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Statistical Analysis And Modeling: Cancer, Clinical Trials, Environment And Epidemiology., Dimitrios Vovoras

USF Tampa Graduate Theses and Dissertations

The current thesis is structured in four parts. Vector smoothing methods are used to study environmental data, in particular records of extreme precipitation, the models utilized belong to the vector generalized additive class. In the statistical analysis of observational studies the identification and adjustment for prognostic factors is an important component of the analysis; employing flexible statistical methods to identify and characterize the effect of potential prognostic factors in a clinical trial, namely "generalized additive models", presents an alternative to the traditional linear statistical model. The classes of models for which the methodology gives generalized additive extensions include grouped survival …

Crystal Engineering Of Multiple Component Crystal Forms Of Active Pharmaceutical Ingredients, David Rudy Weyna

USF Tampa Graduate Theses and Dissertations

Enhancing the physicochemical properties of solid-state materials through crystal engineering enables optimization of these materials without covalent modification. Cocrystals have become a reliable means to generate novel crystalline forms with multiple components and they exhibit different physicochemical properties compared to the individual components. This dissertation exemplifies methodologies to generate cocrystals of active pharmaceutical ingredients (API's) based upon knowledge of supramolecular interactions (supramolecular synthons), while focusing on enhanced delivery through in vitro and in vivo processes with both salts and cocrystals respectively.

The utility of mechanochemistry involving small amounts of an appropriate solvent, or solvent drop grinding (SDG), has been shown …

Potential Habitat Of Acropora Spp. On Florida Reefs, Katherine Wirt

USF Tampa Graduate Theses and Dissertations

Elkhorn and Staghorn corals (Acropora palmata, A. cervicornis) were listed as threatened species under the Endangered Species Act (ESA) in 2005. The threatened status of these species is unprecedented given the vital role they historically played as major constructors of western Atlantic and Caribbean coral reefs. The goal of my study was to evaluate the current extent of habitat of the two species using a database of reported in situ observations. From these observations, potential habitat maps were produced based on benthic substrata and depth parameters throughout the Florida reef tract using GIS software. Locations of 99% of …

Geometric Transformations In Middle School Mathematics Textbooks, Barbara Zorin

USF Tampa Graduate Theses and Dissertations

This study analyzed treatment of geometric transformations in presently available middle grades (6, 7, 8) student mathematics textbooks. Fourteen textbooks from four widely used textbook series were evaluated: two mainline publisher series, Pearson (Prentice Hall) and Glencoe (Math Connects); one National Science Foundation (NSF) funded curriculum project textbook series, Connected Mathematics 2; and one non-NSF funded curriculum project, the University of Chicago School Mathematics Project (UCSMP).

A framework was developed to distinguish the characteristics in the treatment of geometric transformations and to determine the potential opportunity to learn transformation concepts as measured by textbook physical characteristics, lesson narratives, and analysis …

Numerical Simulations Of Heat Transfer Processes In A Dehumidifying Wavy Fin And A Confined Liquid Jet Impingement On Various Surfaces, Mutasim Mohamed Sarour Elsheikh

USF Tampa Graduate Theses and Dissertations

This thesis consists of two different research problems. In the first one, the heat transfer characteristic of wavy fin assembly with dehumidification is carried out. In general, fin tube heat exchangers are employed in a wide variety of engineering applications, such as cooling coils for air conditioning, air pre-heaters in power plants and for heat dissipation from engine coolants in automobile radiators. In these heat exchangers, a heat transfer fluid such as water, oil, or refrigerant, flows through a parallel tube bank, while a second heat transfer fluid, such as air, is directed across the tubes. Since the principal resistance …

Two-Dimensional Computer Model Of Human Atrial Ablation, Samineh R. Esfahani

USF Tampa Graduate Theses and Dissertations

A finite-element model of a two-dimensional slice of human atrial tissue for the study of the electrograms and propagation of action potentials is presented. Action potential propagation is described by a reaction-diffusion model coupled with the complex Courtemanche et al. atrial cell model. The effects of recording electrode size and location on electrograms are presented. Action potential propagation as a result of atrial fibrillation ablation therapy is also modeled by defining a lesion area with decreased electrical conductivity. The effect of electrical conductivity and geometry of the lesion was also studied. It is shown that the success rate of atrial …

