Digital Commons Network^™

System Level Analysis And Design For Wireless Inter-Chip Interconnection Communication Systems By Applying Advanced Wireless Communication Technologies, Xin Zheng

Theses and Dissertations

As the dramatic development of high speed integrated circuits has progressed, the 60 GHz silicon technology has been introduced to enable much faster computer systems and their corresponding applications. However, when signals are propagating at 60 GHz or higher frequencies on a PCB (Printed Circuit Board), the crosstalk among signal buses and devices, trace losses, and introduced parasitic capacitance and inductance between high density traces, become significant and may be severe enough such that the inter-chip communications will not be able to meet computer system signal specifications. High speed circuit signal integrity researchers in both electronic industries and academia have …

Classification Of Natural Phytoplankton Populations With Fluorescence Excitation-Based Imaging Multivariate Optical Computing, Shawna Kathleen Tazik

Theses and Dissertations

Phytoplankton account for the majority of the primary productivity in the ocean and contribute significantly to the global carbon cycle through photosynthesis. A quantitative characterization of phytoplankton cell size and taxonomic composition is essential for understanding marine biogeochemical cycles, quantifying carbon export, and for predicting the ocean’s response to future climate change. Our labs have developed a new instrument for this purpose that combines fluorescence excitation spectroscopy with an all-optical approach to multivariate statistics called multivariate optical computing (MOC). The instrument, known as the Shipboard Streak Imaging Multivariate Optical Computing (SSIMOC) photometer, is a simple filter photometer that images the …

Synthesis And Utility Of Bis-Urea Macrocycles As Nanoreactors And As Ligands For Metal Organic Materials, Sahan R. Salpage

Theses and Dissertations

“Supramolecular chemistry” powered by non-covalent interactive forces forms the crux in the area of host-guest chemistry. Supramolecular assemblies often have different chemical and physical properties than that of its individual molecular entities and are used to develop novel functional materials. Our expertise involves making functional materials from macrocycles, which contain two urea groups and two rigid C shaped spacer groups. These individual macrocyclic components can self-assemble through hydrogen bonding and other non-covalent interactions to form porous supramolecular assemblies that can be used as confined reaction environments and as ligands to synthesize novel metal organic materials.

This dissertation focuses on studying …

Crystal Growth And Characterization Of Reduced Early Transition Metal Compounds Grown Via Hydrothermal And Molten Flux Methods, Anthony J. Cortese

Theses and Dissertations

Interest in new and facile ways to prepare early transition metal reduced oxides has recently been increasing. In the past difficult flux techniques involving vacuum furnaces, expensive metal tubing, complicated electrolytic reduction apparatuses, were used to achieve in situ reduction of fully oxidized transition metal precursors. Often times these techniques were coupled with use of a difficult flux, such as boric acid, which is hard to remove due to its insolubility in water at room temperature. These limitations can be circumvented in multiple ways, including carefully choosing a redox neutral flux, using evacuated fused silica tubes for reaction vessels, and …

Geospatial Modeling And Assessment Of The Environmentally Sensitive Lands In The Midwestern U.S., William M. Soohoo

Theses and Dissertations

Agricultural land-use change, especially corn expansion, has been accelerating since the 2000s to meet the growing bioenergy demand in the United States. This study identifies the environmentally sensitive lands (ESLs) in the U.S. Midwest and explores the environmental implications of land-use changes in this vital agricultural region. A new distance factor is introduced to a soil erodibility model to take wetlands and waterbodies into account. With a GIS-Ranking Model, the ESLs in 2008 and 2011 (two representative years of corn expansion) in the study region are ranked based on their soil erosion severity. Under various scenarios of bioenergy land-use change …

Alongshore Momentum Balance Over Shoreface-Connected Ridges, Fire Island, Ny, Conor Ofsthun

