Digital Commons Network^™

Some Advice On Bice, North Dakota’S Marketable-Product Decision, John Burritt Mcarthur

North Dakota Law Review

No abstract provided.

Electrospinning Applications Air Filtration And Superhydrophobic Materials, Negar Ghochaghi, Adetoun Taiwo

Graduate Research Posters

Electrospinning is a widely applicable technique that generates non-woven fibers in the micro and nano range. In this project two of its applications are highlighted namely filtration media and enhancement of wettability. The first project demonstrates that electrospinning can be used to produce new fiber filtration media with controlled microstructure. The bimodal and unimodal orthogonal and random filters were made and characterized against their filtration efficiency and pressure drop. Figure of Merit (FOM) was also calculated and discussed. It is shown that the FOM increases when the electrospun fibers are arranged into alternating layers of aligned course and fine fibers. …

Gunung Padang: Where Meanings And Archaeologies Coalesce, Sindhunata Hargyono

Antropologi Indonesia

This paper looks at 21st C Gunung Padang as the site where archaeologies’ imaginations coalesce. Specifically, this paper looks at the way Gunung Padang is interpreted by different political communities, such as, international pseudoarchaeologists and indigenous people. I argue that pseudoarchaeologists engage with Gunung Padang to further their classic “rouge researchers” narrative. While geographically proximate self-identified indigenous people engage with the archaeological site to manufacture cultural continuity with the non-culture, yet, exceptional ancestors. This paper also takes Gunung Padang as a tool to problematize the literature that tries to draw boundary between pseudoarchaeology and (real) archaeology. Ultimately, I argue that …

Researchnews, Volume 8, 2014., Dublin Institute Of Technology

Issues

No abstract provided.

Formalising Human Mental Workload As A Defeasible Computational Concept, Luca Longo

Other resources

Human mental workload has gained importance, in the last few decades, as a fundamental design concept in human-computer interaction. It can be intuitively defined as the amount of mental work necessary for a person to complete a task over a given period of time. For people interacting with interfaces, computers and technological devices in general, the construct plays an important role. At a low level, while processing information, often people feel annoyed and frustrated; at higher level, mental workload is critical and dangerous as it leads to confusion, it decreases the performance of information processing and it increases the chances …

Electrodeposition And Characterisation Of Copolymers Based On Pyrrole And 3,4-Ethylenedioxythiophene In Bmim Bf4 Using A Microcell Configuration, Lavinia Astratine, Edmond Magner, John Cassidy, Tony Betts

Articles

Electrochemical copolymerization of pyrrole (Py) and 3,4-ethylenedioxythiophene (EDOT) was performed in an ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate, (BMIM BF4) employing a ‘micro-cell’ in order to use the materials efficiently. Characterization of the copolymers formed on an ITO substrate was performed for different Py: EDOT ratios (1:2, 1:1, 2:1) in both aqueous and ionic liquid electrolytes. Electrochemical and spectroelectrochemical analysis revealed that the properties of the copolymer depend upon the Py/EDOT monomer ratio used. The copolymer PPy-co-PEDOT (2:1) displayed good stability, a switching time of 20 s and a colouration efficiency of 101.3 C-1cm2. The presence of Py in the copolymer stabilised …

Matrix G-Strands, Darryl Holm, Rossen Ivanov

Articles

We discuss three examples in which one may extend integrable Euler–Poincare ordinary differential equations to integrable Euler–Poincare partial differential
equations in the matrix G-Strand context. After describing matrix G-Strand examples for SO(3) and SO(4) we turn our attention to SE(3) where the matrix G-Strand equations recover the exact rod theory in the convective representation. We then find a zero curvature representation of these equations and establish the conditions under which they are completely integrable. Thus, the G-Strand equations turn out to be a rich source of integrable systems. The treatment is meant to be expository and most concepts are explained …

Progress In Zeolite Synthesis Promotes Advanced Applications, Moussa Zaarour, Biao Dong, Izabela Naydenova, Richard Retoux, Svetlana Mintova

Articles

This article outlines the importance of zeolite synthesis and their unique physicochemical characteristics promoting advanced applications. The main strategies for preparation of zeolites including organic-template assisted, organic-template free and alternative procedures are considered for synthesis of crystallites offering control and fine-tuning of their properties. Besides, rational design of zeolites with pre-determined structure, porosity, size, morphology, and composition are more viable by studying carefully the chemical and physical parameters controlling the zeolite synthesis and understanding the crystallization mechanism. Finally, a particular attention to the preparation of zeolites with nanosized dimensions and their utilization in innovative applications including photovoltaic, medicine and holographic …

