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2012

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In Vivo Evaluation Of Microfibrous Bioactive Borate Glasses For Use In Wound Healing, Yinan Lin Jan 2012

In Vivo Evaluation Of Microfibrous Bioactive Borate Glasses For Use In Wound Healing, Yinan Lin

Masters Theses

"This project consisted of two parts focused on in vivo evaluation of microfibrous bioactive borate glasses for use in wound healing. Part one of the project involved subcutaneous implantation of two types of borate glass microfibers and 45S5 glass micro fibers in the dorsum of rats and histologically evaluating the soft tissues at the implant sites at 2 to 4 weeks post surgery. The primary objective was to assess the angiogenic response to the implanted materials. The 13-93B3 and 13-93B3Cu glass microfibers were found to significantly increase the microvascular density in soft tissue, an outcome that suggests these simple and …


Hardened Mechanical Properties And Durability Performance Of Specialized Concretes, Kyle Richard Holman Jan 2012

Hardened Mechanical Properties And Durability Performance Of Specialized Concretes, Kyle Richard Holman

Masters Theses

"Concrete is one of the most produced and utilized materials in the world. Due to the labor intensive and time consuming nature of concrete construction, new and innovative concrete mixes are being explored. Self-consolidating concrete (SCC) is one such method of improving the overall cost and time efficiency of concrete production. SCC is a highly flowable form of concrete. This characteristic drastically reduces the amount of labor and time needed to place the concrete. The highly flowable nature also allows for much easier placement in applications of highly congested reinforcement.

Another rising concern in today's construction industry is environmental responsibility. …


Finite Element Analysis Of Blade-Formation Interactions In Excavation, Osei Brown Jan 2012

Finite Element Analysis Of Blade-Formation Interactions In Excavation, Osei Brown

Masters Theses

"The efficiency and costs of mining operations greatly depend on the efficient design and use of excavators. The performance of these capital-intensive excavators requires thorough understanding of the physical and design factors that affect the formation-cutting tool interaction process. The current body of knowledge, based on experimental and analytical methods, provides limited understanding of these factors, which limits the accurate design and performance of excavators. The soil constitutive equations used in most of the available finite element (FE) models also fail to adequately capture the elastic and plastic behaviors of soil formations. This research initiative uses FE techniques to model …


Laboratory Implementations Of Pmsm Drive In Hybrid Electric Vehicles Applications, Amir E. Saad Jan 2012

Laboratory Implementations Of Pmsm Drive In Hybrid Electric Vehicles Applications, Amir E. Saad

Masters Theses

"Field Programmable Gate Arrays (FPGAs) are one of the today's most successful technologies for developing systems that require real time operation and providing additional flexibility to the designer. This research is focused on developing a control board for a permanent magnet synchronous machine (PMSM) using an FPGA module. The board is configured for individual use of an FPGA, digital signal processor (DSP) or in combination to control the PMSM by generating the required Pulse Width Modulator (PWM) to the inverter in order to drive and control the speed of the PMSM. Since, the exact rotor position and speed are required …


Forward Converter For Solar Power Applications, Nickolas Arthur Mcfowland Jan 2012

Forward Converter For Solar Power Applications, Nickolas Arthur Mcfowland

Masters Theses

"Most solar arrays used today are connected in series and have tremendous power losses in partially shaded conditions. This document explores photovoltaic arrays in a parallel connection to reduce the power losses in other solar cell connected applications. The two main issues with any photovoltaic arrays are solar modules being shaded and the efficiency of the power converters used within the solar array. This thesis concentrates on alleviating these problems with the development of a two phase dc to dc forward converter with a snubber circuit as well as connecting a solar array in parallel to increase the performance in …


Numerical Investigation Of Second-Law Characteristics Of Ramjet Throttling, Jonathan Albert Sheldon Jan 2012

Numerical Investigation Of Second-Law Characteristics Of Ramjet Throttling, Jonathan Albert Sheldon

Masters Theses

"A numerical study of a generic axisymmetric ramjet operating at conditions corresponding to flight Mach 3.0 and a standard altitude of 10 km is presented. The study includes both modeling of steady-state flowfields in the ramjet as well as transient throttling maneuvers in which the throttle is decreased or increased from maximum or minimum throttle positions. The results presented here focus on entropy generation and performance characteristics. Combustion-generated exothermic heat release is modeled using simple volumetric energy addition to the flow within a defined heat release zone. The study utilizes two levels of wall boundary modeling, corresponding respectively to inviscid …


