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2015

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Method Development For The Assignment Of Nmr Peaks And The Determination Of Quaternary Protein Structure Using Reductive Methylation, Pamlea Nicole Brady Jan 2015

Method Development For The Assignment Of Nmr Peaks And The Determination Of Quaternary Protein Structure Using Reductive Methylation, Pamlea Nicole Brady

LSU Doctoral Dissertations

The work described herein is centered on reductive methylation, a chemical modification reaction, which allows for the introduction of methyl groups at the primary amines of the lysine side chain and at the N-terminus. The resulting methyl groups are effective probes for the study of protein structure and dynamics using nuclear magnetic resonance spectroscopy (NMR). Described herein is work conducted on the development of tools for the study of protein structure using reductive methylation, highlighting options for addressing limitations of the labeling method encountered by its practical use. Chapter 1 serves as a brief introduction to protein structure and the …

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Forest Stakeholders, Policies And Trade In India's Forest Sector, Joy Das Jan 2015

Forest Stakeholders, Policies And Trade In India's Forest Sector, Joy Das

LSU Master's Theses

The thesis examines a panel of trade flows during 2009-2013, exploring the influence of regulatory quality on the pattern of forest products imports by India from 143 partner countries. The study applies a pooled regression model followed by Generalized Least Squared (GLS) technique and a more robust Feasible Generalized Least Squared (FGLS) method of estimation with regulatory quality, distance between the partner country and India, total forest area of partner country, GDP and population indicators to assess the impact of partner country’s regulatory quality and other trade-related factors on imports of forest products by India. The results support the notion …

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Well-Quasi-Ordering By The Induced-Minor Relation, Chanun Lewchalermvongs Jan 2015

Well-Quasi-Ordering By The Induced-Minor Relation, Chanun Lewchalermvongs

LSU Doctoral Dissertations

Robertson and Seymour proved Wagner's Conjecture, which says that finite graphs are well-quasi-ordered by the minor relation. Their work motivates the question as to whether any class of graphs is well-quasi-ordered by other containment relations. This dissertation is concerned with a special graph containment relation, the induced-minor relation. This dissertation begins with a brief introduction to various graph containment relations and their connections with well-quasi-ordering. In the first chapter, we discuss the results about well-quasi-ordering by graph containment relations and the main problems of this dissertation. The graph theory terminology and preliminary results that will be used are presented in …

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Dynamic Ventilation And Power Output Of Urban Bicyclists, Alexander Y. Bigazzi, Miguel A. Figliozzi Jan 2015

Dynamic Ventilation And Power Output Of Urban Bicyclists, Alexander Y. Bigazzi, Miguel A. Figliozzi

Civil and Environmental Engineering Faculty Publications and Presentations

Bicyclist intake of air pollutants is linked to physical exertion levels, ventilation rates, and exposure concentrations. Whereas exposure concentrations have been widely studied in transportation environments, there is relatively scant research linking on-road ventilation with travel conditions and exertion levels. This paper investigates relationships among power output, heart rate, and ventilation rate for urban bicyclists. Heart rate and ventilation rate were measured on-road and combined with power output estimates from a bicycle power model. Dynamic ventilation rates increased by 0.4-0.8% per watt of power output, with a mean lag of 0.8 minutes. The use of physiology (ventilation) monitoring straps and …

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Hydrological Influences On Catahoula Lake In An Altered Floodplain, Lincoln Dugue Jan 2015

Hydrological Influences On Catahoula Lake In An Altered Floodplain, Lincoln Dugue

LSU Master's Theses

Floodplain lakes in floodplains of large rivers undergoing intensive alterations are subject to hydrologic alteration. One example is in the Lower Mississippi Alluvial Valley (LMAV) and pivotal habitat for wildlife. Catahoula Lake has experienced hydrologic regime alterations over the past ~150 years that may be contribute to changes in the habitat with expansion of woody plants. A Diversion Channel was constructed in 1972 to provide the natural, annual de-watering of the lake to maintain its ecological integrity, but ecologic changes are still occurring. Our general goal is to understand the hydrologic regime of the lake, particularly the historical hydrologic regime …

