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2015

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Interactions Among Spruce Beetle Disturbance, Climate Change And Forest Dynamics Captured By A Forest Landscape Model, Christian Temperli, Thomas T. Veblen, Sarah J. Hart, Dominik Kulakowski, Alan J. Tepley Jan 2015

Interactions Among Spruce Beetle Disturbance, Climate Change And Forest Dynamics Captured By A Forest Landscape Model, Christian Temperli, Thomas T. Veblen, Sarah J. Hart, Dominik Kulakowski, Alan J. Tepley

Geography

The risk of bark beetle outbreaks is widely predicted to increase because of a warming climate that accelerates temperature-driven beetle population growth and drought stress that impairs host tree defenses. However, few if any studies have explicitly evaluated climatically enhanced beetle population dynamics in relation to climate-driven changes in forest composition and structure that may alter forest suitability for beetle infestation. We synthesized current understanding of the interactions among climate, spruce beetles (Dendroctonus rufipennis) and forest dynamics to parameterize and further advance the bark beetle module of a dynamic forest landscape model (LandClim) that also integrates fire and wind disturbance …


The Rollamo 2015, Missouri University Of Science And Technology Jan 2015

The Rollamo 2015, Missouri University Of Science And Technology

Yearbooks

No abstract provided.


Modeling And Simulation Of Molecular Couette Flows And Related Flows, Wei Li Jan 2015

Modeling And Simulation Of Molecular Couette Flows And Related Flows, Wei Li

Mathematics & Statistics Theses & Dissertations

In this thesis, molecular Couette flow is clearly defined and the modeling and simulation of this kind of flow is systematically investigated. First, the integral equations for the velocity of gaseous Couette flow and related flows are derived from linearized Boltzmann BGK equation with Maxwell boundary condition and solved with high precision by using Chebyshev collocation and chunk-based collocation methods. The velocity profiles of gaseous Couette flows and related flows with a wide range of Knudsen number and the Maxwell boundary condition of various accommodation ratios are obtained. Moreover, the order of convergence of the numerical methods is also discussed …


A Survey Of Methods For Finding Outliers In Wireless Sensor Networks, Dylan Mcdonald, Stewart Sanchez, Sanjay Kumar Madria, Fikret Ercal Jan 2015

A Survey Of Methods For Finding Outliers In Wireless Sensor Networks, Dylan Mcdonald, Stewart Sanchez, Sanjay Kumar Madria, Fikret Ercal

Computer Science Faculty Research & Creative Works

Outlier detection is a well-studied problem in various fields. The unique characteristics and constraints of wireless sensor networks (WSN) make this problem especially challenging. Sensors can detect outliers for a plethora of reasons and these reasons need to be inferred in real time. Here, we survey the current state of research in this area, compare them and present some future directions for smarter handling of outliers in WSN.


Privacy Policy Inference Of User-Uploaded Images On Content Sharing Sites, Anna Cinzia Squicciarini, Dan Lin, Smitha Sundareswaran, Joshua Wede Jan 2015

Privacy Policy Inference Of User-Uploaded Images On Content Sharing Sites, Anna Cinzia Squicciarini, Dan Lin, Smitha Sundareswaran, Joshua Wede

Computer Science Faculty Research & Creative Works

With the increasing volume of images users share through social sites, maintaining privacy has become a major problem, as demonstrated by a recent wave of publicized incidents where users inadvertently shared personal information. In light of these incidents, the need of tools to help users control access to their shared content is apparent. Toward addressing this need, we propose an Adaptive Privacy Policy Prediction (A3P) system to help users compose privacy settings for their images. We examine the role of social context, image content, and metadata as possible indicators of users' privacy preferences. We propose a two-level framework which according …


A Preliminary Investigation Of The Relationship Between Direct Behavior Rating And The Conners 3 Teacher Rating Scale - Short Form, Jessica Stodden Stumme Jan 2015

A Preliminary Investigation Of The Relationship Between Direct Behavior Rating And The Conners 3 Teacher Rating Scale - Short Form, Jessica Stodden Stumme

