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2014

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Articles 52921 - 52950 of 53414

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Mechanical And Thermal Properties Of Polylactide/Polymeric Plasticizers, Wanlapha Apising Jan 2014

Mechanical And Thermal Properties Of Polylactide/Polymeric Plasticizers, Wanlapha Apising

Chulalongkorn University Theses and Dissertations (Chula ETD)

The current study focused on flexibility improvement of polylactide by using three new types of plasticizers: diethyl succinate, glycerol ethoxylate, poly(di(ethylene glycol)adipate). The plasticizer concentrations were varied depending on each type. Mechanical property of the plasticized polymers was investigated. It was found that elongation at break of the plasticized polymers was increased, whereas tensile strength and Young’s modulus were decreased. The plasticized polymer with diethyl succinate exhibited the highest elongation at break. Thermal property of the plasticized polymers containing glycerol ethoxylate yielded the lowest Tg and Tc. When the plasticizers were added, thermal property was reduced, in which the plasticized …

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Characterization Of Bacteriophage Specific To Non-Agglutinable Vibrio Cholerae, Dulyapat Benyajirapatch Jan 2014

Characterization Of Bacteriophage Specific To Non-Agglutinable Vibrio Cholerae, Dulyapat Benyajirapatch

Chulalongkorn University Theses and Dissertations (Chula ETD)

Vibrio spp. the main bacteria found in marine shrimp can cause diseases either in shrimp or human. Using antibiotics is a first option to reduce this problem. Unfortunately, this treatment has no sufficient potential due to antibiotic resistance can occur after long term of use. Therefore, bacteriophage has become a better alternative to control Vibrio spp. in shrimp. In this study, 100 isolates of Vibrio spp. were screened and isolated from Pacific white shrimp Litopaeneus vannamei and cultured water from shrimp hatcheries and ponds. The suspected Vibrio spp. were determined and classified into 5 species including V. cholerae, V. parahaemolyticus, …

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Production And Characterization Of Monoclonal Antibodies Against Listeria Monocytogenes, Korrakot Prommajan Jan 2014

Production And Characterization Of Monoclonal Antibodies Against Listeria Monocytogenes, Korrakot Prommajan

Chulalongkorn University Theses and Dissertations (Chula ETD)

Listeria monocytogenes contaminated in foods is a bacteria that can cause Listeriosis in human and animals. Detection of this bacteria in food products is required in order to reduce the opportunity of infection and increases consumers’ trust on taking food safely. Diagnostic based on immunological method with monoclonal antibody (MAb) specific to pathogen is accurate and precise. The objective of this research was to produce MAbs against L. monocytogenes NCTC 11994 and EGD-e strains by immunization mice with heat-inactivated, sonicated- and SDS-mercaptoethanol treated forms. After cell fusion 21 of hybridoma were obtained. MAbs reacted crossly with some Listeria spp. and …

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Dry Reforming Of Methane In Palladium-Silver-Copper Alloy Membrane Reactor, Sarocha Sumrunronnasak Jan 2014

Dry Reforming Of Methane In Palladium-Silver-Copper Alloy Membrane Reactor, Sarocha Sumrunronnasak

Chulalongkorn University Theses and Dissertations (Chula ETD)

PdAgCu ternary alloy membranes were prepared by the sequential electroless plating of Pd following by electroplating of Ag and Cu onto stainless steel support. The metal composition of the membrane was varied by changing the metal deposition times. The fabricated membranes were then annealed at various temperatures from 500 °C to 600 °C under argon atmosphere in order to form the alloys for 20 to 120 hrs. The Energy Dispersive X-ray spectroscopy (EDX) and X-Ray Diffraction (XRD) were employed to investigate the element distribution in the membrane which provided the insight of the alloying formation. Complete formation of the alloy …

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Preparation Of Polylactide/ Polycaprolactone/Hydroxyapatite Particles, Walaiporn Nguantanom Jan 2014

Preparation Of Polylactide/ Polycaprolactone/Hydroxyapatite Particles, Walaiporn Nguantanom

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research focused on preparation of polylactide/polycaprolactone/hydroxyapatite particles by using the solvent evaporation method. The effects of HA loadings varied in a range of 10-40 wt% and blending ratios between PLA and PCL on the size distribution, morphology, and thermal properties of the composite films were investigated. The results showed that the size distributions of the composite particles were composed of both small and large particles, depending on the HA concentration and blending ratio of PLA/PCL. The addition of HA at 10 wt% exhibited a strong influence on the size distribution of microspheres, while the PLA/PCL blend tended to produce …

