Digital Commons Network^™

Interfacial Effects On Dielectric Properties Of Polymer-Particle Nanocomposites, Sasidhar Siddabattuni

Doctoral Dissertations

"Dielectric materials that are capable of efficiently storing large amounts of electrical energy are desirable for many electronic and power devices. Since the electrical energy density in a dielectric material is limited to εV_b²/2, where ε is the dielectric permittivity of the material and V_b is the breakdown strength, increased permittivity and breakdown strength are required for large energy storage density. Interfacial effects can influence the dielectric properties, especially dielectric breakdown resistance in polymer-particle nanocomposites. Several functional organophosphates were used to modify the surface of titania and barium titanate nanofiller particles in order to achieve covalent interface …

Robust Adaptive Filtering Algorithms For System Identification And Array Signal Processing In Non-Gaussian Environment, Tiange Shao

Doctoral Dissertations

"This dissertation proposes four new algorithms based on fractionally lower order statistics for adaptive filtering in a non-Gaussian interference environment. One is the affine projection sign algorithm (APSA) based on L₁ norm minimization, which combines the ability of decorrelating colored input and suppressing divergence when an outlier occurs. The second one is the variable-step-size normalized sign algorithm (VSS-NSA), which adjusts its step size automatically by matching the L₁ norm of the a posteriori error to that of noise. The third one adopts the same variable-step-size scheme but extends L₁ minimization to Lp minimization and the variable step-size normalized fractionally lower-order …

Applied Palynology: Multidisciplinary Case Studies From Egypt, Gulf Of Mexico And Usa, Mohamed K. Zobaa

Doctoral Dissertations

"Various applications of palynology have been used to study case studies from four different parts of the world, namely northern Egypt, offshore Gulf of Mexico, eastern Tennessee (USA), and New Orleans, Louisiana (USA). In these case studies, palynomorphs (spores, pollen, dinoflagellate cysts, and algae) have been utilized to define zones of hydrocarbon potential, reconstruct paleoenvironmental and paleoclimatic conditions, constrain the ages of the studied rock sequences, and express its potential as a replacement proxy for some expensive organic geochemical analyses. The ability to detect past hurricane activities and their associated damage to the geologic record is here presented as a …

Hilbert Transform Applications In Signal Analysis And Non-Parametric Identification Of Linear And Nonlinear Systems, Zuocai Wang

Doctoral Dissertations

"Hilbert Huang Transform faces several challenges in dealing with closely-spaced frequency components, short-time and weak disturbances, and interrelationships between two time-varying modes of nonlinear vibration due to its mixed mode problem associated with empirical mode decomposition (EMD). To address these challenges, analytical mode decomposition (AMD) based on Hilbert Transform is proposed and developed for an adaptive data analysis of both stationary and non-stationary responses. With a suite of predetermined bisecting frequencies, AMD can analytically extract the individual components of a structural response between any two bisecting frequencies and function like an adaptive bandpass filter that can deal with frequency-modulated responses …

Ceeme: Compensating Events Based Execution Monitoring Enforcement For Cyber-Physical Systems, Thoshitha T. Gamage

Doctoral Dissertations

"Fundamentally, inherently observable events in Cyber-Physical Systems with tight coupling between cyber and physical components can result in a confidentiality violation. By observing how the physical elements react to cyber commands, adversaries can identify critical links in the system and force the cyber control algorithm to make erroneous decisions. Thus, there is a propensity for a breach in confidentiality leading to further attacks on availability or integrity. Due to the highly integrated nature of Cyber-Physical Systems, it is also extremely difficult to map the system semantics into a security framework under existing security models. The far-reaching objective of this research …

Ozone And Terpene Reactions On Indoor Surfaces: Reaction Rates And Implications For Indoor Air Quality, Shi Shu

Doctoral Dissertations

No abstract provided.