Dissertations and Theses @ UNI

A growing body of evidence shows that Direct Behavior Rating (DBR) should continue to be examined as a method of behavior assessment to inform decisions about universal screening as well as progress monitoring for group or individual interventions. Researchers have looked toward DBR as a potential method to capture levels of problem behavior for use in tiered problem solving models. Most research on DBR has focused on comparing its ratings against systematic direct observation. The current study examined the correlation between DBR ratings of academic engagement and disruptive behavior with the Conners 3-Teacher Short (Conners 3-T(S)) form. This is important …


Embolic Stroke As The Initial Manifestation Of Systemic Lupus Erythematosus, Reshma M. Khan, Rajaie Namas, Sachin Parikh, Bernard Rubin Jan 2015

Embolic Stroke As The Initial Manifestation Of Systemic Lupus Erythematosus, Reshma M. Khan, Rajaie Namas, Sachin Parikh, Bernard Rubin

Cardiology Articles

We present a case of a 21-year-old African-American female with no significant medical history, who presented to the emergency department with a one-week history of blurry and double vision. Ophthalmology evaluation revealed bilateral retinal artery occlusion. Further workup with imaging of the brain was consistent with an ischemic stroke. Hereditary hypercoagulable workup was unremarkable and initial testing for antiphospholipid syndrome was positive. She underwent transesophageal echocardiogram (TEE), which showed severe mitral regurgitation and thickening of mitral valve leaflets consistent with Libman-Sacks endocarditis. Autoimmune workup was positive for IF-ANA, anti-RNP, and anti-Smith antibody. She fulfilled 4/11 of the ACR criteria and …


Catalog 2015-2016, University Of North Florida Jan 2015

Catalog 2015-2016, University Of North Florida

UNF Course Catalogs

No abstract provided.


Ciphercard: A Token-Based Approach Against Camera-Based Shoulder Surfing Attacks On Common Touchscreen Devices, Teddy Seyed, Xing-Dong Yang, Anthony Tang, Saul Greenberg, Jiawei Gu, Bin Zhu, Xiang Ciao Jan 2015

Ciphercard: A Token-Based Approach Against Camera-Based Shoulder Surfing Attacks On Common Touchscreen Devices, Teddy Seyed, Xing-Dong Yang, Anthony Tang, Saul Greenberg, Jiawei Gu, Bin Zhu, Xiang Ciao

Research Collection School Of Computing and Information Systems

We present CipherCard, a physical token that defends against shoulder-surfing attacks on user authentication on capacitive touchscreen devices. When CipherCard is placed over a touchscreen’s pin-pad, it remaps a user’s touch point on the physical token to a different location on the pin-pad. It hence translates a visible user password into a different system password received by a touchscreen, but is hidden from observers as well as the user. CipherCard enhances authentication security through Two-Factor Authentication (TFA), in that both the correct user password and a specific card are needed for successful authentication. We explore the design space of CipherCard, …


Modeling Supply Chain Interdependent Critical Infrastructure Systems, Varun Ramachandran Jan 2015

Modeling Supply Chain Interdependent Critical Infrastructure Systems, Varun Ramachandran

Doctoral Dissertations

"While strategies for emergency response to large-scale disasters have been extensively studied, little has been done to map medium- to long-term strategies capable of restoring supply chain infrastructure systems and reconnecting such systems from a local urban area to national supply chain systems. This is, in part, because no comprehensive, data-driven model of supply chain networks exists. Without such models communities cannot re-establish the level of connectivity required for timely restoration of goods and services. This dissertation builds a model of supply chain interdependent critical infrastructure (SCICI) as a complex adaptive systems problem. It defines model elements, data needs/element, the …


Investigation Of Robust Optimization And Evidence Theory With Stochastic Expansions For Aerospace Applications Under Mixed Uncertainty, Harsheel R. Shah Jan 2015

Investigation Of Robust Optimization And Evidence Theory With Stochastic Expansions For Aerospace Applications Under Mixed Uncertainty, Harsheel R. Shah

Doctoral Dissertations

One of the primary objectives of this research is to develop a method to model and propagate mixed (aleatory and epistemic) uncertainty in aerospace simulations using DSTE. In order to avoid excessive computational cost associated with large scale applications and the evaluation of Dempster Shafer structures, stochastic expansions are implemented for efficient UQ. The mixed UQ with DSTE approach was demonstrated on an analytical example and high fidelity computational fluid dynamics (CFD) study of transonic flow over a RAE 2822 airfoil.