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Flame Retardant Property Improvement Of Polyester Fiber Using Inorganic Additives, Warunee Wattanatanom Jan 2014

Flame Retardant Property Improvement Of Polyester Fiber Using Inorganic Additives, Warunee Wattanatanom

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research focused on improving the flame retardancy of polyester and cotton/polyester blended fabrics using intumescent coating via layer-by-layer assembly technique with and without kaolin. The flammability, morphology, thermal stability and mechanical property of coated fabrics were investigated in comparison with uncoated fabrics. Branched polyethyleneimine and ammonium polyphosphate with and without kaolin were respectively used as polycationic and polyanionic to build up the multiple cationic/anionic pairs of layer by deposition technique. The SEM micrographs of coated fabrics compared with uncoated fabrics revealed as well as FT-IR analysis confirmed that layer-by-layer coatings were successfully applied onto the fabrics. The vertical burning …

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Synthesis Of Poly(N-Isopropylacrylamide)-Based Nanogels Via Differential Microemulsion Polymerization For Drug Delivery Systems, Meshaya Pruettiphap Jan 2014

Synthesis Of Poly(N-Isopropylacrylamide)-Based Nanogels Via Differential Microemulsion Polymerization For Drug Delivery Systems, Meshaya Pruettiphap

Chulalongkorn University Theses and Dissertations (Chula ETD)

This thesis is to study the synthesis of poly(N-isopropylacrylamide-co-protic acid) nanogels and their performance to be used as drug delivery carriers. The objective is to achieve thermal/pH-responsive nanogels with a lower critical solution temperature (LCST) close to human body temperature. Differential microemulsion polymerization (DMP) technique, which has been considered the best one to produce nanoparticles of a high solid content with a low surfactant amount, was applied. Specifically, one-step DMP was used for synthesizing poly(N-isopropylacrylamide) (PNIPAM) preparation while two-step DMP was adopted to synthesize poly[N-isopropylacrylamide-co-(acrylic acid)] (poly(NIPAM-co-AA)) and poly[N-isopropylacrylamide-co-(itaconic acid)] (poly(NIPAM-co-IA)) nanogels, in which sodium dodecyl sulphate (SDS) was used …

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Comparison Of Role Of Nano-Sized Extra Supports On Pt-Based Catalyst For Propane Dehydrogenation And Wox-Based Catalyst For Propene Metathesis, Adisak Guntida Jan 2014

Comparison Of Role Of Nano-Sized Extra Supports On Pt-Based Catalyst For Propane Dehydrogenation And Wox-Based Catalyst For Propene Metathesis, Adisak Guntida

Chulalongkorn University Theses and Dissertations (Chula ETD)

In this thesis, the role of nano-sized extra supports was studied. The different types of nano-sized supports (ZrO2, TiO2, Al2O3, and SiO2) were physically mixed with WOx-based catalysts for propene metathesis reaction and Pt-based catalysts for propane dehydrogenation reaction as extra support. The dispersions of active sites were improved in both metathesis and dehydrogenation catalysts by the addition of nano-sized extra supports. The migration of active sites from the main catalyst onto the nano-sized extra support during thermal treatment via thermal spreading is a key for this improvement. The surface energy of nano-sized extra support and concentration of metal active …

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Suitable Catalyst Bed Arrangement Of Silica-Based Supported Tungstenand Hydrotalcite Catalysts For Propylene Production From 1-Butene, Sirada Sripinun Jan 2014

Suitable Catalyst Bed Arrangement Of Silica-Based Supported Tungstenand Hydrotalcite Catalysts For Propylene Production From 1-Butene, Sirada Sripinun

Chulalongkorn University Theses and Dissertations (Chula ETD)

The research studied the design of suitable catalyst beds of hydrotalcite and the modified silica supported tungsten for propylene production from 1-butene. The study started with performing reactions at various values of gas hourly space velocity, feed composition and temperature. Then the reaction rate expressions for each catalyst were determined. It was found that the models could predict well the experimental results. The models were further used to simulate the reaction performance of reactors packed with different catalyst beds. The performance was shown in terms of molar flow rate of propylene and yield of propylene. The performance of the catalyst …

