Digital Commons Network^™

Spectral Radiation Analysis Of Premixed Oxy-Syngas And Oxy-Methane Flames, Naznin Jahan Afrose

Open Access Theses & Dissertations

Oxy-fuel combustion has potential to be an impeccable enhancement of current combustion techniques. For a hydrocarbon burning with oxygen the resulting exhaust stream is composed mainly of carbon dioxide and water vapor. This exhaust allows for easier carbon capture and sequestration since the water can be condensed out. Another advantage is the significant reduction of NOx since much of the nitrogen found in air-combustion systems is eliminated. These processes also provide a higher theoretical efficiency which is advantageous. Although beneficial many of the exhaust gas products radiative characteristics are unknown. Motivated by this, this paper focuses on the spectral radiation …

Multi-3d System: Advanced Manufacturing Through The Implementation Of Material Handling Robotics, Jose Luis Coronel Jr.

Open Access Theses & Dissertations

Since the rise of additive manufacturing (AM), innovation has been at the forefront. Additive Manufacturing systems that incorporate complex processes are steadily being developed. One example is the Multi3D System, which was designed to integrate the ability to print multi-material parts with that of embedding electronics. To achieve this automated process, the Multi3D incorporates a six-axis robotic arm to transfer a build platform containing a printed part, to various manufacturing stations (two fused deposition modeling (Stratasys, FDM400mc) systems and a computer numerical control router (Techno CNC Router). The robot is a Yaskawa Motoman MH50 chosen for its payload capacity of …

Novel Engineered Nanomaterials For Water Remediation And Gas Adsorption: Graphene Oxide And Carbon Nanotubes Decorated With Metal-Organic Frameworks And Magnetic Nanoparticles, Vahid Jabbari

Open Access Theses & Dissertations

In the current study, a series of novel magnetic and non-magnetic hybrid nanocomposites based on metal-organic frameworks (MOFs) of M3(BTC)2 (M: Ni, Cu, Zn, and Cd), graphene oxide (GrO), and carbon nanotubes (CNTs), and Fe3O4 magnetic nanoparticles (MNPs) were developed via a green, simple and versatile solvothermal method at which GrO and CNT were used as platform to grow the MOFs and Fe3O4 MNPs over them. The as-synthesized nanocomposites were characterized by XRD, SEM, TEM, XPS, IR, Raman, TGA, and N2 adsorption/desorption isotherms. Morphological analysis confirmed successful growth of nano-size Fe3O4 MNPs and M3(BTC)2 MOFs over GrO and CNT platforms. …

Towards Analytical Techniques For Optimizing Knowledge Acquisition, Processing, Propagation, And Use In Cyberinfrastructure, Leonardo Octavio Lerma

Open Access Theses & Dissertations

For many decades, there has been a continuous progress in science and engineering applications.

A large part of this progress comes from the new knowledge that researchers acquire, propagate, and use. This new knowledge has revolutionized many aspects of our life, from driving to communications to shopping.

Somewhat surprisingly, there is one area of human activity which is the least impacted by the modern technological progress: the very processes of acquiring, processing, and propagating information. When we decide where to place sensors, which algorithm to use for processing the data – we rely mostly on our own intuition and on …

A Cell Formation Algorithm For Sequential Processes With Alternative Machine Selection In The Automotive Lighting Industry, Victor Manuel Loya Garnica

Open Access Theses & Dissertations

At the present time, there are more than 12 big companies dedicated to design and produce OEM lighting systems for cars and trucks. The manufacturing processes for headlamps, tail lamps and any other exterior vehicle lighting are very common in the auto industry. Still, every automotive lamp assembly is different from brand to brand and even between the different vehicle models. Indeed, there are car headlamps with less than 30 sub-components and others with up to 300 elements. This implies creating diverse part numbers which share or hold varying manufacturing methods within a specific facility. Management of the plant resources …

Synthesis Of Benzofused-P-Indolequinones From 1,4-Naphthoquinone And Selective N-Debenzylation By Dess-Martin Periodinane, Quang Huynh Luu

Open Access Theses & Dissertations

p-Indolequinones are important heterocycles since they display interesting bioactivities such as anticancer activities as well as the ability to trigger drug release in drug targeting research. Additionally, they are also useful in precursors for the synThesis of bioactive compounds. Over decades, many methodologies have been investigated for the synThesis of p-indolequinones. Among those, cyclization of quinones plays an important role in convenient synThesis of these compounds. However, the great majority of these methods only describe quinones as electrophiles in cyclization. In our research, we found an intramolecular nucleophilic attack of quinone to an in-situ generated carbonyl group and developed a …