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Modeling Two-Phase Flow And Heat Transfer In Polygonal Microchannels, Sai Sashankh Rao Jan 2015

Modeling Two-Phase Flow And Heat Transfer In Polygonal Microchannels, Sai Sashankh Rao

LSU Doctoral Dissertations

Microfluidics is a burgeoning research area with applications ranging from microfluidic cooling to biomolecule synthesis. Here we study two problems to gain an improved understanding of two-phase flow and heat transfer in microfluidic devices. We also study a third problem on boundary layer flow out of theoretical interest. In the first problem, we study the heat and mass transfer in polygonal micro heat pipes under small imposed temperature differences. A micro heat pipe, used in electronics cooling, consists of a closed polygonal microchannel filled with a wetting liquid and a long vapor bubble. We model the evaporation, fluid flow, and …

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Development Of New Linking Chemistry With The Fac-{Re(Co)3}+ Core For Eventual Applications In Radiopharmaceuticals In Imaging And Therapy, Aponsu Meregngna Pramuditha Lakmi Abhayawardhana Jan 2015

Development Of New Linking Chemistry With The Fac-{Re(Co)3}+ Core For Eventual Applications In Radiopharmaceuticals In Imaging And Therapy, Aponsu Meregngna Pramuditha Lakmi Abhayawardhana

LSU Doctoral Dissertations

The facile labeling of biomolecules with a radionuclide is a key goal in radiopharmaceutical development. This study explores two different ligand systems for fac-[Re(CO)3L]+ complexes, that could be used in bioconjugation. The first approach uses a tridentate ligand having a sulfonamide linkage and modeled on previously evaluated fac-[Re(CO)3(N(SO2R)dpa)]PF6 complexes. The present goal was to develop new related sulfonamide complexes with more hydrophilic ligands designed to avoid the bioavailability problems that would plague the N(SO2R)dpa ligand system. A series of fac-[Re(CO)3(N(SO2R)dien)]PF6 complexes with different R groups linked to the central nitrogen of a symmetric tridentate sulfonamides were synthesized with the aim …

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Study Of Active Vibration Control Using The Method Of Receptances, Amit Maha Jan 2015

Study Of Active Vibration Control Using The Method Of Receptances, Amit Maha

LSU Doctoral Dissertations

Using the Method of Receptance, it is possible in general to assign 2_x0002_ poles (i.e. n conjugate pairs) of an axially vibrating rod of variable cross section by sensing the state at _x0002_ points along the rod. Using the sensor data, closed loop feedback control gains can be calculated by solving a simple set of linear equations. The feedback gains can be applied to generate the required control force using an actuator. This partial pole assignment can be done without continuous or discrete analytical modeling. Therefore, the physical parameters such as the rigidity, the density, and the variable cross-sectional area …

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Stochastic Modeling Of Semantic Structures Of Online Movie Reviews, Limeng Pu Jan 2015

Stochastic Modeling Of Semantic Structures Of Online Movie Reviews, Limeng Pu

LSU Master's Theses

Facing the enormous volumes of data available nowadays, we try to extract useful information from the data by properly modeling and characterizing the data. In this thesis, we focus on one particular type of semantic data --- online movie reviews, which can be found on all major movie websites. Our objective is mining movie review data to seek quantifiable patterns between reviews on the same movie, or reviews from the same reviewer. A novel approach is presented in this thesis to achieve this goal. The key idea is converting a movie review text into a list of tuples, where each …

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Synergistic Properties-Driven Synthesis Of Aluminides, Antiomonides, And Bioceramics, Pilanda Watkins-Curry Jan 2015

Synergistic Properties-Driven Synthesis Of Aluminides, Antiomonides, And Bioceramics, Pilanda Watkins-Curry