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The Effects Of Additives In Ethylene Glycol Based Lubricant On Slider Lapping Process, Patara Paranusorn Jan 2014

The Effects Of Additives In Ethylene Glycol Based Lubricant On Slider Lapping Process, Patara Paranusorn

Chulalongkorn University Theses and Dissertations (Chula ETD)

Lapping process is a key technology in magnetic recording head manufacturing process. Thin film of metal alloys and metal oxides are fabricated on ceramic substrate called wafer to create the recording heads. In order to control surface properties of the recording head, the precise chemical mechanical nano grinding process is used. In this process the recording heads are treated to achieve the designed surface properties by using lubricants to control the selectivity of material removal. The aim of this study was to determine the effects of additives in ethylene glycol based lubricant on the selectivity of material removal of slider …

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Polydopamine As Active Templates For Fabrication Of Conductive Of Copper Line Pattern, Raweewan Thongprachan Jan 2014

Polydopamine As Active Templates For Fabrication Of Conductive Of Copper Line Pattern, Raweewan Thongprachan

Chulalongkorn University Theses and Dissertations (Chula ETD)

In this research, copper conductive patterns were fabricated on polyethylene terephthalate (PET) substrate by combination of spray drying of polydopamine nanoparticles, and consequently electroless plating process. The polydopamine nanoparticle ink was synthesized by self-polymerization of dopamine hydrochloride at different initial pH 8, 8.5, 9 and 10. The patterns were deposited by site-selective Cu electroless plating process on top of the PDA pattern at the controlled temperature 30 C. The effects of plating time in electroless plating and storage time were studied. Moreover, the adhesion and aspect ratio were also investigated. The conductive lines fabricated were characterized by two-point probe measurement, …

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Design Of Plantwide Control Structure Of A Small-Scale Concentrated Solar Power Process Cooperated With Organic Rankine Cycle And Thermal Storage Systems, Pathawut Bua-Ngam Jan 2014

Design Of Plantwide Control Structure Of A Small-Scale Concentrated Solar Power Process Cooperated With Organic Rankine Cycle And Thermal Storage Systems, Pathawut Bua-Ngam

Chulalongkorn University Theses and Dissertations (Chula ETD)

This work presents a study on control system design of a small-scale electricity generation process for household applications using plantwide control technique. The process are of three sections including parabolic trough solar collector, thermal energy storage, and organic Rankine cycle system. Synthetic oil Dowtherm©A and acetone were chosen as heat transfer fluid and working fluid, respectively. In terms of control objectives, the control structure can keep the process operation at maximum efficiency and response the required work load. Control performance of the control structure proposed is tested under various disturbance changes by using dynamic simulator (SIMSCI DYNSIM). The scenarios investigated …

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Simulation Of Temperature Distribution In A Thermal Drying Oven Based On Three Dimensional Cfd Model, Patsarawan Lipikanjanakul Jan 2014

Simulation Of Temperature Distribution In A Thermal Drying Oven Based On Three Dimensional Cfd Model, Patsarawan Lipikanjanakul

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research presents a study of air velocity in a thermal drying oven in drying zone. To reduce a heat loss, a mass flow rates are decreased from 100% to 10%. The effect of the mass flow rate can be divided into three parts; air velocity, air temperature, and concentration of solvent. A three-dimensional CFD with a non-isothermal model and a transport of diluted species were simulated by using COMSOL. For ensuring the result, all results are compared with MATLAB program by focusing in two-direction (length-height). The parameters of air velocity that uses in this program is the results of …

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Synthesis Of Copper (Core) - Tin (Shell) Nanoparticles By Modified Polyol Process And Replacement Reaction, Bongkot Sakunchangsanoh Jan 2014

Synthesis Of Copper (Core) - Tin (Shell) Nanoparticles By Modified Polyol Process And Replacement Reaction, Bongkot Sakunchangsanoh

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research aimed to prevent the oxidation of copper nanoparticles by protecting them with tin as a core-shell structure. Copper (core) nanoparticles were synthesized though modified polyol process and tin (shell) was synthesized though replacement reaction by using glycerol as polyol liquid, sodium phosphinate monohydrate as a reducing agent and thiourea as a surfactant. The effects of sodium phosphinate monohydrate concentration, thiourea concentration and copper ion to tin ion ratio were investigated. The synthesized-nanoparticles were characterized by transmission electron microscopy (TEM), X-ray diffraction techniques (XRD), energy dispersive X-ray spectrometer (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and differential scanning …

