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Effective Recognition Of Multiple Anions By An Azobenzene--Al$^{\Mathbf{3+}}$ System, Ye Zhang, Ping Jia, Zhangfa Tong, Hai-Bo Liu, Jing Wang

Turkish Journal of Chemistry

A ready-to-use multifunctional coordinative system, 2,2'-dihydroxyazobenzene --aluminum (III) (DHAB--Al$^{3+})$, was created to recognize several anions effectively through three channels, namely colorimetric detection, UV-Vis spectroscopy, and fluorescence spectroscopy. Under naked eye visualization, the H$_{2}$PO$_{4}^{-}$ can be readily distinguished from the other anions by the DHAB--Al$^{3+}$ system through a change in color from reddish-orange to light yellow. H$_{2}$PO$_{4}^{-}$ was qualitatively detected by using UV-Vis and fluorescence spectra. Differentiating SO$_{3}^{2-}$, HPO$_{4}^{2-}$, and HCO$_{3}^{-}$ anions colorimetrically is difficult; thus, CO$_{3}^{2-}$, SO$_{3}^{2-}$, HPO$_{4}^{2-}$, and HCO$_{3}^{-}$ were discriminated by adopting distinct changes in the UV-Vis spectra. CO$_{3}^{2-}$, HPO$_{4}^{2-}$, and HCO$_{3}^{-}$ were accurately quantified using fluorescence spectra. …

Synthesis, Characterization, And Electrical And Optical Properties Of Magnesium-Type Boracite, Tuğba İbroşka, Azmi̇ Seyhun Kipçak, Süreyya Aydin Yüksel, Emek Derun, Sabri̇ye Pi̇şki̇n

Turkish Journal of Chemistry

Synthesis of the magnesium type of the mineral boracite (Mg$_{3}$B$_{7}$O$_{13}$Cl) was studied. Several parameters affecting boracite synthesis were investigated. The raw materials selected were magnesium chloride hexahydrate (MgCl$_{2}$.6H$_{2}$O), magnesium oxide (MgO), and boron oxide (B$_{2}$O$_{3})$. Reaction temperatures were selected between 600~$^{\circ}$C and 900 $^{\circ}$C. Moreover, three different reaction times of 4, 1, and 0.5 h were studied with the determined optimum molar ratio, reaction temperature, and reaction medium. Synthesized boracite characterization analyses were done by the techniques of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscope (SEM). Reaction yields were also calculated. From the results of …

Separation And Preconcentration Of Lead(Ii), Cobalt(Ii), And Nickel(Ii) On Edta Immobilized Activated Carbon Cloth Prior To Flame Atomic Absorption Spectrometric Determination In Environmental Samples, Zeid Abdullah Alothman, Erkan Yilmaz, Mohamed Habi̇la, Mustafa Soylak

Turkish Journal of Chemistry

The synthesis and characterization of ethylenediaminetetraacetic acid immobilized activated carbon cloth was performed in the present work. It was used for preconcentration-separation of lead(II), cobalt(II), and nickel(II) at trace levels as an adsorbent. Factors including pH, concentration and volume of eluent, sample and eluent flow rates, sample volume, and effect of coexisting ions on the solid phase extraction of analytes were examined. The preconcentration factor was 50. The detection limits for Pb(II), Co(II), and Ni(II) were 4.39, 0.99 and 0.91 $\mu $g L$^{-1}$, respectively. The adsorption capacity for Pb(II), Co(II), and Ni(II) ions was found as 11.0, 11.2, and 10.2 …

Properties And Some In Vitro Studies Of 6-Phosphogluconate Dehydrogenase Purified From The Liver Of Chalcalburnus Tarichi, The Only Fish Living In Lake Van's Highly Alkaline Water (Ph 9.8), Muhammet Güler, Vedat Türkoğlu, Mehmet Riza Kivanç

Turkish Journal of Chemistry

In this study, some enzymology parameters and some antibiotics affecting the enzyme activity of 6-phosphogluconate dehydrogenase (6PGD) extracted from t the livers of fish from Lake Van (\textit{Chalcalburnus tarichi}) were investigated because it is an important enzyme-producing NADPH, a reductive power, protecting the cell against the oxidative agents by producing reduced glutathione. The crude enzyme solution was obtained by using the affinity chromatography method. The native molecular weight of the enzyme is $\sim $90,000 $\pm $ 3000 Da and it is composed of two subunits with identical molecular weights of $\sim $46,000 Da as exhibited on sodium dodecyl sulfate-polyacrylamide gel …