Another objective is to devise a DSTE based performance assessment framework through the use of quantification of margins and …


Stability Of Transportation Networks Under Adaptive Routing Policies, Sebastien Boyer, Sebastien Blandin, Laura Wynter Jan 2015

Stability Of Transportation Networks Under Adaptive Routing Policies, Sebastien Boyer, Sebastien Blandin, Laura Wynter

Research Collection School Of Computing and Information Systems

Growing concerns regarding urban congestion, and the recent explosion of mobile devices able to provide real-time information to traffic users have motivated increasing reliance on real-time route guidance for the online management of traffic networks. However, while the theory of traffic equilibria is very well-known, much fewer results exist on the stability of such equilibria, especially in the context of adaptive routing policy. In this work, we consider the problem of characterizing the stability properties of traffic equilibria in the context of online adaptive route choice induced by GPS-based decision making. We first extend the recent framework of “Markovian Traffic …


Mechanism Design For Near Real-Time Retail Payment And Settlement Systems, Zhiling Guo, Robert John Kauffman, Mei Lin, Dan Ma Jan 2015

Mechanism Design For Near Real-Time Retail Payment And Settlement Systems, Zhiling Guo, Robert John Kauffman, Mei Lin, Dan Ma

Research Collection School Of Computing and Information Systems

have made extensive use of interbank netting systems, in which payments are accumulated for end-of-day settlement. This approach, known as deferred net settlement (DNS), reduces the liquidity needs of a payment system, but bears inherent operational risks. As large dollar volumes of retail payments accumulate swiftly, real-time gross settlement (RTGS) is an attractive option. It permits immediate settlement of transactions during the day, but it brings up other risks that require consideration. We propose a hybrid payment management system involving elements of both DNS and RTGS. We explore several hybrid system mechanism designs to allow payment prioritization, reduce payment delays, …


Software Puzzle: A Countermeasure To Resource-Inflated Denial-Of-Service Attacks, Yongdong Wu, Zhigang Zhao, Bao Feng, Robert H. Deng Jan 2015

Software Puzzle: A Countermeasure To Resource-Inflated Denial-Of-Service Attacks, Yongdong Wu, Zhigang Zhao, Bao Feng, Robert H. Deng

Research Collection School Of Computing and Information Systems

Denial-of-service (DoS) and distributed DoS (DDoS) are among the major threats to cyber-security, and client puzzle, which demands a client to perform computationally expensive operations before being granted services from a server, is a well-known countermeasure to them. However, an attacker can inflate its capability of DoS/DDoS attacks with fast puzzle-solving software and/or built-in graphics processing unit (GPU) hardware to significantly weaken the effectiveness of client puzzles. In this paper, we study how to prevent DoS/DDoS attackers from inflating their puzzle-solving capabilities. To this end, we introduce a new client puzzle referred to as software puzzle. Unlike the existing client …


An Adaptive Gradient Method For Online Auc Maximization, Yi Ding, Peilin Zhao, Steven C. H. Hoi, Yew-Soon Ong Jan 2015

An Adaptive Gradient Method For Online Auc Maximization, Yi Ding, Peilin Zhao, Steven C. H. Hoi, Yew-Soon Ong

Research Collection School Of Computing and Information Systems

Learning for maximizing AUC performance is an important research problem in machine learning. Unlike traditional batch learning methods for maximizing AUC which often suffer from poor scalability, recent years have witnessed some emerging studies that attempt to maximize AUC by single-pass online learning approaches. Despite their encouraging results reported, the existing online AUC maximization algorithms often adopt simple stochastic gradient descent approaches, which fail to exploit the geometry knowledge of the data observed in the online learning process, and thus could suffer from relatively slow convergence. To overcome the limitation of the existing studies, in this paper, we propose a …


