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Meet Me At The Liberty Tree: Book I, Aaron J. Romano-Meade

Open Access Theses & Dissertations

The first part of a novel entitled "Meet Me at the Liberty Tree."

Synthesis Of Neoglycoproteins/Neoglycopeptides And Their Immunological Evaluation In The Context Of Chagas Disease, Nathaniel Scott Schocker

Open Access Theses & Dissertations

The protozoan parasite, Trypanosoma cruzi, the etiologic agent of Chagas disease (ChD), has a cell surface covered by immunogenic glycoconjugates. A synthetic glycoarray containing non-reducing α-galactopyranosyl moieties related to mucin O-glycans of the parasite T. cruzi was evaluated by a chemiluminescent enzyme-linked immunosorbent assay (CL-ELISA) with sera from patients with chronic ChD, revealing the disaccharide Galα(1,3)Galβ as the immunodominant glycotope (Chapter 2). This disaccharide comprises the two terminal sugars of the known immunodominant glycotope Galα(1,3)Galβ(1,4)GlcNAcα, which is expressed on glycosylphosphatidylinositol-anchored mucins of the infective trypomastigote stage of T. cruzi and triggers high levels of protective anti-α-Gal antibodies (Abs) in infected …

An Analysis Of Psychologist Postdoctoral Psychopharmacology Training Materials For Critiques Of Neurobiological Hypotheses Of Depression's Etiology, Critical Analyses Of The Dsm's Rigor, And For Consumer/Survivor/Ex-Patient Content., Chris William Nicholas Rowe

Antioch University Dissertations & Theses

There is widespread agreement that neurobiology plays a role in psychological distress and that psychiatric diagnosis and associated psychopharmacological interventions can be helpful. However, there are also unresolved issues surrounding the limits of empirical support for current diagnostic criteria, shortcomings in neurobiological explanations of psychopathology, and unanswered questions about the mechanism, safety, and efficacy of psychiatric medications. This has implications for treatment errors which can precipitate negative socio-economic and health consequences, particularly for vulnerable groups like the Consumer/Survivor/Ex-Patient (c/s/x) population. It is for these reasons that the training psychologists receive to prescribe should, in addition to integrating the critiques of …

Hybrid Surface Phononic Waveguide Using Hyperbolic Boron Nitride, Yuancheng Xu, Navaneeth Premkumar, Yuchen Yang, Brian A. Lail

Electrical Engineering and Computer Science Faculty Publications

Sub-diffraction limited waveguides have been studied as a means to manipulate light into nanoscale regions. Hybrid waveguides are popular candidates in optical regimes for subwavelength confinement and long range propagation. However, advances in the mid-IR are lacking due to high propagation losses and limited confinement. Here we present the first analysis of hybrid phononic waveguide using a hyperbolic material h-BN to generate surface phonon polaritons. The strong coupling between the photonic cylinder and phononic surface enhances the confined field up to 10-3 λo2 (λo is free-space wavelength) and enables propagation distances up to 100 λo. Our work is fully compatible …

Design Of A Thermal Management System For An Oxy-Methane Direct Power Extraction Combustor, Jad Gerges Aboud

Open Access Theses & Dissertations

The overarching goal of this Thesis is to present the design of a thermal management system for an oxy-methane direct power extraction combustor. The design is initiated by performing a 2D analysis on the combustor geometry and then using these results in a 3D model. This is done by using results for heat transfer coefficient and temperatures found from the 2D simulation and importing these to the 3D model. The approach used here couples the combustion process, heat transfer through the chamber wall, and fluid flow behaviors in order to observe the thermal characteristics of the combustor during operation. This …

Modulation Of The Physiological And Biochemical Effects Of Copper Nanoparticles In Kidney Beans (Phaseouls Vulgaris) Treated By Kinetin, Suzanne Annette Apodaca

Open Access Theses & Dissertations

It is imperative to not only understand the impact of engineered nanomaterials (ENMs) in edible plants, but also the interactions they have with various additives used in agriculture. In this study, kidney bean plants were grown in potting soil treated with nano copper (nCu), bulk copper (bCu), and copper chloride (CuCl2) at concentrations of 0, 50, and 100 mg/kg for 55 and 90 days. At 15 days of growth, 0, 10, and 100 μm of kinetin (KN) were applied to plants. Plant tissue samples were harvested at 55 days and seeds were reaped at 90 days. Physiological and biochemical parameters …