Examining Reasons For Bottled Water Consumption: A Case Study In Pensacola, Florida, Marina Leigh Foote

USF Tampa Graduate Theses and Dissertations

Over-consumption in developed economies undoubtedly puts a large strain on the environment, and many would argue that the damage is irreversible. Current uses and rates of consumption of freshwater resources are also deemed to be unsustainable. A large contributor to the high demand for water is the shift in consumer preferences from tap to bottled water. In the last few decades, bottled water companies have set unprecedented records, surpassing all other types of non-alcoholic beverages to become the second largest beverage market next to soda. Bottled water has been on the rise due to its supposed safety, purity and convenience. …

The Positive Illusory Bias: Do Adhd Symptoms Differ Among Young Adolescents With Accurate Versus Discrepant Self-Perceptions?, Sarah A. Fefer

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to gain insight into whether inattentive, hyperactive/ impulsive, and depressive symptoms differ among young adolescents with negative, accurate, or positive self-perceptions of their academic and social competence. Current literature suggests that elementary-age children with ADHD display overly positive self-perceptions, often referred to as the positive illusory bias (PIB; Owens, Goldfine, Evangelista, Hoza, & Kaiser, 2007). Self-reports of academic and social self-concept were compared to teacher ratings and test scores for 164 middle school students in an effort to determine if the PIB was present within this sample. Inattentive and hyperactive/impulsive symptoms were found to …

Cataloguing Diseases And Pests In Captive Corals, Adrienne George

USF Tampa Graduate Theses and Dissertations

Stony corals (Order Scleractinia) are susceptible to a variety of diseases, which can occur from abiotic or biotic factors, or a combination of both. Public aquaria provide opportunities to study coral disease. Because coral mucus is the first line of defense against disease, the Biolog EcoplateTM is a useful tool to detect differences in microbial assemblages in the surface mucopolysaccharide (mucus) layer when comparing healthy and diseased corals. Histological examination is essential to document structural changes in coral tissue in response to diseases. This study identifies and characterizes diseases in captive corals through visual recognition, characterization of carbon utilization by …

A Cross-Cultural Adaptation Of The Irrational Beliefs Inventory From English To Icelandic, Gudmundur Torfi Heimisson

USF Tampa Graduate Theses and Dissertations

The Irrational Beliefs Inventory (IBI) was built to measure self-defeating beliefs as conceptualized in Rational-Emotive Behavior Therapy. The IBI has five factors: worrying, rigidity, problem avoidance, need for approval, and emotional irresponsibility. A three-phase cross-cultural study was conducted to translate and adapt the IBI from English to Icelandic, and a Confirmatory Factor Analysis (CFA) approach was used for a test of factorial validity and cross-cultural invariance.

In Phase 1, the IBI was translated from English to Icelandic, using a forward-translation and back-translation. Two forward-translators and two back-translators were recruited. In Phase 2, qualitative interview methods were used in both the …

Relative Abundance And Spatial Distribution Of Lepomid Sunfishes In The Peace River, Justin Henry Heller

USF Tampa Graduate Theses and Dissertations

This study examines spatially continuous sampling data in order to investigate patterns of abundance and distribution of three recreationally important sunfish species (bluegill, redear, and spotted sunfish) along the main-stem of the Peace River, a large softwater river located in southwest Florida. A total of 467 electrofishing transects were sampled biannually from spring 2008 to spring 2010. Sampling sites ranged from the headwaters of the Peace River in Polk County, FL to the oligohaline waters located in Charlotte County, FL. All fish were collected with boat mounted electrofishing gear, and aquatic habitat and physiochemical water quality measurements were recorded at …

Modeling Endogenous Treatment Eects With Heterogeneity: A Bayesian Nonparametric Approach, Xuequn Hu

USF Tampa Graduate Theses and Dissertations

This dissertation explores the estimation of endogenous treatment effects in the presence of heterogeneous responses. A Bayesian Nonparametric approach is taken to model the heterogeneity in treatment effects. Specifically, I adopt the Dirichlet Process Mixture (DPM) model to capture the heterogeneity and show that DPM often outperforms Finite Mixture Model (FMM) in providing more flexible function forms and thus better model fit. Rather than fixing the number of components in a mixture model, DPM allows the data and prior knowledge to determine the number of components in the data, thus providing an automatic mechanism for model selection.