Robust Evolutionary Algorithms, Brian Wesley Goldman Jan 2012

Robust Evolutionary Algorithms, Brian Wesley Goldman

Masters Theses

"Evolutionary Algorithms (EAs) have shown great potential to solve complex real world problems, but their dependence on problem specific configuration in order to obtain high quality performance prevents EAs from achieving widespread use. While it is widely accepted that statically configuring an EA is already a complex problem, dynamic configuration of an EA is a combinatorially harder problem. Evidence provided here supports the claim that EAs achieve the best results when using dynamic configurations. By designing methods that automatically configure parts of an EA or by changing how EAs work to avoid configurable aspects, EAs can be made more robust, …


Design And Development Of Ionic Liquid Dual-Mode Spacecraft Propellants, Steven P. Berg Jan 2012

Design And Development Of Ionic Liquid Dual-Mode Spacecraft Propellants, Steven P. Berg

Masters Theses

"Energetic ionic liquids capable of dual-mode chemical monopropellant or bipropellant and electric electrospray rocket propulsion are investigated. Following an extensive literature review, ionic liquids [Bmim][dca], [Bmim][NO₃], and [Emim][EtSO₄] are selected for study since their physical properties align well with the current state-of-the-art in chemical and electrospray propellants. Simulations show that these liquids will not be useful for monopropellant propulsion due to the prediction of solid carbon formation in the exhaust and performance 13-23% below that of hydrazine. Considering these ionic liquids as a fuel component in a binary monopropellant mixture with hydroxyl ammonium nitrate shows 1-4% improved specific impulse over …


Investigation Of Drillstring Vibration Reduction Tools, Mohammed Fayez Al Dushaishi Jan 2012

Investigation Of Drillstring Vibration Reduction Tools, Mohammed Fayez Al Dushaishi

Masters Theses

"Drilling related problems such as drillstring vibration is an important cause of premature failure of drillstring components and drilling inefficiency. The vibration of drillstring interferes with measurement collected while drilling. In severe cases, drillstring vibration will lead to wellbore instability that will result in an increase in the operation cost. In the late 1980's, a lot of studies and techniques were developed to mitigate drillstring vibration and downhole vibration measurements were introduced to the industry in two forms; real time measurements and memory devices measurements

A study of drillstring vibration of three different wells located in the Norwegian North Sea …


Numerical Investigation Of Plasma Actuator Configurations For Flow Separation Control At Multiple Angles Of Attack, Thomas Kelsey West Iv Jan 2012

Numerical Investigation Of Plasma Actuator Configurations For Flow Separation Control At Multiple Angles Of Attack, Thomas Kelsey West Iv

Masters Theses

"The primary objective of the study presented in this thesis was to analyze the effectiveness of aerodynamic plasma actuators as a means of active flow control over a low speed airfoil at multiple angles of attack each corresponding to two different flow separation mechanisms (i.e., laminar separation bubble and turbulent flow separation at stall conditions). Detailed parametric studies based on steady and unsteady Navier-Stokes simulations, modified to include the body force term created by the plasma actuator, were performed for a NACA 0012 airfoil at a chord Reynolds number of 10⁵. In particular, parametric studies were performed to investigate the …


Maximum Power Point Tracking Control Of Hydrokinetic Turbine And Low-Speed High-Thrust Permanent Magnet Generator Design, Hailong Zhou Jan 2012

Maximum Power Point Tracking Control Of Hydrokinetic Turbine And Low-Speed High-Thrust Permanent Magnet Generator Design, Hailong Zhou

Masters Theses

"River-based hydrokinetic turbine power generation systems have been studied to introduce an effective energy flow control method. Hydrokinetic turbine systems share a lot of similarities with wind turbine systems in terms of physical principles of operation, electrical hardware, and variable speed capability for optimal energy extraction. A multipole permanent magnet synchronous generator is used to generate electric power because of its ability to reach high power density and high thrust at low speed. A 3-phase diode rectifier is used to convert AC power from the generator into DC power and a boost converter is used to implement energy flow control. …