Dft Study On The Structure And Properties Of Vsc2n@C68, Surendra Bhatta

Open Access Theses & Dissertations

A computational study on the structure and electronic properties of the VSc2N@C68 molecule was carried out using the density functional theory. This molecule is based on the recent report on the synThesis of the VSc2N@C80 and V2ScN@C80 fullerenes. The Sc3N@C68 is also a stable endohedral fullerene that has a cage with fuse pentagonal rings. The doping by a V atom changes the structure as well as the spin state of the Sc3N@C68 from S=0 to S=1 state. Since the C68 has 6332 isomers, we have carried out an extensive search for the lowest energy structure of the C68 in several …

Synthesis And Characterization Of Uranyl Dipyrrin Complexes For Environmental Applications, Duer Bolotaulo Bolotaulo

Open Access Theses & Dissertations

Persistent organic pollutants (POPs) are toxic chemicals that adversely affect the health of human populations as well as the environment. The need to develop remediation methods and materials as well as understand the mechanisms in which they can degrade POPs is necessary. Furthermore, heterogeneous phase metal based catalysts in place today do not fully understand the chemistry underlying degradation processes. The proposed research seeks to synthesize and characterize uranyl dipyrrin complexes to assess and understand the reactivity of uranyl dipyrrins with pollutants. Photophysical and electrochemical techniques will be used to characterize and determine the viability of utilizing the uranyl complexes …

Design Of Experiments-Based Scara Robot Parameter Evaluation For Embedding Electronics Into 3d Print, Sreekara Charith Boppana

Open Access Theses & Dissertations

Additive manufacturing processes combined with enhanced technologies for electronics production enables a highly flexible manufacturing of personalized 3D electronic devices. Due to the enormous progress within the last years, these technologies made their way from prototyping towards manufacturing. The growing request for products manufactured in batch size, making use of a robot to incorporate the electronic components necessary to make functional 3-Dimensional-Structural Electronics will extend the mass production possibilities. There is significant interest in automation of a process is which parameters are influential in the occurrence of assembly defects and which adjustments should be made to those variables to reduce …

Adaptive Switched Capacitor Voltage Boost For Thermoelectric Generation, Rene A. Brito

Open Access Theses & Dissertations

Thermoelectric generators (TEG) and other forms of energy harvesting often provide voltages that are not directly usable by traditional electronics as levels are too low from the TEG. While increasing the number of thermoelectric elements can ultimately increase the power output, there is a tradeoff between size and power. By implementing charge pumps, a proposed circuit technique is described that can boost the TEG output to levels that can be used for energy harvesting applications. Current voltage boost circuits for TEGs simply boost a voltage by a set amount. The proposed circuit consists of an analog chip, to provide several …

The Characterization Of A Recombinant Virophage Integrase, Martin Christopher Chacon

Open Access Theses & Dissertations

Virophages are satellite-like dsDNA viruses that parasitize giant viruses of the family Mimiviridae. Mavirus is the second virophage discovered that associates with its host virus Cafeteria roenbergensis Virus (CroV). When co-infecting their common host cell Cafeteria roenbergensis, a marine zooplankton that is widely spread throughout the oceans, mavirus will inhibit CroV's replication. In addition, mavirus was shown to share high similarities to the Maverick/Polinton eukaryotic DNA transposons. A coding sequence in mavirus genome (MV02) reveals high homology to retroviral integrases such as those found in HIVs. The putative integrase MV02 is predicted to integrate mavirus DNA into the host genome. …

Teacher's Sense Of Self Efficacy And Grit And Its Relationship To Student Achievement, Dino M. Coronado

Open Access Theses & Dissertations

Darling-Hammond (2006) stated that "one of the most damaging myths prevailing in American education is the notion that good teachers are born and not made" (p. xi). On the other hand, if there is a need to improve the education system in the United States, there must be a conscientious effort to identify, recruit, select, and develop quality people to become teachers-there needs to be an emphasis on "quality people."