Epitaxial Electrodeposition Of Metal Oxide Films And Superlattices Which Exhibit Resistance Switching, Rakesh V. Gudavarthy

Doctoral Dissertations

"This dissertation presents an investigation of the electrodeposition of metal oxide films and superlattices on conducting polycrystalline and single crystal substrates. In the first part of the study, electrodeposition of magnetite (Fe₃O₄) films and superlattices in the magnetite/zinc ferrite system which exhibit resistance switching is studied. Paper I reports the electrodeposition of superlattices in the magnetite/zinc ferrite system and shows that only superlattices exhibit multistate resistance switching. In paper II, simple polycrystalline magnetite films electrodeposited on stainless steel crystals exhibit multistate resistance switching which can be tuned by controlling the composition of the films. Paper II describes the epitaxial electrodeposition …

A Geological And Geophysical Study Of The Tendaho Graben In The Afar Depression, Ethiopia: Insights Into Transitional Continental Rifting, David Lee Bridges

Doctoral Dissertations

"A detailed magnetic and gravity study across the Tendaho Graben (the Red Sea propagator within the Afar Depression, Ethiopia) revealed features that can best be interpreted as a continental rift undergoing oceanization. This NW-trending extensional structure is ~50 km wide and it is confined within well-developed NW-trending boarder faults that deform the 2 km thick and ~ 2 Ma basaltic flows of the Afar Stratoids. The age of the basaltic flows becomes progressively younger inward from the boarder faults until it reaches ~30,000 years close to the rift axis. The central part of the Tendaho Graben is characterized by a …

Postcyclic Behavior Of Low-Plasticity Silt, Shuying Wang

Doctoral Dissertations

"Liquefaction of low-plasticity silt has been reported during earthquakes in the recent past. Excess pore pressure builds up due to the dynamic loading and then dissipates. The postcyclic behavior of low-plasticity silt was investigated in this research for materials obtained from the Mississippi River Valley. The experimental program involved specimen preparation using a slurry consolidation approach. A special technique was developed for specimen movement, reducing the testing program time by half. Both static and cyclic triaxial tests were conducted to confirm the ability to prepare replica specimens. In order to characterize the monotonic behavior, triaxial tests were conducted to determine …

Advanced Composites Using Non-Autoclave Processes: Manufacturing And Characterization, V. G. K. Menta

Doctoral Dissertations

"The objective of the present study is to develop non-autoclave processes to manufacture high performance composites for aerospace applications. In Paper 1, vacuum assisted resin transfer molding (VARTM) process was developed for elevated temperature composites. Use of VARTM process for fabricating high temperature resins presents unique challenges such as high porosity and low fiber volume contents. Two different vacuum bagging methods: Seeman Composite Resin Infusion Molding Process (SCRIMP) and Double Vacuum Bagging Infusion (DVBI) process were evaluated. Flow simulation tool was used to predict key flow parameters needed for the successful infusion. In Paper 2, honeycomb sandwich panels were manufactured …

Development Of A Versatile Man-Portable Obscurant Aerosol Generator: Characterization Of Aerosols In Laboratory And Field Environments, Robert William Schaub

Doctoral Dissertations

"The objective of research presented in this dissertation was to develop a readily deployable and environmentally benign obscurant system operating with a single liquid for the visible and near infrared regions. To achieve this objective, research efforts were directed in two areas: i. Evaluating suitable biogenic oils to replace the United States Army's "Fog Oil" as the obscurant fluid. ii. Design, fabrication and validation of a prototype man-portable / vehicle mountable modular obscurant aerosol generator. Petroleum middle distillate - "Fog Oil" has been the material of choice for wide area obscuration for several decades. Large quantities (thousands gallons) of the …

Part-I Characterization Of Phorbol Ester; The Predominant Toxic Component Of Jathropha Curcas And Development Of An Efficient Process For The Detoxification Of Jathropha Curcas Meal Part-Ii Quantification Of 2-Hydroxy-4-(Methylthio) Butanoic Acid And Pantothenic Acid In Bovine Serum And Sea Water Matrices, Balaji Viswanathan

Doctoral Dissertations

"Jatropha curcas is has often been touted as the most sustainable biofuel source. Jatropha curcas is a drought resistant perennial plant belonging to the Euphorbiaceae family. Interest in this plant as a biofuel source is related to high lipid (triglyceride) content of its seeds. However, economics of jatropha as a biofuel source has been marred by the toxicity of the oil and its protein rich meal. As a result of high toxicity the protein rich meal is used only as a very low or no economic value organic fertilizer. Economic return from jatropha can be dramatically enhanced through development of …