A Review Of Doppler Ultrasound Quality Assurance Protocols And Test Devices, Jacinta Browne

Articles

In this paper, an overview of Doppler ultrasound quality assurance (QA) testing will be presented in three sections. The first section will review the different Doppler ultrasound parameters recommended by professional bodies for use in QA protocols. The second section will include an evaluation and critique of the main test devices used to assess Doppler performance, while the final section of this paper will discuss which of the wide range of test devices have been found to be most suitable for inclusion in Doppler QA programmes. Pulsed Wave Spectral Doppler, Colour Doppler Imaging QA test protocols have been recommended over …

Mechanism Of Multiple Grating Formation In High-Energy Recording Of Holographic Sensors, Ali K. Yetisen, Yunuen Montelongo, Nicholas M. Farandos, Izabela Naydenova, Christopher R. Lowe, Seok Hyun Yun

Articles

We report numerical analyses of Bragg diffraction by Denisyuk reflection holograms recorded by a high-energy pulsed laser. An intensity threshold must be passed to pattern a multilayer reflection and transmission hologram, which exhibits a nonlinear fringe structure. Numerical evaluations are provided for the laser light intensity, readout diffraction offset angle, transmission of the layer, and thickness of the polymer matrix during hologram recording. A non-sinusoidal surface pattern is formed at the top of the multilayer structure, and its effect on the diffraction properties of the structure becomes significant when the recording tilt angle is increased. Experimental results show that the …

21st-Century U.S. Safety Professional Educational Standards: Establishing Minimum Baccalaureate Graduate Learning Outcomes For Emerging Occupational Health And Safety Professionals, Wayne Edward Hartz

Antioch University Dissertations & Theses

How can the public be assured of competency in those professing to protect its occupational health and safety (OSH)? Currently, in the U.S. there are 193 higher education OSH programs, 186 with baccalaureate degrees with over 55 different degree titles. This research seeks to define minimum OSH baccalaureate graduate core competencies across all programs by asking: What would employers look for in a portfolio to demonstrate competence in a new OSH graduate? Professional members of the American Society of Safety Engineers (ASSE) participated as subject matter experts in an anonymous online survey to provide framing data. The ASSE Educational Standards …

Knowing The Indigenous Leadership Journey: Indigenous People Need The Academic System As Much As The Academic System Needs Native People, Dawn Elizabeth Hardison-Stevens

Antioch University Dissertations & Theses

This dissertation explores the research question, “How can we create the best learning environments for Indigenous students through good leadership at all levels?” A bridge between cultures provides learning opportunities toward academic success between Indigenous students, families, leaders, and communities. Through personal experience as a practitioner, professional, and education, my research examines and identifies results from personnel and students at five schools, tribal and public, their tribal communities, and two Indigenous people in high profile leadership positions indicating an educational philosophy recognizing Indigenous people need the academic system as much as the academic system needs Native people. Portraits and interviews …

Mental Health Care In Mcallen Texas: Utilization, Expenditure, And Continuum Of Care, Josefina Irigoyen

Antioch University Dissertations & Theses

In 2009, Gawande published an article in The New Yorker that put the unknown mid-sized South Texas city of McAllen on the map. The article stated that McAllen was one of the most expensive health care markets in the country; it caused such media-frenzy that in a few days President Barack Obama (2009) began citing McAllen in his speeches for health care reform. Gawande concluded that overspending in the area was due to overutilization of medical services. The present study examined whether mental health services are overutilized based on archival data on McAllen's mental health services collected from Medicaid, Tropical …

[Introduction To] Identity And Leadership In Virtual Communities: Establishing Credibility And Influence, Dona J. Hickey, Joe Essid

Bookshelf

The presence and ubiquity of the internet continues to transform the way in which we identify ourselves and others both online and offline. The development of virtual communities permits users to create an online identity to interact with and influence one another in ways that vary greatly from face-to-face interaction.