LSU Doctoral Dissertations

The synthesis, characterization, and properties of selected intermetallics and ceramic materials are presented in this dissertation. In our quest to grow single crystal intermetallics from the metal flux technique, new strategies were employed to avoid thermodynamically stable phases and to ensure sample homogeneity of the crystalline product for structure elucidation and accurate measurements of their magnetic and electrical properties. The relationship between the complex crystal structures and magnetic properties are reported for LnCo2Al8 (Ln = La-Nd, Sm, Yb), CeCo2-xMnxAl8 (0 < x < 1), and Pr2Fe4-xCoxSb5 (1 ≤ x < 3). The discovery of magnetic frustration in LnCo2Al8 (Ln = Ce, Nd) and complex magnetic ordering coupled with large positive magnetoresistance of up to 150% and 60% at 200 K with relatively low field of H = 1 T in Pr2Fe4-xCoxSb5 (x ≈ 2 and 2.5) is also reported. The demand of new inorganic solid materials as scaffolds for the engineering of bone tissue has led to the synthesis of calcium magnesium silicates such as, diopside (CaMgSi2O6), akermanite (Ca2MgSi2O7), monticellite (CaMgSiO4), and merwinite (Ca3Mg(SiO4)2)) for studying dimensionality and mechanical properties. This dissertation highlights the synergism of solid state chemistry at the interface of condensed matter physics and biological engineering. The discovery of compounds with tunable magnetic, electrical, and mechanical properties will be described herein.

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Investigating Wave Forces On Coastal Bridge Decks, Guoji Xu Jan 2015

Investigating Wave Forces On Coastal Bridge Decks, Guoji Xu

LSU Doctoral Dissertations

Tsunamis and hurricane induced waves are responsible for many coastal bridge failures, especially in the last decade. In the current study, three countermeasures (reducing the entrapped air, elevating the structures and rigidifying the structures) are considered, two wave types (solitary wave theory and Stokes wave theory) are chosen, and two bridge types (single bridge deck and twin bridge decks) are taken into account. Parametric studies are conducted based on Computational Fluid Dynamics (CFD) software ANSYS Fluent. This dissertation comprises two broad themes according to the wave types adopted. The first one is to make a great effort to investigate solitary …

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I. Synthesis Of Ascarosides For Chemical Biology Studies In Caenorhabditis Elegans, Ii. A Photochemical Approach To Delavayine, And Iii. Remote Hydroxylation By Radical Translocation And Polar Crossover, Kyle Allen Hollister Jan 2015

I. Synthesis Of Ascarosides For Chemical Biology Studies In Caenorhabditis Elegans, Ii. A Photochemical Approach To Delavayine, And Iii. Remote Hydroxylation By Radical Translocation And Polar Crossover, Kyle Allen Hollister

LSU Doctoral Dissertations

The foci of this dissertation are the synthesis of analogs for chemical biology studies, synthetic chemistry method development (with an emphasis on photochemistry), and the application of these methods toward total synthesis. Chapter 1 outlines the synthesis of an array of pheromone analogs that are derivatives of the dideoxy sugar ascarylose. Referred to as ascarosides, such compounds have recently been shown to influence important biological processes in the model organism Caenorhabditis elegans. C. elegans secretes ascarosides into its environment, where the compounds then act as signaling molecules by providing information on factors like population density. Chapter 2 describes the biological …

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Neodymium Isotope Ratios And A Positive Δ13c Excursion: Connecting Oceanographic And Climate Changes Near The M4-M5 Sequence Boundary Of The Late Ordovician, Zachary Wright Jan 2015

Neodymium Isotope Ratios And A Positive Δ13c Excursion: Connecting Oceanographic And Climate Changes Near The M4-M5 Sequence Boundary Of The Late Ordovician, Zachary Wright

LSU Master's Theses

A significant positive carbon isotope excursion first described from the Guttenberg Member of the Decorah Formation in Iowa called the GICE is a defining feature of Late Ordovician chemostratigraphy. It occurs near the M4-M5 sequence boundary of the Late Ordovician and has been correlated across the globe using prominent K-bentonite ash beds and conodont biomarkers. The cause of the GICE has been debated, with some arguing that it represents the initiation of a glacial period in a greenhouse climate 10 Ma before the end Ordovician glaciation and extinction. A variety of cooling signals have been identified across the M4-M5 sequence …