Two DPM models …

Associate Degrees In Health Related Occupations As Predictors Of Success In Physician Assistant Programs, David E. Kotun

USF Tampa Graduate Theses and Dissertations

The primary purpose of this study was to determine if applicants who had an associate degree in the health sciences prior to acceptance to a physician assistant program would do better than those applicants without an associate degree in the health sciences on three measures of success of physician assistant education. The three measures of success used were graduation rates, scores on the Physician Assistant Knowledge Rating and Assessment Tool (PACKRAT), and performance on the national certifying exam, the Physician Assistant National Certification Examination (PANCE). Data used for this dissertation were taken from original source documents and raw data sent …

Rethinking Buffer Operations In A Dual-Store Framework, Melissa Lehman

USF Tampa Graduate Theses and Dissertations

Atkinson and Shiffrin's (1968) dual-store model of memory includes a structural memory store along with control processes conceptualized as a rehearsal buffer. I present a variant of Atkinson and Shiffrin’s buffer model within a global memory framework that accounts for findings previously thought to be difficult for it to explain. This model assumes a limited capacity buffer where information is stored about items, along with information about associations between items and between items and the context in which they are studied. The strength of association between items and context is limited by the number of items simultaneously occupying the buffer. …

Evaluating The Effects Of Beach Nourishment On Loggerhead Sea Turtle (Caretta Caretta) Nesting In Pinellas County, Florida, Corey R. Leonard Ozan

USF Tampa Graduate Theses and Dissertations

The health of Florida's beaches are vital to the survival of loggerhead sea turtles (Caretta caretta), as nearly half of the world's loggerheads nest on the states beaches. Many of the beaches utilized by the turtles have undergone nourishment projects in hopes of combating erosion of the shoreline, protecting beachfront property, and creating more suitable beaches for tourism. Although it is argued that beach nourishment benefits sea turtles by providing more nesting habitat, the effects of the Pinellas County nourishment projects on loggerhead nesting are unknown. Beach nourishment can alter the compaction, moisture content, and temperature of the sand, all …

Device Physics Of Solution Processable Solar Cells, Jason Erik Lewis

USF Tampa Graduate Theses and Dissertations

This Ph.D work reports the studies of photovoltaic devices produced by solution processable methods. Two material systems are of interest: one is based on organic semiconductors, and another on organic/inorganic hybrid composites. Specifically, organic photovoltaic (OPV) devices are made using photoactive materials consisted of a p-conjugated polymer [Poly(3-hexylthiophene), or P3HT] and fullerene derivative [phenyl-C60-butric acid methyl ester, or PCBM] in a bulk heterojunction (BHJ) structure of donor/acceptor network. On the other hand, hybrid photovoltaic (HPV) devices are made from blend of quantum dots and p-conjugated polymers. The QD material presented here are of the lead sulfide (PbS), and lead selenide …

Self-Alignment Of Silicon Microparts On A Hexadecane-Water Interface By Surface Tension, Caroline Elizabeth Liberti

USF Tampa Graduate Theses and Dissertations

Mechanical assembly of systems and structures on the micro-scale can be inefficient as particles of sub-millimeter dimensions are difficult to manipulate. Cutting edge manufacturing methods implement self-assembly as an approach to ordering micro and nano-sized parts into a desired arrangement. This thesis studies a technique utilizing surface tension as a method of actuating microparts on a liquid-liquid interface via lateral capillary interactions. Preliminary experimentation is conducted to investigate the feasibility of developing a new method for self-alignment of microparts by observing the influence of interfacial geometry on the movement of silicon tiles along a hexadecanewater interface. Different surface geometries are …