Investigation Of Occurrence, Elimination And Degradation Of Pharmaceutical And Personal Care Products In Drinking Water Using Liquid Chromatography-Tandem Mass Spectrometry, Chuan Wang

Doctoral Dissertations

"Pharmaceutical and personal care products have benefited humans and animals around the world. However, their presence in natural and treated water system as emerging contaminates may have potentially adverse effects on the aquatic environment and cause development of bacterial resistance. In this research project, a comprehensive liquid chromatography tandem mass spectrometry method has been developed and validated for the analysis of sixteen pharmaceutical compounds using solid phase extraction. Treated and untreated water samples collected across Missouri from water treatment facilities were analyzed to access the distribution of sixteen pharmaceutical compounds in both winter and summer seasons. The results of the …

Synthesis And Binding Studies Of Peptide Mimetics, Anion Receptors, And Kinase Inhibitors, Nanditha G. Nair

Doctoral Dissertations

"A series of novel purine-based fluoroaryl triazoles were synthesized and assayed for their neuroprotective effects of hippocampal slice culture exposed to amyloid beta (Aß) oligomers. A monofluorinated triazole has been identified which has comparable neuroprotective effect as that of flavopiridol and roscovitine against the Aß induced neurotoxicity. Carnosine and histidine are biologically interesting antioxidants. In order to probe whether they exert their antioxidant effect through metal ion chelation, the Cu(ll) ion chelating abilities of these compounds were measured by UV-vis spectroscopy. Amyloid beta, the major component of senile plaques in Alzheimer's disease, is known to complex transition metal ions through …

Absorbing State Transitions In Clean And Disordered Lattice Models, Man Young Lee

Doctoral Dissertations

"Nonequilibrium systems can undergo continuous phase transitions between different steady states. These transitions are characterized by collective fluctuations over large distances and long times similar to the behavior of equilibrium critical points. They also can be divided into different universality classes according to their critical behavior.

This dissertation considers two types of nonequilibrium transitions. First study concerns absorbing state transitions on a randomly diluted lattice. Second study deals with nonequilibrium models with several absorbing states. We investigate two specific nonequilibrium lattice models, i.e., the contact process and the generalized contact process by means of both theoretical and computational approaches.

In …

Aerogels And Films Through Free Radical Polymerization, Anand G. Sadekar

Doctoral Dissertations

"Aerogels are porous lightweight materials, unique among all solids in terms of low density, low thermal conductivity, low dielectric constants and high acoustic attenuation. The penalty for those exceptional properties is fragility. That issue has been addressed by bridging covalently (crosslinking) the elementary nanoscopic building blocks of silica aerogels with polymers. To streamline the crosslinking process we synthesized a bidentate free radical initiator (Si-AIBN) that gets attached on the skeletal nanoparticles and induces crosslinking by surface initiated polymerization (SIP). Here, we extend the scope of Si-AIBN in two directions: (a) we demonstrate extremely adhering, covalently attached polymer coatings on oxidized …

Assessing System Architectures: The Canonical Decomposition Fuzzy Comparative Methodology, Jason Paul Dauby

Doctoral Dissertations

"The impacts of decisions made during the selection of the system architecture propagate throughout the entire system lifecycle. The challenge for system architects is to perform a realistic assessment of an inherently ambiguous system concept. Subject matter expert interpretations, intuition, and heuristics are performed quickly and guide system development in the right overall direction, but these methods are subjective and unrepeatable. Traditional analytical assessments dismiss complexity in a system by assuming severability between system components and are intolerant of ambiguity. To be defensible, a suitable methodology must be repeatable, analytically rigorous, and yet tolerant of ambiguity. The hypothesis for this …

Cross-Layer Design For Network Performance Optimization In Wireless Networks, Xuan Gong

Doctoral Dissertations

"In this dissertation, I use mathematical optimization approach to solve the complex network problems. Paper l and paper 2 first show that ignoring the bandwidth constraint can lead to infeasible routing solutions. A sufficient condition on link bandwidth is proposed that makes a routing solution feasible, and then a mathematical optimization model based on this sufficient condition is provided. Simulation results show that joint optimization models can provide more feasible routing solutions and provide significant improvement on throughput and lifetime. In paper 3 and paper 4, an interference model is proposed and a transmission scheduling scheme is presented to minimize …

Simulink As A Tool For Modelling Communication Systems, Chaitri Avinash Aroskar

Masters Theses

"Simulink is a graphical tool provided by MathWorks to enable model-based design and simulation. This thesis consists of two papers which take advantage of Simulink features in order to model communication systems.