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Modelling Of Channelization In Unconsolidated Formations Due To Liquid Injection, Juan Felipe Bautista Barake Jan 2015

Modelling Of Channelization In Unconsolidated Formations Due To Liquid Injection, Juan Felipe Bautista Barake

LSU Master's Theses

Fluid injection has been increasingly implemented in oil and gas producing fields to optimize hydrocarbon production in both young and mature oil fields across the globe. This situation arises from the realization that early planning of second and tertiary recovery methods may improve project economics significantly. Injectors are then intended to perform at high injection rates with low bottomhole flowing pressures for as long as possible. In the case of injectors drilled in unconsolidated formations, deficient performance often times seems to be the norm. With a majority of these fields being offshore developments in which capital expenditures are high, a …

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Disaggregating Student Outcomes By Race And Income: Educational Equity In Oregon, Anne Sinkey, Ann Curry-Stevens Jan 2015

Disaggregating Student Outcomes By Race And Income: Educational Equity In Oregon, Anne Sinkey, Ann Curry-Stevens

Center to Advance Racial Equity Publications and Reports

This research seeks to answer an emerging question in public school debates: whether race is just a proxy for income when it comes to disparities in educational outcomes among Oregon’s K-12 students. This research set out to respond to this question, and draws from public school data records to answer the question. We investigated student test scores across three different environments: elementary schools, middle schools and high schools. We also investigated student graduation rates from high school. The pattern of findings is absolutely clear: regardless of the site or type of disparities, when we compare how low-income students fare, all …

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String Searching With Ranking Constraints And Uncertainty, Sudip Biswas Jan 2015

String Searching With Ranking Constraints And Uncertainty, Sudip Biswas

LSU Doctoral Dissertations

Strings play an important role in many areas of computer science. Searching pattern in a string or string collection is one of the most classic problems. Different variations of this problem such as document retrieval, ranked document retrieval, dictionary matching has been well studied. Enormous growth of internet, large genomic projects, sensor networks, digital libraries necessitates not just efficient algorithms and data structures for the general string indexing, but indexes for texts with fuzzy information and support for queries with different constraints. This dissertation addresses some of these problems and proposes indexing solutions. One such variation is document retrieval query …

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Natural Order: The Case For Applying Biomimetic Design Principles To Mass Communication Technology Design, William Glass Jan 2015

Natural Order: The Case For Applying Biomimetic Design Principles To Mass Communication Technology Design, William Glass

LSU Master's Theses

In this paper I tested the effectiveness of a biomimetically designed classifier algorithm in an effort to support a new argument for the systemic application of biomimetic design principles to mass communication technology. To supplement the purely system-level test, I conducted a series of interviews with interface-level designers regarding their own design strategies, generally accepted design strategies in the field of mass communication technology design, new design strategies, and the landscape of the field in general. The findings of my test lend strong credence to biomimicry's potential systemic contribution to mass communication technology design, and the tone of the interview …

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The Galaxy Alignment Effect : An Exploration With The Hubble Space Telescope Frontier Fields, Jaford Connor Burgad Jan 2015

The Galaxy Alignment Effect : An Exploration With The Hubble Space Telescope Frontier Fields, Jaford Connor Burgad

Undergraduate Theses and Senior Projects

No abstract provided.

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Writing In The Geometry Classroom, Amy Lynn Rome Jan 2015

Writing In The Geometry Classroom, Amy Lynn Rome

LSU Master's Theses

This study sought a time-efficient way to implement writing in ninth-grade Geometry. Students wrote responses to five expository writing prompts spread out over the spring semester of the 2014-2015 school year. Students’ first attempts were graded and returned to them along with feedback in the form of a teacher-written exemplar. Students rewrote assignments to improve their grades. All first and second attempts were collected and evaluated. We found that students were more successful after seeing the exemplar. Moreover, on assignments occurring later in the semester, more students were able to score in the top categories of the writing assignments on …

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An Efficient Fault Location Algorithm For Shipboard Power Systems, Pedram Jahanmard Jan 2015

An Efficient Fault Location Algorithm For Shipboard Power Systems, Pedram Jahanmard

