Digital Commons Network^™

A Reflective Exploration Of A Multiyear Elementary School Learning Community Experience, Susan Jean Ganley

USF Tampa Graduate Theses and Dissertations

This study reports a reflection upon the experience of a multiyear elementary school learning community designed for improved teaching and learning. The exploration uses interview data to describe the perceptions and reflections of the principal and teachers directly engaged in this project of educational reform. The goal of this process is to gain a deeper understanding of the experience and to determine to what factors the participants attribute the outcomes of this project.

Through an auto-ethnographic reflective critical practice inquiry and extended interviews, this study describes the context and environment of this learning community and how the participants reflect on …

Synthesis Of Small Molecule Inhibitors Of Janus Kinase 2, Phosphodiesterase Iv, Gabaa And Nmda Receptors: Investigation Of Mcmurry, Mannich And Chemoenzymatic Strategies, Meghanath Gali

USF Tampa Graduate Theses and Dissertations

Stilbenoids possess a wide range of biological properties such as, anticancer, antiplatelet aggregation, antiestrogenic, antibacterial, antifungal and antiatherogenic, etc. Owing to these therapeutic values, a great deal of attention attracted in the synthesis of derivatives of stilbenes. During the course of the study, G6 a novel stilbenoid was discovered, through high throughput screening, to be a potent inhibitor of mutated JAK2-V617F. The mutated JAK2 variant has been implicated in various myeloproliferative disorders (MPDs) including polycythemia vera (PV), essential thrombocythemia (ET) and primary myelofibrosis (PMF) has been targeted by therapeutics. Chapter 2 describes the synthesis of analogs of the stilbenoid G6 …

Electronic Structure Characterization Of Nanocrystalline Surfaces And Interfaces With Photoemission Spectroscopy, Sebastian Gutmann

USF Tampa Graduate Theses and Dissertations

In this study, photoemission spectroscopy (PES) was used to investigate the electronic properties of nanocrystalline titanium dioxide (TiO₂), zinc oxide (ZnO), and cadmium selenide (CdSe). Electrospray deposition technique enabled the preparation of thin films in vacuum from a dispersion prepared outside the vacuum chamber. This method also allowed the step-wise formation of interfaces and the monitoring of the evolution of the electronic structure with intermittent PES characterization.

The work function of nanocrystalline TiO₂ and ZnO was measured with ultraviolet photoemission spectroscopy (UPS) and low-intensity x-ray photoemission spectroscopy (LIXPS). Measurements on environmentally contaminated surfaces revealed an instantaneous and …

Statistical Analysis And Mechanistic Modeling Of Water Quality: Hillsborough Bay, Florida, Keith Hackett

USF Tampa Graduate Theses and Dissertations

Nutrient pollution has been identified as a significant threat to U.S. coastal and estuarine water quality. Though coastal and estuarine waters need nutrients to maintain a healthy, productive ecosystem, excess nutrients can lead to eutrophication. There are significant potential negative consequences associated with eutrophication, including loss of habitat, loss of economic activity, and direct threats to human health. Hillsborough Bay experienced eutrophication in the 1960s and 1970s due to a rapidly growing population and associated increases in nutrient pollution. These eutrophic conditions led to more frequent phytoplankton and macroalgae blooms and declines in seagrasses. To address these problems, a series …

Physical Models Of Amyloid Fibril Assembly, Shannon Elizabeth Hill

USF Tampa Graduate Theses and Dissertations

Formation of large fibers and plaques by amyloid proteins is recognized as the molecular hallmark of an increasing number of human disorders, including Parkinson's disease, Alzheimer's disease and even type II diabetes. The broader objective of my research is to unravel the basic mechanisms that initiate and regulate fibril formation by amyloidogenic proteins. This objective is significant because even basic aspects of how fibril formation proceeds from a soluble, monomeric protein to an insoluble amyloid fibril remain much debated. Furthermore, there is increasingly strong evidence suggesting that intermediates of the aggregation process, with properties distinct from those of mature fibrils, …

Utilizing A Computational Model For The Design Of A Passive Dynamic Walker, Craig Alan Honeycutt

USF Tampa Graduate Theses and Dissertations

Recent interest in using passive dynamic walkers (PDWs) for gait rehabilitation studies has presented a need for a robust, easily built mechanism. Unfortunately, these passive robots are hypersensitive to many variables outside of the usual design considerations that are studied when constructing them. By accentuating previous failures instead of suppressing them, this thesis presents a number of problematic situations commonly experienced when testing and tuning a PDW.