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Effect Of Particle Size Of Silica And Sio2/Mao Ratios On Heterogeneous Metallocene Catalyst Performance And Polyethylene Properties, Chalermpong Ramrauytham Jan 2014

Effect Of Particle Size Of Silica And Sio2/Mao Ratios On Heterogeneous Metallocene Catalyst Performance And Polyethylene Properties, Chalermpong Ramrauytham

Chulalongkorn University Theses and Dissertations (Chula ETD)

The metallocene catalyst is one of the catalysts, used to produce polyethylene having narrow molecular weight distribution. So, the metallocene catalyst has been interesting in many researches. To activate metallocene catalyst in ethylene polymerization, methylaluminoxane has been used as cocatalyst because it makes high activity for metallocene catalyst. However, both of them are in solution form, which make fouling in reactor and not good morphology in slurry ethylene polymerization. This problem has been solved by heterogeneous metallocene catalyst. Silica is widely used for heterogeneous metallocene catalyst because of high surface area and good morphology. This research is aimed to study …

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The Effect Of Types Of Alcohol Upon A Support Of Zieglernatta Catalyst To Catalytic Performance, Molecular Weight And Comonomer Composition Distribution, Kanokporn Sinchai Jan 2014

The Effect Of Types Of Alcohol Upon A Support Of Zieglernatta Catalyst To Catalytic Performance, Molecular Weight And Comonomer Composition Distribution, Kanokporn Sinchai

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research investigated the effect of types of alcohol upon a support of Ziegler-Natta catalyst on ethylene polymerization and ethylene/ 1-hexene copolymerization. Alcohols are the Lewis base, which are used during catalyst preparation. The types of alcohol were divided into two systems. First system is the using ethanol as a Lewis base. Second system is the use of a mixture of ethanol with other alcohols such as isopropanol, 1-butanol, 2-butanol, isobutanol, 1-hexanol, 2-hexanol and cyclohexanol. The results showed that the mixture of alcohols did not change the morphology of catalyst. Moreover, these catalysts exhibited the higher activity than the catalyst …

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Impact Of Hydrotalcite Co-Catalyst On Metathesis Of Ethylene And2-Butene Over Silica-Zeolite Supported Tungsten Catalysts, Kriangkrai Aranyarat Jan 2014

Impact Of Hydrotalcite Co-Catalyst On Metathesis Of Ethylene And2-Butene Over Silica-Zeolite Supported Tungsten Catalysts, Kriangkrai Aranyarat

Chulalongkorn University Theses and Dissertations (Chula ETD)

Silica-zeolite supported tungsten oxide catalysts were physically mixed with hydrotalcite synthesized by co-precipitation method and investigated in the metathesis reaction of ethylene and trans-2-butene for propylene production. In this work, the effects of transition metal (a, b, c) doping on the hydrotalcite catalysts and N2-pretreatment on the catalytic properties of hydrotalcite mixed WO3-based catalysts were studied. The use of b-doped hydrotalcite with b/Mg-Al ratio 0.18 mixed with the WO3-based catalysts was found to increase the metathesis activity due to the higher amount of tungsten active species formed on the WO3-based catalysts and the higher isomerization activity of the b-doped hydrotalcite. …

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การผลิตไบโอบิวทานอลจากการย่อยสลายของเปลือกถั่วเหลือง, มานพ บุญเจริญ Jan 2014

การผลิตไบโอบิวทานอลจากการย่อยสลายของเปลือกถั่วเหลือง, มานพ บุญเจริญ

Chulalongkorn University Theses and Dissertations (Chula ETD)

