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A Dual-Factor Model Of Mental Health In High School Students: Group Characteristics And Social Functioning, Amanda Lynn Thalji

USF Tampa Graduate Theses and Dissertations

A dual-factor model of psychological functioning examines the presence of wellness (i.e., subjective well-being; SWB) and psychopathology (i.e., internalizing and externalizing behavior problems) in explaining youth mental health functioning. Using a dual-factor model, previous research has yielded four unique groups of elementary and middle school youth as well as college-age adults with distinct levels of wellness and psychopathology. The present empirical investigation included valid data from 500 adolescents from two high schools (grades 9 to 11). This exploratory study produced four groups of students with unique mental health profiles aligned with previous studies investigating the dual-factor model. Tukey-Kramer comparisons determined …

Analysis And Remediation Of Chlorinated Hydrocarbons In Environmental Media, Jonathan Ticknor

USF Tampa Graduate Theses and Dissertations

The two objectives of this work were to develop a simplified method for the analysis of chlorinated organics in water samples and to improve an existing soil remediation technology. The contaminants considered for these studies were chlorinated hydrocarbons because of their relative frequency of appearance at contaminated sites. The first half of this study involved the analysis of chlorinated ethenes by gas chromatography with flame ionization detection (GC-FID). I tested the hypothesis that the FID response factor is the same for all chlorinated ethene compounds. The rationale for this investigation is that if the hypothesis is correct, a single calibration …

Sea Surface Height: A Versatile Climate Variable For Investigations Of Decadal Change, Philip Robert Thompson

USF Tampa Graduate Theses and Dissertations

Decadal variations in climate are important, because the magnitude of sustained decadal change is often much larger than the often discussed background trends. Climate variability at interannual and longer periods is most often discussed in the context of climate modes defined by sea level pressure (SLP) and sea surface temperature (SST) patterns. However, SLP and SST are not capable descriptors of ocean dynamics. The approximately two decades of global sea surface height (SSH) measurements from satellite altimetry reveal substantial low-frequency redistributions of heat and salt in the ocean, which may or may not be related to defined climate modes. In …

Statistical Estimation Of Physiologically-Based Pharmacokinetic Models: Identifiability, Variation, And Uncertainty With An Illustration Of Chronic Exposure To Dioxin And Dioxin-Like-Compounds., Zachary John Thompson

USF Tampa Graduate Theses and Dissertations

Assessment of human exposure to environmental chemicals is inherently subject to uncertainty and variability. There are data gaps concerning the inventory, source, duration, and intensity of exposure

as well as knowledge gaps regarding pharmacokinetics in general. These gaps result in uncertainties in exposure assessment.

The uncertainties compound further with variabilities due to population variations regarding stage of life, life style, and susceptibility,

etc. Use of physiologically-based pharmacokinetic (PBPK) models promises to reduce the uncertainties and enhance extrapolation between species, between routes, from high to low dose, and from acute to chronic exposure. However, fitting PBPK models is challenging because of …

Synthesis And Physical Properties Of Group 14 Intermetallic Clathrates, Stevce Stefanoski

USF Tampa Graduate Theses and Dissertations

The search of materials relevant for thermoelectric and magnetocaloric applications, as well as materials that interact with light, is an important aspect of the materials science. Such materials can be used for solid-state power generation and refrigeration, as light sources, detectors, or controllers. Intermetallic clathrates have long been of interest for the materials science research. The promise these materials hold for useful applications ranges from thermoelectrics to photovoltaics and optoelectronics to potentially ultra-hard materials and magnetic cooling applications. Their unique physical properties are intimately related to their intriguing structural properties. Thus a fundamental understanding of the chemistry and physics of …

The Mediating Role Of Regulatory Focus In The Relationship Between Transformational/Transactional Leadership And Follower Work Outcomes, Erin J. Walker

USF Tampa Graduate Theses and Dissertations

The purpose of this research was to integrate the areas of leadership and motivation by examining how leaders' behaviors affect their followers' regulatory foci. Specifically, a separate laboratory experiment and field survey were conducted to determine whether leader transformational and transactional behaviors shape followers' work-based promotion and prevention regulatory foci, which in turn affect followers' outcomes at work. Overall, there was limited evidence that inspirational motivation and contingent reward leader behaviors were related to follower work-based regulatory focus, and work-based regulatory focus was related to several work-related outcomes. The moderating role of chronic regulatory focus on the relationship between leader …