The purpose of this quantitative study is to determine the relationship between a high school teacher's grit and sense of self-efficacy and the Houston Independent School District's teacher's Educator Value-Added …

Reconstructing Late Pleistocene And Holocene Paleoenvironments Using Playa-Lunette System Sediments Within The Harney Basin Of Southeastern Oregon, Usa, Joe Collins

Open Access Theses & Dissertations

Paleoenvironmental investigations of the Late Pleistocene and Early Holocene in the Harney Basin of eastern Oregon have been limited to date. This Dissertation investigates and links the stratigraphy of Rimrock Draw Rockshelter (35HA3855) (RDR) and two surrounding playas, Rimrock Lake and Hay Lake, located on the western margin of the Harney Basin, in order to identify paleoenvironmental shifts during the last ~20 kyr. An emphasis also is given to demonstrating the potential for playas in the Harney Basin to record changes in paleoclimate, as well as the application of multivariate statistics to interpret paleoenvironments from sedimentary grain size data. Stratigraphy …

A Novel Approach For Evaluating The Impact Of Fixed Variables On Photovoltaic (Pv) Solar Installations Using Enhanced Meta Data Analysis Among Higher Education Institutions In The United States, Diane N. De Hoyos

Open Access Theses & Dissertations

The global demand for electric energy has continuously increased over the last few decades. Some mature, alternative generation methods are wind, power, photovoltaic panels, biogas and fuel cells. In order to find alternative sources of energy to aid in the reduction of our nation's dependency on non-renewable fuels, energy sources include the use of solar energy panels. The intent of these initiatives is to provide substantial energy savings and reduce dependence on the electrical grid and net metering savings during the peak energy-use hours.

The focus of this study explores and provides a clearer picture of the adoption of solar …

Scalability Improvements To Nrlmol For Dft Calculations Of Large Molecules, Carlos Manuel Diaz

Open Access Theses & Dissertations

Advances in high performance computing (HPC) have provided a way to treat large, computationally demanding tasks using thousands of processors. With the development of more powerful HPC architectures, the need to create efficient and scalable code has grown more important. Electronic structure calculations are valuable in understanding experimental observations and are routinely used for new materials predictions. For the electronic structure calculations, the memory and computation time are proportional to the number of atoms. Memory requirements for these calculations scale as N2, where N is the number of atoms. While the recent advances in HPC offer platforms with large numbers …

Impacts Of Environmental Changes To The Middle Rio Grande Landscape On Ysleta Del Sur Pueblo's Cultural And Cermonial Sustainability, Andrea L. Everett

Open Access Theses & Dissertations

Given future climate scenarios, this Thesis investigates how plausible climate changes will further impact the Native American community of Ysleta del Sur Pueblo's (Tiguas) cultural continuity and access to riparian ecosystem services along the Rio Grande River (specific to Tigua tradition; riparian vegetation used in ceremony, i.e. Gooding's and Coyote willow). The project aims to (1) describe and understand the relationship between regional climatic changes, anthropogenic changes, and major events in Tigua history, (2) identify rates and patterns of riparian vegetation changes, (3) evaluate impacts on cultural and provisioning ecosystem services relevant to Tigua culture, and relate these to climate …

Structural, Dielectric, And Ferroelectric Characterization Of Lead-Free Calcium-Cerium Co-Doped Batio3 Ceramics, Juan Alberto Duran

Open Access Theses & Dissertations

Structure, morphology, and regulation of the dielectric properties via close-composition intervals is demonstrated for variable-cerium, constant-calcium co-doped barium titanate (Ba0.80Ca0.20CeyTi1-yO3; y=0.0-0.25; referred to BCCT). The effect of variable Ce-content on the structure and dielectric properties of BCCT is investigated. X-ray diffraction spectra confirms the studied samples are mainly in BT tetragonal phase with a small secondary phase detected as CaTiO3 in BCCT for y = 0.20 and 0.25. However, the lattice parameter reduction was evident with increasing Ce-content. Composition-driven dielectric constant leap (4,000-5,500) was observed from intrinsic BCT to BCCT for (y = 0.0-0.04). The temperature dependent dielectric constant showed …

New Organosilicon Chemistry, Paulina Elena Gonzalez Navarro

Open Access Theses & Dissertations

The formation of siloxymethylamine intermediates R3SiOCH 2NMe2, 1, as initial products of the reduction of DMF by hydrosilanes catalyzed by Mo(CO)5NMe3 has been reported. These siloxymethylamines can react with R’3SiH to form trimethylamine and disiloxanes, and with chlorosilanes to form disiloxanes and ClCH 2NMe2, Eschenmoser’s salt. I shall illustrate, in Chapter 1, how attempts to react 1, formed in situ in the presence of chlorosilanes R’3SiCl in the hope producing heterosilyl disiloxanes, R3SiOSiR’3, was not successful but led to a newly discovered activation of the Si-Cl bond by DMF.