งานวิจัยนี้ทำการศึกษาการย่อยสลายเปลือกถั่วเหลืองด้วยกรดเพื่อใช้เป็นสารตั้งต้นในการผลิตอะซิโตน เอทานอล และบิวทานอล ด้วยเชื้อ Clostridium saccharobutylicum ATCC BAA 117 การย่อยสลายทำในหม้อนึ่งไอน้ำความดันสูงที่ความเข้มข้น อัตราส่วนของแข็งต่อของเหลว และเวลาในการทำปฏิกิริยาที่ค่าต่างๆ สภาวะที่ดีที่สุดสำหรับการผลิตน้ำตาลรีดิวซ์ที่สูงและสารยับยั้งที่ต่ำ มีดังนี้ ความเข้มข้นกรดร้อยละ 5 โดยปริมาตร อัตราส่วนของแข็งต่อของเหลว 1 ต่อ 5 เวลาการย่อยสลาย 15 นาที น้ำตาลไฮโดรไลเซทประกอบด้วยน้ำตาลรีดิวซ์รวม 31.86 กรัมต่อลิตร รวมทั้งเฟอร์ฟูรัล 0.66 กรัมต่อลิตร และไฮดรอกซีเมทิลเฟอร์ฟูรัล 0.059 กรัมต่อลิตร เฟอร์ฟูรัลที่ความเข้มข้น 0.05 กรัมต่อลิตร ได้แสดงฤทธิ์ยับยั้งการเจริญเติบโตของ C. saccharobutylicum ATCC BAA 117 แต่ไฮดรอกซีเมทิลเฟอร์ฟูรัลไม่มีผลกระทบ การบำบัดโดยใช้ Overliming ด้วยแคลเซียมไฮดรอกไซด์ และการดูดซับด้วยเรซิน XAD-4 และถ่านกัมมันต์ ช่วยปรับปรุงน้ำตาลไฮโดรไลเซทให้สามารถใช้ในการหมักได้อย่างมีนัยสำคัญ การหมักแบบกะที่อุณหภูมิ 35 องศาเซลซียส ค่าความเป็นกรดด่าง 5.5 เมื่อใช้น้ำตาลไฮโดรไลเซท (30-65 กรัมต่อลิตร) ที่ชนิดแหล่งและความเข้มข้นแหล่งไนโตรเจนต่างๆ การผลิตตัวทำละลายที่เหมาะสมจะได้รับจากที่สภาวะอุณหภูมิ 35 องศาเซลเซียส ค่าความเป็นกรดด่าง 5.5 ในอาหารน้ำตาลไฮโดรไลเซทที่ประกอบด้วยน้ำตาลรีดิวซ์ 65 กรัมต่อลิตร ยีตส์สกัด แอมโมเนียมอะซิเตทและน้ำแช่ข้าวโพด ตัวทำละลายรวมมีค่า 15.69 กรัมต่อลิตร ประกอบด้วยอะซิโตน บิวทานอล และเอทานอลเท่ากับ 12.15, 15.69 และ 2.39 กรัมต่อลิตร ตามลำดับ มีผลได้ตัวทำละลายเท่ากับ 0.46 และอัตราการผลิตตัวทำละลาย 0.37 กรัมต่อลิตรต่อชั่วโมง ในงานวิจัยนี้แสดงให้เห็นว่าเปลือกถั่วเหลืองสามารถใช้เป็นแหล่งคาร์บอนที่มีศักยภาพสำหรับการหมักเพื่อผลิตอะซิโตน เอทานอล และบิวทานอล

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Copper-Silver Conductive Film By Spray Pyrolysis Of Copper-Silver Amine Complexes, Walailuk Limkitnuwat Jan 2014

Copper-Silver Conductive Film By Spray Pyrolysis Of Copper-Silver Amine Complexes, Walailuk Limkitnuwat

Chulalongkorn University Theses and Dissertations (Chula ETD)

Copper-silver conductive films were fabricated on glass and polyimide substrates by spray pyrolysis of copper-silver amine complex ink in nitrogen atmosphere. The conductive ink was synthesized by mixing of copper (II) acetate monohydrate, silver oxide, ammonia solution, diethanolamine and distilled water. The effects of molar ratio of copper to silver, spray pyrolysis temperature, sintering time and substrate used were studied. The conductive films obtained contained copper and silver nanoparticles. However, copper-silver alloy particles were not observed. Molar ratio of copper to silver affected copper and silver crystallite sizes. The particle packing density synthesized at 200 oC was more compact than …

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Synthesis Of Cu-Zn Alloy Nanoparticles By Microwave–Assisted Polyol Process, Pornpun Arundechachai Jan 2014

Synthesis Of Cu-Zn Alloy Nanoparticles By Microwave–Assisted Polyol Process, Pornpun Arundechachai

Chulalongkorn University Theses and Dissertations (Chula ETD)