Green And Efficient Synthesis Of Novel Bispyrazoles Through A Tandem Knoevenagel And Michael Type Reaction Using Nanowire Zinc Oxide As A Powerful And Recyclable Catalyst, Khalil Eskandari, Bahador Karami, Saeed Khodabakhshi, Seyyed Jafar Hoseini

Turkish Journal of Chemistry

Zinc oxide nanowires (ZnO NWs) were prepared and characterized by scanning electron microscopy, powder X-ray diffraction, and transmission electron microscopy analyses. ZnO NWs were then employed as heterogeneous and recyclable catalyst for green synthesis of some new and known bispyrazole derivatives through a tandem Knoevenagel and Michael type addition reaction of aromatic aldehyde and pyrazolone. The synthetic method is operationally simple and affords product with high yields in short reaction times.

Corrosion Inhibition By Naturally Occurring Hibiscus Sabdariffa Plant Extract On A Mild Steel Alloy In Hcl Solution, Magda Abdo Mahmoud Ameer, Amany Mohamed Fekry

Turkish Journal of Chemistry

The corrosion inhibition of mild steel alloys is of tremendous technological importance due to their increased industrial applications. Potentiodynamic polarization and electrochemical impedance spectroscopy techniques were used to establish the effect of different concentrations of HCl on the corrosion behavior of mild steel. A study was conducted on the inhibition of dissolution for a mild steel alloy in the most corrosive concentration of HCl (5 M) by adding different concentrations of aqueous extract of \textit{Hibiscus sabdariffa} plant (named karkade or rosselle) as an ecofriendly inhibitor. The extent of corrosion inhibition as measured by the two techniques was comparable. The results …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Cross Coupling Reactions Catalyzed By (Nhc)Pd(Ii) Complexes, Nevi̇n Gürbüz, Emi̇ne Özge Karaca, İsmai̇l Özdemi̇r, Beki̇r Çeti̇nkaya

Turkish Journal of Chemistry

This review is focused on new developments reported during the last 3 years concerning the catalytic performances of in situ formed or preformed NHC--Pd(II) complexes (NHC: $N$-heterocyclic carbene) for cross-coupling reactions such as Heck--Mizoraki (often shortened to the Heck reaction), Kumada, Negishi, Suzuki--Miyaura (often shortened to the Suzuki reaction), Sonogashira and Hiyama couplings, and the Buchwald--Hartwig aminations, which are extremely powerful in the formation of C--C and C--heteroatom bonds. Due to the great number of publications and limited space here, we made a special attempt to compile the relevant data in tables, which we hope will serve as a guide …

Theatre Safety In Louisiana Secondary Schools: A Survey Study, Christopher Pyfrom

LSU Master's Theses

Participation in secondary school theatre can have many benefits including the development of improved reading comprehension, self-concept, and empathy. In the world of professional theatre, each design area has its own department head and several levels of assistants and workers below them. Yet in the world of secondary school theatre, we expect one person to assume all of those roles in addition to the regular responsibilities of teaching. Not many people see theatre as being dangerous when compared to sports, science labs, or vocational education. However, it can contain many of the same risks. This study investigated several factors that …

Relativistic Configuration Interaction Calculations Of The Atomic Properties Of Selected Transition Metal Positive Ions; Ni Ii, V Ii And W Ii, Marwa Hefny Abdalmoneam

Dissertations, Master's Theses and Master's Reports

Relativistic Configuration Interaction (RCI) method has been used to investigate atomic properties of the singly ionized transition metals including Nickel (Ni II), Vanadium (V II), and Tungsten (W II). The methodology of RCI computations was also improved. Specifically, the method to shift the energy diagonal matrix of the reference configurations was modified which facilitated including the effects of many electronic configurations that used to be difficult to be included in the energy matrix and speeded-up the final calculations of the bound and continuum energy spectrum. RCI results were obtained for three different cases:

1. Atomic moments and polarizabilities of Ni II; …

Lenses Of Industry: The Rise Of Industrial Photography In The United States And The Lake Superior Mining District, 1880-1933, Robert Anthony

Dissertations, Master's Theses and Master's Reports

This thesis, Lenses of Industry, examines how industrial companies and engineers adapted photography to their needs in the late nineteenth and early twentieth centuries. Innovations in camera and plate technologies marketed to a broad range of people contributed to a steep rise in the number of photographers in the United States. Recognizing the potential that photography held for industrial companies and engineers, a handful of experts advocated the idea that photography had the potential to make many aspects of business faster, and easier, as well as to make visual records more truthful and accurate. Likewise, innovations in halftone printing technology …