In Chapter 2, we surmised that 1 acts as a transient …

A Unified Cyber-Enhanced Approach For Detecting Cross-Site Scripting Attacks On Web Applications, Bhanukiran Gurijala

Open Access Theses & Dissertations

Cyber-security is one of our nation's most critical security priorities, and its importance continues to grow with the pervasiveness of computers and Web-based applications. In particular, cross-site scripting (XSS) is one of the most common and dangerous types of injection attacks that exploit input validation vulnerabilities. XSS has intensified due to: 1) lack of extensive security domain knowledge of software engineers who are involved in building and/or maintaining Web-applications; and 2) lack of proper software development processes focused on security, resulting in fixes to security vulnerabilities late in the software development lifecycle. Indeed, the cost benefits of removing defects, in …

Design And Experimental Investigation Of An Oxy-Fuel Combustion System For Magnetohydrodynamic Power Extraction, Manuel Johannes Hernandez

Open Access Theses & Dissertations

A general consensus in the scientific and research community is the need to restrict carbon emissions in energy systems. Therefore, extensive research efforts are underway to develop the next generation of energy systems. In the field of power generation, researchers are actively investigating novel methods to produce electricity in a cleaner, efficient form. Recently, Oxy-Combustion for magnetohydrodynamic power extraction has generated significant interest, since the idea was proposed as a method for clean power generation in coal and natural gas power plants. Oxy-combustion technologies have been proposed to provide high enthalpy, electrically conductive flows for direct conversion of electricity. Direct …

A Decision Making Approach For Selection Of Sustainable Pavements In Texas By Integrating Life Cycle Cost Analysis (Lcca), Life Cycle Assessment (Lca) Of Environmental And Social Impacts, Sundeep Inti

Open Access Theses & Dissertations

A sustainable pavement can be defined as the one that minimally impacts future economic opportunities, social conditions, human health, and the environment and still fulfills the engineering objectives. Although a pavement as outlined above is not yet entirely feasible, continual effort from every stakeholder with a vision of achieving sustainable development is essential for the future of society. In this study, one such effort was initiated by proposing a framework for selection of pavement design based on sustainable development.

The concept of sustainability is widely believed to be founded on three criteria: economic, environmental, and social standards. Since the purpose …

Sparse Matrix Diagonalization In The Nrlmol Electronic Structure Code, Md Mahmudulla Hassan

Open Access Theses & Dissertations

Density functional theory (DFT) based simulations are playing a major role in quantum mechanical studies of materials ranging from molecules, nanoparticles to the biological systems as they offer insights that are not directly accessible from experiments and also due to their ability to make sufficiently accurate predictions. The DFT implementation in the NRLMOL electronic structure code employs Gaussian basis sets to express the Kohn-Sham orbitals. A major computationally demanding task in the electronic structure calculations is solution of the generalized eigenvalue problem, that is the determination of nontrivial solutions (λ, c) of Hc = λOc where H and O are …

The Viability Of High-Frequency Oscillation Analysis In Eeg Signals For Seizure Prediction, Bryan David Kern

Open Access Theses & Dissertations

Seizure prediction is a decades-old research problem that has yet to reach any satisfying conclusions. Many studies have tackled the problem with varying results, but there has yet to be any major breakthroughs that define the direction of all future research. However, a promising, new predictor may have presented itself in recent years in the form of high frequency oscillations (HFOs). With the discovery of HFOs (80 - 800 Hz) as a biomarker for epilepsy, new interest has been placed in studying the high frequency content of EEGs to find a possible link between epilepsy and HFOs. In this paper, …

Modeling And Testing Of Functional Materials For Energy System Applications, Hasanul Karim