Catalytic Tri-Reforming Of Biomass-Derived Syngas To Produce Desired H2:Co Ratios For Fuel Applications, Devin Mason Walker

USF Tampa Graduate Theses and Dissertations

This study focuses on upgrading biomass derived syngas for the synthesis of liquid fuels using Fischer-Tropsch synthesis (FTS). The process includes novel gasification of biomass via a tri-reforming process which involves a synergetic combination of CO2 reforming, steam reforming, and partial oxidation of methane. Typical biomass-derived syngas H2:CO is 1:1 and contains tars that deactivate FT catalyst. This innovation allows for cost-effective one-step production of syngas in the required H2:CO of 2:1 with reduction of tars for use in the FTS. To maximize the performance of the tri-reforming catalyst, an attempt to control oxygen mobility, thermal stability, dispersion of metal, …

Mapping And Assessing Urban Impervious Areas Using Multiple Endmember Spectral Mixture Analysis: A Case Study In The City Of Tampa, Florida, Fenqing Weng

USF Tampa Graduate Theses and Dissertations

The advance in remote sensing technology helps people more easily assess urban growth. In this study, the utility of multiple endmember spectral mixture analysis (MESMA) is examined in a sub-pixel analysis of Landsat Thematic Mapper (TM) imagery to map urban physical components in Tampa, FL. The three physical components of urban land cover (LC): impervious surface, vegetation and soil, were compared using the proposed MESMA with a traditional spectral mixture analysis (SMA). MESMA decomposes each pixel to address the heterogeneity of urban LC characteristic by allowing the number and types of endmembers to vary on a per pixel basis. This …

Selling The Third Wave: The Commodification And Consumption Of The Flat Track Roller Girl, Mary Catherine Whitlock

USF Tampa Graduate Theses and Dissertations

In an ethnographic examination of the "modern" roller derby movement that began in the early 2000s, I explore Women's Flat Track Derby in Florida. What does it mean to be a roller derby player? How is she conceptualized and commodified? Or more centrally, how is third wave feminism used as a catalyst of this commodification? In order to fully appreciate, understand, and even embrace roller derby, I look at roller derby leagues as social movement organizations (SMOs) in order to note how they frame themselves and maintain collective identity the commodification of third wave feminism. First, I will explore various …

Stochastic Modeling Of Network-Centric Epidemiological Processes, Divine Wanduku

USF Tampa Graduate Theses and Dissertations

The technological changes and educational expansion have created the heterogeneity in the human species. Clearly, this heterogeneity generates a structure in the population

dynamics, namely: citizen, permanent resident, visitor, and etc. Furthermore, as the heterogeneity in the population increases, the human mobility between meta-populations patches

also increases. Depending on spatial scales, a meta-population patch can be decomposed into sub-patches, for examples: homes, neighborhoods, towns, etc. The dynamics of human

mobility in a heterogeneous and scaled structured population is still its infancy level. We develop and investigate (1) an algorithmic two scale human mobility dynamic model for a meta-population. Moreover,the two …

Molecular Dynamics Of The Rna Binding Cavity Of Influenza A Non-Structural Protein 1 (Ns1) Rna Binding Domain, Christi Leigh Whittington

USF Tampa Graduate Theses and Dissertations

Molecular dynamics simulations were performed on the influenza A non-structural protein 1 (NS1) RNA binding domain (RBD), a homodimer. Fourteen simulations were performed at 298K, nine ionized with 0.1M KCl and five with no ions. Several analysis techniques were employed to study RBD residue flexibility. The focus of the study was the RNA binding cavity formed by side chains of helix 2 (chain A) and helix 2’ (chain B) and cavity intermonomeric salt bridges. Opening of the salt bridges D29–R46’ and D29’–R46 was observed in several of the trajectories. The RNA binding cavity has large flexibility, where the dimension and …

Smart Packaging: A Novel Technique For Localized Drug Delivery For Ovarian Cancer, Eva Christabel Williams

USF Tampa Graduate Theses and Dissertations

Localized drug delivery is emerging as an effective technique due to its ability to administer therapeutic concentrations and controlled release of drugs to cancer sites in the body. It also prevents the contact of harsh chemotherapy drugs to healthy regions in the body that otherwise would become exposed to current treatments.