Further, through a complete design of a 4-legged PDW with knees, simple design axioms brought about by myself and others are put into a practical context and applied directly to design. This thesis …

From Source To Sink: An Isotopic Perspective On The Biogeochemical Relationship Between The Everglades And Florida Bay, Ana Maria Hoare

USF Tampa Graduate Theses and Dissertations

Increasing human populations and activities in coastal areas have led to high nutrient loading and estuarine ecosystem decline. Natural hydrological patterns in South Florida have been drastically altered by changes in water management and land use practices. As a result Florida Bay has experienced a series of negative ecosystem effects including hypersalinity events, degradation of water quality, and harmful algal blooms and declines in upper trophic level populations. To remediate ecosystem decline in Florida's coastal ecosystems, the Comprehensive Everglades Restoration Plan proposes to restore a more natural hydrologic flow in the Everglades. It is expected hydrologic restoration efforts will change …

No More Freeways: Urban Land Use-Transportation Dynamics Without Freeway Capacity Expansion, Lei Zhang, We Xu

TREC Final Reports

Observations of the various limitations of freeway capacity expansion have led to a provocative planning and policy question – What if we completely stop building additional freeway capacity. From a theoretical perspective, as a freeway transportation network matures, there exists a saturation point beyond which any additional freeway capacity would only be counterproductive from a welfare point of view, and worsen the existing urban transportation problems. Traditional benefit/cost analysis of individual freeway capacity expansion projects often ignores long-term induced demand and land use changes and does not represent a systems approach to this important theoretical issue. From a practical perspective, …

Personal Knowledge And The Inner Sciences, Martin Zwick

Complex Systems Faculty Publications and Presentations

This paper conceptualizes spiritual disciplines as sciences. It uses this conceptualization to probe into the similarities and differences between modern science and religious tradition, and into the cultural significance and possible future impact of the “new religions”. The paper draws upon the ideas of Michael Polanyi as a possible bridge between science and religion, and proposes that these ideas are relevant not only to the major Western religions, but to Eastern and non-mainstream Western religions as well. Imagining science as a spiritual path, or gnosis, would challenge an exclusivist understanding of scientific knowledge, and suggest the relevance of such knowledge …

System Dynamics Modeling As A Potentially Useful Tool In Analyzing Mitigation Strategies To Reduce Overdose Deaths Associated With Pharmaceutical Opioid Treatment Of Chronic Pain, Wayne Wakeland, Teresa D. Schmidt, Aaron Gilson, J. David Haddox, Lynn Webster

Complex Systems Faculty Publications and Presentations

Objective. To illustrate a system-level, simulationbased approach for evaluating mitigation strategies to address the dramatic rise in abuse, addiction, and overdose deaths associated with the use of pharmaceutical opioid analgesics to treat chronic pain.

Simulated Interventions. Making available drug formulations with increased tamper-resistance, prescriber education programs, and programs that reduce rates of medical user-related abuse and addiction.

Simulated Outcome Measure. Number of overdose deaths of medical users of pharmaceutical opioid analgesics, including those who abuse or have become addicted.

Methods. A demonstration system dynamics model is developed, tested, and used to evaluate the impact of candidate mitigation strategies on the …

Seasonal Ice Mass-Balance Buoys: Adapting Tools To The Changing Arctic, Chris Polashenski, Don Perovich, Jackie Richter-Menge, Bruce Elder

Dartmouth Scholarship

Monitoring the local mass balance of Arctic sea ice provides opportunities to attribute the observed changes in a particular floe’s mass balance to specific forcing phenomena. A shift from multi- year to seasonal ice in large portions of the Arctic presents a challenge for the existing Lagrangian array of autonomous ice mass-balance buoys, which were designed with a perennial ice cover in mind. This work identifies the anticipated challenges of operation in seasonal ice and presents a new autonomous buoy designed to monitor ice mass balance in the seasonal ice zone. The new design presented incorporates features which allow the …

Arctic Sea-Ice Melt In 2008 And The Role Of Solar Heating, Donald K. Perovich, Jacqueline A. Richter-Menge, Kathleen F. Jones, Bonnie Light