LSU Master's Theses

The Shipboard Power System (SPS) supply energy to sophisticated systems for navigation, communication, weapons, and operation. Due to the ship’s critical operating condition, faults can be very detrimental. Faults in the SPS may happen because of failure of electrical components or by damages that happen during a battle. These faults may interrupt the paths for supplying energy to loads that are not damaged. To enhance survivability of naval ships, SPS requires an efficient fault location algorithm in order to locate and clear the fault as well as provide an alternative path to supply energy to the loads that are not …

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Holecene Paleoenvironmental Reconstruction From The Shark River Estuary, Everglades, Florida, Qiang Yao Jan 2015

Holecene Paleoenvironmental Reconstruction From The Shark River Estuary, Everglades, Florida, Qiang Yao

LSU Doctoral Dissertations

This dissertation examines the paleoecological records from the Shark River Estuary in the southwestern part of the Everglades National Park (ENP), Florida, with primary goal of reconstructing the Holocene history of the coastal mangrove ecosystem in the Florida Coastal Everglades. Roughly 15 meters of sediments were collected from 4 study sites and subjected to loss-on ignition, palynological, and X-ray fluorescence analyses. According to the literature, the earliest communities of Rhizophora mangle (red mangrove) occurred prior to 8,000 cal yr BP in the south-central area of the Belize Barrier Reef Platform. Between 7,000 and 5,000 cal yr BP, Rhizophora was established …

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Sensory Processing And Conducive Study Environments, Katrina Kotta Jan 2015

Sensory Processing And Conducive Study Environments, Katrina Kotta

Undergraduate Theses and Senior Projects

No abstract provided.

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Biofuel Production From Chinese Tallow Tree Seeds Using Microwave Technology, Mohamad Barekati Goudarzi Jan 2015

Biofuel Production From Chinese Tallow Tree Seeds Using Microwave Technology, Mohamad Barekati Goudarzi

LSU Master's Theses

In-situ transesterification (simultaneous extraction and transesterification) of Chinese tallow tree seeds into methyl esters using two microwave systems were investigated in this study. In the first part, utilizing a batch system, parameters tested were catalyst concentration (1-4 wt.%), solvent ratio (2-6 v/w), reaction time (15-60 min) and temperature (50-70°C). A high degree of oil extraction and efficient conversion of oil to biodiesel were found in the proposed range. The process was further optimized in terms of product yields and conversion rates using Dohlert optimization methodology. Based on the experimental results and statistical analysis, the optimal production yield conditions for this …

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Language Processing And The Artificial Mind: Teaching Code Literacy In The Humanities, Jerry Scott Weltman Jan 2015

Language Processing And The Artificial Mind: Teaching Code Literacy In The Humanities, Jerry Scott Weltman

LSU Master's Theses

Humanities majors often find themselves in jobs where they either manage programmers or work with them in close collaboration. These interactions often pose difficulties because specialists in literature, history, philosophy, and so on are not usually "code literate." They do not understand what tasks computers are best suited to, or how programmers solve problems. Learning code literacy would be a great benefit to humanities majors, but the traditional computer science curriculum is heavily math oriented, and students outside of science and technology majors are often math averse. Yet they are often interested in language, linguistics, and science fiction. This thesis …

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Hybridization And Population Structure Of Western Gulf Coast Mottled Ducks, Robert Joseph Ford Jan 2015

Hybridization And Population Structure Of Western Gulf Coast Mottled Ducks, Robert Joseph Ford

LSU Master's Theses

Rates of hybridization between species that do not normally interbreed have increased due to human impacts on natural environments, such as habitat alteration or introductions of non-native species. Human-induced hybridization can be detrimental to wildlife and contribute to species extinctions. In Florida, feral Mallards (Anas platyrhynchos) hybridize with endemic Mottled Ducks (A. fulvigula) at rates close to 9%. However, levels of hybridization between these two species have not been extensively examined in the western Gulf Coast (from Alabama to northern Mexico) despite the potential impact on the Mottled Duck lineage. In this study, I examined the degree of hybridization between …