The Knowledge Accumulation And Transfer In Open-Source Software (Oss) Development, Youngsoo Kim, Lingxiao Jiang Jan 2015

The Knowledge Accumulation And Transfer In Open-Source Software (Oss) Development, Youngsoo Kim, Lingxiao Jiang

Research Collection School Of Computing and Information Systems

We examine the learning curves of individual software developers in Open-Source Software (OSS) Development. We collected the dataset of multi-year code change histories from the repositories for 20 open source software projects involving more than 200 developers. We build and estimate regression models to assess individual developers' learning progress (in reducing the likelihood they make a bug). Our estimation results show that developer's coding and indirect bug-fixing experiences do not decrease bug ratios while bug-fixing experience can lead to the decrease of bug ratio of learning progress. We also find that developer's coding and bug-fixing experiences in other projects do …


Multi-User Multiple Input Multiple Output (Mimo) Communication With Distributed Antenna Systems In Wireless Networks, Karthikeyan Sundaresan, Mohammad Khojastepour, Sampath Rangarajan, Jie Xiong Jan 2015

Multi-User Multiple Input Multiple Output (Mimo) Communication With Distributed Antenna Systems In Wireless Networks, Karthikeyan Sundaresan, Mohammad Khojastepour, Sampath Rangarajan, Jie Xiong

Research Collection School Of Computing and Information Systems

A system and a method are provided. The method includes deploying a plurality of antennas of an access point or a base station as a distributed antenna system. The method further includes configuring the distributed antenna system for multi-user wireless transmissions by applying medium access techniques and power-balanced pre-coding at the access point or the base station. The method also includes providing device localization for devices communicating with the distributed antenna system by applying time-difference-of-arrival techniques to antenna pairs from among the plurality of antennas at the access point or the base station.


A Swirl In The Clouds Near Santa Cruz Island (Images Of Note), Bradley M. Muller, Christopher G. Herbster Jan 2015

A Swirl In The Clouds Near Santa Cruz Island (Images Of Note), Bradley M. Muller, Christopher G. Herbster

Publications

The authors discuss a rare photograph of an atmospheric eddy produced by marine boundary layer flow past terrain.


Formation And Assessment Of A Tool To Evaluate Stem Literacy In Service-Learning Projects, Barbara Hayford, Sally Blomstrom, Lori A. Mumpower Jan 2015

Formation And Assessment Of A Tool To Evaluate Stem Literacy In Service-Learning Projects, Barbara Hayford, Sally Blomstrom, Lori A. Mumpower

Publications

The purpose of the authors’ research was to create a tool to evaluate science, technology, engineering, and mathematics (STEM) literacy in service-learning projects. The researchers posited that components of service-learning, which in this case included the deliverable and reflections, are examples of fundamental STEM literacy and thus can be assessed for STEM learning outcomes. The authors review the literature on service-learning and on STEM literacy. Combining components of literacy-based learning objectives and service-learning objectives with the revised Bloom’s taxonomy in a taxonomy table, they created a general STEM literacy evaluation tool. They then applied the tool to a service-learning project …


The Damaging Effects Of Climate Change Denial, Richard Snow, Mary Snow Jan 2015

The Damaging Effects Of Climate Change Denial, Richard Snow, Mary Snow

Publications

It has been said that those who are denying climate change are like the ostrich that sticks her head in the sand, but is this analogy entirely accurate? By hiding from the threat, does the ostrich make the threat go away, mitigate it, or make it greater? Probably, she does not. However, denying the existence of climate change does exacerbate the problem and exponentially so. As the renowned British economist Nicholas Stern reports, the longer world leaders wait to take serious action to curtail climate change, the more it will cost. As the Chair of the Grantham Research Institute on …


