $\mathcal{R}_0<1$ the DFE point is locally asymptotically stable(L.A.S). In contrast, when $\mathcal{R}_0>1$ we find that the endemic equilibrium is L.A.S. After that, we analyze the $SEI$ model with immigration of infected individuals.

Furthermore, we investigate the direction that the …

Natural Organic Matter Characterization And Lead Speciation As Indicators Of Potential Lead Bioavailability In Aquatic Environments, Giselle Cimprich

Theses and Dissertations (Comprehensive)

Trace metals and natural organic matter (NOM) are ubiquitous in aquatic environments. Some trace metals are essential for aquatic life, while other non-essential metals (like lead) can be toxic if present in great enough concentrations. Natural waters contain a combination of inorganic, and organic ligands capable of binding metals. While the chemistry of inorganic Pb species is well understood, and National Institute of Standards and Technology (NIST) certified K values are readily available, the interactions between metals and organic matter is not so clearly defined. It is important to understand how NOM interacts with metals in the environment, as the …

The Synthesis Of Symmetric Polycyclic Aromatic Hydrocarbons And The Mesomorphic Properties Of Their Brominated Derivatives, Vanessa Bellemore

Theses and Dissertations (Comprehensive)

In this thesis, the synthesis of a series of brominated alkoxy-substituted trinaphthylenes was developed using a nickel-mediated Yamamoto coupling as the main step. Characterization of these compounds led to the discovery of a new set of broad range liquid crystals. They were found to undergo higher order transitions (i.e. glass phases/soft crystals/liquid crystal) via DSC, and also to decompose before reaching an isotropic liquid, as verified via thermogravimetric analysis. Polarized optical microscopy showed a texture characteristic of a columnar hexagonal mesophase. In addition, the aggregation in solution was studied using concentration dependent NMR studies, and the brominated-derivatives were determined to …

Shifting Pedagogy For Adolescent Refugees With Limited Or Interrupted Formal Education: A Case Study Of The Professional Experiences Of A Secondary English Literacy Development Teacher, Stephanie Ledger

Theses and Dissertations (Comprehensive)

In recent years, there has been a large influx of refugees into settlement countries worldwide. In Canada, this displaced population includes many adolescent students of limited or interrupted formal education (SLIFE). Consequently, secondary school teachers are challenged to meet the print literacy needs of SLIFE within traditional ESL instructional settings.

The literature reveals an urgent desire and need for the use of early literacy instructional practices to address the print literacy needs of SLIFE. Despite this acknowledgement, many ESL/ELD secondary school educators are reluctant to shift their pedagogy from traditional ESL to early literacy pedagogy (Dooley, 2009; Dooley & Thangaperumal, …

A Computational Study Of Silver Doped Cdse Quantum Dots, Heather Gaebler

Theses and Dissertations (Comprehensive)

Due to quantum dot’s ability to emit photons when subjected to light of sufficient energy, they have become optimal candidates for biomedical research and for optoelectronic applications. Fascination towards quantum dots arises from the fact that their properties are easily fine-tuned through a variety of different techniques. Electronic doping is a popular technique used to control the properties of quantum dots through the addition of different elements.

Via density functional theory calculations, this work investigated how the structural energies and HOMO-LUMO gaps were altered by the addition of impurity atoms. First, interstitial and substitutional doping styles were investigated at 0 …

A Density Functional Theory Study Of Intrinsically Chiral Semiconductor Nanocrystals, Richard Edwards

Theses and Dissertations (Comprehensive)

A plethora of work has been done in the area of nanoparticles of late due to the fact that chemists (and physicists) have discovered that the properties of nanoparticles differ from both those of the bulk material and the atoms themselves. Nanoparticles have become of high interest for the use as catalysts while materials like graphene, being only one atom thick, have been shown to be great electrical conductors in comparison with the 3D structure of diamond. Among these peculiar nanoscale properties is the phenomenon of nanochirality, where a nanoparticle can exhibit chirality that does not extend to the macroscale …

An Enhanced Spring-Particle Model For Red Blood Cell Structural Mechanics: Application To The Stomatocyte–Discocyte– Echinocyte Transformation, Mingzhu Chen, Fergal Boyle

Articles

Red blood cells (RBCs) are the most abundant cellular element suspended in blood. Together with the usual biconcave-shaped RBCs, i.e., discocytes, unusual-shaped RBCs are also observed under physiological and experimental conditions, e.g., stomatocytes and echinocytes. Stomatocytes and echinocytes are formed from discocytes and in addition can revert back to being discocytes; this shape change is known as the stomatocyte–discocyte–echinocyte (SDE) transformation. To-date, limited research has been conducted on the numerical prediction of the full SDE transformation. Spring- particle RBC (SP-RBC) models are commonly used to numerically predict RBC mechanics and rheology. However, these models are incapable of predicting the full …

Development Of Magnetorheological Elastomers (Mres) For Strength And Fatigue Resistance, J. Mcintyre, Stephen Jerrams

Books/Book Chapters

Natural rubber (NR)-based magnetorheological elastomers (MREs) exhibiting a reasonable switching effect were fabricated and tested. They were strong enough for use in automotive applications but still needed protection against ageing. Ethylene–propylene–diene rubber (EPDM) is a cost-effective material that is frequently used in the automotive industry because of its advantageous range of properties. With these applications in mind, it was a logical progression to the development of EPDM-based MREs. Unlike strain-crystallising NR, EPDM requires reinforcement to render its tensile and fatigue strength suitable for use in most applications. While small amounts of carbon black were sufficient for the NR-based MREs, a …

Advanced Control Architectures For Grid Connected And Standalone Converter Systems, Subhajyoti Mukherjee

Doctoral Dissertations

"This dissertation proposes new control algorithms dedicated towards improving the reliability, computational burden and stability in grid-connected and stand-alone based power electronic converter systems applicable for ac microgrids.

