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Aqueous Geochemistry Of Rhenium And Chromium In Saltstone: Implications For Understanding Technetium Mobility In Saltstone, Amanda Hatfield

All Theses

Incorporation of low level radioactive waste in cementitious materials is an important waste disposal technology in practice at a U.S. DOE facility, the Savannah River Site (SRS), Aiken, SC. One of the major risk drivers, technetium (99Tc)

Stimulated Raman Scattering In Micro Sphere Resonators, Ruoyu Zhang

All Theses

Micro sphere resonators that hold optical whisper gallery modes (WGMs) provide an innovative option for implementing micro optical resonators. The unique properties of the micro sphere resonator make it capable to introduce resonance for various optical phenomenon, like stimulated Raman scattering (SRS), in micron scale.

This thesis illustrates the characteristics of micro sphere resonators and demonstrates the resonance-enhanced SRS in micro sphere resonators with reduce threshold power. Both theoretical and experimental results are presented. Coupling model for WGM is derived in transfer matrix method. Simulation analyses for mode pattern of WGMs are solved based on mathematic model and finite element …

The Fabrication And Study Of Silver Nanoparticle Structures, Aubrie Pfirman

All Theses

Nanotechnology and the synthesis of nanoparticle systems are attractive in part because of interesting, tunable optical and electrical properties that are not observed with bulk material. Silver nanoparticles (Ag NPs) interact with visible light more efficiently than any other system due to the excitation of plasmon resonances, which are the collective oscillations of the free electron density. These collective oscillations produce an enhanced local electromagnetic (EM) field: this field is responsible for highly-utilized phenomena such as surface enhanced Raman scattering (SERS), enhanced fluorescence, surface enhanced infrared absorption (SEIRA), and many others. Many experiments have been conducted to optimize and tailor …

Evaporation And Modeling Water Availability In The Savannah River Basin, Ryne Phillips

All Theses

Four methods for estimating lake evaporation are presented and compared. Three are mass transfer methods that incorporated high resolution satellite imagery obtained from the MODIS sensor on the Terra and Aqua satellites. The fourth is the traditional pan method, which used monthly derived pan coefficients and pan evaporation measurements from a Class A evaporation pan located in Clemson, SC.

The four evaporation methods were used to estimate lake evaporation from the five major lakes in the Savannah River Basin for a period of more than one decade. Analysis of the evaporation rates clearly illustrated the uncertainty in daily, monthly, and …

A Hybrid Agent-Based And Differential Equations Model For Simulating Antibiotic Resistance In A Hospital Ward, Lester Caudill, Barry Lawson

Department of Math & Statistics Faculty Publications

Serious infections due to antibiotic-resistant bacteria are pervasive, and of particular concern within hospital units due to frequent interaction among health-care workers and patients. Such nosocomial infections are difficult to eliminate because of inconsistent disinfection procedures and frequent interactions among infected persons, and because ill-chosen antibiotic treatment strategies can lead to a growth of resistant bacterial strains. Clinical studies to address these concerns have several issues, but chief among them are the effects on the patients involved. Realistic simulation models offer an attractive alternative. This paper presents a hybrid simulation model of antibiotic resistant infections in a hospital ward, combining …

Road Systems And Betweenness, Paul Bankston

Mathematics, Statistics and Computer Science Faculty Research and Publications

A road system is a collection of subsets of a set—the roads—such that every singleton subset is a road in the system and every doubleton subset is contained in a road. The induced ternary (betweenness) relation is defined by saying that a point c lies between points a and b if c is an element of every road that contains both a and b . Traditionally, betweenness relations have arisen from a plethora of other structures on a given set, reflecting intuitions that range from the order-theoretic to the geometric and topological. In this paper we initiate a study …

Quantitative Trait Loci Associated With Waterlogging Tolerance In A Soft Red Winter Wheat Mapping Population, Diana Carolina Ballesteros Benavides