The Impact Of Climate Change On Human Health, Mary Snow, Richard Snow Jan 2015

The Impact Of Climate Change On Human Health, Mary Snow, Richard Snow

Publications

Climate change is impacting human health. An obvious effect of a warmer environment is more frequent and severe heat waves. During the European heat wave of 2003, there were an estimated 35,000 more deaths than normal in the first two weeks of August. Many of the deaths resulted from cardiovascular complications among the elderly. As heat waves become more commonplace in the future, so will the number of heat strokes and the onset of other cardiovascular problems. Higher summertime temperatures also increase tropospheric ozone concentrations which in turn affects people with asthma and causes lung and heart damage. Increases in …


A Systematic Study On Explicit-State Non-Zenoness Checking For Timed Automata, Ting Wang, Jun Sun, Xinyu Wang, Yang Liu, Yuanjie Si, Jin Song Dong, Xiaohu Yang, Xiaohong Li Jan 2015

A Systematic Study On Explicit-State Non-Zenoness Checking For Timed Automata, Ting Wang, Jun Sun, Xinyu Wang, Yang Liu, Yuanjie Si, Jin Song Dong, Xiaohu Yang, Xiaohong Li

Research Collection School Of Computing and Information Systems

Zeno runs, where infinitely many actions occur within finite time, may arise in Timed Automata models. Zeno runs are not feasible in reality and must be pruned during system verification. Thus it is necessary to check whether a run is Zeno or not so as to avoid presenting Zeno runs as counterexamples during model checking. Existing approaches on non-Zenoness checking include either introducing an additional clock in the Timed Automata models or additional accepting states in the zone graphs. In addition, there are approaches proposed for alternative timed modeling languages, which could be generalized to Timed Automata. In this work, …


A Systematic Review Of Social Networks Research In Information Systems: Building A Foundation For Exciting Future Research, Jinwei Cao, Kamile Asli Basoglu, Hong Sheng, Paul Benjamin Lowry Jan 2015

A Systematic Review Of Social Networks Research In Information Systems: Building A Foundation For Exciting Future Research, Jinwei Cao, Kamile Asli Basoglu, Hong Sheng, Paul Benjamin Lowry

Business and Information Technology Faculty Research & Creative Works

Social networking applications such as blogs, instant messengers, podcasts, social networking websites (e.g., Renren in China, Vkontakte in Russia, Facebook), professional networking websites (e.g., LinkedIn), Twitter, and virtual worlds (e.g., Second Life) have become increasingly popular in the last few years. Because these applications have substantial implications for users, organizations, and society, social networks (SNs) have gained attention from information systems (IS) researchers and grown steadily as a research area since 2004 However, to organize the accumulated research and encourage researchers to examine new and pressing issues in SNs, available knowledge needs to be synthesized and research gaps need to …


Mitochondria- Targeted Antioxidant Skq1 Reverses Glaucomatous Lesions In Rabbits, Elena N. Iomdina, Inna P. Khoroshilova-Maslova, Olga V. Robustova, Olga A. Averina, Nadezhda A. Kovaleva, Gjumrakch Aliev, V. Prakash Reddy, Andrey A. Zamyatnin, Maxim V. Skulachev, Ivan I. Senin, Vladimir P. Skulachev Jan 2015

Mitochondria- Targeted Antioxidant Skq1 Reverses Glaucomatous Lesions In Rabbits, Elena N. Iomdina, Inna P. Khoroshilova-Maslova, Olga V. Robustova, Olga A. Averina, Nadezhda A. Kovaleva, Gjumrakch Aliev, V. Prakash Reddy, Andrey A. Zamyatnin, Maxim V. Skulachev, Ivan I. Senin, Vladimir P. Skulachev

Chemistry Faculty Research & Creative Works

Glaucoma is the main cause of irreversible blindness worldwide. This disease is characterized by apoptosis of retinal ganglion cells (RGC) and visual field loss that seems to be related to elevated intraocular pressure (IOP). Several lines of evidences have implicated the crucial role of mitochondrial dysfunction in the pathogenesis of glaucoma. Increased mitochondrial oxidative stress in RGC may underlie or contribute to susceptibility of RGC to apoptosis. In our work we (i) designed a rabbit model of chronic, moderately elevated IOP for studying glaucoma and (ii) demonstrated efficacy of mitochondria- Targeted antioxidant SkQ1 as a tool to reverse several traits …


