Digital Commons Network^™

Theoretical Study Of Electron Impact-Ionization Of Molecules, Ola Al-Hagan

Doctoral Dissertations

"There has been impressive progress in the area of theoretical treatments of electron impact ionization (e,2e) of atoms and molecules in the last decade. Most recently, low to intermediate incident electron energies have been reported for molecular systems. In this dissertation, different theoretical models will be used to calculate the fully differential cross section (FDCS) for (e,2e) processes for low to intermediate incident electron energies for a variety of final state electron angles and energies for the diatomic molecules H₂ and N₂, the triatomic molecule H₂O, and the biomolecule HCOOH.

In addition, there has been a large amount of interest …

Computational Methods For The Discovery And Analysis Of Genes And Other Functional Dna Sequences, Cyriac Kandoth

Doctoral Dissertations

"The need for automating genome analysis is a result of the tremendous amount of genomic data. As of today, a high-throughput DNA sequencing machine can run millions of sequencing reactions in parallel, and it is becoming faster and cheaper to sequence the entire genome of an organism. Public databases containing genomic data are growing exponentially, and hence the rise in demand for intuitive automated methods of DNA analysis and subsequent gene identification. However, the complexity of gene organization makes automation a challenging task, and smart algorithm design and parallelization are necessary to perform accurate analyses in reasonable amounts of time. …

Protein Secondary Structure Prediction Using Blast And Relaxed Threshold Rule Induction From Coverings, Leong Lee

Doctoral Dissertations

"Protein structure prediction has always been an important research area in bioinformatics and biochemistry. Despite the recent breakthrough of combining multiple sequence alignment information and artificial intelligence algorithms to predict protein secondary structure, the Q₃ accuracy of various computational prediction methods rarely has exceeded 75%; this status has changed little since 2003 when Rost stated that "the currently best methods reach a level around 77% three-state per-residue accuracy." The application of artificial neural network methods to this problem is revolutionary in the sense that those techniques employ the homologues of proteins for training and prediction. In this dissertation, a different …

Ultracapacitor Character Analysis And Its Application In Unified Power Quality Conditioner As Energy Storage System, Xiaomeng Li

Doctoral Dissertations

"This dissertation focuses on the Ultracapacitor (UCAP) character analysis and its application in Unified Power Quality Conditioner (UPQC) as an Energy Storage System (ESS) for improved UPQC performance. It includes three parts as described below. The first part is Paper I. The UCAP is a popular choice for the ESS because of its distinct characters. In the application UCAP's transient behavior need to be studied for design purpose. Usually these transient characters are not shown in the product data sheet. In this paper UCAP frequency analysis is performed, and based on the test data the equivalent model of the UCAP …

Scaled Experimental Study On Excavation Of Lunar Regolith With Rakes/Rippers And Flat Blade, Masafumi Iai

Doctoral Dissertations

"As humanity's activities expand to the Moon, Mars, and other extra-terrestrial bodies, it will be necessary to use local resources rather than bringing everything from the Earth. This concept is called In-Situ Resource Utilization (ISRU), which starts with excavation and earthmoving. The present study focuses on loosening and moving of the lunar regolith by a ripper (or rake) and a wide blade with consideration of gravel content. After characterizing the lunar regolith and two of its simulants (JSC-1A and FJS-1), the relationship between the excavation energy and different conditions, namely gravel content, relative density, and tine spacing on a rake, …

Synthesis And Characterization Of Conducting Polymer Nanostructures And Their Application In Sensors, Zhe-Fei Li

Doctoral Dissertations

"A one-step synthesis technique has been used to fabricate sensors by growing polyaniline nanofibers and polyaniline/metal nanocomposites in the active area of an interdigitated electrode array. Polyaniline nanofiber sensors can be fabricated by irradiating an aqueous precursor solution containing aniline, HCl, a metal salt, and ammonium persulfate (APS) with a high pressure Hg lamp. The sensors are ready for operation after polymerization is complete, and no additional processing steps are necessary. These sensors showed faster and more intensity response to various organic vapors than conventional bulk polyaniline sensors due to their larger surface area. A chemisorption model and a diffusion …

Haart Drugs Induce Oxidative Stress And Mitochondrial Dysfunction In Blood-Brain Barrier, Kalyan Reddy Manda