Two voltage sensorless control architectures, one for stand-alone applications and the other for grid-connected application are established in this thesis. The output voltage of a standalone single-phase inverter is controlled directly by controlling the output filter capacitor current without using a dedicated output voltage sensor. A method to estimate the output filter capacitance is also presented. For the grid connected converter, a novel closed loop estimation is presented to estimate the grid …

Phytoforensics: Applications In Vapor Intrusion Assessment, Jordan Lee Wilson

Doctoral Dissertations

"Vapor intrusion (VI) occurs when contaminants in the vapor phase migrate in the shallow subsurface and enter buildings through cracks, seams, and gaps and has been recognized as a serious human-health threat as occupants are exposed to potentially harmful concentrations over long periods of time. The VI pathway has recently (2017) been identified as a primary exposure pathway and implemented into the Hazard Ranking System for inclusion on the Nation Priorities List. However, assessing VI and human exposure is not simple and current methods are time-, cost-, and labor-intensive; intrusive; and temporally and spatially variability. Trees are ideal candidates for …

Numerical And Experimental Study Of New Designs Of All-Vanadium Redox Flow Batteries For Performance Improvement, Mohammed Abdulkhabeer Ali Al-Yasiri

Doctoral Dissertations

"Energy storage is envisioned as a key part of a renewable energy solution incorporated in a grid that overcomes two critical limits of renewable energy: intermittency and uncertainty. Among various technologies, a vanadium redox flow battery (VRFB) offers a promise because of its unique features such as long cycle life, separation of energy and power ratings, and capability of a deep discharge. The remaining challenges, however, include the limited application due to low energy density and complicated geometries. The complex geometry makes it difficult to optimize the performance and can cause a serious concern about leakage of the liquid. The …

Extraction And Quantification Of Sinapinic Acid From Irish Rapeseed Meal And Assessment Of Angiotensin-I Converting Enzyme (Ace-I) Inhibitory Activity, Leah Quinn, Steven G. Gray, Steve Meaney, Stephen Finn, Padraig Mcloughlin, Maria Hayes

Articles

Phenolic compounds, including phenolic acids, are known to play a protective role against the development of cardiovascular disease. The aim of this work was to generate a phenolic acid extract from Irish rapeseed meal, to determine the quantity of sinapinic acid (SA) in this fraction and to assess the ability of this fraction to inhibit the enzyme angiotensin-I converting enzyme (ACE-I; EC 3.4.15.1). A crude phenolic extract (fraction 1), free phenolic acid containing extract (fraction 2), and an extract containing phenolic acids liberated from esters (fraction 3) were generated from Irish rapeseed meal using a methanol:acetone:water solvent mixture (7:7:6). The …

Cd10 − /Aldh − Cells Are The Sole Cisplatin-Resistant Component Of A Novel Ovarian Cancer Stem Cell Hierarchy, Brendan Ffrench, Claudia Gasch, Karsten Hokamp, Cathy Spillane, Gordon Blackshields, Thamir Mahmoud Mahgoub, Mark Bates, Louise Kehoe, Aoibhinn Mooney, Ronan Doyle, Brendan Doyle, Dearbhaile O ’ Donnell, Noreen Gleeson, Bryan T Hennessy, Britta Stordal, Ciaran O ’ Riain, Helen Lambkin

Articles

No abstract provided.

Can Parents’ Growth Mindset And Role Modelling Address Stem Gender Gaps?, Albert Cheng, Katherine Kopotic, Gema Zamarro

Education Reform Faculty and Graduate Students Publications

Despite widespread interest and value in introducing and better-preparing students to enter the science, technology, engineering, and mathematics (STEM) fields, a gender gap persists as women are underrepresented among STEM jobs and degree completion. Although some work has evaluated whether interventions and certain pedagogical practices improve growth mindset, little is known about the mediating role of parents and whether those effects are more pronounced for females. In this study, we explore the extent to which the mindsets of a student’s parents regarding math ability influence the student’s mindset in math ability and longer-term STEM-related outcomes. We pay particular attention to …

Hydrogeochemical Controls On Reactive And Nonreactive Solute Transport In Heterogenous Porous Media, Mahta Gholizadeh Ansari

Masters Theses

"This work examines how physical and chemical heterogeneity can affect reactive and non-reactive transport in porous media. The effect of heterogeneity of the porous media is investigated both on dissolution rate of magnesite and attenuation time of nonreactive contaminants in non-reactive media. Various spatial distribution were created using statistical parameters in PETREL.A total of 6793 transport modeling simulations were run using CrunchFlow. Lasso regression was used to select most significant features and those features are then used in linear regression and deep learning models.

The magnesite dissolution simulations were performed under different permeability ratios (magnesite /sand permeability) and inlet pH. …

Electromechanical Instability In Silicone-And Acrylate-Based Dielectric Elastomers, Liang Jiang, Yanfen Shou, Shaojuan Chen, Jianwei Ma, Tony Betts, Stephen Jerrams

Articles

Electromechanical instability (EMI) is regarded as a significant factor in preventing dielectric elastomers (DEs) fromachieving large voltage-induced deformations. In this study, the strain-stiffening effect was used to control the occurrence of EMI in DEs. The results show that the stretching ratio required to provide a feasible strain-stiffening effect in silicone rubber (SR) was smaller than that needed for a commercial DE material, VHB 4910. The experimental data were compared with currently used models for the simulation of EMI in DEs. We found that EMI could be eliminated in the deformation of these elastomers when pre-stretching was used. Through the application …