Physiochemical Characteristics Contributing To The Cytotoxicity Of Transition Metal Oxides, Chi-Heng Wu Jan 2012

Physiochemical Characteristics Contributing To The Cytotoxicity Of Transition Metal Oxides, Chi-Heng Wu

Masters Theses

"In the past ten years nanotechnology has not only evolved to play a prominent role in our economy but also increased the concern over potential adverse effects caused by nanomaterials to human health and the environment. Nanotoxicity is to understand the nature and origin of the toxicity imposed by nanomaterials. Studies from our laboratory have shown that nanoparticle induces oxidative stress, perturbs calcium homeostasis, alter gene expression, and produces pro-inflammatory responses. We also identified a trend of toxicity: TiO₂ < Cr₂O₃ < Fe₂O₃ < Mn₂O₃ < NiO < ZnO < CuO. We then asked a question: what are physiochemical factors of transition metal nanoparticles that contributed to this increasing cytotoxicity. In this thesis I investigated the correlation between physicochemical properties and toxicity of the transition metal oxides in the 4th Period of the Periodic Table of Elements. Particle size, BET surface area, point of zero charge, metal dissolution, and degree of surface adsorption of transition metal oxide nanoparticles were measured. There were no increasing trends in both particle size and specific surface area. The point of zero charge showed an increasing trend as TiO₂ < Cr₂O₃ < Fe₂O₃ < NiO < CuO = ZnO < Mn₂O₃. The number of available binding sites of nanoparticle showed an increasing trend as Cr₂O₃ > ZnO > CuO > NiO > Fe₂O₃ > Mn₂O₃ > TiO₂. The degree of adsorption on the surface of nanoparticles showed an increasing trend with atomic …


Gray Gas Analysis Of Radiative Preheating Effects On Shock Induced Combustion, Pratibha Raghunandan Jan 2012

Gray Gas Analysis Of Radiative Preheating Effects On Shock Induced Combustion, Pratibha Raghunandan

Masters Theses

"The use of detonations in combustors has been receiving increased attention in recent times. The presence of shock waves in such combustors invariably poses the existence of two domains that present different physics for the flow processes. The variation of upstream temperature due to radiative heating by the products of combustion was given particular attention in the present study. The modeling of heat transfer across a normal shock wave of negligible thickness was done by considering the reactants and the products of combustion to be in radiative equilibrium with each other. The quantification of emissivity of the products of combustion …


Multiple-Input Multiple-Output System On A Spinning Vehicle With Unknown Channel State Information, Aditya Muralidhar Jan 2012

Multiple-Input Multiple-Output System On A Spinning Vehicle With Unknown Channel State Information, Aditya Muralidhar

Masters Theses

"This thesis work presents the investigations into the performance of a multiple-input multiple-output (MIMO) system with its transmitters on a spinning vehicle and no available channel state information (CSI) at the transmitter or the receiver. The linear least squares approach is used to estimate the channel and the estimation error is measured. The spinning is simulated based on a sample radiation pattern of a patch antenna. The antenna gains at different angles are obtained from this pattern and are used to model spinning. Spinning gives rise to a periodic component in the channel which can be estimated based on the …


Control And Operation Of Multiple Distributed Generators In A Microgrid, Shyam Naren Bhaskara Jan 2012

Control And Operation Of Multiple Distributed Generators In A Microgrid, Shyam Naren Bhaskara

Masters Theses

"Small sized synchronous generator based distributed generators (DG) often have low start-up times, and can serve as dispatchable generators in a microgrid environment. The advantage is that it allows the power network to operate in a true smart grid environment. The disadvantage is that such DGs typically tend to have low inertia and the prime movers driving these resources need to be controlled in real time for them to operate effectively in islanded, grid-connected modes and during transition from grid-connected mode to islanded mode and vice versa. When multiple DGs are present in the microgrid, the overall control can become …


Bond, Transfer Length, And Development Length Of Prestressing Strand In Self-Consolidating Concrete, Krista Beth Porterfield Jan 2012

Bond, Transfer Length, And Development Length Of Prestressing Strand In Self-Consolidating Concrete, Krista Beth Porterfield