Theses and Dissertations

Bathymetric variations, such as shoreface-connected ridges (SFCRs), modify inner shelf circulation, altering the significance of and relationships between alongshore momentum balance terms. The inner shelf of Fire Island, NY provides a study site representative of SFCRs around the world. During the winter of 2014, hydrodynamic observations (~12 m depth) from 6 ADCPs, 3 SeaGauge pressure sensors, 2 tide gauges, and 2 meteorological buoys were collected over a region of the inner shelf spanning a full wavelength of one such SFCR. Analysis of the data, under westward wind forcing, revealed a predominantly alongshore circulation with localized offshore (onshore) current veering over …

Studies Of Asphalt Roofing Sealant Failure For Shingle Systems Subjected To High Wind Conditions For Both Elastic And Viscoelastic Sealant Material Response, Artem Aleshin

Theses and Dissertations

It has been documented that the sealant between asphalt roof shingles may delaminate at significantly lower wind speeds than those for which they are rated, with major consequences on safety and repair costs. In perspective, developing more resilient material systems and devising more effective installation procedures are sensible strategies to mitigate this problem. A practical approach may also entail adding a second self-sealing strip. In the first portion of this thesis, the elastic structural response of an asphalt roof shingle-sealant system consisting of individual three-tab shingles, which are bonded to the underlying shingles with two sealant strips and are subjected …

Investigation And Development Of Friction Stir Welding Process For Unreinforced Polyphenylene Sulfide And Reinforced Polyetheretherketone, Hossain Ahmed

Theses and Dissertations

The joining of thermoplastics through welding, a specific form of fusion bonding, offers numerous advantages over mechanical joining. It eliminates the use of costly fasteners and has only a limited effect on the strength of the parts being joined since it does not require the introduction of holes and loading pins, and it does not create significant stress concentrations. A specific form of welding, Friction Stir Welding, was investigated for the creation of butt joints of unreinforced polyphenylene sulfide (PPS) and short carbon fiber reinforced polyetheretherketone (PEEK) plates. Friction stir welding requires a rotating pin, a shoulder arrangement, relative movement …

Solving Atomic Structures Using Statistical Mechanical Searches On X-Ray Scattering Derived Potential Energy Surfaces, Christopher James Wright

Theses and Dissertations

Engineering the next generation of materials, especially nanomaterials, requires a detailed understanding of the material’s underlying atomic structure. These structures give us better insight into structure-property relationships, allowing for property driven material design on the atomic level. Even more importantly, understanding structures in-situ will translate stimuli and responses on the macroscopic scale to changes on the nanoscale. Despite the importance of precise atomic structures for materials design, solving atomic structures is difficult both experimentally and computationally. Atomic pair distribution functions (PDFs) provide information on atomic structure, but the difficulty of extracting the PDF from x-ray total scattering measurements limits their …

Modern Estimation Problems In Group Testing, Md Shamim Sarker

Theses and Dissertations

In the simplest form of group testing, pools are formed by compositing a fixed number of individual specimens (e.g., blood, urine, swab, etc.) and then the pools are tested for a binary characteristic, such as presence or absence of a disease. Group testing is commonly used to screen for a variety of sexually transmitted diseases in epidemiological applications where the main goal is to increase testing efficiency. In this dissertation, we study three estimation problems that are motivated by real-life applications. We propose new methods to model group testing data for both single and multiple infections. In the first problem, …

Semiparametric Joint Dynamic Modeling Of A Longitudinal Marker, Recurrent Competing Risks, And A Terminal Event, Piaomu Liu

Theses and Dissertations

The joint modeling framework has found extensive applications in cancer and other biomedical research. For example, recent initiatives and developments in precision medicine call for appropriate prognostic tools to assist individualized or personalized approaches in cancer diagnosis and treatment. Data generated by clinical trials and medical research often include correlated longitudinal marker measurements and time- to-event information, which are possibly a recurrent event, competing risks, and a survival outcome. Primary interests of joint modeling include the association between the longitudinal marker measurements and time-to-event data, as well as predictions of survival probabilities of new observational units from the same population. …

A Qualitative Study Of How Communities Think About And Act Upon Hunger In The Presence Of A Food Banking System, Eliza Miriam Fishbein