Does Low-Level Arsenic Exposure Predict Blood Pressure In Children?, Tania Angelica Mayorga

Open Access Theses & Dissertations

Background & Significance: Inorganic arsenic is a heavy metal naturally found in soil and human exposure to this heavy metal causes adverse effects. Exposure risks are particularly high in developing children. Arsenic is mainly found in bedrock. It is also a by-product of smelting, it is used in cement production, and historically is has been found in crop pesticides. Among other ill-effects, arsenic exposure in humans can cause respiratory diseases, peripheral neuropathy and liver fibrosis. In particular arsenic has been shown in many studies to be a contributing factor in the risk for hypertension in adults however no studies have …

High Performance Computing In Air Quality Models An Their Applications, Roberto A. Perea

Open Access Theses & Dissertations

High Performance Computing has become an important tool for many applications and services in the areas of Air Quality research. One important aspect is the use of computational technology in simulation and modeling of complex Air Quality models which makes it affordable in terms of data analysis, processing and speed. For this Dissertation, three projects using Air quality models were developed using high performance computing.

For the first project, ozone concentrations for the Paso del Norte Region are simulated using air quality models and compared against experimental data. For the second project, the Development of models and optimization of codes …

A Methodology For Use Of Digital Image Correlation For Hot Mix Asphalt Testing, Estefany Ramos

Open Access Theses & Dissertations

Digital Image Correlation (DIC) is a relatively new technology which aids in the measurement of material properties without the need for installation of sensors. DIC is a noncontact measuring technique that requires the specimen to be marked with a random speckled pattern and to be photographed during the test. The photographs are then post-processed based on the location of the pattern throughout the test. DIC can aid in calculating properties that would otherwise be too difficult even with other measuring instruments.

The objective of this Thesis is to discuss the methodology and validate the use of DIC in different hot …

Just, Smart: Civil Rights Protections And Market-Sensitive Vacant Property Strategies, James J. Kelly Jr.

Journal Articles

This essay, prepared for and published by the Center for Community Progress, a national, non-profit intermediary dedicated to developing effective, sustainable solutions to turn vacant, abandoned and problem properties into vibrant places, examines the legal and normative implications of local governments' use of neighborhood real estate market data to strategically focus vacant property remediation tools. I and other writers, such as Frank Alexander, Alan Mallach and Joseph Schilling, have argued for the importance of understanding the economic feasibility of market-based rehabilitation of derelict, vacant houses in making decisions as to how and when to use a variety of code enforcement, …

21st Century Arms Control Challenges: Drones, Cyber Weapons, Killer Robots, And Wmds, Mary Ellen O'Connell

Journal Articles

The world faces tough arms control challenges from preventing the development and use of weapons of mass destruction to regulating the new weapons of the computer revolution. This article considers what works in arms control. Using military force in violation of international law to destroy nuclear facilities, to stop weapons shipments, or to punish the use of prohibited weapons typically fails. Diplomacy paired with lawful counter-measures has the superior track record. Reviving the art of diplomacy and re-committing to authentic international law will pay dividends in peace and security.

Assessment Of Variation Of Nest Survival For Grassland Birds Due To Method Of Nest Discovery, Tara J. Conkling, Jerrold L. Belant, Travis L. Devault, Guiming Wang, James A. Martin

United States Department of Agriculture Wildlife Services: Staff Publications

Capsule Interpretation of nest survival estimates may be improved by incorporating the search method used to locate nests as a covariate.

Aims To compare annual survival estimates for Dickcissel Spiza americana nests and determine if incorporating search method (structured, opportunistic, or behavioural searches) improved model fit.

Methods Dickcissel nests were located using structured, opportunistic, or behavioural searches over three years (2011–2013) in Mississippi, USA. Models were used to estimate daily survival rates (DSRs) and to analyse factors influencing nest survival.