Masters Theses

"Due to its economic advantages, the use of self-consolidating concrete (SCC) has increased rapidly in recent years. However, because SCC mixes typically have decreased amounts of coarse aggregate and high amounts of admixtures, industry members have expressed concerns that the bond of prestressing strand in SCC may be compromised. While the bond performance of prestressing strand in a new material such as SCC is an important topic requiring investigation, the results are only applicable if the research is completed on strands with similar bond quality as the strands used in the field. Therefore, the objectives of this research program were …


Direct Shear Testing Of Fractured Rocks From Missouri Used To Evaluate Potential Fault Reactivation Induced By Carbon Dioxide Sequestration, Ishan Kumar Jan 2012

Direct Shear Testing Of Fractured Rocks From Missouri Used To Evaluate Potential Fault Reactivation Induced By Carbon Dioxide Sequestration, Ishan Kumar

Masters Theses

"Geological storage projects of CO₂ are designed to maintain secure storage for thousands of years. Carbon Capture and Storage has been identified as one of the methods which is used to reduce global emission of CO₂ and achieve lower concentration of CO₂ in the atmosphere by capturing the CO₂ from the flue gases and storing it in underground formations. Potential leakage of injected CO₂ from the reservoir to the surface is caused by the reactivation of pre-existing faults and fractures which is caused by the change in the state of stresses and the pore pressure. To avoid damage to the …


Sputter Deposition Of Thin-Film Capacitors Onto Low Temperature Co-Fired Ceramic Substrates, Jack Murray Jan 2012

Sputter Deposition Of Thin-Film Capacitors Onto Low Temperature Co-Fired Ceramic Substrates, Jack Murray

Masters Theses

"Single layer thin film capacitor structures were fabricated on the surface of low temperature co-fired ceramic (LTCC) substrates using sputter deposition. The capacitor structures had areas between ~10⁴ µm² to ~10⁶ µm² and featured ~200 nm Al or Pt electrodes with 150-1500 nm Al₂O₃ dielectric layers. Impedance analysis and current-voltage testing were carried out to determine the effect of electrode material and dielectric thickness upon capacitor performance. Capacitance values for devices with Al electrodes ranged from ~10 to ~700 pF, depending on capacitor area and dielectric thickness, and the fit to expected values was better than devices with Pt or …


3d Spatio-Temporal Analysis For Compressive Sensing In Magnetic Resonance Imaging Of The Murine Cardiac Cycle, Brice Aaron Hirst Jan 2012

3d Spatio-Temporal Analysis For Compressive Sensing In Magnetic Resonance Imaging Of The Murine Cardiac Cycle, Brice Aaron Hirst

Masters Theses

"This thesis consists of two major contributions, each of which has been prepared in a conference paper. These papers will be submitted for publication in the SPIE 2013 Medical Imaging Conference and the ASEE 2013 Annual Conference.

The first paper explores a three-dimensional compressive sensing (CS) technique for reducing measurement time in MR imaging of the murine (mouse) cardiac cycle. By randomly undersampling a single 2D slice of a mouse heart at regular time intervals as it expands and contracts through the stages of a heartbeat, a CS reconstruction algorithm can be made to exploit transform sparsity in time as …


Parametric Moment Closure For Non-Linear State Dependent Stochastic Systems, Ritesh Arora Jan 2012

Parametric Moment Closure For Non-Linear State Dependent Stochastic Systems, Ritesh Arora

Masters Theses

"This research highlights the use of moment closure approximation techniques to provide analytical approximations to nonlinear state dependent systems. Nonlinear systems are often difficult to solve and often approximated through the use of simulation. However, Moment Closure has the capability to derive an approximate solution by making a closed form solution out of open set of differential equations representing nonlinear system behavior in both transient and equilibrium state. It is this capability of approximating the closed form solution to complex systems that draws interest in the use of this method within systems engineering. This research further extends to the stability …


Effects Of High Volume Fly Ash And Powder Activators On Plastic And Hardened Concrete Properties, Drew Alexander Davis Jan 2012

Effects Of High Volume Fly Ash And Powder Activators On Plastic And Hardened Concrete Properties, Drew Alexander Davis