Theses and Dissertations

Hunger is often addressed by providing food directly to those experiencing symptoms of food insecurity and hunger. Even with the availability of government food assistance programs, food insecurity and hunger rates continue to rise. Many local community organizations (e.g., small food banks, faith-based organizations, schools) across the country have come together to create and implement a variety of nongovernment food programs. Although there is no evidence these programs lower food insecurity and hunger rates, community organizations appear to be strongly committed to sustaining these programs. Little is known about the basis for this commitment, i.e., “ the will to act …

Spatio-Temporal Analysis Of The Occupational Fatal Victimization Of Law Enforcement Officers In The Us, Xueyi Xing

Theses and Dissertations

The models with constant coefficients of the covariates across space and time are commonly used in spatio-temporal analyses. However, the associations between risk factors and the outcome could have locally differential temporal trends in many cases. In this study, a Bayesian latent cluster modeling strategy is employed to identify potential spatial clusters in which locally specific sets of temporally varying coefficients of covariates are allowed. A state-level panel data of police officers occupational fatal victimization for the years 1979-2010 is used. To accommodate overdisperson and excess zeros, a negative binomial model and zero-inflated Poisson/negative binomial models are also utilized. A …

Investigating Cross Talk Between The High And Low Iron Sensors In Saccharomyces Cerevisiae, John S. Hepburn

Theses and Dissertations

Iron is essential for nearly all life on earth. Cells must maintain sufficient levels of this important nutrient due its function as a central co-factor for many cellular processes. Although iron is extremely plentiful, its poor solubility requires specialized import. On the other side, too much iron inside the cell can lead to the generation of reactive oxygen species (ROS), which have deleterious effects on many cellular functions and have been implicated in a wide variety of diseases such as cancer and Alzheimer’s disease. Using the model eukaryote Saccharomyces cerevisiae, or budding yeast, our research group has accomplished much in …

Regression Models For Count Data Based On The Double Poisson Distribution, Rebecca Wardrop

Theses and Dissertations

This paper explores the double Poisson distribution. The probability mass function and the difficulties associated with derivative-based optimization for this distribution are discussed. Stata software developed for estimation of double Poisson regression is detailed. Simulations are used to test the software. Data which are over-, under-, and equidispersed relative to the Poisson are generated and the software is utilized to estimate a regression model, a zero-inflated model, and a marginalized zero-inflated model all based on the double Poisson distribution. The estimated power of the test for φ = 1 for the double Poisson models are compared to the power of …

Methane Separation And Purification Via Pressure Swing Adsorption, Lutfi Erden

Theses and Dissertations

Investigations on alternative energy sources have gained increasing attention due to significant shortage in the fossil fuel reserves and increase on the usage of internal combustion engines. Natural gas which mainly consists of Methane has a significant role in short term solution of this issue. Although methane as a greenhouse gas is over 20 times more potent by weight than carbon dioxide, if released directly into the atmosphere, it is a valuable energy source. However, methane is not extracted % 100 pure from the source. Natural gas generally contains many other contaminants such as water, other hydrocarbons, Carbon dioxide, Nitrogen, …

The Impact Of The Choice Of The Item Response Theory Model Used In The Analysis Of Student Response Data From Statewide Educational Assessments, Maureen O’Gorman Petkewich

Theses and Dissertations

The practical significance of the item response theory model (IRT) choice on the results of a statewide assessment was investigated at multiple decision making levels: the examinee level, school and district summary levels, and in terms of impact to subgroups. Data for the study included the student response matrix for South Carolina’s 2014 Palmetto Assessment of State Standards (PASS). The Rasch model, used with PASS and in nearly half of PASS-like multiple-choice statewide assessments in other states, was compared to another popular IRT model used in similar statewide assessments: the 3PL model.