Results DSRs for Dickcissels were best explained by quadratic date, nest age, age found, and year, but incorporating search method …

Impacts Of Colonial Waterbirds On Vegetation And Potential Restoration Of Island Habitats, Christopher R. Ayers, Katie C. Hanson-Dorr, Sadie O'Dell, Charles D. Lovell, Michael L. Jones, Jason R. Suckow, Brian S. Dorr

United States Department of Agriculture Wildlife Services: Staff Publications

Colonial waterbirds have impacted forested island ecosystems throughout their breeding range, changing vegetation, and soil characteristics and bird communities. Our objectives were to (1) determine effects of three levels of colonial waterbird exclusion on overall vegetation diversity and growth, and survival of a candidate restoration species (black elderberry; Sambucus nigra canadensis); (2) investigate effects of different planting techniques on survival and growth of black elderberry; and (3) determine effects of waterbird colonization on soil chemistry. In 2012, we investigated effects of three levels of waterbird exclusion (none control plots [CON]; partial, which excluded waterbirds larger than gulls [PEX]; and …

Non-Target Species Mortality And The Measurement Of Brodifacoum Rodenticide Residues After A Rat (Rattus Rattus) Eradication On Palmyra Atoll, Tropical Pacific, William C. Pitt, Are R. Berentsen, Aaron B. Shiels, Steven F. Volker, John D. Eisemann, Alexander S. Wegmann, Gregg R. Howald

United States Department of Agriculture Wildlife Services: Staff Publications

The use of rodenticides to control or eradicate invasive rats (Rattus spp.) for conservation purposes has rapidly grown in the past decades, especially on islands. The non-target consequences and the fate of toxicant residue from such rodent eradication operations have not been well explored. In a cooperative effort, we monitored the application of a rodenticide, ‘Brodifacoum 25W: Conservation’, during an attempt to eradicate Rattus rattus from Palmyra Atoll. In 2011, Brodifacoum 25W: Conservation was aerially broadcasted twice over the entire atoll (2.5 km²) at rates of 80 kg/ha and 75 kg/ha and a supplemental hand broadcast application …

Collisions Between Eagles And Aircraft: An Increasing Problem In The Airport Environment, Brian E. Washburn, Michael J. Begier, Sandra E. Wright

United States Department of Agriculture Wildlife Services: Staff Publications

Most known fatalities for both Bald Eagles (Haliaeetus leucocephalus) and Golden Eagles (Aquila chrysaetos) are associated with humans (e.g., collisions with vehicles and artificial structures). Notably, the risk of collisions between eagles and aircraft is an increasing problem at civil airports and military airfields. Of the 234 eagle collisions with civil and military aircraft reported to the Federal Aviation Administration, the U.S. Air Force, and the U.S. Navy during 1990–2013, 52% caused damage to the aircraft. During this 23-yr time period, Bald Eagle–aircraft collisions increased by 2200% and Golden Eagle–aircraft collisions increased by 400%. Eagle–aircraft collisions …

Dynamics Of Virus Shedding And Antibody Responses In Influenza A Virus-Infected Feral Swine, Hailiang Sun, Fred L. Cunningham, Jillian Harris, Yifei Xu, Li-Ping Long, Katie Hanson-Dorr, John A. Baroch, Paul Fioranelli, Mark W. Lutman, Tao Li, Kerri Pedersen, Brandon S. Schmit, Jim Cooley, Xiaoxu Lin, Richard G. Jarman, Thomas J. Deliberto, Xiu-Feng Wan

United States Department of Agriculture Wildlife Services: Staff Publications

Given their free-ranging habits, feral swine could serve as reservoirs or spatially dynamic ‘mixing vessels’ for influenza A virus (IAV). To better understand virus shedding patterns and antibody response dynamics in the context of IAV surveillance amongst feral swine, we used IAV of feral swine origin to perform infection experiments. The virus was highly infectious and transmissible in feral swine, and virus shedding patterns and antibody response dynamics were similar to those in domestic swine. In the virus-inoculated and sentinel groups, virus shedding lasteddays, respectively. Antibody titres in inoculated swine peaked at 1 : 840 on day 11 post-inoculation (p.i.), …

Boa Constrictor (Boa Constrictor), Are R. Berentsen, Juan G. Garcia-Cancel, Edna M. Diaz-Negron, Oscar A. Diaz-Marrero, Alberto R. Puente-Rolón, Robert N. Reed, Kurt C. Vercauteren

United States Department of Agriculture Wildlife Services: Staff Publications

USA: PUERTO RICO: MUNICIPALITY OF CABO ROJO: Cabo Rojo National Wildlife Refuge (17.978958°N, 67.170910oW; NAD 83). 10 November 2014. O. A. Diaz-Marrero. Verified by S. M. Boback. National Museum of Natural History, Smithsonian Institution (USNM Herp Image 2838a, b; photo vouchers). First municipality record for this exotic species; all previous reports were restricted to the Municipality of Mayaguez, located ca. 25 km north of Cabo Rojo National Wildlife Refuge. Reynolds et al. (2013. BioI. Invasions 15:953-959) concluded that Boa Constrictor introductions into Puerto Rico were likely related to the pet trade and that they genetically matched snakes belonging to the …