This study reports on a model chemotherapy drug delivery system comprising non-ionic surfactant vesicles (niosomes) packaged within a temperature-sensitive chitosan network. This smart packaging, or package-within-a package system, provides two distinct advantages. First, the gel prevents circulation of the niosomes and maintains delivery in the vicinity of a tumor. …

Evaluation Of Repeated Biomarkers: Non-Parametric Comparison Of Areas Under The Receiver Operating Curve Between Correlated Groups Using An Optimal Weighting Scheme, Ping Xu

USF Tampa Graduate Theses and Dissertations

Receiver Operating Characteristic (ROC) curves are often used to evaluate the prognostic performance of a continuous biomarker. In a previous research, a non-parametric ROC approach was introduced to compare two biomarkers with repeated measurements. An asymptotically normal statistic, which contains the subject-specific weights, was developed to estimate the areas under the ROC curve of biomarkers. Although two weighting schemes were suggested to be optimal when the within subject correlation is 1 or 0 by the previous study, the universal optimal weight was not determined. We modify this asymptotical statistic to compare AUCs between two correlated groups and propose a solution …

Moral Friction, Moral Phenomenology, And The Improviser, Benjamin Scott Young

USF Tampa Graduate Theses and Dissertations

This dissertation offers a phenomenology of that mode of self-interpretation in which it becomes possible for an interpreter to intentionally participate in the production of moral norms to which the interpreter himself or herself feels bound. Part One draws on Richard Rorty's notion of the "ironist" in order to thematize the phenomenon I call "moral friction"; a condition in which an interpreter becomes explicitly aware of the historical and cultural contingencies of their own moral vocabularies, practices, and concerns and as a result find themselves incapable of feeling the normative weight implicit in these. Part Two draws on Heidegger's existential …

Integrable Couplings Of The Kaup-Newell Soliton Hierarchy, Mengshu Zhang

USF Tampa Graduate Theses and Dissertations

By enlarging the spatial and temporal spectral problems within a certain Lie algebra, a hierarchy of integrable couplings of the Kaup-Newell soliton equations is constructed. The recursion operator of the resulting hierarchy of integrable couplings is explicitly computed. The integrability of the new coupling hierarchy is exhibited by showing the existence of infinitely many commuting symmetries.

Effects Of Random Cross-Sectioned Distributions, Fiber Misalignment And Interphases In Three-Dimensional Composite Models On Transverse Shear Modulus, Jarrett Zitko

USF Tampa Graduate Theses and Dissertations

Finite element analysis was implemented to evaluate the transverse shear modulus of a unidirectional glass/epoxy fiber-matrix composite based on pure shear displacement boundary conditions. Unit cells consisting of three-dimensional glass cylinders surrounded in square-cuboid epoxy matrices were modeled to represent "Representative Volume Element" (RVE) configurations in periodic and random-periodic square cell arrangements of variable size. Three RVEs were constructed and analyzed: A single unit cell, a 9-cell (3 x 3) array, and a 25-cell (5 x 5) array. Additionally, the unit cell was modeled to include an interphase. Three sets of cell arrangements were constructed and evaluated: a periodic square …

Corrosion Evaluation And Durability Estimation Of Aluminized Steel Drainage Pipes, Mersedeh Akhoondan

USF Tampa Graduate Theses and Dissertations

Aluminized steel pipes are expected to have a long service life, e.g. 75 years. Spiral ribbed aluminized pipes (SRAP) have been widely specified and used by the Florida Department of Transportation (FDOT) for drainage of runoff water. Confidence in the long term durability of SRAP has been challenged by recent unexpected early corrosion failures in various Florida locations. SRAP premature corrosion incidents have occurred in two modalities. Mode A has taken place in near-neutral soil environments and has often been associated with either gross manufacturing defects (i.e. helical cuts) or corrosion concentration at or near the ribs. Mode B took …

The Mediating Effect Of Distress Caused By Constipation On Predictors Of Quality Of Life Of Hospice Patients With Cancer., Abdel Alkhalouf

USF Tampa Graduate Theses and Dissertations

Abstract

The Mediating Effect of Distress Caused by Constipation on Predictors of Quality of Life of Hospice Patients with Cancer.