The first paper employs Simulink to create projects to supplement a purely lecture oriented course: Communication Systems I. The projects cover Linear systems, Analog modulation and Digital modulation concepts in a set of six projects. These projects have been designed based on Gagne's nine events of instruction to enhance their impact on students' learning process. The paper also outlines the advantages of this approach over the conventional programming …

Creating A Sustainable Transportation Workforce: Identifying Skills, Abilities And Knowledge For Future Transportation Workforce, Sandhya Gopalakrishnan

Masters Theses

"The recruitment and retention of a transportation workforce capable of adapting to the requirements of emerging sustainable technologies is an important concern for engineering managers in transportation. Although there is an increasing demand for transportation professionals to fill positions stemming from retirement or created by innovations in sustainable transportation systems, the supply is decreasing. The objective of this research was to fill the gap between the supply and demand of skilled workforce by presenting a life-cycle framework for recruiting and retaining the transportation workforce as part of succession planning efforts funded by the U.S. Department of Transportation's Transportation Education Development …

Comparison Of Matrix Pencil And Prony Analysis For Estimating Electromechanical Modes In Noisy Signals For Power System Applications, Lisa L. Grant

Masters Theses

"As modern power systems continue to grow and evolve, accurate system stability analysis and oscillation control become increasingly important to guarantee system security. Network instability due to power system oscillations caused by the natural modes of the system is becoming a common occurrence. Modal analysis techniques can estimate the eigenvalues of large nonlinear systems from their dynamics responses. The extracted modal information can be applied to detect low frequency oscillations and assess stability margins for power system monitoring and preventive control. Modal information is also useful for low-frequency oscillation damping controller design. This thesis examines two techniques for modal identification …

Assess Commercialization Feasibility Of Algae-Based Bio-Fuel With Dashboard And Scorecard Technologies, Madhur Chopra

Masters Theses

"The growing energy depleting energy supplies and increasing environmental pollution has motivated researchers across the globe to look for alternative energy sources. Various energy sources have been identified but none of them have the capability of realistically replacing the fossil fuels and meeting the current demand. Algae based bio-fuels give some hope but producing them at large scale is a challenge which needs to be overcome.

The underlying objective of this research project is two folds. Firstly, the project aims to assist with the commercialization of algae based bio-fuels by developing Dashboard based and Balanced Scorecard based monitoring prototypes. The …

Effect Of Web Atmospheric Cues On Users' Emotional Responses In Ecommerce, Tanvi Joginapelly

Masters Theses

"The internet has revolutionized the shopping experience. As consumers' emotional responses play an important role in predicting behavioral intentions and satisfaction, it is imperative to study e-commerce from an affective perspective and identify the website design features that influence consumers' emotional responses. This research adopted the stimulus-organism-response (S-O-R) model to examine the effects of web atmospheric cues. mainly vividness and interactivity, on users' emotional responses in e-commerce, and their influence on users' purchasing intentions.

The study had three stages: First, experts in human computer interaction (HCI) were recruited and asked to evaluate and rate 25 different e-commerce websites on interactivity …

Geological And Geomorphological Evolution Of The Egyptian Nile Between Aswan And Kom Ombo: A Remote Sensing And Field Study Approach, Leslie Lansbery

Masters Theses

"This work uses field and remote sensing studies to examine structural controls of the Egyptian Nile between Aswan and Kom Ombo (referred here to as AKN). This segment of the Egyptian Nile incises through Cretaceous Nubian sandstone and Precambrian crystalline rocks separated by a shallowly-dipping to theN unconformity. It was only 0.8 Ma that the Egyptian Nile connected to the rest of the sub-Sahara Africa drainage system. Prior to this time, the Egyptian Nile evolved independently through 8 phases: Pre-Eonile (Ma), Eonile (6.0-5. 4 Ma), Gulf Phase (5.4-3.3 Ma), Paleonile Phase (3.3-1.8 Ma), Desert Phase (1.8-0.8 Ma), Prenile Phase (0.8-0.4 …