Patriation And Patrimony: The Path To The Charter, John M. Finnis

Journal Articles

This annotated Coxford Lecture is the first account dedicated to tracing the part played in the 1980-82 patriation of the Canadian Constitution by the British House of Commons, particularly by its Select Committee on Foreign Affairs. This committee, for which author was the adviser, investigated the propriety of the UK Parliament’s acceding to a request for amendment of the British North America Act 1867 (as amended) if the amendment were opposed by a substantial number of Provinces and it would affect their powers. Against the firm opposition of the Canadian government (secretly being assisted by the British government), the Committee …

The Fair Market Value Of Public Resources, Bruce R. Huber

Journal Articles

This Article explores the problem of public resource sales with particular reference to natural resources managed by the federal government. Lands owned by the United States hold trillions of dollars' worth of natural resources. Federal agencies earn billions in annual revenue from resource sales, yet critics assert that billions more could be reaped if resources were sold for a fair price. Although federal law has increasingly required that agencies price resources at fair market value, this requirement is surprisingly difficult to interpret and even more dfficult to implement and enforce. This Article analyzes the various forces that bear on public …

Can Trained Field Community Workers Identify Stroke Using A Stroke Symptom Questionnaire As Well As Neurologists? Adaptation And Validation Of A Community Worker Administered Stroke Symptom Questionnaire In A Peri-Urban Pakistani Community., Maria Khan,, Ayeesha Kamran Kamal, Muhammad S. Ilyas, Muhammad Islam, Iqbal Azam Syed, Azam Virk,, Alia Nasir, Hasan Rehman,, Anita Arif,, Muhammad Jan,, Anjum Akhtar,, Minaz Mawani, Junaid Abdul Razzak,, Omrana Pasha

Department of Medicine

Background: Stroke is a leading cause of morbidity and mortality worldwide. There is a paucity of data from South Asia where stroke is highly prevalent. Validated tools administrable by Community Health Workers (CHWs) are required to identify stroke in the community in a resource strapped region such as this.

Methods: The study was conducted in a transitional slum in Karachi, Pakistan. Questionnaire for Verifying Stroke-Free Status (QVSFS) was adapted and translated into Urdu. Two CHWs, trained by a neurologist, selected 322 community dwelling subjects using purposive sampling. Each CHW collected data independently which was validated by a vascular neurologist who …

Innovative Web Applications For Analyzing Traffic Operations, Natasha Petrovska

Electronic Theses and Dissertations 2010 - 2019

The road traffic along with other key infrastructure sectors such as telecommunication, power, etc. has an important role in economic and technological growth of one country. Traffic engineers and analysts are responsible for solving a diversity of traffic problems, such as traffic data acquisition and evaluation. In response to the need to improve traffic operation, researchers implement advanced technologies and integration of systems and data, and develop state-of-the-art applications. This thesis introduces three novel web applications with an aim to offer traffic operators, managers, and analysts’ possibility to monitor the congestion, and analyze incidents and signal performance measures. They offer …

Keeping An Eye On Cheaters: Cognitive And Social Determinates Of Successful Deontic Reasoning In Preschool Children, Patrick D Ii Sellers

Electronic Theses and Dissertations 2010 - 2019

Deontic reasoning is a domain of reasoning concerning permissions, obligations, and prohibitions founded on conditional logic (Wason,1968). The inclusion of a social valence to deontic rules leads to increased rule violation identification in both adults (Cosmides & Tooby, 1992) and children (Harris & Nunez, 1996), suggesting an evolutionary advantage for a specific class of reasoning known as “cheater-detection” (Fiddick, 2004). The current investigation is the first attempt to understand the cognitive and social variables that account for children’s logical reasoning advantage in social violation situations.

Methionine Sulfoxide Reductase (Msr) Modulates Lifespan Andlocomotion In Drosophila Melanogaster, Lindsay Bruce

Electronic Theses and Dissertations 2010 - 2019

Oxidative stress is considered a major factor in the etiology of age related diseases and the aging process itself. Organisms have developed mechanisms to protect against oxidative damage resulting from increased production of reactive oxygen species during aging. One of the major antioxidant systems is the methionine sulfoxide reductase (Msr) enzyme family. The two major Msr enzymes, MsrA and MsrB, can stereospecifically reduce the S and R epimers, respectively, of methionine sulfoxide in proteins back to methionine. This study, using Drosophila melanogaster, decribes the first animal system lacking both MsrA and MsrB. The loss of either MsrA or MsrB had …