Key positive outcomes for hospice patients include the prevention and alleviation of physical and psychological distress, maintenance of physical and mental functioning and all aspects of quality of life. This research used secondary analysis of previously gathered data to answer new research questions with alternative strategies to examine relationships not previously analyzed. The researchers collected data from 717 cancer patients who had been admitted to one of two private hospices. The aim of their experimental intervention was to define the …

Economic Culture And Trading Behaviors In Information Markets, Khalid Nasser Alhayyan

USF Tampa Graduate Theses and Dissertations

There are four main components for influencing traders' behaviors in an information market context: trader characteristics, organizational characteristics, market design, and external information. This dissertation focuses on investigating the impact of individual trader characteristics on trading behaviors. Two newly-developed constructs, highly relevant to information market contexts, were identified to increase our understanding about trading behaviors: trader's economic culture and trader independence. The theory of planned behavior is used as the theoretical basis to postulate hypotheses for empirical testing. Data collected from subjects through a series of web-based experiments shows that trader participation can be fostered through recruiting individuals who are …

Theory And Modeling Of Graphene And Single Molecule Devices, Lyudmyla Adamska

USF Tampa Graduate Theses and Dissertations

This dissertation research is focused on first principles studies of graphene and single organic molecules for nanoelectronics applications. These nanosized objects attracted considerable interest from the scientific community due to their promise to serve as building blocks of nanoelectronic devices with low power consumption, high stability, rich functionality, scalability, and unique potentials for device integration. Both graphene electronics and molecular electronics pursue the same goal by using two different approaches: top-down approach for graphene devices scaling to smaller and smaller dimensions, and bottom-up approach for single molecule devices. One of the goals of this PhD research is to apply first-principles …

Resisting Criminalization Through Moses House: An Engaged Ethnography, Lance Arney

USF Tampa Graduate Theses and Dissertations

Neoliberal restructuring of the state has had destructive effects on families and children living in urban poverty, compelling them to adapt to the loss of social welfare and demolition of the public sphere by submitting to new forms of surveillance and disciplining of their individual behavior. A carceral-welfare state apparatus now confines and controls the bodies of expendable laborers in urban spaces, containing their threat to the neoliberal socioeconomic order through criminalization and workfare assistance, resulting in a new symbiosis of prison and ghetto. The resulting structures of punishment, police surveillance, and criminalization primarily surround African Americans living in high …

Becoming The Corporate Native...Virtually: An Ethnography And Corporate Culture Assessment Of A Virtual Organization, Jennifer Laurel Avery

USF Tampa Graduate Theses and Dissertations

This dissertation presents an investigation of a rarely studied business entity in the cross disciplinary literature on organizational culture, a completely virtually organized firm. Subscribing to a conviction that any culture can only be understood through an approach that uncovers the lived experiences of its members, I employ the traditional anthropological method of participant observation as my foundational data gathering technique. In an effort to help engage anthropology with the cross disciplinary organizational culture literature generally, I also use two well-known methods of corporate culture assessment from the management sciences. I provide a number of recommendations to the sponsors of …

Therapeutic Peptide-Based Vaccination Strategies Against Hpv-Induced Cancers, Kelly Barrios Marrugo

USF Tampa Graduate Theses and Dissertations

There is an urgent need for the development of an effective therapeutic vaccine against cancer caused by human papilloma virus (HPV). We focused on HPV-induced malignancies because of their high worldwide prevalence (e.g., cervical carcinoma and head & neck cancer). A successful therapeutic vaccine could prevent the 250 000 deaths/year worldwide and the 2.25 billion dollars that

are expended in related care in the US.

We used an HPV-induced mouse cancer model to test vaccines

composed of a CD8 T cell peptide epitope administered with potent adjuvants designed to generate vast numbers of high avidity cytotoxic T lymphocytes specific for …

Behavioral And Immunological Phenotypes Of Transgenic Mice Overexpressing Human Secreted Amyloid Precursor Protein Alpha: Implications For Autism, Antoinette R. Bailey

USF Tampa Graduate Theses and Dissertations

Autism is a heterogeneous neurodevelopmental disorder that is characterized by impaired social interaction and communication as well as restricted and repetitive behaviors and focused interests. In addition to the cardinal behavioral characteristics observed for diagnosis, autistic individuals exhibit a number of comorbid conditions as well as a variety of aberrant immunological features. Recent studies report that plasma from autistic children contained elevated levels of secreted amyloid precursor protein alpha (sAPP-á), the á-secretase cleavage product of the amyloid precursor protein (APP) which is ubiquitously expressed in the brain, spleen, thymus and other organs. Interestingly, the sAPP-á fragment functions as a neurotrophic …