Graduate Theses and Dissertations

Waterlogging is caused when water stays superficially in the soil for an extended period of time, creating an anaerobic environment which decreases plant growth and grain yield at maturity. Despite the impact of waterlogging on wheat production both globally and in the southeastern U.S., very little is known about the genetic control of waterlogging tolerance in wheat. The objective of this study was to determine the amount of genetic variation for vegetative stage waterlogging tolerance present within a wheat recombinant inbred line (RIL) population and to identify quantitative trait loci (QTL) associated with tolerance and productivity. Experiments were carried out …

Voluntary Exercise Can Strengthen The Circadian System In Aged Mice, T. L. Leise, Mary E. Harrington, P. C. Molyneux, I. Song, H. Queenan, E. Zimmerman, G. S. Lall, S. M. Biello

Psychology: Faculty Publications

Consistent daily rhythms are important to healthy aging according to studies linking disrupted circadian rhythms with negative health impacts. We studied the effects of age and exercise on baseline circadian rhythms and on the circadian system's ability to respond to the perturbation induced by an 8 h advance of the light:dark (LD) cycle as a test of the system's robustness. Mice (male, mPer2luc/C57BL/6) were studied at one of two ages: 3.5 months (n=39) and >18 months (n=72). We examined activity records of thesemice under entrained and shifted conditions as well as mPER2::LUC measures ex vivo to assess circadian function in …

Light Sea Fermions In Electron-Proton And Muon-Proton Interactions, Ulrich D. Jentschura

Physics Faculty Research & Creative Works

The proton radius conundrum [Pohl, Nature 466, 213 (2010)NATUAS0028-083610. 1038/nature09250 and Antognini, Science 339, 417 (2013)SCIEAS0036-807510.1126/ science.1230016] highlights the need to revisit any conceivable sources of electron-muon nonuniversality in lepton-proton interactions within the standard model. Superficially, a number of perturbative processes could appear to lead to such a nonuniversality. One of these is a coupling of the scattered electron into an electronic vacuum-polarization loop as opposed to a muonic one in the photon exchange of two valence quarks, which is present only for electron projectiles as opposed to muon projectiles. However, we show that this effect actually is part of …

A Qualitative Analysis Of The Example Of George Orwell: From His Lived Experience To Ours, Christian Webster Gallagher

All-Inclusive List of Electronic Theses and Dissertations

No abstract provided.

Waveguiding Of Surface Phonon Polariton, Franklin Manene, Brian A. Lail, Edward C. Kinzel

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Metal losses lead to unacceptably low propagation lengths in THz and LWIR waveguides. While SPP based waveguides provide relatively good confinement and attenuation in the near-IR and visible these are insufficiently bound to the surface in the THz and LWIR. We study using surface phonon polaritons for waveguiding at these frequencies. An eigenmode approach was applied to model a hybrid waveguide structure at λ=10.6 μm. The results show that phonon-coupled hybrid waveguide of silicon carbide BCB and gold exhibit enhanced propagation length and confinement at LWIR. © 2013 IEEE.

Using Resonance Raman Cross-Section Data To Estimate The Spin State Populations Of Cytochromes P450, Piotr J. Mak, Qianhong Zhu, James R. Kincaid

Chemistry Faculty Research and Publications

The cytochromes P450 (CYPs) are heme proteins responsible for the oxidation of xenobiotics and pharmaceuticals and the biosynthesis of essential steroid products. In all cases, substrate binding initiates the enzymatic cycle, converting ferric low-spin to high-spin state, with the efficiency of the conversion varying widely for different substrates, so documentation of this conversion for a given substrate is an important objective. Resonance Raman (rR) spectroscopy can effectively yield distinctive frequencies for the ν₃ ‘spin state marker’ bands. Here, employing a reference cytochrome P450 (CYP101), the intensities of the ν₃ modes (I_LS) and (I_{HS …}

Second Nature: An Exploration In Planning And Design For A Place- And Community-Based Museum Process, Erin E. Hicks