Model fit checks indicated that the 3PL had …

Essays On Retirement, Labor Supply, And Living Arrangements, Anudeep Gill

Theses and Dissertations

Three changes in the U.S. Social Security program affected recent cohorts of older individuals: repeal of the earnings test, increases in the normal retirement age, and increases in the delayed retirement credit. All three policy changes were expected to affect work decisions for those eligible for social security benefits. The first two chapters of my dissertation assess the impact of these policy changes. In the first chapter, using data from the Survey of Income Program and Participation (SIPP) for the years 1996-2013, I study the influence of the three policy changes on the retirement and benefit-claiming decisions of older men …

Dosimetry, Activation, And Robotic Instrumentation Damage Modeling Of The Holtec Hi-Storm 100 Spent Nuclear Fuel System, C. Ryan Priest

Theses and Dissertations

The Holtec HI-STORM 100 spent fuel storage system is an intermediate storage mechanism for SNF assemblies. Long term licensing and storage requires consideration of material degradation of the stainless steel multi-purpose canister holding the spent fuel. This material degradation is predicted to take the form of environmentally assisted cracking on weld interfaces of the stainless steel cylinder. Several of these spent fuel storage arrays are located in coastal environments. These sites include both the Hope Creek and Diablo Canyon nuclear power stations. A multi-sensory robotic package is being designed for non-destructive assay of the cask annular environment. It will be …

Measurements Of Electrostatic Double Layer Potentials With Atomic Force Microscopy, Jason Giamberardino

Theses and Dissertations

The aim of this thesis is to provide a thorough description of the development of theory and experiment pertaining to the electrostatic double layer (EDL) in aqueous electrolytic systems. The EDL is an important physical element of many systems and its behavior has been of interest to scientists for many decades. Because many areas of science and engineering move to test, build, and understand systems at smaller and smaller scales, this work focuses on nanoscopic experimental investigations of the EDL. In that vein, atomic force microscopy (AFM) will be introduced and discussed as a tool for making high spatial resolution …

Development Of Reactions And Methods For Labeling Biomolecules In Cells, Enoch Agbesi Adogla

Theses and Dissertations

The complexity of cellular environments presents a challenge to efforts at studying and elucidating biomolecules in cells. Covalent ligation of biomolecules with fluorescent molecules that have a reactive functional group that can react with a complementary functional group on biomolecules is one way that has been utilized to study biomolecules. It enables visualization and tracking of ligation and transportation of molecules within the cell. However, the myriad of functional groups within the cell makes achieving selectivity difficult. To circumvent this problem, reactions that do not interfere with biology have been developed. These reactions, referred to as bioorthogonal reactions must be …

Physics Based Modeling Of Guided Waves For Detection And Characterization Of Structural Damage In Nde And Shm, Banibrata Poddar

Theses and Dissertations

Guided waves based damage detection techniques are popular for their ease of generation and detection along with their ability to travel long distances. Accurate and efficient modeling is a key for successful implementation of guided waves for NDE/SHM. However, efficient prediction of scattering from various damage is challenging due to the complex nature of these guided waves.

This dissertation presents as physics based efficient and accurate modeling techniques to predict ultrasonic wave propagation and their interaction with various damage. Detection and characterization of damage in structures can typically be divided into two categories, active and passive. This research is aimed …

Positioning Commuters And Shoppers Through Sensing And Correlation, Rufeng Meng

Theses and Dissertations

Positioning is a basic and important need in many scenarios of human daily activities. With position information, multifarious services could be vitalized to benefit all kinds of users, from individuals to organizations. Through positioning, people are able to obtain not only geo-location but also time related information. By aggregating position information from individuals, organizations could derive statistical knowledge about group behaviors, such as traffic, business, event, etc.

Although enormous effort has been invested in positioning related academic and industrial work, there are still many holes to be filled. This dissertation proposes solutions to address the need of positioning in people’s …

The Development Of A Miniature Spatial Heterodyne Raman Spectrometer For Applications In Planetary Exploration And Other Extreme Environments, Patrick Doyle Barnett

Theses and Dissertations

Space exploration is arguably one of the most important endeavors our species has ever undertaken. Rapid advances in rocketry and robotics in recent years has allowed for positioning of complex scientific instruments on other planets with a precision that was previously thought impossible. This, along with the need for more sophisticated chemical measurements to achieve the goals of new, more ambitious missions and recent advances in in-situ and remote spectroscopic techniques, has led to a boom in the use of spectroscopic instruments for space exploration. However, future missions to the moons of Jupiter and Saturn, along with other planetary bodies …