Dartmouth Scholarship

There has been a marked decline in the summer extent of Arctic sea ice over the past few decades. Data from autonomous ice mass-balance buoys can enhance our understanding of this decline. These buoys monitor changes in snow deposition and ablation, ice growth, and ice surface and bottom melt. Results from the summer of 2008 showed considerable large-scale spatial variability in the amount of surface and bottom melt. Small amounts of melting were observed north of Greenland, while melting in the southern Beaufort Sea was quite large. Comparison of net solar heat input to the ice and heat required for …

Informal Karst Education In The United States And Internationally, Leslie A. North

USF Tampa Graduate Theses and Dissertations

Despite the abundance of karst terrains and the important role they play in a wide variety of roles including supplying freshwater drinking supplies, no single, comprehensive study investigates the role of informal education for the improved understanding and protection of the terrains. Commonly overlooked anthropogenic karst disturbances partially occur because of the poor dissemination of scientific information to the general populace and policymakers and budgetary and time constraints of municipalities, thus generating a need to use informal education to fill these shortcomings. The purpose of this study was to: 1) establish the status of and quantify the amount of karst-related …

Synthesis And Antimicrobial Activities Of S,S'-Heterosubstituted Disulfides, Praveen Ramaraju

USF Tampa Graduate Theses and Dissertations

Antibiotic resistance is a particularly critical health concern and has increased dramatically over the past two decades. For over a decade the Turos laboratory has been designing small molecules to target pathogenic microbes such as Staphylococcus aureus and the resistant variants like methicillin-resistant Staphylococcus aureus (MRSA). Previously, N-thiolated Β-lactams, N-thiolated 2-oxazolidinones and aromatic disulfides that were synthesized in Dr. Turos' lab have shown strong activity against these bacteria. The present work describes the synthesis and antimicrobial activities of a related structural class called S,S'-heterosubstituted disulfides. For ages, sulfur (elemental) has been used as an antibacterial for controlling infestation and bacterial …

Guiding Electric Fields For Electroporation Applications, Jose Rey

USF Tampa Graduate Theses and Dissertations

Electroporation is the critical step in an electric field mediated drug or gene delivery protocol. Electroporation based protocols have been successfully demonstrated in cancer clinical trials, however, its impact in other applications is still under investigation. A significant roadblock to long term functioning of implantable biosensors in vivo is the tissue reaction in the form of fibrous encapsulation that results in reduced transport to the sensing element of the biosensor. In vivo gene electroporation has a great potential as a means to modify the transport properties of tissues in the proximity of the sensing element of implantable biosensors.

This dissertation …

Effects Of Solids Loadings And Particle Size Distribution On Siphon Ceramic Candle Filters, Danielle Renzi

USF Tampa Graduate Theses and Dissertations

In the rural areas of Madagascar only 29% of the population has access to clean water and 10% has access to improved sanitation. It has been estimated that environmental risk factors, such as inadequate access to clean drinking water and proper sanitation, are responsible for 94% of the diarrheal disease burden. This study was focused on testing a point-of-use technology called the Tulip filter, which is a siphon ceramic candle filter impregnated with silver. The purpose is to assess its feasibility for implementation in rural regions of Madagascar through a laboratory study performed at the University of South Florida.

The …

Improvements To A Real-Time, Satellite-Derived Surface Current Product (Oscar) And Evaluation In The Intra-American Sea, Mindy Jo Robinson

USF Tampa Graduate Theses and Dissertations

A method of creating real-time height fields using available gridded altimetry data combined with extrapolated values computed using linear predictive coding for use in the Ocean Surface Currents Analysis, Real-time (OSCAR) is developed and tested. This method is implemented by Earth and Space Research (ESR) to produce operational height fields that are in turn used to calculate the geostrophic component velocity of OSCAR. The gridded altimetry product used in OSCAR is evaluated against sea level measured by tide gauges while the operational total near-surface velocity from OSCAR (geostrophic plus Ekman component velocity) is evaluated using ocean velocities from moored and …

Apparent Total Evaporative Resistance For Clothing Ensembles At High Heat Stress Levels, Patrick Rodriguez

USF Tampa Graduate Theses and Dissertations

Donning protective clothing for mitigation of hazard from chemical agents poses a problem in the form of heat stress. When choosing protective clothing, many factors must be taken into account including insulative properties and evaporative resistance. This study calculated and compared R_e,T,a for three clothing ensembles at levels of heat stress past the level of compensation for heat gain to determine if R_e,T,a values varied or remained the same with changes in heat stress level. A three-way mixed model analysis of variance demonstrated significant differences for estimated R_e,T,a values among ensembles, heat stress levels and interactions among …