In this research, copper-zinc alloy nanoparticles were synthesized through the microwave-assisted polyol co-reduction process in ethylene glycol. The effects of molar ratio of copper to zinc ratio, sodium hydroxide to metal ratio and method of adding ascorbic acid were studied. The particles size, microstructure and morphology of nanoparticles obtained were characterized by XRD, SEM and TEM. The particles obtained synthesized at copper to zinc at 90:10, sodium hydroxide to metal ratio at 5:1 and dropping ascorbic acid at room temperature. The results confirmed the formation of copper-zinc alloy with diameters of particles in range of 20-50 nm. The conductive ink …

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Effect Of Aluminosilicate Type In The Physically Mixed Support On Wox/Sio2-Aluminosilicate Catalyst For Metathesis Of Ethylene And 2-Butene, Kittayanee Suwanthorn Jan 2014

Effect Of Aluminosilicate Type In The Physically Mixed Support On Wox/Sio2-Aluminosilicate Catalyst For Metathesis Of Ethylene And 2-Butene, Kittayanee Suwanthorn

Chulalongkorn University Theses and Dissertations (Chula ETD)

Silica supported tungsten catalysts were physically mixed with different acidic material types (similar particle size ≈ 53-106 µm) as an extra support and compared with the case as bi-support. All catalysts were tested in the metathesis reaction of ethylene and trans-2-butene to propylene and characterized by XRD, NH3-TPD, FTIR-pyridine, UV-vis, Raman, SEM-EDX, TPR and TPO, systematically comparing with reference catalyst, which were physically mixed with SiO2 as the extra support. Adding acidic material resulted in an increased total acidity of the catalysts. Moreover, it could improve the WOx dispersion on the surface and increase the active site precursors. These led …

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Determination Of Interconnection Rate For Thailand's Mobile Telecommunication Industry, Thanoot Yamajinda Jan 2014

Determination Of Interconnection Rate For Thailand's Mobile Telecommunication Industry, Thanoot Yamajinda

Chulalongkorn University Theses and Dissertations (Chula ETD)

Relatively high and unbalanced level of termination rates can cause conflict between operators, and create burden for the consumers. It is within the regulator’s responsibility to step in and intervene with the situation. This thesis aims to find an appropriate solution to determine the mobile interconnection rate of Thailand. The calculation utilized a bottom-up cost model developed with modern efficient operation assumption. Three possible costing approaches, i.e. Long Run Incremental Cost (LRIC), Long Run Average Incremental Cost (LRAIC), and Long Run Average Incremental Cost Plus (LRAIC+) were studied. LRAIC+ was chosen as the standard basis for the calculation framework to …

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Study And Analysis Of Electrolyte Imbalance In A Vanadium Redox Flow Battery, Kittima Ngamsai Jan 2014

Study And Analysis Of Electrolyte Imbalance In A Vanadium Redox Flow Battery, Kittima Ngamsai

Chulalongkorn University Theses and Dissertations (Chula ETD)

Electrolyte imbalance which is an important problem for long-term operation of a vanadium redox flow battery (VRB) is studied and analyzed in this research. A cause of the electrolyte imbalance is firstly studied. The air oxidation of vanadium (V(II)) which is the side reaction in an electrolyte reservoir is investigated. The effects of the ratio of the electrolyte volume to air-electrolyte solution interface area and the ingredients of electrolyte solution on the rate of air oxidation of V(II) are investigated. The results show that the high ratio of the electrolyte volume to air-electrolyte solution interface area can retard the oxidation …

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การควบคุมแบบโมเดลพรีดิกทีฟในการสกัดแบบเสริมฤทธิ์ของไอออนนีโอดิเมียมด้วยเยื่อแผ่นเหลวที่พยุงด้วยเส้นใยกลวง, วรรษมนต์ คอนเอม Jan 2014

การควบคุมแบบโมเดลพรีดิกทีฟในการสกัดแบบเสริมฤทธิ์ของไอออนนีโอดิเมียมด้วยเยื่อแผ่นเหลวที่พยุงด้วยเส้นใยกลวง, วรรษมนต์ คอนเอม

Chulalongkorn University Theses and Dissertations (Chula ETD)