Doctoral Dissertations

"The era of highly active antiretroviral therapy (HAART) has controlled AIDS and its related disorders considerably; however, the prevalence of HIV-1-associated neurocognitive disorders (HAND) has been on the rise in the post-HAART era. In view of these developments, we investigated whether a HAART drug combination of 3'-Azido-2', 3'-deoxythymidine (AZT) and Indinavir (IDV) can alter the functionality of the blood-brain barrier (BBB) endothelial cells, thereby exacerbating the condition. Viability of hCMEC/D3 cells (in vitro model of BBB) that were exposed to the drugs was significantly reduced after a 72 hr treatment, in a dose-dependent manner. Reactive oxygen species (ROS) were highly …

Characterization Of Diamond Thin Films And Related Materials, Travis K. Mckindra

Doctoral Dissertations

"Thin carbon films including sputtered deposited graphite and CO₂ laser-assisted combustion-flame deposited graphite and diamond thin films were characterized using optical and electron microscopy, X-ray diffraction and micro-Raman spectroscopy. Amorphous carbon thin films were deposited by DC magnetron sputtering using Ar/O₂ gases. The film morphology changed with the oxygen content. The deposition rate decreased as the amount of oxygen increased due to oxygen reacting with the growing film. The use of oxygen in the working gas enhanced the crystalline nature of the films. Graphite was deposited on WC substrates by a CO₂ laser-assisted O₂/C₂H₂ combustion-flame method. Two distinct microstructural areas …

Chemical Bath Deposition And Electrodeposition Of Epitaxial Semiconductor Materials For Application In Photovoltaic Devices, Guojun Mu

Doctoral Dissertations

"This dissertation investigates the chemical bath deposition of zinc oxide and electrodeposition of cuprous iodide on polycrystalline and single crystal substrates. Paper I describes the chemical bath deposition and characterization of titled epitaxial zinc oxide nanospears on Si(001) single crystal substrate. In Paper II, the chemical bath deposition of zinc oxide nanospears from highly alkaline solutions is discussed in detail, including a thermodynamic calculation of saturation and speciation of Zn(II) in aqueous solution, and a kinetic study of the deposition process. In this paper the epitaxial zinc oxide is reported grown on Au(100), (110), and (111) single crystals. Paper III …

Sensor Data-Based Decision Making, Ahmet Soylemezoglu

Doctoral Dissertations

"Increasing globalization and growing industrial system complexity has amplified the interest in the use of information provided by sensors as a means of improving overall manufacturing system performance and maintainability. However, utilization of sensors can only be effective if the real-time data can be integrated into the necessary business processes, such as production planning, scheduling and execution systems. This integration requires the development of intelligent decision making models that can effectively process the sensor data into information and suggest appropriate actions. To be able to improve the performance of a system, the health of the system also needs to be …

Dependency Of Machinability In Gray Cast Iron On Nitride-Induced Age Strengthening, Jared Teague

Doctoral Dissertations

"Work of previous researchers has suggested that room temperature age strengthening in gray cast irons improves machinability. Verification and quantification of the machinability improvement is important to industry. Improved machinability will reduce overall manufacturing costs and reduce raw material consumption by decreasing the rate at which tools are replaced. Experimental work was performed to determine a connection between improved machinability in gray cast iron and changes in machining mechanics. An industrial tool wear study verified that age strengthening improved machinability by reducing tool wear to less than one-quarter of the unaged value. Laboratory tests on iron castings from the same …

Phase Equilibria In Iron Phosphate System, Liying Zhang

Doctoral Dissertations

"The main objectives of this research were to synthesize iron phosphate compounds, study phase equilibria in the iron phosphate system, focusing on the glass forming area, and investigate glass formability and properties based on the liquidus regions. Twelve iron phosphate compounds were successfully prepared and studied in terms of liquidus temperature or decomposition behavior. The liquidus surface of the Fe₃PO₇- Fe(PO₃)₃ system was re-determined and found to be significantly different from that originally presented by Wentrup in 1935. Eutectic points exist at 58.0 mole% Fe₂O₃ (1070⁰C), 42.7 mole% Fe₂O₃ (925°C), and 37.0 mole% Fe₂O₃ (907°C). The latter two eutectic points …