A Rapid And High Content Assay That Measures Cyto-Id-Stained Autophagic Compartments And Estimates Autophagy Flux With Potential Clinical Applications, Sujuan Guo, Yanping Liang, Susan F. Murphy, Angela Huang, Haihong Shen, Deborah F. Kelly, Pablo Sobrado, Zhi Sheng Jan 2015

A Rapid And High Content Assay That Measures Cyto-Id-Stained Autophagic Compartments And Estimates Autophagy Flux With Potential Clinical Applications, Sujuan Guo, Yanping Liang, Susan F. Murphy, Angela Huang, Haihong Shen, Deborah F. Kelly, Pablo Sobrado, Zhi Sheng

Chemistry Faculty Research & Creative Works

The lack of a rapid and quantitative autophagy assay has substantially hindered the development and implementation of autophagy-targeting therapies for a variety of human diseases. To address this critical issue, we developed a novel autophagy assay using the newly developed Cyto-ID fluorescence dye. We first verified that the Cyto-ID dye specifically labels autophagic compartments with minimal staining of lysosomes and endosomes. We then developed a new Cyto-ID fluorescence spectrophotometric assay that makes it possible to estimate autophagy flux based on measurements of the Cyto-ID-stained autophagic compartments. By comparing to traditional autophagy approaches, we found that this assay yielded a more …


In Planta Variation Of Volatile Biosynthesis: An Alternative Biosynthetic Route To The Formation Of The Pathogen-Induced Volatile Homoterpene Dmnt Via Triterpene Degradation In Arabidopsis Roots, Reza Sohrabi, Jung Hyun Huh, Somayesadat Badieyan, Liva Harinantenaina Rakotondraibe, Daniel J. Kliebenstein, Pablo Sobrado, Dorothea Tholl Jan 2015

In Planta Variation Of Volatile Biosynthesis: An Alternative Biosynthetic Route To The Formation Of The Pathogen-Induced Volatile Homoterpene Dmnt Via Triterpene Degradation In Arabidopsis Roots, Reza Sohrabi, Jung Hyun Huh, Somayesadat Badieyan, Liva Harinantenaina Rakotondraibe, Daniel J. Kliebenstein, Pablo Sobrado, Dorothea Tholl

Chemistry Faculty Research & Creative Works

Plant-derived volatile compounds such as terpenes exhibit substantial structural variation and serve multiple ecological functions. Despite their structural diversity, volatile terpenes are generally produced from a small number of core 5- to 20-carbon intermediates. Here, we present unexpected plasticity in volatile terpene biosynthesis by showing that irregular homo/norterpenes can arise from different biosynthetic routes in a tissue specific manner. While Arabidopsis thaliana and other angiosperms are known to produce the homoterpene (E)-4,8-dimethyl-1,3,7-nonatriene (DMNT) or its C16-analog (E,E)-4,8,12-trimethyl-1,3,7,11-tridecatetraene by the breakdown of sesquiterpene and diterpene tertiary alcohols in aboveground tissues, we demonstrate that Arabidopsis roots biosynthesize DMNT by the degradation of …


Palladium-Catalyzed Annulation Of 9-Halophenanthrenes With Alkynes: Synthesis, Structural Analysis, And Properties Of Acephenanthrylene-Based Derivatives, En Chih Liu, Min-Kuan Chen, Jen-Yi Li, Yao-Ting Wu Jan 2015

Palladium-Catalyzed Annulation Of 9-Halophenanthrenes With Alkynes: Synthesis, Structural Analysis, And Properties Of Acephenanthrylene-Based Derivatives, En Chih Liu, Min-Kuan Chen, Jen-Yi Li, Yao-Ting Wu