Gaming Literacy: Construct Validation And Scale Construction, Kenneth Allen Rosenberg

USF Tampa Graduate Theses and Dissertations

This thesis is the first attempt to construct a standardized measure of literacy for the medium of video games, filling a gap in the literature by synthesizing various items of skills, behaviors, and affective components from existent studies and determining their correlations through analyzation of survey data. The five categories that were derived from conceptual review and factor analysis have high measures of internal consistency: Information and Systems Management; Exploration and Enjoyment; Teamwork; Design; and Socialization. To test for external consistency and reliability, the proposed gaming literacy model was compared to the Novak and Hoffman (1997) construction of flow, using …

Design Of Small Scale Anaerobic Digesters For Application In Rural Developing Countries, Laurel Erika Rowse

USF Tampa Graduate Theses and Dissertations

The high incidence of upper respiratory diseases, contamination of waterways due to pathogens and nutrients from human and animal wastes, unsustainable deforestation, gender disparities in burden of disease due to unequal exposure to indoor air pollutants, and carbon black emissions from the burning of solid fuels are interrelated problems in many developing countries. Small scale anaerobic digestion provides a means of alleviating these problems by treating livestock waste onsite to produce biogas (methane and carbon dioxide) in rural areas in developing countries. Fuel can then be used for cooking, lighting, and heating. Methane fuel is an alternative to traditional three-stone …

Thermophysical Characterization Of Nanofluids Through Molecular Dynamic Simulations, John Shelton

USF Tampa Graduate Theses and Dissertations

Using equilibrium molecular dynamics simulations, an analysis of the key thermophysical properties critical to heat transfer processes is performed. Replication of thermal conductivity and shear viscosity observations found in experimental investigations were performed using a theoretical nanopthesis-fluid system and a novel colloid-fluid interaction potential to investigate the key nanofluid parameters. Analysis of both the heat current (thermal conductivity) and stress (shear viscosity) autocorrelation functions have suggested that the dominant physical mechanisms for thermal and momentum transport arises from enhancements to the longitudinal and transverse acoustic modes energy transfer brought about by the increased mass ratio of the nanopthesis to the …

Examining The Attitudes And Outcomes Of Students Enrolled In A Developmental Mathematics Course At A Central Florida Community College, Leila Sisson

USF Tampa Graduate Theses and Dissertations

Examining students' attitudes toward mathematics has become extremely popular. This study examined the attitudes and outcomes of Beginning Algebra students at a central Florida community college. Quantitative methods were used to examine the students' initial composite attitudes toward mathematics. The initial composite attitude was used to examine the relationship between CPT scores and State Competency Exam scores. Further analysis was conducted to examine completers' and non-completers' initial attitudes. The composite change score was determined and quantitative methods were used to examine interactions between class sections, age, gender, and ethnicity.

The study began with 217 students and ended with 158. The …

Late Cretaceous Faunal Dynamics In The Western Interior Seaway: The Record From The Red Bird Section, Eastern Wyoming, Joshua Stephen Slattery

USF Tampa Graduate Theses and Dissertations

Studies examining bioevents (e.g., mass extinctions, faunal turnovers, diversification events) usually only scrutinize a short interval prior to such events, however, understanding their actual paleobiological implications requires a thorough understanding of the background conditions. The objective of this study is to document the background biodiversity dynamics in a single lithofacies of the Upper Cretaceous Pierre Shale that was deposited in an offshore setting of the Western Interior Seaway (WIS) and to place these changes into an environmental context. To assess the background biodiversity dynamics, the concretionary faunas of the Baculites eliasi through B. clinolobatus biozones of the Pierre Shale in …

Using Stratified Item Selection To Reduce The Number Of Items Rated In Standard Setting, Tiffany Nicole Smith

USF Tampa Graduate Theses and Dissertations

The primary purpose of this study was to evaluate the effectiveness of stratified item sampling in order to reduce the number of items needed in Modified Angoff standard setting studies. Representative subsets of items were extracted from a total of 30 full-length tests based upon content weights, item difficulty, and item discrimination. Cut scores obtained from various size subsets of each test were compared to the full-length test cut score as a measure of generalizability. Applied sampling results indicated that 50% of the full-length test is sufficient to obtain cut scores within one standard error of estimate (SEE) of the …