Identity and Leadership in Virtual Communities: Establishing Credibility and Influence explores the notion of establishing an identity online, managing it like a brand, and using it with particular members of a community. Bringing together a range of voices exemplifying how participants in online communities influence one another, this book serves …

Defeasible Reasoning And Argument-Based Systems In Medical Fields: An Informal Overview, Luca Longo, Pierpaolo Dondio

Conference papers

The first aim of this article is to provide readers informally with the basic notions of defeasible and non-monotonic reasoning, logics borrowed from artificial intelligence. It then describes argumentation theory, a paradigm for implementing defeasible reasoning in practice as well as the common multilayer schema upon which argument-based models are usually built. The second aim is to describe the selection of argumentbased applications in the medical and health-care sectors. Finally, the paper will conclude with a summary of the features, which make defeasible reasoning and argumentation theory attractive, that emerge from the applications under review. The target reader is a …

Corporate Responsibility, Marketing, And Reputation: A Stakeholder Approach For Sustainable Car Fleet Management, Roland Vogt

Plymouth Business School Theses

Corporate responsibility is increasingly involved in corporate reputation, and so, in the economic success of a company. Car fleet operating companies are exposed to criticism and, as a direct result of this many corporate protagonists responsible for the operation of car fleets are developing measures to decrease CO2 emissions and fuel consumption. A second trend is the increasing usage of image-generating marketing actions in the worldwide ‘information society’. For various reasons, these image campaigns do not always lead to the expected improvements in corporate reputation. The crucial question is, how do these marketing actions, in the name of corporate social …

Building Capacity For The Scholarship Of Teaching And Learning (Sotl) Using International Collaborative Writing Groups, Elizabeth Marquis, Mick Healey, Michelle Vine

International Journal for the Scholarship of Teaching & Learning

Objective: To understand participants’ perceptions of the impact of an innovative International Collaborative Writing Group (ICWG) initiative on their individual and collective SoTL capacity.

Methods: A mixed method research design included participant surveys (phases 1 and 3), and focus groups and interviews (phase 2). Data from all three phases of research have been triangulated in order to facilitate an in-depth understanding of participants' experiences.

Findings: Findings reveal four key themes: mentoring and leadership, the creation of community, diversity of perspectives, and experiential learning and professional skill development.

Discussion and Implications: Through the opportunities presented in relation …

Reproductive Phase Determination In Male Meagre (Argyrosomus Regius, Sciaenidae): Testis Development And Histologic Corroboration Of A Gross Anatomical Scale, Nuno Prista, Leonel Gordo, Jose L. Costa, Maria J. Costa, Cynthia M. Jones

OES Faculty Publications

Reproductive stage determination of male gonads has received sparse attention in fish biology literature with few studies detailing the building of gross anatomical-and histologic scales. The meagre (Argyrosomus regius) is one of the world's largest sciaenids and supports a significant regional fishery in European and North African waters whose reproductive patterns are yet to be fully investigated. In the present study, we derive a macroscopic grading system for meagre testis using semi-quantitative graphs that feature the testis variability along the species size range and time of the year. We then describe the histological stages and reproductive phases of …

The Impact Of Changing Surface Ocean Conditions On The Dissolution Of Aerosol Iron, Matthew P. Fishwick, Peter N. Sedwick, Maeve C. Lohan, Paul J. Worsfold, Kristen N. Buck, Thomas M. Church, Simon J. Ussher

OES Faculty Publications

The proportion of aerosol iron (Fe) that dissolves in seawater varies greatly and is dependent on aerosol composition and the physicochemical conditions of seawater, which may change depending on location or be altered by global environmental change. Aerosol and surface seawater samples were collected in the Sargasso Sea and used to investigate the impact of these changing conditions on aerosol Fe dissolution in seawater. Our data show that seawater temperature, pH, and oxygen concentration, within the range of current and projected future values, had no significant effect on the dissolution of aerosol Fe. However, the source and composition of aerosols …

Economic Synthesis Of Quinaldinium Fluorochromate(Vi), (Qnfc), And Solvent-Free Periodic Acid Oxidation Of Alcohols Catalyzed By Qnfc, Melek Özdemi̇r, Hati̇ce Beyti̇ye Özgün

Turkish Journal of Chemistry

A 1:1:1 stoichiometric reaction between CrO_3, aqueous HF, and quinaldine affords orange crystalline quinaldinium fluorochromate(VI) (QnFC) (C_{10}H_9NH[CrO_3F]) in 99.4% isolated yield. A highly efficient, simple, chemoselective, and environmentally benign procedure for QnFC (3 mol%) catalyzed oxidation of primary and secondary alcohols to aldehydes and ketones using 1.1 equiv of H_5IO_6 under solvent-free conditions is described.