Modeling Of Novel Coaxial Cable Bragg Grating Sensor By Coupled Mode Theory, Songping Wu

Doctoral Dissertations

"A new sensor based on the novel concept of coaxial cable Bragg grating (CCBG) has been developed for the integrity of civil infrastructure monitoring. In this dissertation work, fundamental research is conducted in sensor modeling and applications, which correspond to the first four papers of the dissertation. A coupled mode theory (CMT) is first applied to establish a physics-based model for CCBG. A numerical solution of the coupled wave equations for CCBG has been derived and validated. As an indicator of sensor sensitivity, the quality factor (Q-factor) of CCBG as a function of sensor structural/material parameters was analytically investigated by …

Nonlinear Modeling And Simulation Of Radial Forging Process, Jian Chen

Doctoral Dissertations

"Radial forging is an important manufacturing process to produce large cannon barrels. It is used to improve the material properties and reduce the porosity of the billet. The objective of this study is to develop finite element models to investigate the behavior of the workpiece and predict the elimination of void defects in the radial forging process. A nonlinear coupled finite element model has been developed to study the behavior of a large-diameter tube subjected to mechanical and thermal loadings in hot radial forging. The model is formulated in a three-dimensional frame, accounting for both axial and circumferential effects. A …

Probability Theory On Time Scales And Applications To Finance And Inequalities, Thomas Matthews

Doctoral Dissertations

"In this dissertation, the recently discovered concept of time scales is applied to probability theory, thus unifying discrete, continuous and many other cases. A short introduction to the theory of time scales is provided. Following this preliminary overview, the moment generating function is derived using a Laplace transformation on time scales. Various unifications of statements and new theorems in statistics are shown. Next, distributions on time scales are defined and their properties are studied. Most of the derived formulas and statements correspond exactly to those from discrete and continuous calculus and extend the applicability to many other cases. Some theorems …

Receiver Function Studies Of Crustal Structure, Composition, And Evolution Beneath The Afar Depression, Ethiopia, Sattam A. Almadani

Doctoral Dissertations

"The dissertation utilizes a set of sophisticated computer programs developed at the Geophysics group at Missouri S&T to characterize crustal properties beneath the Afar Depression in Ethiopia where extensional tectonics dominates. In this study, measurements of crustal thickness (H), crustal mean Vp/Vs [which is related to Poisson's ratio (Σ)], and the sharpness of the Moho (R) were determined using teleseismic data from 18 broadband seismic sensors that we deployed along a profile of 250 km long with a station spacing of ~ 10 km. The stations had been recording continuously for an entire year from December 2009 until December 2010. …

Strength Adjustable Preformed Particle Gels For Conformance Control, Jia Zhou

Doctoral Dissertations

"Reservoir heterogeneity and early water breakthrough (also known as fingering) represent two of the greatest challenges to recover crude oil efficiently. Gel treatments have been implemented as a cost-effective method to plug high permeability zones and thus improve sweep efficiency in reservoirs. However, when extensive cross-flows exist between formation layers, gel treatments become less efficient. Polymer was used in polymer flooding to increase the viscosity of the injected fluids and to correct the fingering problem. However, such treatment may be uneconomical since dramatic viscosity loss (80-90%) is caused by shearing degradation during the injection process near the wellbore.

This research …

Effect Of Initial Conditions On Molecular Mixing In A High Schmidt-Number Rayleigh-Taylor Mixing Layer, Lakshmi Ayyappa Raghu Mutnuri

Masters Theses

"Characterizing molecular mixing in Rayleigh-Taylor instability (RTI) driven flows where the density and velocity fields are coupled is essential for developing exacting predictive models. Sensitivity of the Rayleigh Taylor mixing layer to initial conditions is a topic that is being explored extensively in interests of accurate turbulent mix model development and its direct consequence in various applications like design of inertial confinement fuel capsule and atmospheric modeling. As part of the current work, an experimental investigation of the effect of initial conditions on molecular mixing in a low Atwood number(~7.5 x 10⁻⁴), high Schmidt number(~1000), RTI driven mixing layer is …