Robust Frequency-Domain Turbo Equalization For Multiple-Input Multiple-Output (Mimo) Wireless Communications, Jian Zhang

Doctoral Dissertations

"This dissertation investigates single carrier frequency-domain equalization (SC-FDE) with multiple-input multiple-output (MIMO) channels for radio frequency (RF) and underwater acoustic (UWA) wireless communications. It consists of five papers, selected from a total of 13 publications. Each paper focuses on a specific technical challenge of the SC-FDE MIMO system. The first paper proposes an improved frequency-domain channel estimation method based on interpolation to track fast time-varying fading channels using a small amount of training symbols in a large data block. The second paper addresses the carrier frequency offset (CFO) problem using a new group-wise phase estimation and compensation algorithm to combat …

The Functionalization Of Single Wall Carbon Nanotubes For Bioapplications, Pu Zhang

Doctoral Dissertations

"In the past few years, the functionalization of carbon nanotubes has received considerable attention due to their extraordinary mechanical, electrical, optical and thermal properties. Using single wall carbon nanotube as a platform in bioanalytical and biomedical applications has also been extensively studied. This dissertation consists of four papers. In the first paper, various methods to functionalize single wall carbon nanotubes with immobilized enzyme for bioanalytical application were investigated. It was found that the covalent functionalization method was not an ideal methodology for enzyme addition neither in terms of enzyme loading amount nor activity retention compared to other methods. Use of …

Ceramic Dielectrics For High Energy Density Capacity Application, Sheng Chao

Doctoral Dissertations

"The objective of this dissertation is to investigate the relationship between the processing parameters, microstructural development, defect chemistry and electrical properties of titanium oxide (TiO₂) dielectrics for high energy density capacitor applications. The effects of aliovalent dopants on the dielectric properties of TiO₂ ceramics were investigated, aiming to further improve the desired dielectric properties especially at elevated temperatures (up to 200°C). Due to the segregation of acceptor type impurities in the starting powders, space charge polarization took place in TiO₂ ceramics with relative large grain size (>̲500nm), leading to high dielectric loss and low energy storage efficiency. Increased ratio …

Adaptive Resource Allocation For Cognitive Wireless Ad Hoc Networks, Behdis Eslamnour

Doctoral Dissertations

"Widespread use of resource constrained wireless ad hoc networks requires careful management of the network resources in order to maximize the utilization. In cognitive wireless networks, resources such as spectrum, energy, communication links/paths, time, space, modulation scheme, have to be managed to maintain quality of service (QoS). Therefore in the first paper, a distributed dynamic channel allocation scheme is proposed for multi-channel wireless ad hoc networks with single-radio nodes. The proposed learning scheme adapts the probabilities of selecting each channel as a function of the error in the performance index at each step.

Due to frequent changes in topology and …

Development Of Embedded Modulated Scatterer Technique: Single- And Dual-Loaded Scatterers, Kristen M. Donnell

Doctoral Dissertations

"Health monitoring of infrastructure is an important ongoing issue. Therefore, it is important that a cost-effective and practical method for evaluating complex composite structures be developed. A promising microwave-based embedded sensor technology is developed based on the Modulated Scatterer Technique (MST). MST is based on illuminating a probe, commonly a dipole antenna loaded with a PIN diode (also referred to as a single-loaded scatterer, or SLS), with an electromagnetic wave. This impinging wave induces a current along the scatterer length, which causes a scattered field to be reradiated. Modulating the PIN diode also modulates the signal scattered by the probe, …

Adsorption And Segmental Dynamics Of Acrylate And Methacrylate Polymers Adsorbed On A Silica Surface, Piyawan Krisanangkura

Doctoral Dissertations

"Poly(isopropyl acrylate)-d₇ (PIPA- d₇) was studied using ²H solid-state NMR and modulated differential scanning calorimetry (MDSC). The polymer was deuterated on the methyl groups and side-chain methine. The PIPA- d₇ was adsorbed onto Cab-O-Sil silica. These two types of deuterons each showed their own characteristic deuterium nuclear magnetic resonance (NMR) spectra for bulk PIPA- d₇. The ²H NMR spectra of adsorbed PIPA- d₇ samples showed the presence of heterogeneity of the segmental dynamics. A residual powder pattern was found in the spectra of the surface samples at higher temperatures, indicating that the segments were tightly attached to the silica. The …