Performance Assessment Of Predicted Heat Strain In High Heat Stress, Ronald Eugene Long

USF Tampa Graduate Theses and Dissertations

Heat stress is a common physical agent associated with many occupations. The most commonly used method of assessing heat stress exposure is an empirical method using the Wet Bulb Globe Temperature Index but his method is limited in its ability to parse out individual contributors to the heat stress. The International Organization for Standardization (ISO) published a rational model called Predicted Heat Strain (PHS) in 2004, and rational methods have the advantage of separating out the individual pathways for heat exchange. The objective of this research was a performance assessment of the current PHS model. This experimental design consisted of …

The Search For The Missing Mantles Of Differentiated Asteroids: Evidence From Taxonomic A-Class Asteroids And Olivine-Dominated Achondrite Meteorites, Michael Peter Lucas

USF Tampa Graduate Theses and Dissertations

The apparent rarity of taxonomic A-class asteroids poses a significant paradox for understanding asteroid differentiation and the dynamical evolution of the early solar system. Based on results from asteroid taxonomic surveys, and on the abundances and mineralogy of different achondrite meteorites, it appears that olivine-dominated mantle remnants are missing from both the asteroid population and in meteorite collections. Several scenarios to explain this paradox have been proposed: (1) olivine mantle material has been stripped away by collisions and only remains as small fragments (< ~5 km), (2) A-class asteroids are abundant but have been altered in some way masking their presence, or (3) differentiated asteroids did not form thick olivine-rich mantles.

We have approached these questions through the collection of taxonomic and observational data on known A-class …

Crystal Engineering Of Pharmaceutical Cocrystals, Sreya Mukherjee

USF Tampa Graduate Theses and Dissertations

Pharmaceutical cocrystals use principles of crystal engineering for the design of crystalline forms of drugs and can improve their solubility, bioavailability, stability and other important properties without changing the efficacy of the drug. Herein reported are pharmaceutical cocrystals of two API's, caffeine and Pentoxifylline.

Research has indicated that caffeine has the ability to reverse AB; plaque deposition in the brain (believed to be the primary cause of Alzheimer's pathogenesis) and thus revert memory and improve cognitive impairment. But owing to the fast absorption rate and short half life, a controlled release formulation of caffeine would be clinically beneficial. Thus, novel …

New Media Photographic Representations Of Women`S Collegiate Volleyball: Game Faces, Action Shots, And Equipment, Alicia Pack

USF Tampa Graduate Theses and Dissertations

Researchers consistently find that mainstream media often represent women athletes in stereotypical ways including trivialization, sexualization, infantilization, passivity, and utilization of camera down-angles. However, research on new media's visual representation of women athletes is still in its infancy. This study adds to the growing literature on new media's representation of women athletes and concurs with previous findings suggesting that new media might be an outlet that can counter old media gender stereotypes. This thesis used mixed methods of qualitative content analysis and photovoice in order to better understand how Big East volleyball players are represented in photographs on websites: Instances …

Book Review: Karst Rock Feature Karren Sculpturings, Jo De Waele

International Journal of Speleology

No abstract provided.

Cover: Volume 40, Issue 2

International Journal of Speleology

No abstract provided.

Why Do All Casinos Seem To Be The Same? A Glance Into Casino Games, Gambling Machines And The Doctrine Of Fair Use, Eric D. Gorman

North Dakota Law Review

No abstract provided.