The 2009 And 2011 Hazard Events At San Vicente Volcano, El Salvador: Vulnerability, Resettlement, And Disaster Risk Reduction, Luke Bowman

Dissertations, Master's Theses and Master's Reports

Scientists from a variety of disciplines have made major advancements in the geophysical and social aspects of hazard science. Despite these advancements, economic losses and the number of people affected by disasters continue to rise. The field of disaster risk reduction (DRR) attempts to counter this rising trend of disaster losses by integrating a variety of disciplines to holistically solve complex problems related to risk and vulnerability. Frequent disasters in El Salvador provide insight into the evolution of DRR and its application during and after two hydrometeorological disasters in the department of San Vicente in 2009 and 2011. This dissertation …

Investigating The Effect Of Photographic Representations On Scores Of The Stroke And Aphasia Quality Of Life Scale-39 For People With Moderate To Severe Aphasia, Samantha Studrawa

LSU Master's Theses

Background: The Stroke and Aphasia Quality of Life-39 (SAQOL-39) is a valid and reliable measure of quality of life (QOL) for stroke survivors and people with mild-to-moderate aphasia However, it could not be validated for people with severe aphasia due to their language deficits. Research has shown that combining pictures with written text can support communication effectiveness of people with aphasia. Combining language modalities in this way is a form of alternative or augmentative communication (AAC). The use of AAC has been explored as a possibility to improve communication for people with severe aphasia (Dietz, McKelvey & Beukelman, 2006). Aim: …

Development And Operation Of A Mobile Test Facility For Education, Christopher Davis

Dissertations, Master's Theses and Master's Reports

The automotive industry saw a large shift towards vehicle electrification after the turn of the century. It became necessary to ensure that new and existing engineers were qualified to design and calibrate these new systems. To ensure this training, Michigan Tech received a grant to develop a curriculum based around vehicle electrification. As part of this agenda, the Michigan Tech Mobile Laboratory was developed to provide hands-on training for professional engineers and technicians in hybrid electric vehicles and vehicle electrification. The Mobile Lab has since then increased the scope of the delivered curriculum to include other automotive areas and even …

Model Predictive Control Of Building Energy Management Systems In A Smart Grid Environment, Jeremy Dobbs

Dissertations, Master's Theses and Master's Reports

Buildings are a major source of energy consumption. In the United States, buildings are responsible for more than 70% of all power consumption. Over 40% of this building power consumption is from the Heating, Ventilation, and Air Conditioning (HVAC) systems. Modern technologies such as building Energy Storage Systems (ESS), renewable energy sources, and advanced control algorithms allow for so-called Smart Buildings to increase energy efficiency. Smart Buildings further benefit from existing in a Smart Grid environment, where information such as pricing and anticipated power load is sent over two way communitcation between the grid operator and the power consumer.

The …

Identity And Ritual: The American Consumption Of True Crime, Rebecca Frost

Dissertations, Master's Theses and Master's Reports

This dissertation examines the consumption of crime narratives in America, from seventeenth century execution sermons to the contemporary genre of true crime. These crime narratives serve to encourage orientation of the community toward the figures involved, including criminal and victim, and adapt with changing cultural and social norms. In responding to situations that have disrupted communal order, the crime narrative functions as a restoration ritual that aids members of the community responding to and recovering from the presented threat: a crime or transgression of taboo. While early religious texts focused on the figure of the criminal, a community member that …

Investigating The Role Of Objective And Subjective Task Complexity On Retirement Investment Plan Earnings Judgments, Natasha Hardy

Dissertations, Master's Theses and Master's Reports

This research addressed the effect of retirement plan task complexity on retirement plan earnings estimates. Past research has shown that increased task complexity results in more decision-making errors as well increased use of heuristics, or rules of thumb, which can result in non-optimal outcomes such as under-saving or disproportionate equity/income balances (Benartzi & Thaler, 2001, 2007; Maynard & Hakel, 1997). This research used two experiments to test whether individuals would judge a retirement investment plan with high task complexity to be more profitable than a plan with low task complexity - a non-normative and potentially costly bias. Experiment 1 used …

Development Of High Capacity Hyperbranched Nitric Oxide Donors For Controlling Subcutaneous Inflammation, Sean Hopkins