Masters Theses

This study was performed to examine the effects of high volumes of Class C fly ash modified by powder activators upon the plastic and hardened properties of concrete. In a companion study, five Missouri area cements and five Class C fly ashes were examined for incompatibilities, with the most and least reactive combinations being scaled up to full scale concrete testing. Two baseline concrete mixtures were examined, the only difference in mixtures being the sources of portland cement and fly ash. Fly ash replacement was examined at 50% and 70% replacement (by total cementitious mass). Three powder activators were used …


A Feasibility Analysis Of Retrofitting Existing Roadway Lighting Infrastructure With Led Technology, Sean Michael Schmidt Jan 2012

A Feasibility Analysis Of Retrofitting Existing Roadway Lighting Infrastructure With Led Technology, Sean Michael Schmidt

Masters Theses

LED technology has advanced towards use in high intensity lighting purposes. LED luminaires have a significantly longer expected lifetime than traditional high-intensity discharge lighting systems. Due to these recent improvements in LED technology, there is a growing need for a comprehensive method to analyze the applicability of LED luminaires for use on major routes and roadways. This research investigates the acceptability of LED luminaires for use on major roadways through a feasibility analysis using data collected at various LED street light testing sites. Nine distinct LED luminaires were analyzed in field testing. The field data was then analyzed and compared …


Identification Of Starry Milia-Like Cysts In Seborrheic Keratoses And Malignant Melanomas Using Image Processing Techniques, Viswanaath Subramanian Jan 2012

Identification Of Starry Milia-Like Cysts In Seborrheic Keratoses And Malignant Melanomas Using Image Processing Techniques, Viswanaath Subramanian

Masters Theses

"Seborrheic keratoses are the most common benign tumors found in older individuals. Seborrheic keratoses are normally benign in nature, but sometimes in a large lesion area of seborrheic keratoses, secondary tumors, or squamous cell carcinoma in situ or malignant melanoma may occur. It has been found that seborrheic keratoses have a few features that distinguish them from melanomas. Milia-like cysts, comedo-like openings and network-like structures are the most prominent features found in seborrheic keratoses. Comedo-like openings are pigmented structures and are mostly oval yellowish, brown or black in appearance. They can also be observed in melanocytic lesions and melanomas. Milia-like …


Effect Of Side Edge Distance And Concrete Materials On Corrosion In Precast Prestressed Concrete Panels, Dayi Zhang Jan 2012

Effect Of Side Edge Distance And Concrete Materials On Corrosion In Precast Prestressed Concrete Panels, Dayi Zhang

Masters Theses

"This study involved the spalling problem found in some partial-depth precast prestressed bridge decks in the state of Missouri. Recently, panels of several bridges have exhibited corrosion of the prestressing steel tendons causing concrete spalling at the edges of panels. Some of the exposed tendons are corroded to the point of rupture. The effect of factors, namely concrete side edge distance and concrete material type, on steel corrosion in chloride-contaminated reinforced concrete was investigated in this study. Wet-dry cycle tests and accelerated corrosion tests were carried out on sixty-three specimens designed with three different side edge distances and three different …


Biblical Hermeneutics, Michael L. Dusing Jan 2012

Biblical Hermeneutics, Michael L. Dusing

Syllabus Repository

No abstract provided.


Sustainability In The Plastics Industry: Concerns, Issues, And Strategies, Bonnie Bachman, Shristy Bashyal, Margaret Baumann Jan 2012

Sustainability In The Plastics Industry: Concerns, Issues, And Strategies, Bonnie Bachman, Shristy Bashyal, Margaret Baumann

Economics Faculty Research & Creative Works

An increased corporate emphasis on sustainability can be seen in such areas as: annual reports with published sustainability goals, sustainability management systems with balanced scorecards and dashboards, websites using increased screen area and space for sustainability communications, internal and external stakeholder opinion gathering, development of sustainable supply chain plans, and marketing strategies focusing on green or sustainable consumers. To address this ever increasing attention to sustainability, a research project to understand sustainability in the plastics industry was initiated with the membership of the Society of Plastics Engineers (SPE). This paper focuses on the results of the research (global survey) and …


Trans-Boundary Movement Of Hazardous Waste: Evidence From A New Micro Data In The European Union, Mahelet G. Fikru Jan 2012