Modeling And Parameter Study Of Bistable Spherical Compliant Mechanisms, Chester Smith

USF Tampa Graduate Theses and Dissertations

The bistable spherical compliant mechanism (BSCM) is a novel device capable of large, repeatable, out-of-plane motion, characteristics that are somewhat difficult to achieve with surface micromachined microelectromechanical systems. An improved pseudo-rigid-body model (PRBM) to predict the behavior of the BSCM is presented. The new model was used to analyze seven different versions of the device, each with a different compliant joint length. The new model, which adds torsion, is compared with a finite element analysis (FEA) beam model. The new model more closely approximates the results yielded by FEA than previous models used to analyze the BSCM. Future work is …

Evolution/Creationism Controversy: Analysis Of Past And Current Policies In Public Schools And The Practice Of Allowing Students To Opt-Out Of Learning Evolution Concepts, Jacquelyn Hoffmann Speake

USF Tampa Graduate Theses and Dissertations

Recent anti-evolution legislation, in the form of Academic Freedom bills, has been introduced in many state legislatures over the last three years. The language in the proposed Academic Freedom bills may allow different interpretations of what can be taught in the science classrooms, and possibly spur parents to take advantage of their perceived parental rights to request their child be opted-out of class when the scientific theory of evolution is taught. Five research questions guided the analysis of participant responses to questions and perception statements focusing on secondary school administrators' actions, perceptions, and awareness as they relate to their decision …

A Novel Device For Cell-Cell Electrofusion, Justin T. Stewart

USF Tampa Graduate Theses and Dissertations

Cell transplantation therapy is a potentially powerful tool and can be used to replace defective cells with healthy cells. This offers the possibility of alleviating the destructive symptoms for many diseases such as Parkinson's disease, Alzheimer's disease, stroke, spinal cord trauma, Type I diabetes and many more. While there are many diseases that could be positively impacted from cell transplantation therapy, the focus of this research is insulin dependent, Type I Diabetes.

The Islets of Langerhans are composed of various types of cells located in the pancreas and are responsible for a variety of biochemical functions. Specifically, the beta Islet …

Foraminiferal Assemblages On Sediment And Reef Rubble At Conch Reef, Florida Usa, Christy Michelle Stephenson

USF Tampa Graduate Theses and Dissertations

Benthic foraminiferal assemblages are widely used to interpret responses of the benthic communities to environmental stresses. This study compares epibiotic foraminiferal assemblages, collected from reef rubble, with those from reef sediments. The study site, Conch Reef, is the site of the Aquarius Underwater Habitat research facility and includes protected areas used only for scientific studies. Although a number of studies have enumerated foraminiferal taxa from the Florida reef tract, no projects have focused on the assemblages that occur at Conch Reef.

Sediment and reef rubbles samples were collected via SCUBA from a depth range of 13 to 26 m during …

Relationships Between Educator Beliefs, Perceptions Of Educational Practices And Skills, Ps/Rti Implementation, And Educational Outcomes, Kevin Stockslager

USF Tampa Graduate Theses and Dissertations

This study examined the relationships between pilot school status and Problem-Solving/Response to Intervention (PS/RtI) implementation, educator variables and PS/RtI implementation, and PS/RtI implementation and student and systemic outcomes following the final year of a 3-year PS/RtI implementation Project. School-Based Leadership Team (SBLT) members from 34 pilot schools in seven demonstration districts received training, as well as ongoing technical assistance and coaching, related to PS/RtI implementation. Data on educator's beliefs, perceptions of educational practices, and perceptions of PS/RtI skills; PS/RtI implementation; and student and systemic outcomes were collected from the 34 pilot schools, as well as 27 comparison schools. To examine …

The Role Of Contextual Associations In The Selection Of Objects, Noah Patrick Sulman

USF Tampa Graduate Theses and Dissertations

This paper describes a sequence of experiments addressing basic questions about the control of visual attention and the relationship between attention and object recognition. This work reviews compelling findings addressing attentional control on the basis of high-level perceptual properties. In five experiments observers were presented with a rapid sequence of object photographs and instructed to either detect or selectively encode a verbally cued object category. When these object categories (e.g. "baseball") were preceded by contextual images associated with a given object category (e.g. "baseball diamond"), observers were less likely to accurately report information about the target item. This effect obtained …