Chemistry Faculty Research & Creative Works

The palladium-catalyzed annulation of 9-bromoand 9-chlorophenanthrenes with alkynes gave 4,5-disubstituted acephenanthrylenes in yields of 58–95% (9 examples). Asymmetric alkynes, such as 1-phenyl-1-propyne, 1-phenyl- 1-hexyne, and 1-cyclopropyl-2-phenylethyne, regioselectively form (cyclo)alkyl-substituted products, following the regular rule that governs the carbopalladation of alkynes. This synthetic protocol can also be utilized in annulations with several p-extended bromoarenes, such as 7-5] helicene, 5- 4] helicene, 9-bromoanthracene, 3-bromoperylene, and 3-bromofluoranthene, to give the corresponding annulated products in moderate to good yields (51–86 %; 6 examples). Similarly, bromocorannulene produced highly curved 1,2-disubstituted cyclopentacorannulenes. Reactions of 6,12-dibromochrysene and 4,7-4] helicene with di(4-tolyl) ethyne provided the twofold annulated products …


Palladium-Catalyzed Reaction Of Haloarenes With Diarylethynes: Synthesis, Structural Analysis, And Properties Of Methylene-Bridged Arenes, Che-Wei Lee, En Chih Liu, Yao-Ting Wu Jan 2015

Palladium-Catalyzed Reaction Of Haloarenes With Diarylethynes: Synthesis, Structural Analysis, And Properties Of Methylene-Bridged Arenes, Che-Wei Lee, En Chih Liu, Yao-Ting Wu

Chemistry Faculty Research & Creative Works

Fluorenes and methylene-bridged polyarenes were easily and efficiently synthesized from haloarenes (or aryl triflates) and diarylethynes by a one-pot, two-step procedure. This protocol involves the palladium-catalyzed cycloisomerization and a subsequent base-mediated retro-aldol condensation. A major advantage is that the starting materials need not have ortho functional groups to complete the annulation. The backbone of the designed products was enlarged using dihaloarenes, highly π-conjugated haloarenes, or diarylalkynes. The mechanism of the formation of benzo[a]fluorene was investigated. The bowl-shaped structure of methylene-bridged indenocorannulene was verified by X-ray crystallography. The photophysical and electrochemical properties of the products thus prepared were investigated.


Boron Nitride Colloidal Solutions, Ultralight Aerogels And Freestanding Membranes Through One-Step Exfoliation And Functionalization, Weiwei Lei, Vadym Mochalin, Dan Liu, Si Qin, Yury G. Gogotsi, Ying Chen Jan 2015

Boron Nitride Colloidal Solutions, Ultralight Aerogels And Freestanding Membranes Through One-Step Exfoliation And Functionalization, Weiwei Lei, Vadym Mochalin, Dan Liu, Si Qin, Yury G. Gogotsi, Ying Chen

Chemistry Faculty Research & Creative Works

Manufacturing of aerogels and membranes from hexagonal boron nitride (h-BN) is much more difficult than from graphene or graphene oxides because of the poor dispersibility of h-BN in water, which limits its exfoliation and preparation of colloidal solutions. Here, a simple, one-step mechano-chemical process to exfoliate and functionalize h-BN into highly water-dispersible, few-layer h-BN containing amino groups is presented. The colloidal solutions of few-layer h-BN can have unprecedentedly high concentrations, up to 30 mg ml-1, and are stable for up to several months. They can be used to produce ultralight aerogels with a density of 1.4 mg cm …


What Is Equity? Ways Of Seeing, Christa Jackson, Cynthia Taylor, Kelley Buchheister Jan 2015

What Is Equity? Ways Of Seeing, Christa Jackson, Cynthia Taylor, Kelley Buchheister

Department of Child, Youth, and Family Studies: Faculty Publications

Prospective teachers must be prepared for their role in providing equitable access for learning high quality mathematics. Therefore, it is imperative that mathematics teacher educators provide opportunities to develop an equity-centered orientation in teacher preparation courses. In this study, we begin to address this issue by identifying what prospective teachers attend to in a classroom vignette of an African American male student who is above grade level in mathematics and exhibits disruptive behavior during instruction. The results of the study indicate that while participants are beginning to attend to cultural influences, most responses are focused on classroom management strategies