Dead Time And Count Loss Determination For Radiation Detection Systems In High Count Rate Applications, Amol Patil

Doctoral Dissertations

"This research is focused on dead time and the subsequent count loss estimation in radiation detection systems. The dead time is the minimum amount of time required between two events to permit detection of those events individually by a radiation detection system. If events occur during the system dead time, they are lost. Such lost information can be important in many applications including high-precision spectroscopy, positron emission tomography (PET), and the scanning of spent nuclear fuel. Understanding of the behavior of radiation detection systems is important; thus this work included a comprehensive review of dead time and pulse pile-up models …

Behavior Of Externally Bonded Fiber Reinforced Polymer Systems For Strengthening Concrete Girders In Shear, Michael Shawn Murphy

Doctoral Dissertations

"Deficiencies in shear resistance are a primary concern in concrete members due to the sudden and unpredictable nature of shear failures. Shear deficiencies in concrete structures can arise due to improper design, long-term deterioration, man-made damages, increases in loads, or as a result of over strengthening in flexure. A number of shear strengthening techniques offer a cost effective means for restoring or enhancing the shear capacity of a concrete member. The use of externally bonded fiber reinforced polymers (FRP) is one such technique that has gained recent recognition for its high strength-to-weight ratio and simplicity of application. The development of …

Experimental And Computational Investigations Of Hydrogen Safety, Dispersion And Combustion For Transportation Applications, Shravan K. Vudumu

Doctoral Dissertations

"Hydrogen is an energy carrier that can be produced from a variety of sources, offering one of the viable solutions to the increasing demands for clean and sustainable energy. Compared to the conventional fuels, hydrogen has distinct properties that need to be properly accounted for during its safer storage and delivery as well as more efficient and cleaner utilization. The broader objective of this study is to contribute to the scientific knowledge necessary to overcome key technical barriers to the widespread implementation of hydrogen in transportation applications. Specifically, lower flammability limit of hydrogen is first measured with an enhanced experimental …

Factors Controlling Ductility In Ultrafine Grain Aluminum Alloys Under Monotonic And Cyclic Loading, Partha Sarathi De

Doctoral Dissertations

"Ultrafine grained (UFG) Al processed by severe plastic deformation (SPD) methods are characterized by high strength and a limited uniform ductility. Friction stir processing (FSP), an offshoot of friction stir welding has emerged as a new technique to produce UFG alloys. FSP-UFG Al alloys show a distinctly different behavior with higher uniform elongation and improved high cycle fatigue life as compared to other SPD processed variants. The objective of this work was to study the microstructural basis for such mechanical behavior in FSP-UFG Al alloys.

To study the mechanical behavior of FSP Al alloys, a subsize bending fatigue and uniaxial …

Identifying Multiple Steady States In The Design Of Reactive Distillation Processes, Thomas Karl Mills

Doctoral Dissertations

"Global homotopy continuation is used to identify multiple steady states in ideal reactive flash and reactive distillation systems involving a reaction of the form A+B [symbol for <--> C taking place in the liquid phase. The choice of specifications has an influence on the existence of multiple solutions for both the flash and the column. For the flash, specification of the heat input or withdrawal can give rise to multiplicities while specification of the split fraction does not. Specification of one internal energy balance variable and one external material balance variable does not produce multiplicities in the column; however, specification of …

Solid Oxide Fuel Cell Electrode Characterization And Improvement For Fuel Flexibility And Supplemental Power Production, Isaiah D. Kellogg

Doctoral Dissertations

"Solid oxide fuel cells (SOFC) were fabricated and the electrodes tested for their individual catalytic effectiveness in various fuels by exposing each electrode to mixed gas while the opposite electrode was exposed to its respective pure gas. Mixed hydrogen and oxygen gas was successfully utilized as fuel in a single chamber SOFC (SC-SOFC). The conditions at which the porous nickel-yttria-stabilized zirconia (Ni-YSZ) cermet anode performed well did not significantly overlap the conditions at which the La₀.₈Sr₀.₂Fe₀.₈Co₀.₂ oxide (LSCF) cathode performed well, but there was significant catalytic activity at both electrodes which increased the open circuit voltage (OCV) beyond that predicted …