Theoretical Considerations For Understanding Technological Pedagogical Content Knowledge (Tpack), Charles R. Graham

Faculty Publications

The technological pedagogical content knowledge (TPACK) framework is increasing in use by educational technology researchers around the world who are interested in issues related to technology integration. Much that is good can be found in the TPACK framework; however considerable theoretical work needs to be done if TPACK research is to cohere and constructively strengthen the field of educational technology. This paper uses Whetten’s (1989) criteria for theory building as a lens for examining the TPACK framework. Specific weaknesses are identified, which in turn suggest areas needing theoretical development. This paper calls for researchers to increase emphasis on using research …

Instruction And Physical Environments That Support Process Writing In Elementary Classrooms, Monica Thomas Billen, Brad Wilcox, Damon Bahr, Jill Shumway, Byran Korth, Elizabeth Yates, Timothy G. Morrison, Sue Simmerman, Stan V. Harwarad, Nancy Peterson, Linda E. Pierce

Faculty Publications

This study conducted in eight Utah school districts documented the amount of time devoted to elementary writing instruction and described classroom physical environments related to that instruction. One-hundred-seventy-seven full-day observations were completed during a one-week period. Results indicated that process-writing time was dominated by explicit instruction from the teacher. Other elements of the writing workshop were implemented, but in a fragmented way. Classroom physical environments were generally not literacy rich. Process-oriented teachers had richer environments than those who focused on conventions.

The Structural And Conceptual Interweaving Of Mathematics Methods Coursework And Field Practica In An Era Of Mathematics Reform, Damon L. Bahr, Eula Ewing Monroe, Dennis L. Eggett

Faculty Publications

This paper describes a study of observed relationships between the design of a preservice mathematics methods course with accompanying field practicum and changes in the extent to which participating preservice teachers identified themselves with the mathematics reform movement after becoming inservice teachers. The curriculum of the course with its embedded field practicum experiences was designed to support preservice teachers in interweaving methods coursework and pedagogical instruction with classroom practice. University and public school structures were interwoven by conducting weekly mathematics methods course sessions held at a public school site followed immediately by related classroom practicum experiences. The interweaving of conceptualizations …

In Vitro Analysis Of Immersed Human Tissues By Raman Microspectroscopy, Franck Bonnier, A. Mehmood, Peter Knief, Aidan Meade, Helen Lambkin, Kathleen Flynn, V. Mcdonagh, C. Healy, T. C. Lee, Fiona Lyng, Hugh Byrne

Articles

Raman microspectroscopy is a powerful tool for the analysis of tissue sections, providing a molecular map of the investigated samples. Nevertheless, data pre-processing and, particularly, the removal of the broad background to the spectra remain problematic. Indeed, the physical origin of the background has not been satisfactorily determined. Using 785 nm as source in a confocal geometry, it is demonstrated for the example of the protein kappa-elastin that the background and resulting quality of the recorded spectrum are dependent on the morphology of the sample. Whereas a fine powder yields a dominant broad background, compressed pellets and solution-cast thin films …

A Practical Photoelectrochemical Cell Using Nonprecious Metal Electrodes, Patrick Enright, Tony Betts, John Cassidy

Articles

Abstract: Photoelectrochemical cells (PECs) can be used to harvest light from the oxidation of dissolved organic matter. Similar to fuel cells but requiring light to operate, PECs contain a light assisted electrode that oxidises electron rich materials (anode); these electrons then flow to a typically Pt cathode where O₂ is normally the electron acceptor. In this work a PEC cell containing inexpensive materials was shown to (a) mineralise typical organic compounds present in waste water and (b) produce electricity from their decomposition. The PEC cell consisted of a TiO₂ coated conducting ink anode exposed to a light source, …

Non Aggregated Colloidal Silver Nanoparticles For Surface Enhanced Resonance Raman Spectroscopy, Aoife Power, John Cassidy, Tony Betts

Articles

Silver nanoparticles with a tuneable l max were produced as colloids by heterogeneous nucleation. The synthesis process is both fast and repeatable, producing stable PVA capped nanoparticles. The colloid’s effectiveness in the SERRS system was investigated using Rhodamine 6G, R6G, Crystal Violet, CV, and Malachite Green, MG, as probe molecules. A clear sensing trend was observed, where the Raman signal emitted was significantly enhanced by the addition of silver nanoparticles. A build up of signal intensity is observed until an optimum ratio is achieved, followed by a decline in signal intensity as the concentration of nanoparticles is further increased. The …