Good Men Grow Corn: Embodied Ecological Heritage And Health In A Belizean Mopan Community, Kristina Linda Baines

USF Tampa Graduate Theses and Dissertations

Recent developments in land rights and land use in the Toledo district, Belize has generated anthropological and activist interest surrounding traditional ecological knowledge and practice, and the role of heritage in communities. This study explores the connection between ecological knowledge and practices, and the concurrent construction of heritage, and community health and wellness, broadly defined. Developing and using the concept of "embodied ecological heritage," this dissertation takes a phenomenological approach to understanding the convergence of ecological heritage and health in multiple realms of everyday life, arguing that lived experience of participating in "traditional" practices is fundamentally connected to wellness in …

Paleo-Indian To Spanish Occupation Around Choctawhatchee Bay, Northwest Florida, As Documented In A Private Artifact Collection, Deena Woodward

USF Tampa Graduate Theses and Dissertations

This project documents and analyzes a substantial private collection of artifacts from archaeological sites around Choctawhatchee Bay, northwest Florida. The goals are to determine what the materials can contribute to the archaeological record, how they enhance our knowledge of the people who lived there over the past 2000 years, and how this information can be used to expand or contradict models of prehistoric lifeways in this region. This is done by comparing artifact assemblages, looking at site distribution patterns, and using pXRF trace-element analysis to compare Late Archaic clay objects with those from elsewhere along the Gulf.

Examination of the …

Drug Discovery From Floridian Mangrove Endophytes, Jeremy Beau

USF Tampa Graduate Theses and Dissertations

A significant challenge of the 21st century is the growing health threat stemming from drug-resistant infectious diseases. There is an undeniable need to discover new, safe and effective drugs with novel mechanisms of action to combat this threat. A study of drugs currently on the market showed that natural products account for approximately 75% of new anti-infective drugs, either as new agents or analogs based upon their structure. Unfortunately, major pharmaceutical companies have cut back tremendously in natural products research in part due to the frustrating obstacle of frequent rediscovery of compounds. Fungi in particular are difficult to work with …

Synthesis And Anti-Mrsa Activity Of Hydrophilic C3-Acylated N-Thiolated Β-Lactams And N-Acyl Ciprofloxacin-N-Thiolated Β-Lactam Hybrids, Biplob Bhattacharya

USF Tampa Graduate Theses and Dissertations

The Turos laboratory has been working with N-thiolated β-lactams for years trying to understand the mode of action and structural features it needs to have biological activity. Over the years new data has shown promising inhibitory activity against various microbes.

In this dissertation, a review of the vast amount of work carried out on N-thiolated β-lactams in Turos laboratory has been done and their novelty, in terms of structure and mechanism has been discussed. A complete outline of our work in the discovery and ongoing development of these compounds, starting from our initial, unexpected finding of antimicrobial activity for one …

Perceptions Of Hispanic Female Esl Students Toward First-Year College Writing Courses: A Phenomenological Examination Of Cultural Influences, Barbara B. Booker

USF Tampa Graduate Theses and Dissertations

The role of culture as a phenomenon guided this qualitative study, which examined the influence of diverse Hispanic cultures on the attitudes and perceptions towards college writing courses of female Hispanic students who are non-native speakers of English. With the increasing number of Hispanic immigrants coming to the U.S., the minority student population at our nation's colleges and universities has also risen. Community colleges have become the means through which many of these Hispanic immigrants obtain a college education.

The eight women who participated in this study self-identified as Hispanic. All were first generation college students who had been born …

Stable Carbon Isotope Discrimination By Rubisco Enzymes Relevant To The Global Carbon Cycle, Amanda J. Boller

USF Tampa Graduate Theses and Dissertations

Five different forms of ribulose 1,5-bisphosphate carboxylase/oxygenase (RubisCO; IA, IB, IC, ID, II), the carboxylase of the Calvin-Benson-Bassham cycle (CBB), are utilized by plants, algae and autotrophic bacteria for carbon fixation. Discrimination against ¹³C by RubisCO is a major factor dictating the stable carbon isotopic composition (δ¹³C = {[¹³C/¹²C sample/¹³C/¹²C standard] - 1} X 1000) of biomass. To date, isotope discrimination, expressed as ε values (={[¹²k/¹³k] - 1} X 1000; ¹²k and ¹³k …