Museum Studies Projects

Museums are and have been engaged in a paradigm shift. Much has been written about the social roles of museums and many in the field have sought to define museums, taking a position on why the museum exists, who it is for, and why it continues. Is the museum a temple or a forum? I wondered why it could not be both— and more—more inclusionary, more participatory, and more reflective of community. Could this be the museum of the future? This project explores how a museum transforms both physically and theoretically by applying an educational mission onto a hypothetical museum: …

Razing Awareness: The Bethlehem Steel Administration Building, Steve Bukowski

Museum Studies Projects

Razing Awareness: The Bethlehem Steel Administration Building is a practice in the process of coordinating and opening a professional-grade museum exhibit. Hosted by the Steel Plant Museum of Western New York, "Razing Awareness" explored the history and controversial demolition of the Bethlehem Steel Administration Building in Lackawanna, New York. The exhibit featured artwork, photography, and artifacts from the building itself, weaving art and history together to construct a narrative about historic preservation and the establishment of a sense of place.

Lawyering Outside The Box: Confronting The Creativity Crisis, Samantha A. Moppett

Southern Illinois University Law Journal

The Great Recession was not only a defining moment in world history and for the United States economy; it was also a turning point for the legal profession.  The economic downturn resulted in a long-term structural adjustment in the legal services market that will adversely impact the legal profession permanently.  Accordingly, lawyers need to be creative in adapting to the changing realities of law practice.

Yet, despite the need for creative approaches to address the changing legal landscape, a disturbing phenomenon was recently identified: creativity in the United States is declining.  Moreover, legal education and the legal practice impose barriers …

Portable Nano-Hydro Power Generator For The Dc House Project, Andrew Aw, James Biggs

Electrical Engineering

This senior project report explains the construction and design of a small, portable water generator that converts kinetic energy flowing in small creeks to electrical energy as a renewable source of energy for the DC House. The DC House, in short, is a project to build a self-sustainable house for Third World countries that utilizes only DC electricity. The system consists of two converters and a charge controller for a 12V lead-acid battery. The first converter converts the hydro generator voltage output to 15 Volts for safe and proper charging of the lead-acid battery by the charge controller. The second …

Analysis Of Energy Flow In Us Globec Ecosystems Using End-To-End Models, J. J. Ruzicka, J. H. Steele, S. K. Gaichas, T. Ballerini, D. J. Gifford, R. D. Brodeur, E. E. Hofmann

CCPO Publications

End-to-end models were constructed to examine and compare the trophic structure and energy flow in coastal shelf ecosystems of four US Global Ocean Ecosystem Dynamics (GLOBEC) study regions: the Northern California Current, the Central Gulf of Alaska, Georges Bank, and the Southwestern Antarctic Peninsula. High-quality data collected on system components and processes over the life of the program were used as input to the models. Although the US GLOBEC program was species-centric, focused on the study of a selected set of target species of ecological or economic importance, we took a broader community-level approach to describe end-to-end energy flow, from …

Looking Forward Transdisciplinary Modeling, Environmental Forecasting, And Management, D. B. Haidvogel, E. Turner, E. N. Curchitser, E. E. Hofmann

CCPO Publications

No abstract provided.

Scrap Dissolution In Molten Iron Containing Carbon For The Case Of Coupled Heat And Mass Transfer Control, Ajay Kumar Shukla, Brahma Deo, D. G.C. Robertson

Materials Science and Engineering Faculty Research & Creative Works

The scrap dissolution in an actual process like the BOF is affected both by mass transfer and heat transfer. In this paper, the mass transfer of carbon in liquid melt is considered along with heat transfer. The approaches used in this paper to model the scrap dissolution phenomenon include the application of Green's function, quasi-static, integral profile, and the finite difference approach for different Biot numbers. Mass transfer coefficients are calculated using the Chilton-Colburn's analogy for the case of forced convection. Since the quasi-static approach requires the least computational time, it is used for a detailed parametric study, including the …