3d Seismic Depth Imaging And Velocity Model Building In Anisotropic Media: Serri Oil And Gas Field, Saudi Arabia, Ali Jomaah Alsalem

Theses and Dissertations

Seismic imaging is a significant element in hydrocarbon exploration to locate drilling prospects and it relies mainly on an accurate velocity model. Prestack depth migration (PreSDM) versus traditional post-stack time migration has become a common method for seismic velocity model building and imaging. This methodology accounts for seismic velocity anisotropy of the propagating waves in the subsurface with a higher level of accuracy in positioning the seismic events in their true positions in the subsurface.

In this thesis, we examine a 303 km2 of 3D seismic data acquired by Saudi Aramco in the Serri field of North-West Saudi Arabia. The …

Implementation Of Agile Project Management In The Classroom, Michael Jerrod Myers

Theses and Dissertations

The world of engineering and engineering practices is advancing rapidly. In response to this rapid change, engineering education practices have to advance to ensure students are properly trained for the workforce. The purpose of this report is to address and substantiate the hypothesis that if engineering instruction incorporated Agile project management methods, then students will be challenged by professors to accomplish course objectives with a systematic and timely approach that will improve assessment performance metrics and present the framework of how agile methods of project management can be integrated into the classroom. The agile methods incorporated will also encourage the …

Hadronic Lorentz Violation In Chiral Perturbation Theory, Rasha Kamand

Theses and Dissertations

The leading-order Lorentz-violating hadronic Lagrange densities are constructed using chiral perturbation theory. This is done for both pions and nucleons starting from a two-flavor quark-level Lagrangian that consists of dimension-four Lorentzviolation operators. The effective Lagrangians are first constructed in the absence of external fields. The formalism is then extended to include interactions with external fields. The presence of Lorentz violation modifies the transformation behavior of external fields under the chiral group SU(2)L × SU(2)R. This in turn leads to modified pion and nucleon covariant derivatives. By expanding parts of both mesonic and baryonic Lagragians in terms of physical pion and …

Using Synthetic Lectins To Investigate Metastatic Potential In Colon Cancer, Erin E. Gatrone

Theses and Dissertations

Cancer is a disease that affects millions of people each year and it is well established that early diagnosis is a key factor towards improving survival rate, with that in mind there is a great need for better diagnostics. From the earliest onset of cancer, changes can be detected in the type and amount of carbohydrates expressed by the cancer cells, i.e., aberrant glycosylation. This process results in differing glycosylation patterns that can be used to detect cancer. Aberrant glycosylation can also greatly affect the potential of cancer cells to metastasize and can be used to stage the disease as …

The Relationship Between Peer-Self Concept And Academic Self-Concept In Elementary Students: A Person-Oriented Perspective, Catherine Jorgensen Snyder

Theses and Dissertations

Self-concept is one of the most researched constructs in educational psychology (Marsh, Xu, & Martin, 2012). It has been established that there are different domains of self-concept which fall into two main categories, academic and non-academic (Shavelson, Hubner, & Stanton, 1976). Unfortunately, little research has been conducted on the non-academic areas of self-concept and little is known about how social self-concept interrelates with academic self-concept. The focus of this study was to contribute to the research base by investigating the relationship between a facet of nonacademic self-concept, namely peer self-concept, and achievement self-concept among elementary students.

The current research utilized …

Semiparametric Estimation Methods For Complex Accelerated Failure Time Model, Yinding Wang

Theses and Dissertations

The proportional hazards (PH) model and the accelerated failure time (AFT) model are the two most popular survival models in fitting the right-censored data. The AFT model is a useful alternative to the PH model, particularly when the PH assumption is not satisfied. Usually, the linear association is assumed with logarithm of survival time in the AFT model. However, the nonlinear association may exist in practice. The first project aims to handle the nonlinear component in the AFT model, which is called the semiparametric additive partial accelerated failure time (AP-AFT) model. Two estimation methods based on the rank-smooth method and …