Dissertations, Master's Theses and Master's Reports

Implanted medical devices undergo complications the longer they remain in contact with tissue or blood. This rejection of foreign materials by our body is one of the largest reasons innovations in biomedical sensors and implanted technology are being held back. One means to hold off this unwanted response is through the utilization of nitric oxide (NO) releasing materials. Two unique NO releasing polymeric materials were synthesized and characterized before being implanted subcutaneously. Both NO releasing materials described used S-nitrosothiol (RSNO) chemistry as the main mechanism for NO release. The first material described covalently links an RSNO to the backbone of …

Systematic Study Of The Biological Effects Of Nitric Oxide (No) Using Innovative No Measurement And Delivery Systems, Weilue He

Dissertations, Master's Theses and Master's Reports

Nitric oxide (NO) is recognized as the most important small signaling molecule in the human body. An imbalance of NO is closely associated with many serious diseases such as neurological disorders, cardiovascular diseases, chronic inflammations and cancers. Herein two chemiluminescence-based devices (a real-time NO measurement device and a controllable NO delivery device) were developed to facilitate the NO quantitative study and obtain information for NO related drug design.

The first device used for real-time measuring NO(g) flux from living cells was developed and validated. The principle was to use a two-chamber design, with a cell culture chamber and a gaseous …

Extracting Flow Features Using Bag-Of-Features And Supervised Learning Techniques, Yifei Li

Dissertations, Master's Theses and Master's Reports

Measuring the similarity between two streamlines is fundamental to many important flow data analysis and visualization tasks such as feature detection, pattern querying and streamline clustering. This dissertation presents a novel streamline similarity measure inspired by the bag-of-features concept from computer vision. Different from other streamline similarity measures, the proposed one considers both the distribution of and the distances among features along a streamline. The proposed measure is tested in two common tasks in vector field exploration: streamline similarity query and streamline clustering. Compared with a recent streamline similarity measure, the proposed measure allows users to see the interesting features …

The Mechanisms Of Α-Amanitin Resistance In The Fruit Fly Drosophila Melanogaster, Chelsea L. Mitchell

Dissertations, Master's Theses and Master's Reports

Insect pesticide resistance has become a costly problem in the US. To make things more problematic, resistance to one pesticide is often associated with cross-resistance to other toxins, including pesticides that have not yet even been developed. In this study, we investigated a possible type of cross-resistance in the model fruit fly Drosophila melanogaster, some stocks of which are resistant to the very potent mushroom toxin α-amanitin. Because α-amanitin is solely produced by mushrooms, and because D. melanogaster does not feed on mushrooms in nature, the fruit flies should not be resistant to this toxin. In order to understand …

Multi-Instrumental Investigation Of Volcanic Outgassing At Pacaya Volcano, Guatemala., Carlo Prandi

Dissertations, Master's Theses and Master's Reports

Pacaya is one of the most active volcano in the world and it is only ≈30Km South of Guatemala City, the capital of Guatemala, that has a population of about 2 million of people and a surrounding metropolitan area where ≈4.5 million of people live. So mitigate the volcanic hazard improving the knowledge and the understanding of Pacaya is fundamental to decrease the risk factor at which the surrounding population is exposed. This study aims to furnish a new large database, the analysis, the comparison and the interpretations of data that come from different techniques of sampling, about the volcanic …

The Bootstrap Estimation In Time Series, Yun Liu

Dissertations, Master's Theses and Master's Reports

Time series, a special case in dependent data sequence, is widely used in many fields. In time series, linear process models are quite popularly used. General form of linear process indicates the time dependence property of time series, AR(p), MA(q) and ARMA(p;,q) models are all linear process models. In this report, simulations are based on the simplest models of these linear process models, such as AR(1), MA(1) and ARMA(1,1) models. AR(1)-SEASON, which is developed based on AR(1) model by changing the weight of residuals, is also considered in this report. To deal with dependent data sequence, common methods which aim …

Legacy And Opportunity In Northern Hardwood Forests, Wilfred Previant

Dissertations, Master's Theses and Master's Reports

Northern hardwood management reflects a combination of historic exploitation, current efforts for sustainability, and a desired future condition that incorporates complexity, resiliency, and adaptability. Stand structure and species diversity were assessed at two study locations within Michigan (USA): (1) long-term northern hardwood cutting trials at the Ford Forestry Center (FFC; Michigan Technological University, USA); and (2) vernal pool habitat within Pictured Rocks National Lakeshore (PRNL). Following the fifth cutting entry at the FFC, age structure and pre- and post-harvest relative species abundance, stocking, and volume were compared across three diameter-limit treatments, three residual basal area treatments, and an uncut control. …