Open Access Theses & Dissertations

Energy efficiency is one of the key concerns addressing the problem of global warming. Numerous research has been going on in order to improve the efficiency of energy conversion systems to reduce the polluted emission in the atmosphere. One of the approach is monitoring and maintaining the critical parameters of operation such as temperature to ensure the desired reactions, however, the harsh environment present in these systems makes the use of current temperature sensing solutions such very challenging to implement. Wireless temperature sensors are getting increasing attention as a potential solution, however, the need of energy storage devices such as …

Density Functional Study Of Reactivity And Regioselectivity Of H2o@C60, Govinda Bahadur Kc

Open Access Theses & Dissertations

The exohedral reactivity of endohedral fullerene has aroused significant interest because of its potential applications in biology, medicine and material science. The encapsulation of a single water molecule without any hydrogen bonding to other compounds, inside the hydrophobic environment of C60 is an intriguing topic to study about. In 2011, Kurotobi and Murata successfully synthesized H2O@C60 fullerene. The presence of a polar water molecule inside the cage is expected to cause changes in the exohedral reactivity of C60. In order to find out the impact of an entrapped single water molecule on the reactivity of C60 fullerene, we use density …

Removal Of Endocrine Disrupting Compounds From Water And Wastewater Using Ecofriendly Materials, Alma Lili Loya Posada

Open Access Theses & Dissertations

Endocrine disrupting chemicals (EDCs) are compounds considered pollutants of emerging concern. The United States Environmental Protection Agency (USEPA) defines emerging pollutants as new chemicals without regulatory status and with an impact on the environment and human health that is poorly understood. Bisphenol A (BPA) has been considered an EDC and found to be ubiquitous in the environment because of its presence in a multitude of products including food and beverage packaging, flame retardants, adhesives, building materials, electronic components, and paper coatings Currently, BPA is not regulated by the federal government in the US and waste water treatment plants are not …

Equation Of State Of A Dense And Magnetized Neutron System, Md Masud

Open Access Theses & Dissertations

Neutron stars (NSs) are the windows to check the validation of physical laws at extreme conditions, for example, at very high densities and strong magnetic fields and thus to reach the equations of state (EoS) for a better understanding of the structure as well as the composition of the NSs. In our investigations, it is found that the system's (NSs) pressure becomes anisotropic due to the breaking of rotational symmetry in the presence of strong magnetic fields, which even can be significantly sufficient to lead into the deformation of NSs or to destroy itself.

Geology And Mineralization Controls Surrounding The Palmarejo Mining District - A Compilation Of Remote And Hands On Exploration Techniques, Castulo Molina Sotelo

Open Access Theses & Dissertations

Exploration is the base of the mining industry, and it is often taken as synonymous with "finding a mine". In reality it is a more complex process; where the selection, evaluation, screening and testing of successively smaller areas lead to the discovery of an economic deposit. Once the deposit is found, the economic factors become more important than the geological ones, and then the exploration becomes a tool to give sustainability to the mining operation through time.

The silver and gold deposits of the world-class Palmarejo District are typical, intermediate sulfidation- style epithermal, precious metal occurrences, hosted in Cretaceous- to …

A Geophysical Investigation At The Potrillo Maar, Manuel Moncada Gutierrez

Open Access Theses & Dissertations

The Potrillo Volcanic Field (PVF) is a unique geological site located in Doña Ana County the southernmost part of New Mexico, and part of northern part of Chihuahua, Mexico. The main feature of the southern PVF is Potrillo Maar. This maar-volcano straddles the international boundary between United States and Mexico and lies within the southern part of the Rio Grande Rift. The Potrillo Maar was formed about 20,000 years ago in three major events that formed basalt lava flows and ejecta deposits that consist of crustal and mantle xenoliths.

The purpose of this Thesis is to determine the area of …

Reconstructing Dinosaur Foot Tracks And Identifying New Footprints Using Structure From Motion Photogrammetry, Valeria V. Martinez

Open Access Theses & Dissertations

The use of 3-D Structure from Motion models to study fossils is a relatively new technique that has an advantage over traditional field methods, such as plaster casts or collecting samples, because it is non-destructive and can be easily shared with a wide audience. It is also ideal for use with persons with disabilities because it does not require field access and it can be manipulated for optimum computer viewing or printed with a 3-D printer for tactile examination as needed. Our study focused on a known site in Cristo Rey, New Mexico where Cretaceous Iguanadon and Ankylosaur footprints have …