Analysis Of Laminated Architectural Glazing Subjected To Combined Wind And Debris Impact Loading, Mahesh Shibarooru Shetty

Doctoral Dissertations

"Laminated glazing has been a popular form of window glazing in recent years and is found to be effective during extreme weather conditions like hurricane. Laminated glass is composed of two glass layers with a polymer as an interlayer. The main objective of this work involves studying the stress response, failure and damage analysis of rectangular laminated architectural glazing against combined wind and windborne debris impact. Here both small-hard (like roof gravel) and large-soft (like timber) windborne debris are considered. The stress response of the rectangular laminated architectural glazing was modeled using the finite element code ABAQUS. The effect of …

A Study Of The Growth And Structure Of Chromium And Iron Oxide Films On Pd(001) Using X-Ray Photoelectron Diffraction And Low Energy Electron Diffraction, Tina Dhekial-Phukan

Doctoral Dissertations

"In this study, attempts were made to grow well-ordered chromium- and iron-oxide films on a Pd(001) surface, and two sample preparation techniques, the multilayer and the sequential growth techniques, were used to grow these transition metal oxide films. The study is a part of a larger project that aims to look into the interaction between metal substrates and the overlayers grown on them. Previous studies of oxide films on Ag(001) resulted in the growth of 4-fold and 3-fold symmetry oxide structures from the multilayer and sequential growth techniques respectively. The present investigation's goal was to study how the growth of …

Application Of Quality Engineering To Investment Portfolio Selection And Optimization, Vivek Kulinchandra Jikar

Doctoral Dissertations

"The Taguchi System of Quality Engineering (TSQE) is a widely accepted philosophy and set of tools and techniques to rapidly design and manufacture high quality, low cost products and services. It is heavily focused on creating stable system designs that allow a product or system to perform as desired by customers in the environment of their choice. This research demonstrates the power of the TSQE to manage an investment portfolio. In particular, it uses the concept of design stability to select investments and optimize portfolios. It proposes a new design stability-based investment screening metric and discusses its application. Further, this …

Advanced Dynamic Response Improvement Methods For Dc-Dc Power Electronic Converters, Lisheng Shi

Doctoral Dissertations

"Dc-dc power electronic converters supplying electric power to digital processors, data centers, and telecommunication systems are required to exhibit a fast dynamic response in response to their instantaneous electric load variations. This requirement is becoming more and more stringent as the operating voltage of such loads is continuously reducing. This voltage level reduction has reached a point where conventional control approaches can barely meet the dynamic response demanded by such loads. In order to overcome this issue, several approaches focusing on the dynamic response improvement for dc-dc converters have been proposed in the literature. Unfortunately, most of them have at …

Capillary Electrophoresis Of Pteridines In Urine And Plants And Quantification Of Pharmaceutical And Personal Care Products In Missouri Waste Water, Stephen E. Gibbons

Doctoral Dissertations

"Capillary electrophoresis (CE) is a powerful technique that separates molecules based on their respective charge and hydrodynamic size. The major advantages of CE are high separation efficiency, small sample volume requirements, simple to no sample preparation and often organic solvents are not required for the separation.

The work presented in this dissertation utilized capillary electrophoresis for the analysis two different classes of compounds in different matrices. The first project investigated pteridines in urine and plants. The second project investigated pharmaceutical and personal care products (PPCP's) in Missouri waste water.

As cancer continues to be one of the top three causes …

Dynamic Reconfiguration And Control Of Smart Power Systems, Pinaki Mitra

Doctoral Dissertations

"To address the increasing demand and complexity, modern power systems need intelligence at almost all levels which can transform them into 'smart' power systems. The term 'smart power systems' not only refers to the terrestrial power systems with a significant penetration of distributed energy resources and energy storage such as plug-in electric vehicle parking lots (SmartParks), but also includes other isolated power systems, such as the power systems of naval electric ships. The research presented in this dissertation contributes to the dynamic reconfiguration and control of both terrestrial and ship power system with the application of computational intelligence methods.

In …