Trans-Boundary Movement Of Hazardous Waste: Evidence From A New Micro Data In The European Union, Mahelet G. Fikru

Economics Faculty Research & Creative Works

The paper explores a new micro dataset on the export of hazardous waste generated in Europe. A total of 16 745 industrial facilities generated hazardous waste in 2009 out of which 1 272 exported some or all of the waste. A measure of the export intensity of facilities is introduced by using export of hazardous waste as a percentage of total hazardous waste generated. The study finds that 96% of the export stays within Europe and rarely goes to developing countries. The major driving force behind firms' decision to export hazardous waste may be the stringency of general environmental policies …


A Comparison Analysis Of Defensive Routines And Theories-In-Use Of Engineering And Non-Engineering Managers, Tyria Riley Jan 2012

A Comparison Analysis Of Defensive Routines And Theories-In-Use Of Engineering And Non-Engineering Managers, Tyria Riley

Doctoral Dissertations

"Engineering managers are managers who have an understanding of both the technical and business world in organizations. Many lead teams of their peers who are purely technical individuals. However, the success of an engineering manager depends on being able to function in both worlds when necessary. There is a stigma that engineers experience challenges in areas such as communication, conflict resolution, and leadership. Due to these challenges, defensive routines are likely to exist. Defensive routines are behaviors that are common in many managers and may hinder the success of an organization. This research uses a case study approach to measure …


X-Ray Crystallography For The Study Of Nickel And Iron Salicylaldimines, Carla Schmiesing Eribal Jan 2012

X-Ray Crystallography For The Study Of Nickel And Iron Salicylaldimines, Carla Schmiesing Eribal

Doctoral Dissertations

"X-ray diffraction of single crystals has developed dramatically over the last century by combining fundamental theories of light, diffraction, and statistics to generate the complete, geometric structure of molecules. The quality of the resulting X -ray structure data are reported in R₁ < 5%, wR2 < 12% and a goodness of fit value of one. This technique was applied specifically to the evaluation of the spin crossover (SCO) compound [Fe(salpm)₂]BF₄ʺ0.5EtOH and how the molecule's geometry changed during a two-step thermal LS-HS conversion. The crystal structure was measured at 100,175,225, and 296 K to yield final R₁ values of 0.047, 0.054, 0.051, and 0.058, respectively. The coordination bond lengths show the spin transitions occur between 100-175K at one crystallographically unique Fe and between 175-225K at the other Fe site. No strong long range interactions are found, suggesting a gradual spin transition. Reaction ofNi(Nalkyl-sal)₂ complexes with Ni(N0₃)₂ form either nickel dimeric, [Ni₃(Rsal)(N0₃)(MeOH)]₂ or trinuclear complexes, Ni₃(Rsal)₄(N0₃)₂. The binuclear complexes, with orthogonal bridging ligands, show overall ferromagnetic interactions. The crystal structures for Ni₃(Rsal)₄(N0₃)₂ from methyl to benzyl were solved and indicate no steric restriction on formation for the series. The trinuclear compounds form an isosceles triangle of metal atoms with the isopropyl analog showing an overall antiferromagnetic interaction with J=+11.386 and J23=-13.891. Lastly, xanthene spirolactam derivatives were structurally analyzed to determine binding modes for their selective and sensitive (µM) detection of metals Cr³⁺, Fe³⁺, Ni²⁺, Co²⁺ and the nerve gas mimic, dichlorophosphate"--Abstract, page iii.


Prediction And Performance Of Single Piles In Clay Soils Under Vibratory Loadings, Domenica Cambio Jan 2012

Prediction And Performance Of Single Piles In Clay Soils Under Vibratory Loadings, Domenica Cambio

Doctoral Dissertations

"This study developed a model for predicting the response, in terms of amplitude versus frequency of single piles under lateral vibratory loadings embedded in clay or fine silty soils. The model incorporates frequency dependent parameters and the effects of soil non-linearity through the relationship between soil shear modulus and damping with strain. A computer program, Dyna5, was used to generate the computed response of single piles using the Novak and El-Shamouby (1983) approach. Soil non-linearity was accounted for by incorporating spline interpolation routine into Dyna5. Sliding and coupled rocking vibrations were addressed. The computed responses were predicted and compared with …