Role Of Air Gap In Scrap Dissolution Process, Ajay Kumar Shukla, Brahma Deo, D. G.C. Robertson

Materials Science and Engineering Faculty Research & Creative Works

The role of the air gap formed between scrap and a solidified metal shell at the beginning of the scrap dissolution process has been investigated. The effect of air gap has been investigated for different Biot numbers (10 to 100) and ratios of air gap to liquid melt heat transfer coefficient (0.1 to 0.9). The predictions of the mathematical model are compared with the experimental results reported elsewhere. The role of air gap is found to be significant only for low Biot numbers (< 50) and for low ratios of air gap to liquid melt heat transfer coefficient (< 0.25). © 2013 The Minerals, Metals & Materials Society and ASM International.

Environmental Literacy Of Sixth Grade Students In Arkansas: Implications For Environmental Education Reform, Lisa Suzanne Wood

Graduate Theses and Dissertations

Environmental education must be better integrated into K-12 curriculum to advance environmental literacy. Producing a citizenry that can understand and address the complex environmental issues facing the world today and in the future is essential to sustainable life on this planet.

Using the Middle School Environmental Literacy Survey, 6th grade students across Arkansas were surveyed to obtain a baseline measure of environmental literacy based on the four domains of environmental literacy included in the survey; ecological knowledge, environmental affect, cognitive skills, and behavior. Individual domain scores were combined into a composite environmental literacy score. Results were then compared to the …

Congruent And Incongruent Effects Of Ethnic Music On Ethnic Menu Item Selection, Ryan David Muniz

Graduate Theses and Dissertations

This study investigated what impact ethnic music had on ethnic menu item selection. College students were randomly divided into three groups and listened to one randomly assigned sound treatment in sensory booths. Three hundred and five participants completed the questionnaire with measures of expected price value and willingness to pay value. One of the groups listened to an Italian folk music, the second group listened to a Thai folk music, and the third group listened to a restaurant background noise in order to examine if the music will impact each participant menu items selection and perceived price values. The result …

Monodentate, Bidentate And Photocrosslinkable Thiol Ligands For Improving Aqueous Biocompatible Quantum Dots, Hiroko Takeuchi

Graduate Theses and Dissertations

Water-soluble Quantum Dots (QDs) are highly sensitive fluorescent probes that are often used to study biological species. One of the most common ways to render QDs water-soluble for such applications is to apply hydrophilic thiolated ligands to the QD surface. However, these ligands are labile and can be easily exchanged on the QD surface, which can severely limit their application. As one way to overcome this limitation while maintaining a small colloidal size of QDs, we developed a method to stabilize hydrophilic thiolated ligands on the surface of QDs through the formation of a crosslinked shell using a photocrosslinking approach. …

Contributing Factors That Affect The Achievement Of African-American Females Taught By Caucasian Teachers On The Arkansas Literacy Exam: A Case Study, Felicia Renee Smith

Graduate Theses and Dissertations

This qualitative intrinsic case study was designed to assist Caucasian educators with the researched academic skills and behaviors to engage African-American females in the learning environment. The study provided strategies and recommendations to promote self-worth, self-motivation, self-efficacy, and morale in African-American females when they did not perform as well as or higher than their Caucasian peers in a high school English classroom on the state literacy examination instructed by a Caucasian teacher. The research site was a low socioeconomic urban high school with a majority of minorities with several native based home languages. The study took an in-depth approach to …

Dropping Out In Southeast Kansas: Why Students Leave School Early, Garon Kent Wire

Graduate Theses and Dissertations

This qualitative study takes a deeper look into the lived experiences of students in southeast Kansas who have dropped out of high school. As a result, school and community leaders are better informed to create effective strategy, policy, and practice in dropout prevention.