Mechanisms Of Placental Dysfunction In Pregnancy Malaria, Jared Lybbert

Electronic Theses and Dissertations 2010 - 2019

The molecular mechanisms by which pregnancy malaria affects the outcome of fetal development are unknown. Megalin, which has been well studied in kidney, has high expression in the placenta from early stages to term, and is proposed to be an important factor in extensive maternofetal exchange during development of the fetus. Pregnancy malaria (PM) is characterized by inflammation in placenta and is associated with low birthweight (LBW), stillborn birth, and other pathologies. It is hypothesized that PM disturbs megalin function/expression/distribution in the brush boarder of syncytiotrophoblast which, in turn, may contribute significantly to pathology of LBW. Our studies show that …

Mmo Gaming Culture: An Online Gaming Family, Michael Perez

Electronic Theses and Dissertations 2010 - 2019

This study examines the social organization of Gaiscíoch, a large online gaming community that exists within the simulated world of a massively multiplayer online role playing game (MMORPG). It provides an ethnographic account of an online gaming community that is open to any player without skill or time commitment requirements, but still maintains high status within the game world. This project identifies eight elements that make this inclusive, friendly, and casual community successful in virtual worlds that tend to be dominated by communities that have a competitive, strict, and exclusive approach to online gaming (social interaction, code of values, leadership, …

Paleodemography Of Highland Beach The Demographic Parameters Of A Native American Population From Southeastern Florida, Christopher Hennessey

Electronic Theses and Dissertations 2010 - 2019

Those who practice within the field and those who wish to discredit the field have long debated the field of paleodemography. In 1999 and again in 2000, researchers who used paleodemographic analysis assembled in Rostock, Germany to amend the present issues and change the way research is conducted in the future (Hoppa and Vaupel 2002). As a result of these meetings, researchers created the Rostock Manifesto. While many scholars accepted the change in the suite of methodologies carried out under the new guidance, little has been said on the effectiveness of the manifesto. In this thesis, I argue that the …

Noise Radiation From A Cylindrical Embossment Immersed In Turbulent Boundary Layer Flow, Benjamin Skyler Bryan

Electronic Theses and Dissertations 2010 - 2019

This dissertation will consider the sound radiation from forward-facing steps and a three dimensional cylindrical embossment of very low aspect ratio mounted on a plate. Glegg et al (2014) outlined a theory for predicting the sound radiation from separated flows and applied the method to predicting the sound from forward-facing steps. In order to validate this theory it has been applied to the results of Catlett et al (2014) and Ji and Wang (2010). This validation study revealed that the original theory could be adjusted to include a mixed scaling which gives a better prediction. RANS simulations have been performed …

Perceptions Of The Environment: An Ethnographic Study Of Sensory Awareness And Environmental Activism Among South Florida Yoga Practitioners, Meagan L. Weisner

Electronic Theses and Dissertations 2010 - 2019

The practice of yoga is an increasingly popularized movement within the West that incorporates the desire for physical fitness, spiritual consciousness, and environmentalism. Emanating from the New Age movement, the popularity of yoga has proliferated as a subculture that seeks to encourage mind–body wellbeing while representing an ethos that assumes environmental responsibility. This thesis examines the techniques of modern yoga and the influence that asana (posture) and meditational relaxation have on the senses and subsequently on environmental awareness and activism.

Perceived Job Satisfaction Of Resident Assistants In Student Housing At Three Florida Public Universities, Teeranai Ovathanasin

Electronic Theses and Dissertations 2010 - 2019

The purpose of this study was to determine differences in satisfaction of public university Resident Assistants (RAs) with regard to several job satisfaction factors identified on the Resident Assistant Satisfaction Survey (RASS), specifically as compared to Casey’s (2009) normative sample of RAs in privatized university housing. The RASS outlined eight Employment Aspect Factors and three Criterion Factors to determine RA job satisfaction. This study also determined if there were differences in job satisfaction for public university RAs based on gender, racial ethnic identification, or academic class standing. Resident Assistants from three Research I Florida institutions in the United States completed …

Perceptions Of Ambiguous Events, Cleopatre Paulvin

Electronic Theses and Dissertations 2010 - 2019

This study looked at the effects of stereotypes in the media on memory for ambiguous events. The latter were stimuli created to portray individuals of two different racial groups (white and black) in situations that did not necessarily negatively implicate these actors. Two hundred and thirty six participants took part and viewed these events as well as six media clips. Three groups of media clips were shown: clips with black actors, white actors, and both races. A subset of participants, the explicit condition, were asked to rate the media clips for stereotypes, whereas another group, the implicit condition, were instructed …