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The Implementation Of Two Cooperative Learning Structures, Rally Coach And Teams-Games-Tournaments, In High School Chemistry Courses, Joanna Miketinas Stewart Jan 2015

The Implementation Of Two Cooperative Learning Structures, Rally Coach And Teams-Games-Tournaments, In High School Chemistry Courses, Joanna Miketinas Stewart

LSU Master's Theses

To combat the obstacles that students experience in chemistry, two cooperative learning strategies, Rally Coach and Teams-Games-Tournaments, were implemented in five chemistry courses at East Ascension High School. Rally Coach called for two students to work as a pair and peer tutor to successfully complete practice problems for each lesson. Teams-Games-Tournaments required students to work in groups of four to complete practice problems and compete for team points as a review. Every student experienced both learning strategies. A comparison was made to see which cooperative learning strategy better helped student performance, including comparisons of effects on different student demographics and …

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Using Stormwater Modeling In Iterative Site Design: An Integration Of Techniques From Engineering And Landscape Architecture, Brooke Erin Morris Jan 2015

Using Stormwater Modeling In Iterative Site Design: An Integration Of Techniques From Engineering And Landscape Architecture, Brooke Erin Morris

LSU Master's Theses

Landscape Architects currently do not have an efficient method for including stormwater quantities in early stages of their design process. With stormwater control infrastructure and theory rapidly shifting in favor of stormwater management with Green Infrastructure or Low Impact Development technologies (LIDs), landscape architects and planners are increasingly making layout and sizing decisions for stormwater design. Due to the development of modeling tools, it is now possible to rapidly produce quantifiable stormwater values for complex site designs at a range of scales. This paper proposes a methodology for the utilization of the EPA – Stormwater Management Model (SWMM), in conjunction …

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Metacommunity Dynamics And The Biogeography Of Central Louisiana Crayfishes, William Robert Budnick Jan 2015

Metacommunity Dynamics And The Biogeography Of Central Louisiana Crayfishes, William Robert Budnick

LSU Master's Theses

The greatest diversity of crayfishes, especially of rare Orconectes species, is found in the central Louisiana watersheds (Red River, Mermentau, Calcasieu, and Vermillion-Teche), and most species are widely distributed among the drainages. The purpose of this research was to lay groundwork for species distribution and metacommunity modelling for crayfishes in this region. To address this goal, two field studies were performed in the summers of 2013 and 2014, as well as an indoor laboratory study. Analyses of broadly distributed species indicated no significant correlations between species abundances and habitat variables nor any significant environmental gradients for those species. Within-drainage variability …

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La Grad Act’S Effects On Developmental Faculty: A Case Study, Patricia Kuhlman Van Brunt Jan 2015

La Grad Act’S Effects On Developmental Faculty: A Case Study, Patricia Kuhlman Van Brunt

LSU Doctoral Dissertations

Over the past 50 years, state legislatures have placed mandates on higher education institutions to lower attrition, thereby increasing student retention and completion. This study investigated and sought to understand the relationship between the Louisiana Granting Resources and Autonomy for Diplomas Act, or the LA GRAD Act (2010), and developmental education. More specifically, it focused on the perceptions of the mandate held by developmental education faculty who are employed at a public, urban Louisiana community college. This study utilized the four-framework approach by Bolman and Deal (2013) to decipher how developmental classrooms, academic departments, and a higher education institution as …

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A Test Of The Effectiveness Of The Active Learning Technique Think-Pair-Share In A High School Science Classroom, Michael Francis Lowe Jan 2015

A Test Of The Effectiveness Of The Active Learning Technique Think-Pair-Share In A High School Science Classroom, Michael Francis Lowe

LSU Master's Theses

In this study, the active learning technique think-pair-share was tested in an independent high school non-honors chemistry classroom to see if it was more effective than teaching techniques already being used in the chemistry classes. Two classes of tenth grade chemistry students were combined as a test group and a third class of tenth grade chemistry students acted as the control. Learning gains for pre and post-tests from three different chemistry units were analyzed and no significant difference was found between the results of the control and test groups, indicating that think-pair-share was as effective as teaching methods already in …

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