Framed as a phenomenology, data was collected by conducting in-depth, face-to-face interviews with 12 participants and a focus-group interview with four participants. The researcher administered a survey/questionnaire to an additional 15 participants. Utilizing the Streamlined Codes-To-Theory Model (Saldana, 2009); organizational, structural, and elaborative coding techniques were implemented to reduce the data into categories, which led to the …

Sedimentary Provenance Of The Wedington Member, Fayetteville Shale, From Age Relations Of Detrital Zircons, William Tyson Cains

Graduate Theses and Dissertations

U-Pb geochronology of detrital zircons collected from the Chesterian Wedington Sandstone allows interpretation of sediment provenance and dispersal patterns in the southern midcontinent during the Late Mississippian. Detrital zircons analyzed from six samples of Wedington Sandstone yielded a final result of 565 concordant analyses used for interpretation. Results are plotted as Probability-Density Plots to interpret the spectrum of ages. Significant peaks occurred at 350-500 Ma, 950-1250 Ma, 1300-1500 Ma, 1600-1800 Ma, 1800-2300 Ma, and >2500 Ma. These peaks are interpreted as sourced by crystalline rocks within the Laurentian craton from Taconic-Acadian, Grenville, Midcontinent Granite-Rhyolite, Yavapai-Mazatzal, Paleoproterozoic, and Superior Provinces. The …

Towards The Total Synthesis Of Antascomicin B. Efforts To Construct The C1-C21 Fragment, Juliette Rivero-Castro

Graduate Theses and Dissertations

Antascomicin B is a macrolide isolated from a strain of Micromonospora. It possesses structural similarities to FK506 and rapamycin and exhibits potent binding ability to FKBP12. Recent reports suggest that small molecule ligands of FKBP12 possess potent neuroprotective and neurodegenerative properties in mouse models of Parkinson's disease. Our approach to the C1-21 fragment of antascomicin B involves an asymmetric amino-Claisen rearrangement originally developed by Tsunoda et al.35 report the scalability of the preparation and rearrangement of an allylic amide possessing a silyloxy group at the terminal position of the alkene. The Tsunoda-Claisen rearrangement uses inexpensive (S)-α-methylbenzylamine as the chiral …

Bacterially-Mediated Formation Of Rock Coatings In Kärkevagge, Swedish Lapland: A Mineralogical And Micro-Environmental Analog For Mars, Cassandra L. Marnocha

Graduate Theses and Dissertations

The search for past or present life on Mars is, for now, limited to surface environments. An often neglected surface environment that could have served as an abode for life and could presently preserve evidence of that life is that of rock coatings. Rock coatings are mineral accretions on rock surfaces. On Earth, they are widespread and occur with considerable chemical diversity. There is growing evidence for a biotic role in their formation on Earth, particularly with respect to rock varnish. As a result, rock varnish has become a target of astrobiological interest on Mars, where varnish-like coatings have been …

An Experimental And Computational Evaluation Of The Importance Of Molecular Diffusion In Gas Gravity Currents, Jeremy Jac Herman

Graduate Theses and Dissertations

The accidental release of hazardous, denser-than-air gases during their transport or manufacture is a vital area of study for process safety researchers. This project examines the importance of molecular diffusion on the developing concentration field of a gas gravity current released into a calm environment. Questions which arose from the unexpectedly severe explosion in 2005 at Buncefield, England were of particular interest. The accidental overfilling of a large tank with gasoline on a completely calm morning led to a massive open air explosion. Forensic evidence showed that at the time of ignition, a vapor cloud, most of which now appears …

Attitudes And Behaviors In Online Communities: Empirical Studies Of The Effects Of Social, Community, And Individual Characteristics, Richard Kumi

Graduate Theses and Dissertations

Online communities and communities of practice bring people together to promote and support shared goals and exchange information. Personal interactions are important to many of these communities and one of the important outcomes of personal interactions in online communities and communities of practice is user-generated content. The three essays in the current study examines behavior motivation in online communities and communities of practice to understand how Social and personal psychological factors, and user-generated influence attitudes, intentions and behaviors in online communities.

The first essay addresses two research questions. First, how does Social capital influence exchange and combination behaviors in online …