On The Peculiar Reactivity Of A C,N-Annelated Isoindole Core, Iaroslav Baglai, Valerie Maraval, Zoia Vsevolodivna Voitenko, Carine Duhayon, Yulian Mihailovich Volovenko, Remi Chauvin

Turkish Journal of Chemistry

C-, N-, and/or O-methylation products were generated from 11H-isoindolo[2,1-a]quinazoline-5-one upon treatment with NaH followed by iodomethane under air, and possible recrystallization from methanol. Two products were fully characterized by NMR and X-ray diffraction analysis. In accordance with the HSAB principle, this soft methylating agent (MeI) leads mainly to the C,C-dimethylated product 11,11-dimethyl-11H-isoindolo[2,1-a]quinazoline-5-one, which was previously not observed, beside the N-methylated product, in a procedure using methyl tosylate as a hard methylating agent of the same substrate in the initial absence of a base. A mechanism is finally proposed for the formation of methyl 2-(3-methyl-4-oxo-3,4-dihydroquinazolin-2-yl)benzoate as an oxidation side product.

Nh-Acidities And Hammett Correlation Of 3-Para Substituted Phenyl-1,2,4-Oxadiazol-5(4h)-Ones And 1,2 \Lambda^43,5-Oxathiadiazole 2-Oxides In Nonaqueous Media, Nedi̇me Dürüst, Yaşar Dürüst, Emi̇ne Özge Gözlükaya

Turkish Journal of Chemistry

NH acidities of some 3-(p-substitutedphenyl)-1,2,4-oxadiazol-5(4H)-ones and 4-(p-substitutedphenyl)-1,2 \lambda^43,5-oxathiadiazole 2-oxides were determined in methanol by means of potentiometric titration with sodium methoxide. pK_a values of the title compounds calculated from the potentiometric data were interpreted on the basis of structural effects caused by para-substituted groups on the phenyl ring by plotting pK_a values versus Hammett \sigma_p^+ constants, which gave excellent linear correlations.

Experimental Investigation Of Drag Reduction Effects Of Polymer Additives On Turbulent Pipe Flow Using Ultrasound Doppler Velocimetry, Şeri̇fe Zeybek Vural, Göknur Bayram, Yusuf Uludağ

Turkish Journal of Chemistry

Drag reduction in fully developed turbulent pipe flow with 4 concentrations (200 to 500 wppm or mg/kg) of low molecular weight sodium carboxymethylcellulose (CMC) in aqueous solutions was investigated experimentally. Drag reduction was determined by pressure drop measurements. Maximum drag reduction achieved was 22% using 500 wppm CMC solution. To observe the impact of the presence of CMC on the flow, ultrasound Doppler velocimetry (UDV) was employed to monitor the instantaneous velocity distributions. Experimental measurements were used to calculate Fanning friction factor and radial distributions of the axial time-averaged velocity, velocity fluctuation (turbulent intensity), and eddy viscosity. Two impacts of …

Synthesis, Spectral, And Thermoanalytical Studies On The New Heterobimetallic [Mg(Ii)-Ti(Iv)]-\Mu-Oxoisopropoxide And Its \Beta-Diketonates, Rajesh Kumar

Turkish Journal of Chemistry

The new heterobimetallic [Mg(II)-Ti(IV)]-\mu-oxoisopropoxide was synthesized on treatment of magnesium acetate with titanium(IV) isopropoxide in refluxing decalin in 1:2 molar ratio and characterized by liberated isopropanol, elemental, spectral (IR, ^1H and ^{13}C NMR, and mass), thermal analysis, and molecular weight data. The reactions of [Mg(II)-Ti(IV)]-\mu-oxoisopropoxide compound with \beta-diketones in different molar ratios (1:1--1:4) yielded mono to tetra derivatives [{MgO_2Ti_2(OPr^i)_{6-n}L_n}] (where n is 1--4 and L = acetylacetonate/benzoylacetonate anion)] of the \mu-oxo complex and were characterized by elemental, liberated isopropanol, and spectral analysis (IR and ^1H and ^{13}C NMR). These studies revealed interesting facets in support of plausible structures of the …

Platinum Or Nickel Nanoparticles Decorated On Silica Spheres By Microwave Irradiation Technique, Ayşe Bayrakçeken

Turkish Journal of Chemistry

Supported catalysts are of great interest because of their wide range of application possibilities. In this study, firstly silica spheres were synthesized and then platinum and nickel nanoparticles were incorporated on this silica by microwave irradiation, which is an efficient technique for catalyst preparation. Synthesized silica spheres and catalysts were characterized by BET, X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, and transmission electron microscopy techniques. Pt or Ni nanoparticles well dispersed over silica support were obtained using microwave irradiation.