งานวิจัยนี้นำเสนอการประยุกต์ใช้การควบคุมแบบโมเดลพรีดิกทีฟโดยเปรียบเทียบกับการควบคุมแบบพีไอดีสำหรับการควบคุมความเข้มข้นของไอออนนีโอดิเมียมในการสกัดแบบเสริมฤทธิ์ผ่านเยื่อแผ่นเหลวที่พยุงด้วยเส้นใยกลวงเพื่อควบคุมความเข้มข้นของไอออนนีโอดิเมียมขณะออกจากมอดูลของเส้นใยกลวงให้เข้าสู่ค่าเป้าหมาย โดยอาศัยค่าไอเอดีเป็นดัชนีชี้วัด ระบบที่ศึกษาคือ การสกัดไอออนนีโอดิเมียมในสารละลายกรดไนตริก สารสกัดคือ D2EHPA และ TOPO ผสมกันในอัตราส่วน 1:1 สารละลายนำกลับคือกรดซัลฟิวริกความเข้มข้น 1 โมลต่อลิตร รูปแบบการไหลผ่านมอดูลเส้นใยกลวงแบบไหลผ่านครั้งเดียวและสารละลายป้อนไหลสวนทางกับสารละลายนำกลับ และศึกษาสมรรถนะของตัวควบคุมทั้งสองแบบ เมื่อมีความคลาดเคลื่อนระหว่างแบบจำลองกับกระบวนการจริง ที่สภาวะปกติผลการจำลองแสดงให้เห็นว่า ตัวควบคุมทั้งแบบพีไอดีและโมเดลพรีดิกทีฟสามารถควบคุมความเข้มข้นของไอออนนีโอดิเมียมให้เข้าสู่ค่าเป้าหมายได้เร็วกว่ากระบวนการที่ไม่ใช้ตัวควบคุม โดยตัวควบคุมแบบโมเดลพรีดิกทีฟสามารถควบคุมความเข้มข้นของไอออนนีโอดิเมียมให้เข้าสู่ค่าเป้าหมายได้เร็วกว่าตัวควบคุมแบบพีไอดี และเมื่อแบบจำลองมีความคลาดเคลื่อนไปจากกระบวนการจริง ตัวควบคุมทั้งสองแบบสามารถควบคุมความเข้มข้นให้เข้าสู่ค่าเป้าหมายได้ โดยตัวควบคุมแบบโมเดลพรีดิกทีฟให้สมรรถนะที่ดีกว่าการควบคุมแบบพีไอดีทั้งกรณีที่แบบจำลองมีความถูกต้องและแบบจำลองมีความคลาดเคลื่อนไปจากกระบวนการจริง

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Laboratory Investigation And Numerical Modelling Of Track Foundation For High-Speed Railway Construction On Bangkok Soft Soil, Phitsanu Pholkainuwatra Jan 2014

Laboratory Investigation And Numerical Modelling Of Track Foundation For High-Speed Railway Construction On Bangkok Soft Soil, Phitsanu Pholkainuwatra

Chulalongkorn University Theses and Dissertations (Chula ETD)

The government of Thailand has recently decided to launch a high-speed railway project to promote regional economy and improve the logistics of trade to connect with other countries in Southeast Asia community. Raising a complication regarding the load transfers will certainly induce many problems to the railway system. Moreover, the constructions of railway substructures in the past often involve the low quality of materials especially in the Central Plain of Thailand. Therefore, it is necessary to determine the sources of construction materials for railway substructure materials. This study consists of two main objectives. The first objective is to investigate the …

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Effect Of Citric Acid On Hydrodesulfurization Activity Of Dibenzothiophene And 4,6 Dimethyldibenzothiophene Over Como Catalyst On Al2o3-Zro2 Support, Pawinee Sintarako Jan 2014

Effect Of Citric Acid On Hydrodesulfurization Activity Of Dibenzothiophene And 4,6 Dimethyldibenzothiophene Over Como Catalyst On Al2o3-Zro2 Support, Pawinee Sintarako

Chulalongkorn University Theses and Dissertations (Chula ETD)

The effect of citric acid on the HDS activity of DBT and 4,6 DMDBT on CoMo/γ-Al2O3-ZrO2 catalysts has been investigated. It has been found that the CoMo/γ-Al2O3-ZrO2 physically mixed with 10wt.% of ZrO2 shows the highest HDS conversion of DBT in the presence of pyridine. The addition of ZrO2 as a secondary support obviously suppresses the influence of pyridine on HDS activity of DBT over CoMo/γ-Al2O3 based catalyst. The synergistic benefits of ZrO2 and citric acid on HDS activity of DBT and 4,6 DMDBT over CoMo/γ-Al2O3 catalyst are not found. The modification of CoMo/γ-Al2O3 catalyst by citric acid can inhibit …