Laboratory And Field Investigation Of Mixing, Morphology And Optical Properties Of Soot And Secondary Organic Aerosols, Noopur Sharma

Dissertations, Master's Theses and Master's Reports

Soot/ black carbon particles are believed to be the second largest anthropogenic contributor to the Earth’s radiative forcing, and are emitted from combustion processes. Freshly emitted soot has a fractal-like structure in which monomers are arranged into branched chain-like configuration. In the atmosphere, soot mixes with and is processed by interacting with other co-existing particle and vapors. The processing that soot undergo after emission alters its morphology; for example, condensation of vapors results into coated, mixed or compacted soot depending upon the environmental conditions. Changes in soot morphology have a strong and direct influence on its optical properties.

The unique …

Decomposing The Blocks Of A Steiner Triple System Of Order 4v-3 Into Partial Parallel Classes Of Size V-1, Leah C. Tollefson

Dissertations, Master's Theses and Master's Reports

In this report we present a summary and our new results on finding partial parallel classes of uniform size of Steiner triple systems, STS(v). We show several results for STS(4v - 3), where v = 3 mod 12 and v = 9 mod 12. In Chapter 1 we provide background knowledge and introduce the problem. In Chapter 2 we discuss some important known results to the problem, introduce the needed ingredients, and explain the methodology of the construction. Finally, in Chapter 3, we conclude with a summary and discuss possibilities for future work.

Using Cognitive Word Games To Promote Lexical Memory Access And Vocabulary Retrieval In Second Language Learners, Kejkaew Thanasuan

Dissertations, Master's Theses and Master's Reports

Fluency in a second language (L2) is one of the most important skills for the modern world. However, adults learning a new language face many obstacles, including motivation, time, and other challenges in learning. Technology learning tools may help solve these problems. In this dissertation, I tested the effectiveness of cognitive word games as a vocabulary learning method, with the main goal of investigating how different word games including a crossword paradigm task, a free association task and a word-stem completion task were effective at improving vocabulary memory access. The games selectively increased semantic (meaning) or orthographic (spelling) associations in …

The Effect Of Water Temperature On In-Stream Sediment Concentration And Transport Rate, Jennie Tyrrell

Dissertations, Master's Theses and Master's Reports

Global climate change may result in rising temperatures. As a result, ecological health and the human use of rivers may be impacted. The hydrologic cycle, watershed hydrology, and in-stream hydraulics are dynamic systems, influenced by human activities, natural events, and climate. Although known drivers like precipitation and stream velocity govern sediment processes, the effect of water temperature on sediment transport remains unclear. In-stream sediment movement could lead to blocked harbors, flooding, and degradation of vulnerable fish habitat. To better understand how fluctuations in water temperature affect sediment dynamics, six transport models were analyzed on the Niobrara River, with water temperatures …

Enabling Techniques For Expressive Flow Field Visualization And Exploration, Jun Tao

Dissertations, Master's Theses and Master's Reports

Flow visualization plays an important role in many scientific and engineering disciplines such as climate modeling, turbulent combustion, and automobile design. The most common method for flow visualization is to display integral flow lines such as streamlines computed from particle tracing. Effective streamline visualization should capture flow patterns and display them with appropriate density, so that critical flow information can be visually acquired. In this dissertation, we present several approaches that facilitate expressive flow field visualization and exploration. First, we design a unified information-theoretic framework to model streamline selection and viewpoint selection as symmetric problems. Two interrelated information channels are …

Deterministic And Stochastic Inversion Techniques Used To Predict Porosity: A Case Study From F3-Block, Hao Wu

Dissertations, Master's Theses and Master's Reports

Within large-scale sigmoidal bedding of the F3-block in the shallow zone there appear to be some indicators of hydrocarbon deposits. In order to characterize target zone in the sigmoidal bedding, I combine the analysis of inverted results of post-stack seismic data with rock-physics relationships developed from well log data to predict the porosity, which ranges from 20% to 33%, for different system tracts in this area. The methods used in this study include conventional deterministic inversion and novel stochastic inversion. Through a rock physics analysis of the density, velocity and gamma-ray logs in two wells, I constructed relationships between the …