Spectrophotometric Determination Of Molybdenum Using Surfactant-Mediated Liquid--Liquid Extraction, Rameshwar Dass, Jitander Kumar Kapoor, Sunita Gambhir

Turkish Journal of Chemistry

A new spectrophotometric method has been developed for determination of molybdenum using surfactant-mediated liquid--liquid extraction. Molybdenum(V) obtained by ascorbic acid reduction in 2.5 M H_2SO_4 reacted spontaneously with thiocyanate and cetyl trimethyl ammonium bromide (CTAB), forming an intense orange yellow complex that was extracted quantitatively into 1,2-dichloroethane and absorbed at 460 nm. The absorbance of the extract was found to be stable for more than 24 h. Beer's law was obeyed over the concentration range 0.1--4.2 \mu g Mo mL^{-1} of the extract. The linear range for an accurate determination was found to be 1.2--2.6 \mu g Mo mL^{-1}. The …

Aryl Butenoic Acid Derivatives As A New Class Of Histone Deacetylase Inhibitors: Synthesis, In Vitro Evaluation, And Molecular Docking Studies, Peruze Ayhan Eşi̇yok, Özlem Seven, Gülüzar Eymur, Gamze Bora Tatar, Di̇dem Dayangaç Erden, Kemal Yelekçi̇, Hayat Yurter, Ayhan Sitki Demi̇r

Turkish Journal of Chemistry

New aryl butenoic acid derivatives have been synthesized by combining hydroxy- or methoxy-substituted phenyl rings as the capping group, with a double bond in the short linker as well as metal binding groups, enoic ester, and salts bearing either methyl or morpholine. These compounds have been shown to possess promising histone deacetylase inhibition activities via in vitro fluorometric assay and molecular docking studies.

Pw_{12}-Aptes@Mcf: Effective Nanosized Mesoporous Composites For The Oxidation Of Benzyl Alcohols, Razieh Fazaeli, Hamid Aliyan, Somaieh Parishani Foroushani, Zahra Mohagheghian

Turkish Journal of Chemistry

The surface of mesocellular silica foam (MCF) was modified by grafting 3-aminopropyl-triethoxysilane (APTES) to have a positive charge, and thus to provide sites for the immobilization of H_3PW_{12}O_{40} (PW_{12}). This modified nanosized mesoporous silica (PW_{12}-APTES@MCF) was characterized by FTIR, XRD, BET, and TEM. XRD and adsorption--desorption analysis shows that the mesostructure of silica remains intact after various modifications, while the spectral technique shows the successful grafting of the neat PW_{12} inside the porous silica support. The oxidation of alcohols occurs effectively and selectively with H_2O_2 as the oxidant. PW_{12}-APTES@MCF was used as the catalyst. The catalyst can be reused several …

Preparation And Characterization Of Nonmetal Promoter Modified Cuznal Catalysts For Higher Alcohol From Synthesis Gas Through Complete Liquid Phase Method, Shirui Yu, Xiaodong Wang, Wei Huang

Turkish Journal of Chemistry

A complete liquid phase technology and a function regulator were applied to prepare CuZnAl catalysts for higher alcohol synthesis. Characterizations showed that the introduction of the function regulator can change the reduction ability of copper oxides and the surface basicity of catalysts. Activity tests indicated that the selectivity of higher alcohol is high when considerable medium-strong basicity and the synergistic effects of copper ion and metal copper exist on the catalytic surface. The optimized modified CuZnAl catalyst without any metal additives provides a CO conversion of 28.9%, C_{2+}OH selectivity of up to 42.8%, and hydrocarbon selectivity of 2.5%, with a …

Spectroscopic Investigation And Oxidation Of The Anticholinergic Drug Atropine Sulfate Monohydrate By Hexacyanoferrate(Iii) In Aqueous Alkaline Media: A Mechanistic Approach, Manjunath Meti, Sharanappa Nandibewoor, Shivamurti Chimatadar

Turkish Journal of Chemistry

The oxidation of the anticholinergic drug atropine sulfate monohydrate by hexacyanoferrate(III) in aqueous alkaline media was investigated spectrophotometrically by monitoring the decrease in absorbance of hexacyanoferrate(III) (HCF(III)). Oxidation products were identified. The oxidation mechanism was proposed from kinetic studies. The reaction constants involved in the different steps of the mechanism were calculated. The effects of added products, ionic strength, and dielectric constant of the reaction were investigated. The polymerization test revealed that oxidation occurred with intervention of free radicals. The activation parameters were evaluated.