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Understand Management Of Public-Private Partnership In A Secondary Private Hospital Providing Services To Citizens Registered Under Different Insurance Schemes, Rani Sachadev Jan 2014

Understand Management Of Public-Private Partnership In A Secondary Private Hospital Providing Services To Citizens Registered Under Different Insurance Schemes, Rani Sachadev

Chulalongkorn University Theses and Dissertations (Chula ETD)

In light of the recent public-private partnership law reenacment in various industries, it seems that the healthcare's public insurances would largely benefit from increase participation of the private sector but since there has not been any published framework on management of public-private partnership in public health insurance, this study has been undertaken to shine a light on financial and medical care delivery in a secondary private hospital. This study was conducted in a secondary private hospital located in Bangkok providing UC, SSS and for-profit medical care to citizens. This is a study aimed to understand the management strategies regarding finance …

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Innovative Wind Energy Micro-Generation System: A Case Study For Rooftop Turbine Ventilator, Ponnson Kaewtip Jan 2014

Innovative Wind Energy Micro-Generation System: A Case Study For Rooftop Turbine Ventilator, Ponnson Kaewtip

Chulalongkorn University Theses and Dissertations (Chula ETD)

Wind micro-generation has become an approach for new age wind energy. Whereas, the conventional and centralized wind farms only work well with wind speed beyond 8 m/s, these are only capable when locating within the remote wind zones. To develop wind-power generation that can generate electricity right at point of uses, will reduce transmission and distribution losses and minimize investment costs. This study uses innovative approach to develop Vertical Axis Wind Turbine (VAWT), through redesign and modification an internal frame of standard rooftop ventilators, transforming into Rooftop Turbine Ventilator (RTV) micro-generation system, based on VAWT. In order to cope with …

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Effects Of Acemannan Deacetylation On Biological Activity Of Gingival Fibroblast, Jaroenporn Chokboribal Jan 2014

Effects Of Acemannan Deacetylation On Biological Activity Of Gingival Fibroblast, Jaroenporn Chokboribal

Chulalongkorn University Theses and Dissertations (Chula ETD)

Acemannan extracted from Aloe vera gel is unique in the presence of acetylated mannose residues and was reported to accelerate mice buccal wound healing. In order to assert structural and biological roles of mannose acetyl groups, high-molecular-mass DeAcAM of various DDAs were prepared by alkaline hydrolysis at 80°C for 5 min using varied concentrations of NaOH. All of the DeAcAMs are not cytotoxic to HGFs and their effects on cell proliferation and VEFG and type I collagen expressions were further investigated. In general, bioactivities of the DeAcAMs were lost to some extents upon the removal of the mannose acetyl groups …

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Application Of A Hough Search For Continuous Gravitational Waves On Data From The Fifth Ligo Science Run, J. Aasi, J. Abadie, B. P. Abbott, Teviet Creighton, H. Daveloza, Mario C. Diaz, Soma Mukherjee, Volker Quetschke, Malik Rakhmanov, Robert Stone, A. S. Stroeer, Lappoon R. Tang, Cristina V. Torres Jan 2014

Application Of A Hough Search For Continuous Gravitational Waves On Data From The Fifth Ligo Science Run, J. Aasi, J. Abadie, B. P. Abbott, Teviet Creighton, H. Daveloza, Mario C. Diaz, Soma Mukherjee, Volker Quetschke, Malik Rakhmanov, Robert Stone, A. S. Stroeer, Lappoon R. Tang, Cristina V. Torres

Physics & Astronomy Faculty Publications

We report on an all-sky search for periodic gravitational waves in the frequency range 50–1000 Hz with the first derivative of frequency in the range −8.9 × 10−10 Hz s−1 to zero in two years of data collected during LIGO's fifth science run. Our results employ a Hough transform technique, introducing a χ2 test and analysis of coincidences between the signal levels in years 1 and 2 of observations that offers a significant improvement in the product of strain sensitivity with compute cycles per data sample compared to previously published searches. Since our search yields no surviving candidates, we present …

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